Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
Introduction
2
2.1
Experiments
Reagents and Instruments
All the chemicals used were of analytical purity
No.1
Experimental Methods
The isothermal evaporation method was employed in this study. According to the phase equilibrium composition, an appropriate quantity of salts
and distilled water were mixed together as a series of
artificial synthesized brines and loaded into clean polyethylene containers(15 cm long, 10 cm wide and 7
cm high) and then the containers were put into the
SHH-250 type thermostatic evaporator for the isothermal evaporation at (2730.1) K. The crystal behaviors of the solid phases were observed periodically.
When enough new solids appeared, the solids were
separated from the solutions, dried at 273.15 K and
waited to identify. Meanwhile, 5.0 mL of the sample
of the clarified solution was taken from the liquid
phase and diluted to a final volume of 100 mL in a
volumetric flask filled with the deionized water to
analyze the liquid phase components. Another 5.0 mL
of sample was taken to measure the density. The remainder of the solution continued to be evaporated to
reach the next metastable equilibrium point.
The densities() of the equilibria solution were
measured by means of a density bottle method with a
115
3
Analytical Methods
116
Determined values of salts solubility, density and pH value of equilibrated solution in the quaternary
system NaCl +Na2CO3 +Na2SO4 +H2O at 273.15 K*
Composition of solution, w(B)(%)
No.
1,A
2
Vol.26
w(NaCl)
25.23
25.23
w(Na2CO3)
0.00
0.50
w(Na2SO4)
1.55
1.53
w(H2O)
73.23
72.74
J(Na2CO3)
0.00
1.84
J(Na2SO4)
5.78
5.63
Density,
/(gcm3)
pH
ncl+ns
ncl+ns
1.2109
1.2145
9.31
9.60
Solid phase
25.01
0.64
1.55
72.80
91.95
2.35
5.69
ncl+ns
1.2165
9.41
24.31
1.16
1.50
73.03
90.14
4.29
5.57
ncl+ns
1.2219
9.21
23.83
1.85
1.59
72.74
87.40
6.77
5.83
ncl+ns
1.2261
9.42
23.36
2.63
1.38
72.64
85.37
9.60
5.03
ncl+ns
1.2289
9.43
7,B
24.19
6.13
0.00
69.68
78.15
21.85
0.00
nc+ncl
1.2268
11.08
23.73
3.29
0.31
72.68
86.85
12.02
1.12
nc+ncl
1.2226
10.52
23.76
3.28
0.31
72.65
86.86
12.00
1.14
nc+ncl
1.2259
10.24
10
23.65
3.33
0.32
72.70
86.64
12.21
1.16
nc+ncl
1.2276
9.81
11
22.80
3.98
0.89
72.33
82.40
14.38
3.22
nc+ncl
1.2364
9.41
0.00
6.90
2.22
90.88
0.00
75.69
24.31
nc+nsc
1.0961
11.47
12,G1
13
0.47
6.03
1.91
91.60
5.58
71.72
22.69
nc+nsc
1.0921
11.26
14
5.38
8.77
2.35
83.50
32.61
53.13
14.27
nc+nsc
1.1628
10.61
15,E
21.85
5.69
1.01
71.45
76.52
19.93
3.55
nc+nsc+ncl
1.2440
10.41
16,G2
0.00
5.15
2.25
92.60
0.00
69.56
30.44
ns+nsc
1.0794
11.84
17
0.45
5.31
2.07
92.17
5.69
67.82
26.49
ns+nsc
1.0842
11.50
18
1.25
5.71
2.43
90.62
13.30
60.83
25.87
ns+nsc
1.1014
10.78
19
5.46
7.90
2.87
83.77
33.63
48.65
17.71
ns+nsc
1.1556
10.21
20,F
22.46
4.33
1.08
72.13
80.60
15.54
3.86
ns+nsc+ncl
1.2377
10.18
21
22.14
5.23
1.03
71.59
77.95
18.41
3.64
nsc+ncl
1.2426
10.36
22
22.35
4.73
1.06
71.85
79.40
16.82
3.78
nsc+ncl
1.2392
10.38
Fig.1
Metastable phase diagram of quaternary system NaCl +Na2CO3 +Na2SO4 +H2O at 273.15 K(A) and
part enlargement diagram of Fig.1(A)(B)
On the basis of data collected in Table 1, the relationship between the physicochemical properties of
solution(density and pH value) and the mass fraction
of sodium chloride w(NaCl) are shown in Figs.2 and
3, respectively. Fig.2 shows that in the process of water evaporation, the density of the equilibrated solution increases regularly with the increasing of sodium
chloride concentration in a w(NaCl) range of 022%,
and reaches the maximum values at the co-saturation
point E(1.2440 g/cm3) and point F (1.2377 g/cm3). In
No.1
Fig.2
117
Conclusions
Zhang Y. S., Zheng M. P., Nie Z., et al., Sea-lake Salt and Chemical
Industry, 2005, 34, 1
[2]
Zheng X. Y., Tang Y., Xu Y., Salt Lakes of Tibet, Science and
Technology Press, Beijing, 1989, 5
Fig.3
[3]
[4]
[5]
Su Y. G., Li J., Jiang C. F., Journal of Chemical Industry and Engineering, 1992, 43, 549
[6]
Guo Z. Z., Liu Z. Q., Chen J. Q., Acta Chimica Sinica, 1991, 49, 937
[7]
Fang C. H., Niu Z. D., Liu Z. Q., Acta Chimica Sinica, 1991, 49,
1032
[8]
Nie Z., Zheng M. P., Acta Geosicientia Sinica, 2001, 22, 271
[9]
[10]
Institute of Qinghai Salt-Lake, Chinese Academy of Science, Analytical Methods of Brines and Salts, Science Press, Beijing, 1984, 75
[11]
Sang S. H., Yin H. A., Zeng Y., Acta Chimica Sinica, 2006, 64,
2247
[12]
Sang S. H., Yu H. Y., Cai D. Z., Chinese Journal of Inorganic Chemistry, 2005, 21, 1316
[13]
Lin X. F., Zeng Y., Zheng Z. Y., Journal of Salt Lake Research,
2007, 15, 24
[14]
Zheng Z. Y., Zeng Y., Chen J., et al., Chem. J. Chinese Universities,
2008, 29(2), 336