Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
Cl2
19.) Given equal molalities of the following aqueous solutions, which will exhibit the highest
boiling point?
NaCl
FeCl3
CaF2
I2
20.) Which of the following is least soluble in water?
potassium chloride ethanol
ammonia
diethyl ether CH3CH2OCH2CH3
21.)
22.) Given 0.2 molal solutions of different solvents, which among the following will give the
greatest freezing point depression?
ethanol (Kf = 1.99 oC/ molal)
water (Kf = 1.86 oC/ molal)
o
benzene (Kf = 5.12 C/ molal) chloroform (Kf = 4.68 oC/ molal)
Vapor pressure at 30 C
CH3Br
8.75 torr
CHBr3
0.91 torr
CBr4
1425.1 torr
149.5 oC
195 oC
3.56 oC
3.83
6.72
1.95
Kb (oC/m)
For nos 23-25.) Identify which beaker has the liquid substance with the:
23.) highest Hvap
C. CHBr3 (this requires solving)
24.) strongest London dispersion force between molecules C. CBr4
25.) most polar molecules
A. CH3Br
For nos. 26-27.) A nonvolatile, nonreactive solute is added to each beaker resulting in solutions
each having equal mole fractions. Assuming that the solute is soluble in all liquids, choose
which beaker will have:
26.) the highest vapor pressure
C. CBr4
27.) the least vapor pressure lowering
B. CHBr3
28.) If the solute added resulted in solutions with equal molalities instead, which of the
beakers above will contain the solution with the least change in boiling point? C. CBr4
29.)
At what conditions will solid, liquid, and gaseous Y2 exist? at P = 5 atm and T = 0oC
34.)
35.)
H2
Which of the following will have the greatest kinetic energy at 300 K?
N2
F2
all will have the same kinetic energy
36.) Which gas will escape first if all were placed inside a balloon?
CH4
NO2
Br2
CO2
37.) The density of a gas at given temperature, pressure and volume will be equal to
MRT
(MWRT)/P
(PMW)/ (RT)
(nRT)/P
38.) The partial pressure of Argon gas in a closed cylindrical can is 5.25 atm and that of
Nitrogen gas is 6.89 atm. Which of the following is TRUE for the gases inside the container?
The total pressure inside is equal to sum of half contribution of each gas
The mole fraction of nitrogen gas is less than argon
The mole fraction of argon gas is equal to (Ptotal PAr)/Ptotal
Argon gas will escape last if the container is punctured
39.)
Low T, High P
Low T, Low P
High T, High P
High T, Low P
40.) Car tires easily explode during summer period. The gas law that best describes this
phenomenon is
Grahams Law of Effusion
Charles Law
Boyles Law
Hess Law
) in
Consider the equilibrium reaction for the dissociation of the colored species HMmCl:
HMmCl(s) HMm+(aq, red) + Cl-(aq)
HMm+(aq, red) + H2O(l) Mm(aq, green) + H3O+(aq)
44.) A pinch of HMmCl(s) is dissolved in 5.0 mL distilled water and placed in an ice bath. The
resulting color of the solution would be:
red
green
yellow
Solid HMmCl forms
45.) If 3.0 grams of NaOH is placed in the above solution, the color of the solution is expected to
be:
green orange
yellow
red
Consider the following sets of solutions:
Set A: 10.0 mL of 0.05 M NaOH
Set B: 5.0 mL of 0.10 M H2SO4
Set C: 10.0 mL of 0.05 M Ca(OH)2
46.) What is the pOH of the solution formed by mixing Set A and Set C, and adding 10.0 mL
water?
2.30
1.12
12.88
1.30
12.70
47.) What is the pH of the solution made by mixing Set A and Set B? (do stoichiometry)
1.78
1.60
1.48
1.30
12.22
48.) In the confirmatory test for carbonate anion, solid barium carbonate (BaCO3) is added with
acetic acid (CH3COOH) to dissolve the salt. Carbonate anion is confirmed when effervescence
(evolution of gas) is observed. When carbonic acid (H2CO3) is added to a solution of sodium
acetate (NaCH3COO), effervescence is observed initially, followed by slight vinegar smell. From
these observations, the correct order of increasing acidity is:
H2O > H2CO3 > CH3COOH
H2CO3 > CH3COOH > H2O
H2O < CH3COOH < H2CO3
H2O < H2CO3 < CH3COOH
H2CO3 < H2O < CH3COOH
49.) Predict the direction of reaction for the following system when placed in boiling water:
CH3NH2 + H2SO4 CH3NH4+ + HSO4 + heat
forward
backward reaction is not possible
neither direction
50.) Which of the following solutions (at the same volume) will boil first at 760 mmHg
atmospheric pressure?
0.1 m AlCl3
0.05 m KOH
0.05 m acetic acid
0.12 m dextrose solution
Problem Solving:
1.) At conditions of 25oC and 380 mm Hg, the density of sulfur dioxide (SO2) is 1.27 g/L. The
rate of effusion of sulfur dioxide through an orifice is 4.48 mL/s.
a.) What is the density of a sample of gas that effuses through an identical orifice at the rate of
6.78 mL/s under the same conditions?
b.) What is the molar mass of the gas in a.)?
c.) The unknown gas in a.) was determined to be 44.5 % carbon, 51.8% nitrogen, and 3.7%
hydrogen. Determine the molecular formula of the gas.
Answer:
6.78 mL/s
x g/L =
1.27 g/L
x g/L
b.)
1.27 g/L
6.78 mL/s
4.48 mL/s
x g/L = 0.5545 g/L
P(MWgas ) = density RT
MWgas
MWgas
L atm
380 mm Hg
760 mm Hg
1 atm
= 27.1 g/mol
no. of H atoms
3.7/1.01 = 3.66
no. of C atoms
44.5/12.01 = 3.71
no. of N atoms
51.8/14.01 = 3.70
= MR T
30.52 g
L atm
MWsolute
2.75 atm =
0.08206
(25 + 273 K )
mol
K
1.00
mL
1.00
L
1.2 103 g
1.00 g 1000 mL
MWsolute = 226.16 g/mol
b.)
new BP = Tb + 100oC (normal BP of water)
Tb = K b m
30.52 g solute
C
226.16 g solute/mol solute
Tb = 0.520
kg solvent
1.0 kg solvent
3
Tb = 0.0585 C
new BP = 100.0585 oC