Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
ingredient in many
sour/tart foods; salts & esters are malates. first
isolated from apple juice by Carl Wilh. Scheele 1785.
Tartaric acid (grape juice), white cryst org acid occ in
many plants: grapes, banana & tamarinds, main acid
in wine. sour taste, antioxidant. tartrates
Citric acid ( lemon juice): natural preservative, benign
cleaning agent & antioxidant. adds sour taste to foods
(spice) Important intermediate of citric acid cycle that
occurs in almost all life. Lemons, limes have particularly
high concentrations: 8% dry weight (6g per 100g juice)
Benzoic acid (cranberry juice) benzoic acid can be
purified by recrystallization from water because of its
high solubility in hot water and poor solubility in cold
water. Strong preservative & antifungal compound.
Urinary tract disinfections common preservative in
many foods, cons. Safe.
Malic acid
Malic acid causes the sourness of green apples
and grapes conferrring a tart taste to wine. From
malus = apple
Sourness
Sourness is due to presence of
free H + ions released by acids.
Constituents of the
vinegar tree: tannins,
anthocyanins,
organic acids:
malic, citric, &
tataric plus smaller
amounts of
succinic, maleic,
fumaric and
ascorbic acid
Rhus typha,
staghorn sumach
The leaves of certain sumacs yield tannin (mostly pyrogallol),
a substance used in vegetable tanning. Leather tanned with
sumac is flexible, light in weight, and light in color, even
bordering on being white. Also many organic acids
Dried sumac wood is fluorescent under long-wave UV light
Benzaldehyde
This colorless liquid has a characteristic pleasant almondlike odor & is the primary component of bitter almond oil.
It is commonly employed to confer almond flavor.
Food preservation
1762 Italian priest L. Spallanzani : discovered that meat did not
spoil when heated in sealed flask.
1795 Nicholas Appert started to can foods in glass jars for
Napoleons army
1810 English Peter Durand started tin cans.
1860 Isaac Solomon of Baltimore adding CaCl2 raised boiling
temp & shortened processing time from 6 h to 45 min
canned foods are full with NaCl & sugar
Leukoptape +
TOB treats
blisters on trips
Citric
acid
Lactic acid
pH
Aloe Vera
Asparagus
Avocados
Beers
Beets
Cabbage
Carrots
Coconut
Celery
Horseradish
Mangos
Olives, black
Peas
Potatoes
Pumpkin
Spinach
Squash
Tea
6.1
6.
6.3 - 6.6
4.0 - 5.0
5.3 - 6.6
5.2 - 5.4
5.9 - 6.3
5.5 - 7.8
5.7 - 6.0
5.4
5.8 - 6.0
6.0 - 7.0
5.8 - 6.4
5.6 - 6.0
4.8 - 5.2
5.5 - 6.8
5.0 - 5.4
7.2
PLANT
pH
Apples
3.3 - 3.9
Bananas
4.5 - 5.2
Grapefruit
4.8 5.3
Apricots
3.3 - 4.8
Blackberries 3.9 - 4.5
Blueberries
3.1 - 3.4
Cherries
3.2 - 4.5
Cranberry juice 2.3 - 2.5
Chili sauce
2.8 - 3.7
Grapes
3.5 - 4.5
Limes
1.8 - 2.0
fermented green Olives
3.6 - 3.6
Plums
2.8 - 3.0
Sauerkraut
3.4 - 3.6
Raspberries
3.2 - 3.6
Rhubarb
3.1 - 3.2
Strawberries 3.0 - 3.9
Tomatoes
4.3 - 4.9
Acetyl L Carnitine
Jack beans
alfalfa
L-DOPA
Dopamine is a hormone & neurotransmitter in both
vertebrates & invertebrates producing increased heart rate
and blood pressure. Because dopamine cannot cross
blood-brain barrier L-DOPA - a precursor is given.
L-DOPA (3,4-dihydroxy-L-phenylalanine) is an amino
acid found in plants and made from L-Tyrosine in the
human body. L-DOPA is converted into dopamine in
brain & body; also dietary supplement & a prescription
drug Levodopa (INN) administered in Parkinson's
disease; also used as a component in marine adhesives.
Fava beans Vicia faba contain non-proteinogenic AA levodopa:
250 mg in a half-cup = 1 pill L-DOPA given
to Parkinson patients, who do not produce enough DOPA.
Fava beans also contain Tyramine, large dietary intake of
tyramine (especially when taking MAO inhibitors) causes cheese
response defined as an increase in systolic blood pressure of 30 mm
Hg or more + vasoconstriction, increased heart rate & blood pressure
Alpha
& Gamma
linolenic acids
Peppermint
Calamus root
Cedarwood
Majoram
Cassia
Orange peel
Hops
Rose petals
Violet
15 oz
14 oz
13 oz
12 oz = 1 lbs
12 oz
10 oz
1 oz
0.2 oz
0.1 oz
Raffia wax is from Raffia palm the Madagascan sago palm which
holds the record for having the largest leaves of all plants.
Candelilla wax is obtained from the stems of a Mexican
weed in the Euphorbiaceae which is boiled with some
water, brown aromatic wax is skimmed off the surface.
Paraffin waxes are distillation products of natural mineral
oil colourless, & odorless. They are soluble in organic
solvents except ethanol & have unusually high melting point.
Soap Manufacturing
Soaps are Na or K salts of fatty acids with 12-18 C atoms. Na soaps
are normally harder than K soaps. Highly saturated fats like tallow give
harder soaps than low molecular weight fats like coconut oil.
Soaps are produced by the saponificastion of fat blends
with an alkaline solution. The fats hydrolyse into
glycerol & fatty acids. Brine or solid salt is then added
to the solution. Since soap but not glycerol is insoluble
in salt solution, soap will float on top. Glycerol will be
in the salt solution & can be recovered from it.
Soap can be purified ( and made less alkaline) by dissolving it in hot
water, boiling it for a short time and then salting it out. Last boiling
is with added water to make the appearance less greasy.
Soap Making
Rendering & Clarifying of Fat: 1. Any oil can be used for making soap, diesel
fuel, glycerin, nitroglycerin , candles, emulsifiers etc. If you use unpurified fat like
kitchen drippings etc you should first render the fat. Rendering is the process of
melting solid fat particles. Cut fat in pieces and let it melt. Remove solid particles =
cracklings by straining. Unclear greasy mixtures can be clarified by placing the fat
, an equal amount of water & 2 tablespoons of NaCl in the pan, and bring to a boil.
When removing from heat cool and add cold water (one quart to 1 gallon of fat).
Mixture will separate into 3 layers: on top purified or clarified fat, on the bottom
water and in the center impurities.
Fatty acids are liberated by the addition of mineral acid, usually a 10% excess
of sulfuric acid or HCl. When very short-chain acids are present, the alcohol is
removed prior acidification under vacuum with the addition of sufficient water
to keep soaps in solution. If the amount of acids is important, the long-chain
acids are separated from the aqueous medium by allowing the mixture to stand
in the cold.
Zizyphus jujuba
Saponins
Saponins are secondary metabolites found in
particular abundance in various plant species. Most
of them are glycosides that form soap-like foaming
when shaken in aqueous solutions. The aglycone
(glycoside-free portion) of the saponins are termed
sapogenins; it is either a triterpene or steroid.
Most saponins, which readily dissolve in water, are
poisonous to fish. Therefore, in ethnobotany, saponins
are primarily known for their use by indigenous people
in obtaining aquatic food sources
Stearic acid
comes in
flakes
Stearic acid
comes in
flakes
Candle Making
Early candles were made from beeswax. Rind\se the empty
comb and place it in a pan together with 2 parts of water to
prevent the wax from catching fire. Heat until wax is melted &
continue cooking for a while. You can add Paraffin wax of up
to 90 % to make the candles cheaper. In the old days they
added tallow from beef, and a half pound of saltpeter = nitrate.