Problema 32

Determine las composiciones, temperaturas y flujos de cada etapa por el mtodo BP

1.-Propiedades de los componentes

componente
fi
etano
30.00
propano
200.00
n-butano
370.00
n-pentano 350.00
n-hexano
50.00
1000

zi
0.03
0.20
0.37
0.35
0.05
1

Pc
709.8000
617.4000
550.7000
489.5000
440.0000

A1
5.3839
5.3534
5.7416
5.8537
6.0392

A2
2847.9210
3371.0840
4126.3850
4598.2870
5085.7580

A3
434.8980
414.4880
409.5179
394.4148
382.7940

a1
11.5161
15.5868
20.7978
25.6463
30.1785

a2
0.0140
0.0250
0.0314
0.0389
0.0520

a3
8.5403E-06
1.4043E-05
1.9285E-05
2.3973E-05
3.0488E-06

2.-Calculo de la temperatura de alimentacin (se encuentra en el punto de roco) para tomar como referencia

a4
-1.1061E-08
-3.5263E-08
-4.5887E-08
-5.8426E-08
-2.7640E-08

a5
3.1622E-12
1.8645E-11
2.3810E-11
3.0799E-11
1.3467E-11

componente
etano
propano
n-butano
n-pentano
n-hexano

P
250
zi
0.03
0.2
0.37
0.35
0.05

267.280291
Ki
10.7142956
3.7167731
1.54408643
0.6546359
0.29558699

zi/ki
0.002799997
0.053810118
0.239623892
0.534648341
0.169154943
1.000037292

3.-Suposicin de las temperaturas

T1
T2
T3
T4
T5
T6
T7
T8
T9
T10
T11
T12
T13
T14
T15
372.2803357.2803342.2803 327.2803 312.2803 297.2803 282.2803267.2803252.2803 237.2803 222.2803 207.2803192.2803177.2803 162.2803

4.-Suposicin de flujos
V1
0
L1
1150

V2
1380
L2
1150

V3
1380
L3
1150

V4
1380
L4
1150

V5
1380
L5
1150

V6
1380
L6
1150

V7
1380
L7
1150

V8
1380
L8
1150

V9
380
L9
1150

V10
380
L10
1150

V11
380
L11
1150

V12
380
L12
1150

V13
380
L13
1150

V14
380
L14
1150

V15
380
L15
1150

V16
380
L16
770

5.-Calculo de los valores de Kij

Etapa

T1
T2
T3
T4
T5
T6
T7
T8
T9
T10
T11
T12
T13
T14
T15
T16
372.280 357.280 342.280 327.280 312.280 297.280 282.280 267.280 252.280 237.280 222.280 207.280 192.280 177.280 162.280 147.280
componente K1
K2
K3
K4
K5
K6
K7
K8
K9
K10
K11
K12
K13
K14
K15
K16
etano
18.1591 16.9856 15.8470 14.7444 13.6788 12.6513 11.6628 10.7143 9.8065 8.9402 8.1162 7.3348 6.5967 5.9021 5.2512 4.6440
propano 7.1904 6.6159 6.0672 5.5445 5.0481 4.5780 4.1342 3.7168 3.3255 2.9602 2.6207 2.3064 2.0171 1.7522 1.5109 1.2926
n-butano 3.5018 3.1583 2.8368 2.5369 2.2581 2.0001 1.7623 1.5441 1.3448 1.1637 1.0002 0.8533 0.7222 0.6061 0.5040 0.4150
n-pentano 1.6956 1.5043 1.3282 1.1666 1.0190 0.8849 0.7637 0.6546 0.5572 0.4706 0.3943 0.3274 0.2693 0.2192 0.1765 0.1404
n-hexano 0.8773 0.7654 0.6639 0.5725 0.4905 0.4174 0.3526 0.2956 0.2457 0.2024 0.1652 0.1334 0.1066 0.0841 0.0655 0.0503

6.-Realizando la matriz tridiagonal

componente
A2
etano
1150.00

A3
1150.00

A4
A5
A6
A7
A8
A9
A10
A11
A12
A13
A14
A15
A16
1150.00 1150.00 1150.00 1150.00 1150.00 1150.00 1150.00 1150.00 1150.00 1150.00 1150.00 1150.00 1150.00

propano
n-butano
n-pentano
n-hexano
componente
etano
propano
n-butano
n-pentano
n-hexano
B9
-4876.474
-2413.689
-1661.023
-1361.729
-1243.373
componente
etano
propano
n-butano
n-pentano
n-hexano
C9
3397.292
1124.882
442.223
178.835
76.928
componente
etano
propano
n-butano
n-pentano

1150.00
1150.00
1150.00
1150.00

1150.00
1150.00
1150.00
1150.00

B1
-1150.000
-1150.000
-1150.000
-1150.000
-1150.000
B10
-4547.292
-2274.882
-1592.223
-1328.835
-1226.928
C1
23440.124
9129.926
4358.459
2075.988
1056.207
C10
3084.141
995.848
380.067
149.816
62.774
D1
0.00
0.00
0.00
0.00

1150.00
1150.00
1150.00
1150.00

1150.00 1150.00 1150.00 1150.00 1150.00 1150.00

1150.00 1150.00 1150.00 1150.00 1150.00 1150.00
1150.00 1150.00 1150.00 1150.00 1150.00 1150.00
1150.00 1150.00 1150.00 1150.00 1150.00 1150.00

B2
-24590.124
-10279.926
-5508.459
-3225.988
-2206.207
B11
-4234.141
-2145.848
-1530.067
-1299.816
-1212.774

B12
-3937.234
-2026.447
-1474.250
-1274.403
-1200.698

C2
21868.837
8372.721
3914.743
1832.871
916.238
C11
2787.234
876.447
324.250
124.403
50.698
D2
0.00
0.00
0.00
0.00

B3
-23018.837
-9522.721
-5064.743
-2982.871
-2066.238

C12
2506.744
766.507
274.449
102.323
40.491

B13
-3656.744
-1916.507
-1424.449
-1252.323
-1190.491
C3
20347.233
7651.476
3500.861
1609.867
790.057
C13
2242.793
665.819
230.325
83.304
31.952
D3
0.00
0.00
0.00
0.00

B4
-21497.233
-8801.476
-4650.861
-2759.867
-1940.057

1150.00
1150.00
1150.00
1150.00

1150.00 1150.00 1150.00 1150.00 1150.00

1150.00 1150.00 1150.00 1150.00 1150.00
1150.00 1150.00 1150.00 1150.00 1150.00
1150.00 1150.00 1150.00 1150.00 1150.00

B5
-20026.762
-8116.410
-4266.231
-2556.231
-1826.911

B6
-18608.816
-7467.653
-3910.189
-2371.169
-1726.028

B7
-17244.723
-6855.250
-3581.998
-2203.848
-1636.625

B8
-15935.728
-6279.147
-3280.839
-2053.398
-1557.910

B14
-3392.793
-1815.819
-1380.325
-1233.304
-1181.952

B15
-3145.450
-1724.135
-1341.525
-1217.073
-1174.887

B16
-2534.727
-1261.175
-927.686
-823.359
-789.112

C4
18876.762
6966.410
3116.231
1406.231
676.911

C5
17458.816
6317.653
2760.189
1221.169
576.028

C6
16094.723
5705.250
2431.998
1053.848
486.625

C7
14785.728
5129.147
2130.839
903.398
407.910

C8
3726.474
1263.689
511.023
211.729
93.373

C14
1995.450
574.135
191.525
67.073
24.887

C15
1764.727
491.175
157.686
53.359
19.112

D4
0.00
0.00
0.00
0.00

D5
0.00
0.00
0.00
0.00

D6
0.00
0.00
0.00
0.00

D7
0.00
0.00
0.00
0.00

D8
-30.00
-200.00
-370.00
-350.00

n-hexano
D9
0.00
0.00
0.00
0.00
0.00
componente
etano
propano
n-butano
n-pentano
n-hexano
P9
-2.9542
-0.9782
-0.3845
-0.1555
-0.0669
componente
etano
propano
n-butano
n-pentano
n-hexano

q9
0.0261
0.1739
0.3217
0.3043
0.0435

0.00
D10
0.00
0.00
0.00
0.00
0.00
P1
-20.3827
-7.9391
-3.7900
-1.8052
-0.9184
P10
-2.6819
-0.8660
-0.3305
-0.1303
-0.0546
q1
0.0000
0.0000
0.0000
0.0000
0.0000

q10
0.0261
0.1739
0.3217
0.3043
0.0435

0.00
D11
0.00
0.00
0.00
0.00
0.00

0.00
D12
0.00
0.00
0.00
0.00
0.00

P2
-19.0164
-7.2806
-3.4041
-1.5938
-0.7967
P11
-2.4237
-0.7621
-0.2820
-0.1082
-0.0441

P3
-17.6932
-6.6535
-3.0442
-1.3999
-0.6870
P12
-2.1798
-0.6665
-0.2387
-0.0890
-0.0352

q2
0.0000
0.0000
0.0000
0.0000
0.0000

q11
0.0261
0.1739
0.3217
0.3043
0.0435

D13
0.00
0.00
0.00
0.00
0.00

P13
-1.9503
-0.5790
-0.2003
-0.0724
-0.0278
q3
0.0000
0.0000
0.0000
0.0000
0.0000

q12
0.0261
0.1739
0.3217
0.3043
0.0435

q13
0.0261
0.1739
0.3217
0.3043
0.0435

0.00
D14
0.00
0.00
0.00
0.00
0.00
P4
-16.4146
-6.0577
-2.7098
-1.2228
-0.5886

0.00
D15
0.00
0.00
0.00
0.00
0.00
P5
-15.1816
-5.4936
-2.4002
-1.0619
-0.5009

P14
-1.7352
-0.4992
-0.1665
-0.0583
-0.0216

P15
-1.5345
-0.4271
-0.1371
-0.0464
-0.0166

q4
0.0000
0.0000
0.0000
0.0000
0.0000

q5
0.0000
0.0000
0.0000
0.0000
0.0000

q14
0.0261
0.1739
0.3217
0.3043
0.0435

q15
0.0261
0.1739
0.3217
0.3043
0.0435

0.00

0.00

-50.00

P6
-13.9954
-4.9611
-2.1148
-0.9164
-0.4232

P7
-12.8572
-4.4601
-1.8529
-0.7856
-0.3547

P8
-3.2404
-1.0989
-0.4444
-0.1841
-0.0812

q6
0.0000
0.0000
0.0000
0.0000
0.0000

q7
0.0000
0.0000
0.0000
0.0000
0.0000

q8
0.0261
0.1739
0.3217
0.3043
0.0435

D16
0.00
0.00
0.00
0.00
0.00

q16
0.0390
0.2597
0.4805
0.4545
0.0649

componente
x1
x2
etano
16146848202.3238 792183314.9911
propano
284878.8993
35883.1764
n-butano
545.0100
143.8034
n-pentano
1.3944
0.7724
n-hexano
0.0011
0.0011
16147133627.6284 792219342.7445
x9
16.1956
0.7572
0.5013
0.3586
0.0466
17.8592
componente
etano
propano
n-butano
n-pentano
n-hexano
x9
0.9068
0.0424
0.0281
0.0201
0.0026

x10
5.4735
0.5963
0.4669
0.3487
0.0460
6.9313
x1
1.0000
0.0000
0.0000
0.0000
0.0000
x10
0.7897
0.0860
0.0674
0.0503
0.0066

P
250.0000
componente
x
etano
1.0000
propano
0.0000
n-butano
0.0000
n-pentano
0.0000
n-hexano
0.0000

T1
8.2035
Ki
1.0002
0.1795
0.0352
0.0075
0.0017

x11
2.0312
0.4878
0.4393
0.3404
0.0455
3.3442

x3
41657944.4561
4928.5835
42.2439
0.4846
0.0014
41662915.7696

x12
0.8273
0.4118
0.4170
0.3335
0.0451
2.0347

x2
1.0000
0.0000
0.0000
0.0000
0.0000
x11
0.6074
0.1459
0.1314
0.1018
0.0136

Kixi
1.0002
0.0000
0.0000
0.0000
0.0000

x13
0.3676
0.3569
0.3991
0.3278
0.0447
1.4961
x3
0.9999
0.0001
0.0000
0.0000
0.0000

x12
0.4066
0.2024
0.2049
0.1639
0.0221
P
250.0000
x
0.9997
0.0000
0.0000
0.0000
0.0000

T2
8.2241
Ki
1.0005
0.1795
0.0352
0.0075
0.0017

x13
0.2457
0.2386
0.2668
0.2191
0.0299

x4
x5
2354454.5325 143436.8205
740.7552
122.2823
13.8767
5.1210
0.3462
0.2831
0.0021
0.0036
2355209.5128 143564.5105
x14
0.1751
0.3161
0.3863
0.3233
0.0444
1.2453
x4
0.9997
0.0003
0.0000
0.0000
0.0000
x14
0.1406
0.2539
0.3102
0.2596
0.0357

P
T3
250.0000 8.2093
Kixi
x
Ki
1.0002 0.9999 1.0003
0.0000 0.0001 0.1795
0.0000 0.0000 0.0352
0.0000 0.0000 0.0075
0.0000 0.0000 0.0017

x15
0.0859
0.2849
0.3876
0.3254
0.0446
1.1283
x5
0.9991
0.0009
0.0000
0.0000
0.0000
x15
0.0761
0.2524
0.3435
0.2884
0.0395

Kixi
1.0001
0.0000
0.0000
0.0000
0.0000

x6
9448.0829
22.2590
2.1336
0.2666
0.0071
9472.7492

x7
675.0843
4.4867
1.0089
0.2909
0.0168
680.8877

x8
52.5065
1.0060
0.5445
0.3704
0.0473
54.4746

x7
0.9915
0.0066
0.0015
0.0004
0.0000

x8
0.9639
0.0185
0.0100
0.0068
0.0009

x16
0.0390
0.2597
0.4805
0.4545
0.0649
1.2987
x6
0.9974
0.0023
0.0002
0.0000
0.0000
x16
0.0300
0.2000
0.3700
0.3500
0.0500

P
T4
P
T5
250.0000 8.2207
250.0000 8.2532
x
Ki
Kixi
x
Ki
0.9997 1.0004 1.0001 0.9991 1.0009
0.0003 0.1795 0.0001 0.0009 0.1796
0.0000 0.0352 0.0000 0.0000 0.0352
0.0000 0.0075 0.0000 0.0000 0.0075
0.0000 0.0017 0.0000 0.0000 0.0017

Kixi
1.0000
0.0002
0.0000
0.0000
0.0000

1.0002
P
T6
250.0000 8.3523
componente
x
Ki
etano
0.9974 1.0023
propano
0.0023 0.1800
n-butano
0.0002 0.0353
n-pentano
0.0000 0.0075
n-hexano
0.0000 0.0017

1.0002

1.0002

1.0002

1.0002

P
T7
P
T8
P
T9
P
T10
250.0000 8.7061
250.000010.4788
250.000014.3369
250.0000100.0000
Kixi
x
Ki
Kixi
x
Ki
Kixi
x
Ki
Kixi
x
Ki
Kixi
0.9997 0.9915 1.0075 0.9989 0.9639 1.0336 0.9962 0.9068 1.0919 0.9902 0.7897 3.0137 2.3799
0.0004 0.0066 0.1812 0.0012 0.0185 0.1873 0.0035 0.0424 0.20110.0085 0.0860 0.7447 0.0641
0.0000 0.0015 0.0356 0.0001 0.0100 0.0371 0.0004 0.0281 0.0406 0.0011 0.0674 0.2086 0.0141
0.0000 0.0004 0.0076 0.0000 0.0068 0.0080 0.0001 0.0201 0.0089 0.0002 0.0503 0.0624 0.0031
0.0000 0.0000 0.0017 0.0000 0.0009 0.0018 0.0000 0.0026 0.0020 0.0000 0.0066 0.0197 0.0001
1.0002
1.0001
1.0001
1.0000
2.4612

P
T11
P
T12
P
T13
P
T14
P
T15
P
T16
250.0000 40.7115
250.000067.8937
250.0000101.1094
250.0000133.5590
250.0000161.4938
250.0000195.5799
componentex
Ki
Kixi x
Ki
Kixi x
Ki
Kixi x
Ki
Kixi x
Ki
Kixi x
Ki
Kixi
etano
0.6074 1.55190.9426 0.4066 2.14510.8722 0.2457 3.04710.7486 0.1406 4.12680.5803 0.0761 5.21830.3971 0.0300 6.7553 0.2027
propano
0.1459 0.31720.0463 0.2024 0.48150.0974 0.2386 0.75520.1802 0.2539 1.11230.2824 0.2524 1.49890.3784 0.2000 2.0787 0.4157
n-butano
0.1314 0.07180.0094 0.2049 0.12100.0248 0.2668 0.21230.0566 0.3102 0.34410.1067 0.3435 0.49900.1714 0.3700 0.7497 0.2774
n-pentano
0.1018 0.01760.0018 0.1639 0.03270.0054 0.2191 0.06370.0139 0.2596 0.11260.0292 0.2884 0.17450.0503 0.3500 0.2813 0.0985
n-hexano
0.0136 0.00450.0001 0.0221 0.00930.0002 0.0299 0.02010.0006 0.0357 0.03900.0014 0.0395 0.06460.0026 0.0500 0.1121 0.0056
1.0001
1.0000
1.0000
1.0000
0.9998
0.9999

T1
T2
T3
T4
T5
T6
T7
T8
T9
T10

SUPUESTO
372.2803
357.2803
342.2803
327.2803
312.2803
297.2803
282.2803
267.2803
252.2803
237.2803

ITERADO
8.2035
8.2241
8.2093
8.2207
8.2532
8.3523
8.7061
10.4788
14.3369
100.0000

132551.8738
121840.2589
111603.4280
101799.0143
92432.4911
83479.3582
74842.8516
65946.9984
56617.0481
18845.8782

T11
T12
T13
T14
T15
T16

222.2803
207.2803
192.2803
177.2803
162.2803
147.2803

40.7115
67.8937
101.1094
133.5590
161.4938
195.5799

32967.2340
19428.6347
8312.1225
1911.5543
0.6186
2332.8493
924912.2138

0.1600