12-07-14 JR - IPLCO JEE-MAIN (2011) WTM-10 Q'PAPER

Narayana Sri Chaitanya IIT Academy
Sri Sarvani Educational Society
COMMON CENTRAL OFFICE_MADHAPUR_HYD

Jr.IPLCO
Time : 3:00
JEE MAIN
2011 Model
Dt:12-07-14
Marks : 360
IMPORTANT INSTRUCTIONS:
1. There are three parts in the question paper A, B, C consisting of Physics,
Maths and Chemistry having 30 questions in each part of equal weightage.
Each question is allotted 4 (four) marks for each correct response.
2. Candidates will be awarded marks as stated above in instruction for correct
response of each question. 1/4 (one fourth) marks will be deducted for
indicating incorrect response of each question. No deduction from the total
score will be made if no response is indicated for an item in the answer sheet.
3. There is only one correct response for each question. Filling up more than one
response in each question will be treated as wrong response and marks for
wrong response will be deducted accordingly as per instruction
12-07-14_Jr. IPLCO_JEE-MAIN_SYLLABUS
Physics:
Circular
Motion(Excluding
verticle
circle):
Kinematics,Dynamics(centripetal
force,centrifugal force),banking,Angle of banking and problems on these topics (100%)

WTM-10
12-07-14_Jr.IPLCO_(JEE-Main 2011)
Mathematics:
Section formula, area of triangle , locus, transformations of axes
Chemistry:
Dissociation of polyprotic acids, Salt hydrolysis, Buffer solutions, Theory of indicators,
Solubility of sparingly soluble salts and solubility product (100 %)
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Space for Rough Work
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MATHEMATICS
1.
A1 , A2 , A3 ..... An are n points whose coordinates are x1 , y1 , x2 , y2 , x3 , y3 ..... xn , yn . A1 A2
is bisected at G1 , G1 A3 is divided in the ratio 1:2 at G2 . G2 A4 is divided in the ratio 1: 3 at

G3 and so on until all the points are exhausted. Then the coordinates of the final point
so obtained is
lx1 mx2 kx3 ly1 my2 ky3
,
l mk
lmk
1)
2.
x , y
i i
i
3)
2)
xi yi
n
n
4)
xi yi
2n 2n
P,Q,R and S are the points on line joining the points P a, x and T b, y such that
5a 3b 5 x 3 y
,
is the mid point of
8
8
PQ=QR=RS= ST, then

1) PQ
3.
2) QR
3) RS
4) ST
The orthocenter, circumcenter, centroid and incentre of the triangle formed by (0,0),
(a,0) and (0,a) lie on
1) x 2 y 2 1
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2) y=x
3) y=2x
4) y=3x
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4.
A string of length 12 is bent first into a square PQRS and then into an isosceles triangle
PQT by keeping the side PQ of the squares as base then area of the square PQRS: Area
of the triangle PQT =
1) 3 : 2
5.
2)
3) 2 : 3
2 :1
Line joining A b cos , b sin and B a cos , a sin is produced to the point M x, y
such that AM:MB = b:a then x cos
1) -1
6.
4) 1: 2
2) 0

y sin
2
2
3) 1
4) 2
Let A h, k P 1,1 C 2,1 be the vertices of a right angle triangle with AC as its
hypotenuse. If the area of the triangle is 1 then the set of values of K can taken is given
by
1) 1,3
7.
2) 0, 2
3) 1,3
4) 3, 2
The mid points of the sides AB and AC of a triangle ABC are 3,5 , 3, 3 then the
length of the side BC is
1) 40
8.
2) 20
3) 30
4) 18
The points with coordinates 2a,3a 3b, 2b and c, c are collinear

1) for all values of a,b,c
2) for no values of a,b,c
3) iff a,c/5, b are in H.P
4) iff a,2c/5, b are in H.P
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9.
If A(1,2),B(4,1) and P be a point on x-axis such that PA+PB is minimum then P=

1) (2,0)
10.
2) (3,0)
3) (4,0)
4) (1,0)
If A(x1,y1), B(x2,y2) and C(x3,y3) are the vertices of a triangle ABC and
x1 - 22 x2 +27 x3 y1 - 22 y2 +27 y3
then D lies
,
6
6
1) inside triangle ABC

2) outside triangle ABC but inside BAC
3) outside triangle ABC but inside ABC
4) outside triangle ABC but inside ACB
11.
The locus of point of intersection of the lines y mx a 2 m 2 b 2 and my x

a 2 b 2 m 2 is ( m R)
1 1
1) x 2 y 2 2 2
a b
3) x 2 y 2 a 2 b 2
2) x 2 y 2 a 2 b 2
4)
1
1
2 a 2 b2
2
x
y
12.
From a variable point P perpendiculars PM,PN are drawn to x and y axes respectively.
If the line through MN passes through fixed point(a,b), locus of P is
1) xy ax by
2) xy ab
3) xy bx ay
4) x y xy
13.
Vertices of a variable triangle are 3, 4 , 5cos ,5sin and 5sin , 5cos , where R
. Locus of its orthocenter is
1) x 2 y 2 6 x 8 y 25 0
2) x 2 y 2 6 x 8 y 25 0
3) x 2 y 2 6 x 8 y 25 0
4) x 2 y 2 6 x 8 y 25 0
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14.
ABC is right angled at C. if A 1, 2 circumcentre of triangle ABC is at 6, 2 ,length
AC is 8 units, the possible positions of C are

1) 37 / 5,34 / 5 , 37 / 5, 24 / 5
2) ( 37 / 5, - 14 / 5) , ( 37 / 5,34 / 5)
15.
3) ( 37 / 5,14 / 5) , ( 37 / 5,34 / 5)
4) 37 / 5,6 / 2 , 37 / 5,14 / 5
P and Q are two variable points on the axes of x and y respectively such that
OP +OQ =a , then the locus of foot of perpendicular from origin on PQ is
2
2
1) x y x y axy
2
2
2) x y x y axy
2
2
3) x y x y a x y
16.
2
2
4) x y x y axy
A straight line segment AB of length a moves with its ends on the axes. The locus of
the point P which divides the ends A and B of the segment AB in the ratio 1:2 internally
is
2
2
2
2) 9 x 4 y 4a
1) 9 x 2 4 y 2 a 2
2
2
2
3) 9 x 4 y 8a
17.
If A 4,0 , B 4,0 are any two points and PA PB 4 . The locus of P is

1) 3x 2 y 2 12
18.
4) 9 x 2 9 y 2 4a 2
2) 3x 2 y 2 12
3) 3x 2 3 y 2 9
4) 3x 2 y 2 8
If (2,0)(0,2)(2,2) are the midpoints of the sides of the triangle ABC then the
circumcentre of triangle ABC is
1) (1,1)
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2) (2,2)
3) (0,0)
4) (4,4)
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19.
If A(1,3),B(-3,5)& C(5,-1) and P be a point in the plane such that PA=PB=PC, then PA=
1) 2 5
2) 5 10
3) 5 5
4) 5
20.
A 2,5 , B 4, 11 and the locus of C is 9 x 7 y 4 0 then the locus of the centroid of

ABC is
1) 27 x 21 y 8 0 2) 3x 4 y 2 0 3) 24 x 22 y 6 0
4) 5 x 3 y 7 0
21.
If A(7,4),B(4,1) then the number of points P in the plane such that APB = and area of
22.
triangle APB is 6.25 square units is

1) 0
2) 2
3) 3
4) 4
The points ( a, 2 - 2a) , ( 1 - a, 2a) and ( - 4 - a, 6 - 2a) are collinear then a =
p
2
1) 1
23.
2)
3
2
3)
-1
2
4)
1
2
Assertion(A): If G is the centroid of triangle ABC, where A(5,-1), B(3,2) and C(7,1),
then the area of triangle ABG is 5/2 square units
Reason(R): If D,E and F are the midpoints of the sides BC, CA& AB of triangle ABC
respectively then area of ABC=4 (area of DEF )
1) Both A and R are true and R is correct explanation of A
2) Both A and R are true and R is not correct explanation of A
3) A is true and R is false
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4) A is false and R is true

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24.
Assertion (A): If A(7,-2),B(5,4) and C is a point on the line through AB such that
25
AC 2
= , then C =
, - 6
or
AB 3
3
17
, 2
3
AP l
= , then P divides AB
PB m
Reason (R) : If P is a point on the line through AB such that

in the ratio l:m internally only
1) Both A and R are true and R is correct explanation of A
2) Both A and R are true and R is not correct explanation of A

3) A is true and R is false
4) A is false and R is true
25. Under the rotation q , if 7 x 2 + 7 y 2 + 2 xy = 1 reduces to 8 x 2 + 6 y 2 = 1 then q equals

1)
26.
27.
p
3
p
6
3)
p
2
4)
p
4
If A 3, 4 , B 1, 2 , C 5,6 , D x, 4 are vertices of a quadrilateral such that

ABD 2ACD , then x =
1) 6
2) 9
3) 69
4) 96
o
If the axes are rotated through an angle 30 in the clockwise direction, the point
4, 2 3
1) 2,3
28.
2)
in the new system is
2) 2, 3
3)
3, 2
4)
3,5
When the origin is shifted to a suitable point, the equation 2 x 2 y 2 4 x 4 y 0 .

Transformed as 2 x 2 y 2 8 x 8 y 18 0 .The point to which origin was shifted is
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1) 1, 2
29.
2) 1, 2
3) 1, 2
4) 1, 2
If the square ABCD where A 0,0 , B 2,0 , C 2, 2 and D 0, 2 undergoes the following
three transformations successively:
i) f1 x, y y, x
ii) f 2 x, y x 3 y, y
x y x y
,
then the final figure ABCD is
2
2
iii) f3 x, y
1) square
2) parallelogram
3) rhombus
4) rectangle
2
30. If the equation y - 8 x - 4 y +12 = 0 is transformed to y2 = 4ax, when the origin is shifted
to (1,2), then a equals

1) 1
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2) 2
3) 2
4) 1
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PHYSICS
31.
A projectile u, is launched from horizontal plane, find angular velocity as observed

from the point of projection at the time of landing
1)
32.
g
u cos
2)
g
2u cos
3)
g sin
u
4)
g
2u sin
A spotlight S rotates in a horizontal plane with a constant angular velocity of 0.1

rad/sec. The spot of light P moves along the wall at a distance of 3m. The speed of the
spot P when 45o is ____ m/sec
3m
1) 0.8 m/s
33.
2) 0.9 m/s
3) 0.6 m/s
4) 0.4 m/s
A boy whirls a stone in a horizontal circle of radius 1.5 m and at height 2.0 m above
level ground. The string breaks, and the stone files off horizontally and strikes the
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ground after travelling a horizontal distance of 10 m. What is the magnitude of the
2
centripetal acceleration of the stone while in circular motion? g =10 m / s
1) 90m / s 2
34.
2) 125 m / s 2
3) 120 m / s 2
4) 166.6 m / s 2
A projectile is launched horizontally with 20 ms 1 from some height. Find radius of

curvature of path at t = 2 sec.
1) 80 2m
35.
2) 40 2m
3) 160 2m
4) 20 2m
A small block of mass 100 g moves with uniform speed in a horizontal circular groove,
with vertical side walls, of radius 25 cm. If the block takes 2.0s to complete one round,
find the normal reaction by the side wall of the groove
1) 0.25 N
36.
2) 0.5 N
3) 1 N
4) 2 N
Two different masses are connected to two light and inextensible strings as shown in the
figure. Both masses rotate about a central fixed point with constant angular speed of 10
rad s-1 on a smooth horizontal plane. Find the ratio of tensions
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T1
in the strings.
T2
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2M
TM
1M
T
1R
1R
.25kg
10
cm
22R
2121
1)
37.
38.
2)
5
4
3)
3
4
4)
3
8
The angular acceleration of a particle moving along a circular path with uniform speed
is
1) uniform but non-zero
2) zero
3) variable
4) such as cannot be predicted from the given information
A particle is revolving with a constant angular acceleration in a circular path of
radius r. Find the time when the magnitude of centripetal acceleration will be equal to
the magnitude of tangential acceleration.
1)
39.
9
8
1)
3)
1
2
4)
A small coin of mass 40 g is placed on the horizontal surface of a rotating disc. The disc
starts from rest and is given a constant angular acceleration 2rad / s 2 . The
coefficient of static friction between the coin and the disc is s 3 / 4 and coefficient of
kinetic friction is k 0.5 . The coin placed at a distance r = 1 m from the centre of the
disc. The magnitude of the resultant force exerted by the disc on the coin just before it
starts slipping is
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vertical
40.
1) 0.2 N
2) 0.3 N
3) 0.4 N
4) 0.5 N
A circular road of radius R is banked for speed v = 40 km/hr. A car of mass m attempts
to go on the circular road, the friction co-efficient between the tyre & road is negligible
1) The car cannot make a turn without skidding
2) if the car runs at a speed less that 40 km/hr, it will slip up the slope
3) if the car runs at the correct speed of 40 km/hr, the force by the road on the car is
equal to mv 2 / r
4) if the car runs at the correct speed of 40 km/hr, the force by the road on the car is
greater the mg as well as greater then mv 2 / r
41.
A disc of radius R has a light pole fixed perpendicular to the disc at the circumference
which in turn has a pendulum of length R attached to its other end as shown in fig. the
disc is rotated with a constant angular velocity . The string is making an angle 30o
with the rod. Then the angular velocity of disc is
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30oR
R
1)
42.
3g
1/2
3 g
2)
2
R
1/2
3)
3R
1/2
2g
4)
3 3R
1/2
A table fan rotating at a speed of 2400 rpm is switched off and the resulting variation of
the rpm with time is shown in the figure. The total number of revolutions of the fan
before it come to rest is:
Rev/min
2400
600
8 16 24
t(s)
43.
1) 420
2) 280
3) 190
4) 16800
The average acceleration vector for a particle having a uniform circular motion in one
complete revolution
v2
1) a constant vector of magnitude
r
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v2
2) in magnitude and perpendicular to the plane of circle
r
44.
45.
3) equal to the instantaneous acceleration vector at the start of the motion

4) a null vector
Assume that the earth goes round the sun in a circular orbit with a constant speed of
30km/s.
1) the average velocity of the earth from 1st Jan, 1990to 30th june, 1990 is zero
2) the average acceleration during the above period is 60km / s 2
3) the average speed from 1st jan, 1990 to 31st dec, 1990 is zero
4) the instantaneous acceleration of the earth points towards the sun.
For a particle in a uniformly accelerated (speed increasing uniformly) circular motion.
1) velocity is radial and acceleration is tangential only
2) velocity is tangential and acceleration is radial only
3) velocity is radial and acceleration has both radial and tangential components
4) velocity is tangential and acceleration has both radial and tangential components
46.
A curved section of a road is banked. If there is friction force between road and tyres of
the car and the car moves without slipping, then
1) horizontal component of normal reaction alone is the centripetal force
2) horizontal component of friction alone is the centripetal force
3) horizontal component of the net force by the road is the centripetal force
4) vertical component of normal reaction balances the weight of car
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47.
ur
A person applies a constant force F on a particle of mass m and finds that the particle
moves in a circle of radius r with a uniform speed v as seen from an inertial frame of
reference.
1) this is not possible
2) there are other forces on the particle
mv 2
3) the resultant of the other forces is
towards the center
r
ur mv 2
4) F =
is compulsory
r
48.
A particle moves with deceleration along the circle of radius R so that at any moment of
time its tangential and normal acceleration are equal in moduli. At the initial moment t
=0 the speed of the particle equals vo , then:
I) The speed of the particle as a function of the distance covered s will be
1) v voe s / R
49.
2) v vo e s / R
3) v voe R / s
4) v voe R / s
The angular velocity of a stone projected at a speed 20 m/s at an angle 60 0 with

horizontal when the stone is moving horizontally about the point of projection is
1) 1 rad/s
50.
2) 1/2 rad/s
3) 1/3 rad/s
4) 1/4 rad/s
A particle A moves along a circle of radius of R = 50 cm so that its radius vector r

relative to the point O rotates with the constant angular velocity w =0.40 rad/s. Then
speed of the particle, and the modulus of its total acceleration will be
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A
r
w
51.
1) v 0.4m / s , w 0.4 m / s 2
2) v =0.4m / s , w =0.32 m / s 2
3) v =0.2m / s , w =0.08 m / s 2
4) changing for both v and w w.r.t time
The kinetic energy K of a particle moving along a circle of radius R depends on the
distance covered s as K = as 2 where a is a constant. The magnitude of total force acting
on the particle is
s2
1) 2a
R
52.
s 2
2) 2as 1 2
R
1/2
3) 2 as
4) 2a
R2
s
A car of mass m is moving horizontally on a circular path of radius r. At an instant its

speed is v and is increasing at a rate a
1) the acceleration of the car is towards the center of the path
2) the magnitude of the frictional force on the car is than
mv 2
r
3) the friction coefficient between the ground and the car is not less than a/g
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1
4) the friction coefficient between the ground and the car is tan
53.
v2
rg
Let a particle moving in a circle of radius 2 m with its speed increasing at a rate 2 m / s 2 .
At an instant speed of the particle is 2 m/s, then its net acceleration will be
1) 2 2m / s 2
54.
2) F1 F2
4) 4 2m / s 2
3) F1 F2
4) The information is insufficient to find the relation between F1and F2 .

The seconds hand of a watch has length 6cm. Speed of its end point and magnitude of
difference of velocities at two perpendicular positions will be
1) 6.28 & 0 mm/s
2) 8.88 & 4.44 mm/s
3) 8.88 & 6.28 mm/s
56.
3) 6m / s 2
A train A runs from east to west and another train B of the same mass runs from west to
east at the same speed along the equator. A presses the track with a force F1 in
magnitude and B presses the track with a force F2 in magnitude. Then,
1) F1 F2
55.
2) 4m / s 2
4) 6.28 & 8.88 mm/s
When a conical pendulum of length l having a bob of mass m, is rotating at a rate w in

horizontal circular path, then
1) the tension in the string is m g 2 +( lw2 )
2) the tension in the string is m g 2 +lw2

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g 2
3) the height of point of suspension above the center of circular path is l - 2
w
g
4) the height of point of suspension above the center of circular path is 2
w
2
57.
58.
A ring of mass 2 kg and of radius 0.25m is making 300rpm about an axis through its
center perpendicular to its plane. The tension (in N) developed in the ring is
1) 50
2) 100
3) 175
4) 250
In the figure shown a smooth ring is connected to rod AB, while rod CD passes through
ring. At the given instant angular velocity of rod AB about hinge A is 1 rad / s and
AC CB instantaneous angular velocity of rod CD about hinge C is
1) 1 rad / s
59.
2)
1
rad / s
2
3)
3
rad / s
2
4)
3
rad / s
2
A particle moves in a circle of radius R at constant angular speed w. The maximum and
minimum angular speeds of the particle, about a point in plane of the circle at a distance
3R from the centre, are respectively
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1)
60.
ww
,
2 4
2)
ww
,
3 4
3) w,
w
4
4)
w
,0
2
The magnitude of rate of change of acceleration in a uniform circular motion of angular

frequency w and radius R is
1) 0
2) Rw3
3) 2Rw3
4) Rw2
CHEMISTRY
61.
An aqueous solution contains 10% ammonia by mass and has density of 0.99 g/cc.
5
Calculate hydrogen ion concentration in solution Kb 2 10
1) 102
62.
2) 9.26 1013
3) 9.26 1010
4) 7.4 106
19
For the reaction [ Ag (CN )2 ]
Ag 2CN , the equilibrium constant at 25C is 4 10 .
If a solution is 0.1 M in KCN and 0.03 M in AgNO 3 originally at equilibrium, the

concentration of Ag+ is
63.
1) 7.5 1016 M
2) 7.5 1018 M
3) 1.25 1016 M
4) 1.25 1017 M
For pure water at 25oC and 50oC the correct statement is
1)
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2)
3)
4)
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64.
65.
Two buffers X and Y of pH 4.0 & 6.0 respectively are prepared from adding weak
acid HA & its salt NaA. Both the buffers are 0.5M in HA. What would be the pH of the
solution obtained by mixing equal volumes of two buffers? ( KHA=1 105 )
1) 5.0
2) 6.30
3) 5.70
4) 4.30
5
10
An acidbase indicator has KHIn
.The acid form of the indicator is red & the
basic form is blue. The change in H required to change the indicator form 75% red to
75% blue is
1) 8 105 M
2) 9 105 M
3) 1105 M
4) 3 104 M
66.
On mixing equal volumes of each of the following solutions, the precipitation of AgCl
will take place in case of (Ksp for AgCl = 1.8 1010 )
1) 105 M AgNO3 with 104 M NaCl solution
2) 10- 5 M NaCl with 105 M AgNO3 solution
3) 103 M AgNO3 with 108 M NaCl solution
4) 103 M NaCl with 108 M AgNO3 solution
67.
Which of the following statement(s) is/are correct regarding titrations?

1) In a titration of weak acid with strong base,the pH at the half equivalence point is
pKa.
2) In the acid base titration involving strong base and weak acid, methyl red can be
used as an indicator
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3) The ionization constants of weak diprotic acid are in the order of Ka1 >> Ka2
4) At half equivalence point, it will form acid buffer (For weak base, weak acid
titration) at its maximum capacity where [acid] = [salt]
68.
pH of a mixture of 1 M benzoic acid (pKa = 4.20) and 1 M sodium benzoate is 4.5. In

300 mL buffer, the volume of benzoic acid is :
1) 200 ml
69.
70.
2) 150 ml
3) 100 ml
4) 50 ml
For preparing a buffer solution of pH=6 by mixing sodium acetate and acetic acid, the
ratio of concentration of salt and acid
should be
1) 1:10
2) 10:1
3) 10:1
4) 1:100
One student makes a curve of a titration of a weak diprotic acid by NaOH of equivalent
strength. Which of the following curve is correct regarding to above titrations
1)
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2)
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4) None of these
3)
71.
Hydrolysis constant of two salts of weak acids HA and HB with strong base are 108 and
106 . If the dissociation constant of third acid HC is 102 . The order of acidic strengths
of three acids will be

1) HA HB HC 2) HB HA HC 3) HC HA HB 4) HA = HB = HC
72.
A weak acid HX has the dissociation constant 1105 it forms a salt NaX on reaction
with alkali. The percentage hydrolysis of 0.1 M solution of NaX is
1) 0.0001
73.
2) 0.01
3) 0.1
4) 0.15
A buffer solution contains 100 mL of 0.01 M CH 3COOH and 200 mL of 0.02 M

CH3COONa. 200 mL of water is added. pH before and after dilution are : (pKa = 4.74)
1) 5.04, 5.04
74.
2) 4.08 , 4.08
3) 1.54 , 1.54
4) 5.34, 5.34
The pK a of weak acid HA is 4.8 and the pKb of a weak these BOH is
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4.78. The pH of an aqueous solution of corresponding salt BA will be :

1) 9.22
75.
2) 8.73
3) 7.01
4) 4.79
Which of the following is a buffer solution

1) 500 ml of 0.1M CH 3COOH 500 ml of 0.1M NaOH
4) 500 ml of 0.1M CH 3COOH 500 ml of 0.1M HCl
76.
77.
Phenolphthalein does not act as an indicator for the titration between :

1) KOH and H2SO4
2) Ba(OH)2 and HCl
3) NaOH and acetic acid
4) oxalic acid and KMnO4
If S1 , S2 , S3 & S4 are the solubilites of AgCl in H 2O , 0.01M CaCl2 , in 0.01M NaCl & in
0.05M AgNO3 respectively at certain temperature, the correct order of sdubilities is
(1) S1 S2 S3 S 4 (2) S1 S3 S2 S4 (3) S1 S2 S3 S4 (4) S1 S3 S4 S 2
78.
Two solubility products of Al ( OH ) 3 and Zn ( OH ) 2 are 8.5 10- 23 and 1.8 10- 14 respectively.If
NH 4OH is added to a solution containing Al 3+ and Zn 2+ ions, then substance precipitated first is
1) Al ( OH ) 3
Jr.IPLCO
2) Zn ( OH ) 2
3) both simultaneously
4) None of these
Page 24

WTM-10
79.
What is the minimum pH required to prevent the precipitation of ZnS in a solution that
is 0.01M ZnCl2 and saturated with 0.1M H2S? (Given: KSp 1021 , Ka1 Ka2 1020 )
(1) 8
80.
81.
82.
(2) 1
(3) 2
(4) 4
The pH of a solution is increased from 3 to 6; its H + ion concentration will be

1) reduced to half
2) doubled
3) reduced by 1000 times
4) increased by 1000 times.
pH of 0.01M ( NH 4 ) 2 SO4 and 0.02M NH 4OH buffer ( pK a of NH 4+ =9.26 ) is

1) 4.74+ log 2
2) 4.74 log 2
3) 4.74+ log 1
4) 9.26+ log 1
Regarding titration of Na2CO3 & HCl which of the following statements is wrong .
(1) At the start of titration, hydrolysis of CO32 not takes place
(2) At the first equivalent point amphiprotic ion, pH 1 2 pKa1 pKa2
(3) Before the first equivalent point the titrating solution act as a buffer solution of
HCO3 & CO32 and between the first and second equivalent point the titrating solution
act as a buffer solution of H 2CO3 & HCO3

(4) In this titration, using methyl orange indicator, the volume of the acid required at
the equivalence point is twice that of the acid required using phenolphthalein indicator.
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Page 25

WTM-10
83.
2.5 ml of
2
2
12
M weak mono acidic base Kb 110 is titrated with M HCl in water at
5
15
14
25o C . The concentration of H ion at equivalence point is K w 1 10
1) 3.7 1013 M
84.
2) 3.2 107 M
3) 3.2 102 M
4) 2.7 102 M
The H in 0.2M solution of HCOOH is 6.4 103 .To this solution formate is
added so as to adjust the conc. of HCOONa to one mole per liter. What will be the
4
PH of solution K a for HCOOH 2.4 10 , of HCOONa 0.75
1) 10.8
85.
2) 4.19
3) 6.25
4) 7
Equal volume of following solutions are mixed. In which case the pH of resulting
solution
will
be
average
pH
value
of
two
solutions
of HCN 1010 , K a of CH 3COOH K b of NH 3 1.8 105
1) HCl pH 2 and NaOH pH 12

2) HCl pH 2 and pH pH 4 NaOH
3) HCN pH 2 and NaOH pH 12
4) CH 3COOH ( PH =5) and NH 3( aq) ( pH =10)
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Page 26

WTM-10
86.
Amount of NaHCO3 in an antacid tablet is to be determined by dissolving the tablet in

water and titrating the resulting solution with HCl. Which indicator is most suitable in
this titration?
Acid
87.
H 2CO3
2.5 104
HCO3
2.4 108
(1) Methyl orange PK In 3.7
(2) Bromothymol blue PK In 7
(3) Phenolphthalein PK In 9.3
(4) Alizarin yellow PK In 12.5
The Ka of HNO2 is 4.0 104 . The pH of 0.04MNaNO2 solution is

1)8
88.
Ka
2)6
3)4
4)2
What compound, if any, will precipitate when 80 mL of 1.0 105 M Ba OH 2 is

5
added to 20 mL of 1.0 10 M Fe2 SO4 3
K sp Fe OH 3 2.6 1039 , K sp BaSO4 1.1 1010
1) Fe OH 3
89.
2) BaSO4
3)BOTH
4) Fe OH 2
The following pH range where the indicator shows change in colour are given
i. 4 9.7
ii. 7.46 10.0
iii. 6.5 4
which of the above pH range represent titration of

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Page 27

WTM-10
I. Strong acid/strong base S A / S B ,
II. Weak acid/ strong base WA / S B
III. weak base/strong acid WA / S A
90.
1. i I , ii II , iii III
2) iii I , ii II , i III
3. ii I , iii II , i III
4) i I , iii II , ii III
The percentage degree of hydrolysis of a salt of weak acid (HA) and weak base (BOH)
in its 0.1 M solution is found to be 10 %. If the molarity of the solution is 0.05 M. the
percentage hydrolysis of the salt should be :
1) 5%
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2) 10%
3) 20%
4) None of these
Page 28

WTM-10
Paper Setters Names: HYD/KPDS

Maths
Mr. A GIRI BABU
9177217567
Physics
Mr. BHASKAR REDDY
8499034313
Chemistry
Mr. G NARESH
9949247148
Paper Verifiers Names: VIJ-VEDAVYAS
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Maths
Mr. K BABU RAO
Ph : 9295034455
Physics
Mr. AMARANATH
Ph : 8096637372
Chemistry
Mr. SVS
Ph : 9440285626
Page 29

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