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A general design procedure for thermosiphon reboilers was presented in 1960 by Fair (22). This
method is flexible enough to allow inclusion of newer and
more reliable correlations as they evolve. Pertinent
areas of research concentration in the past ten years
have included two-phase flow friction losses, boiling
coefficients, and two-phase heat-transfer coefficients.
Fairs method involves a nestled series of trial and crror
calculations, starting with a rough estimate as a pre76
liminary design. T h e outermost loop is thc cornparison of the flow performance of the preliminary
design with the available head. A secondary inner
loop consists of assuming a total fraction vaporized, and
estimating the circulation rate. This may require
correction of the preliminary design a t this point, or,
if not, then the heat-transfer raie is calculated by proceeding to another trial and error loop that converges
on the assumed fraction vaporized. Additional calculation loops could be incorporated to include the effect of
variation of liquid phase friction factor and lengthwise inside tube temperature profile effects. Fairs method requires selection of a boiling coefficient in the deterrnination of the two-phase coefficient. Fair (24) also presented a reviey of the state-of-the-art for reboilers in
general, including kettle-type units. Fair (23) lists references for holdup correlations. T h e essentials of a
computer program were later discussed by Fair (24)
based on earlier work (22).
T h e problems involved in estimating circulation and
heat-transfer rates were discussed by Hughmark (40)
with the utilization of a lengthwise temperature profile.
T h e overall design approach is essentially the same as
Fairs method, with a simplification in the form of a
correlation for predicting the inside coefficient. Prediction of the circulation rate was considered by Hughinark
in a later report (44) in which the two-phase pressure
drop was calculated by means of a polynomial in terms
of the Froude number and volume fraction liquid.
Pressure drop calculated values are point values and
the total pressure drop is obtained by integration over
the tube length. Hughmark (45) has summarized his
efforts (40, 42, 44) with therniosiphon design. Inside
coefficient relationships are presented for the liquidsensible heat region, nucleate boiling region, and the
two-phase region (slug, annular, and mist flow). T h e
HUGH R. McKEE
Steam
Thermosiphon
Reboiler
Tubes
Figure 7.
VOL. 6 2
NO. 1 2
DECEMBER 1970
77
I N D U S T R I A L A N D E N G I N E E R I N G CHEMISTRY
TABLE I.
Surface
Fluid
Aniline
Aniline
Stainless steel
Benzene
Brass
Chromium
304 Stainless
Stainless steel
n-Butyl alcohol
Alcohol, n butyl
Carbon tetrachloride
Cyclohexane
Diphenyl
Alcohol, ethyl ethanol
Ethylene glycol
Generalized correlation
independent of flow pattern
Annular
Pool boiling
Pool boiling
Inside horizontal, vertical
Copper
Brass
304 Stainless
Copper
347 Stainless
A-nickel
Copper and stainless steel
Atmospheric pressure
Burnout data included
Pressure drop data included
11 correlations
Data from 14 runs
Copper
Annular
Inside tubes, across flat
plate
Annular
Neon
Nitrogen
Pentane
Potassium carbonate,
35% and 50%
Stainless steel
Sodium
Nickel
Meta-terphenyl,
orthoterphenyl, 4.35y0 puraterphenyl in meta-terphenyl (SantowaxMonsan to)
Water
Horizontal disk
Pool boiling
Pool boiling
Copper
Other correlations
Copper
Polished chromium
Hydrogen
Isopropyl alcohol
Alcohol, isopropyl
Methyl alcohol
Alcohol, methyl
Mercury
Comments
Flow pattern
Inside horizontal, vertical
Pool boiling
Annular
Pool boiling
Annular
Inside horizontal
vertical
1 and 3 atm
30"-78"K temperature
range
30'-78 OK temperature
range
and
Boiling
Two-phases (gas-liquid)
Review
nisms was modified by Chen (72) to account for the suppression effect of the moving fluid on the boiling rate.
T h e conditions of convective heat transfer are met at the
limits of 0% and 100% quality, and in the boiling, twophase region the interaction between the mechanisms
is accounted for. I t is a t this point that empiricism
enters the model, that is, in the determination of the
interaction effect. Chen's approach provides the designer with a method of obtaining a forced con-
NO. 1 2
DECEMBER
1970
79
TABLE I I .
Sjsteni
.lir-Water
Air-lvater
.\ir-\Vater
Boiling water
V E R T I C A L FLOW TWO-PHASE
CORRELATIONS
Comments
Rejerence
Introductory survcy
Survcy advocating Duklers
(20, 2 1 ) approach
Energy equation discussion
(theory)
Film thickncss, film flow rate
study
Pressure drop and holdup
study comparison with experimcntal data
Pressure drop in slug flow, experimciital study
Elevated pressure effects, cxperimeiital study
(77)
(76)
(76, 74)
(30.1
17)
(33)
1631
80
I N D U S T R I A L AND ENGINEERING C H E M I S T R Y
where V , is the mean velocity of the liquid-vapor mixture, D is the diameter, and gc is the gravitational constant.
The Davis correlation for pressure drop ( f20%) is
applicable to the same pressure range as the LockhartMartinelli correlation : for the turbulent-turbulent flow
regime with liquid Reynolds numbers above 8000, and
the vapor Reynolds numbers above 21 00 ; for liquid Reynolds numbers between 6000 and 8000, providing the
vapor flow rate is great enough to obtain a Froude number above 100.
The inclusion of interfacial roughness considerations
into the Lockhart-Martinelli correlation improved the
pressure-drop prediction, as shown by McMillan et al.
(62). Among the fluids used in horizontal systems was
trichloromonofluoromethane.
Baroczy (7) modified the Lockhart-Martinelli twophase pressure drop gradient ratio, r$li2, by considering
the ratio of the two-phase gradient to the total liquid
gradient
The standard of comparison seems to have been established by Lockhart-Martinelli. There must be some
satisfaction in having produced the most often quoted,
compared, and modified work in the field. The Lockhart-Martinelli standard appears not only in pressuredrop correlations, but also in two-phase coefficient correlations.
There are several design methods currently available :
the classic local coefficient approach utilizing average
conditions and properties in the two-phase region, the
VOL. 6 2
NO. 1 2
DECEMBER 1 9 7 0
81
statistical or empirical approach, and the more sophisticated method of Fair. T h e first is dangerous for the
serious designer. Realistically and traditionally, the
designer has functioned in the realm of experience and
expedience. He, therefore, tends toward the second or
empirical approach, which is highly useful for repeat
routine work, but suffers from the limitation of producing
questionable results when extrapolated beyond the conditions of the original data. Sufficient material is now
available to produce a satisfactory iriethod of design, if
one remembers that investigations into areas such as flow
control are still incomplete. The more theoretical approach overcoines the extrapolation limitation, but demands more effort to successfully set up the calculating
procedure. The ubiquitous piper seems to be demanding his due for the pleasure of flexibility.
REF E R ENC ES
(1 j Anderson, G . H . and hlantzourdnis, B. G.. "T>\o-Ph;isc (G'is-Liquid) I'low
Phenomena," Chem. Eng. S - L ~12
. , (Z),109-126 (1960).
(2) h n d c r s o n : R . J. a n d Russcll, T . 'IV. F., "Dcsigning for T s o - P h a b c Floi*," P a r t
Yorh), 139-44 ( D e i . 6,1965).
ind Russcll,T. 'IV. F.. "Dcsigning lor Tuo-I'hdsc Florc," I'.iri
11, zbid., 99-104 (Dcc. 20,1965).
(4) Anderson, R . J. a n d Russcll, T. I V . F., "Designing for 'Two-l'htiic Flow," P x t
111, i h d . . 87-90 (Jan. 3,1966).
(5) Bakcr. O.,
"Design of Pipclincs for Simultaneous Flow of Oil a n d Gas," 011 Gas
J . , 53 ( 1 2 ) , 185-195 (JuI) 1954).
(6) Bankoff. S. G . : "\!ari,rble Density Single Fluid h l o d r l for T\r.o-l'h,tic Flov with
Particular licicrcncc to Stedm-TVatcr Tlo\v," 7'rans. AS'.ifL', 265-272 (1960,.
( 7 ) Barocrv C. J., "A Syatem,itic Corrcl.ition for Two-Ph.ise I'ressurc Drop,"
AICIiE P & r . 37, Hc'it Transfer Conference. 1.0s Angclcs, 1965.
(8) Bcaver, P. R . .ind Hughm,irk. G . )I,,
.lIC/ii: J . >14 (j),746-749 (Scpt. 1968).
(9) Berglcs. :\. E . , LopinSi: I<. r . , . ~ n dFiori; SI. l'., "Critic,il Hc,it l'lux a n d F l < w
Pattern 0bserv;itions for Low Prcssurc !$-,iter Flowing in T u b e
Srr. C. 89 (1): 69 (1967),
h d t , R . R . , J r . , "An Euperimcnt,il ln\csti$cition of Boiling
(10) B L t t , T . A .
117) DeGance. A . E.a n d Atherton, I t . I V , , thid.. P a r t 11, (8), 151-158 (r\pr. 20,
1970).
(18) Dengler. C . 1;.and r\ddoms, J. N . , " H c a t Transfcr Slechnnism for V d p o r i z ~ rion of Il'nter in a \-ertical Tube," Chem. hng.P r o q , . S ~ m p Ser.
,
l h , 52, 95-102
(1956).
(19) Dr<i)cr,D. E,, "Kuclc,itc Boiling of Hydrogen," I n d . finq, Chon.. I ~ u n d a w . 4, (2);
167-171 ( M a y 1965).
(20) Dukler, A . E.;'IVicks 111, hf.. a n d Clcvcl:ini, R . G . . "Frictional 111 Prcrsurc
D r o p in Two-Phase F l o w A . A Comparison of 1:sisring Corrclations for Pressure Loss a n d Holdup," .AIChE J . , 10 ( I ) , 38-43 (1964).
(21) Dukler, A . E., \ V d s 111, hI., a n d Clcvcland, I<. G., "l'riciion,il Pressure
Drop in Two-Phase F l o ~
: B. A n Approach T h r o u g h Similarity I\n.ilysis,"
ibid., pp 44-51.
(22) Fair, J. R . "LVhat You N c c r l to Design Thcrmosiphon Iicboilcrs," Pelroi.
H e j n r r : 39 (2):'105-123(Fcb. 1960).
(23) F a r , J. R.. "\'aporizer and Ilcboilcr Dciign," P a r t I , Chrm. Eng. (.\-ew York),
70 (14), 119-124 (July 8, 1963).
(24) Fair, J. It., ibzd., Part 11, (lh),101-104 (Aug, 5, 1963).
(25) Forstcr, K . E. a n d Greif, R . , "Hcat Trmsfcr to a Boiling Liquid-hIcchanisni
a n d Correlation3," J . Hcal 7ionrfer. 8 1 il), 43-53 (1959).
(26) Gambill. \V. R . a n d Bundy, R . D.: '"ish-Flux
Hear Transfer Characteristics
of P u r c Ethylene Glycol in Axid1 and Swirl Flow," ilIChC J . , 9 ( l ) ,55-59 (1963).
(27) Gumbill, \ \ I . R . . "A Survry of Boiling Burnout," Bri!. Cl;em. E V , ~ 8. . (2), 93-98
(Fcb. 1963).
(28) Gamhill, 'IV. R . , "Gencralked Prediction of Burnout H c a t Flux for Flowing,
Subcoolcd, IVctting Liquids," C h m . L'ng. Progr., Sjwp. Ser., 5 9 (41),71-87, (1963).
(29) Gambill, W.K . , "An Experirncnral Investigation of t h c Inhcrcnt Uncertaintv
in Pool Boiling Critical Hcat Fluxes to Saturated \t'ater," AIChE J.: 10 (4), 502508 (1964).
(30) Gill, L . E., Hewitt, G. F., a n d Lacuv P. M . C., "Data on the U p w a r d s .4nnular Flow of .lir-TVdter hlixtures," Chrm:'Eng. Scz.; 20 (2), 71-88 (1965).
(31) Gilmore, C. H . . " S u c l e a t e Boiling--A Correlation," Client. Eng. Progr., 54
(lo), 77-79 (Oct. 1958).
(32) Gilmorc, C. H., "Processing liotcs," O i l Gas J.,59 (jl), 79 (Dec. 18,1961).
(33) Griffin, P. a n d 'IVallis, G . B., "Two-Phase Slug Floii," J . Heat Transjer: 83C,
307-320 (Aug. 1961).
(34) Grouse, S. I V . , Jr., "An Index to Two-Phasc Gas-Liquid Flow Literature,"
1I.I.T. Press, Cambridge, l f a s s . , 1966.
82
I N D U S T R I A L A N D E N G I N E E R I N G CHEMISTRY
(65) Nicklin. D . J., e t a i . , "Two-l'h,irc Flow in Vc:tic,il Tubes," 7'rani. Inr!. Chem.
I;'n,q., 4 0 ( I ) , 61-68 (1962).
I : , "HoM' to Ertirn'ite I'rcssurc I l r o p
k ) . 74 (17), P d r t 4, 159 (.lug. 14. 196
a n d Iabin, H. S., C h o n Eng. Progr.: 50
(68) Schrock. V. E . a n d Grossman, L . Sl.>"Forced C
.\ucl. Sci. Eng., 12, 474 1~1962).
(69) Shcllcnc, K.R., Stcrnlinz. C. V.. C h u r c h . D . hi.,and Sn)-dci, K . H.,
Chcm.
h n g . Progr., Sjmp. S'er. 82,64:'102-113 :1963).'
(70) Stahcl, E. P.a n d Ferrcll, J. K., "He,it Transfer," I A D .L N G .C111:hr,, 60 ( I ) ,
75-83 (Jdn. 1968).
(71) T o n g , L . S.,"Boilins H c a t Transfer a n i Two-I'haw Ilow," J o h n T V i l c y :ind
Sons, I n c . , 1st ed., 1965.
( 7 2 ) T r i p a t h v C . S. D., "Litcraturc Survey ,ind Cvaluntion of the \',irioua Possiblc
Methods ok'ferforming Two-I'h,ise Flow Pressurc Drop Calcul;itions," ?V
S. I.
T h e s i a , Dcpt. of Chem. Cng., T h e Univcrsity of T u l s . ~ ,I'ulsa, Okl.i., 1967.
(73) Tripathv. C . S. "Hvdr.iulic Pcrformancc cf Thermosiphon Rcboilcr," M.S.
Thesis, T h b Univeksity bf Tulsa, Tuls'i, Okla., 1968.
(74) Van Deemter, J. J. a n d V a n Der V a a n , E. T.: "hlomcntum :and Energy
Balance for Dispersed Two-Phase F l o ~ , ",lp,bi. Sci. R e s . , A10 (Z), 102-108 (1961).
(75) v a n 'Ifijk, \V. R., Vor, A . S.:
Boiling Bin,a.ry Liquid .Mixturcr:"
(76) Vohr, J., " T h c Encrgy Equati
281 ( M a y 1962).
v o n Glahn, U. I . , "An Empirical Relation for Predictinm V r i r l rr'rctions with
(7?'wo-Phase, Steam IVater Flow,'' .VAS.A 7 i c h . .Vote, D-l18$(Jan. 1962).
(78) \Vallis, G.D . , "The Transition from Floodins to Upw;irds Cocurrent :\nnular
Flow in a Vertical Pipe,'' C.1:. '41. Encrqy . A d z , , Reiic!or Group, R e / > . R-742 (Fcb.
1962).
(79) \Veitwatcr, J. I$',, "Boiling of Liquids," in h d v a n c c r in Chcmicd I,nginecring,
Vol. I , Academic Prcss l n c . , Kew York, 1956.
(80) \Vest\\.atcr: J. W.,
ibid., Vol. 11, 1958.
"A\-cragc Volumetric Conccntration i n Two(81) Zubcr, N. and Findlay, J
Phase Flow Systems," .J. Hea
nsjcr, 87C (4), 453-468 (Nov. 1965).