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1.
113
XII Chemistry
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2.
3.
4.
(ix)
C6H5OC3H7
(x)
CH3CH2OCH2CH2CH2Cl
Write the structures of the compounds whose names are given below :
(i)
3, 5-dimethoxyhexane-1, 3, 5-triol
(ii)
cyclohexylmethanol
(iii)
2-ethoxy-3-methylpentane
(iv)
3-chloromethylpentan-2-ol
(v)
p-nitroanisole
(ii)
(iii)
Williamson synthesis
(iv)
Reimer-Tiemann reaction.
(v)
Kolbes reaction
(vi)
114
XII Chemistry
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115
XII Chemistry
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5.
(ii)
(iii) cumene is oxidised in the presence of air and the product formed
is treated with dilute acid.
6.
(iv)
(v)
propene to propan-l-ol.
(ii)
anisole to phenol
(iii)
butan-2-one to butan-2-ol
(iv)
ethanal to ethanol
(v)
phenol to ethoxybenzene
(vi)
1-phenylethene to 1-phenylethanol
(vii)
formaldehyde to cyclohexylmethanol
(x)
(xi)
(xii)
116
XII Chemistry
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7.
8.
10.
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XII Chemistry
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(ii)
CH3 CH2 OH
443 K
CH2 = CH2
(iii)
2CH3CH2OH
CH3CH2OCH2CH3
413 K
11.
(iv)
CH3OH + CH3I
CH3OCH3 + HI
(v)
CH3OH + (CH3)3 CI
(CH3)3C O CH3 + HI
(ii)
(iii)
(iv)
(v)
(vii)
(a)
(b)
118
XII Chemistry
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(x)
(ix)
(x)
(xi)
(xii)
13.
(ii)
(iii)
(iv)
(ii)
(iii)
(iv)
(v)
(vi)
*14. Which of the following compounds gives fastest reaction with HBr and
why?
(i)
(CH3)3COH
(ii)
CH3CH2CH2OH
119
XII Chemistry
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*15. What is the function of ZnCl2 (anhyd) in Lucas test for distinction between
1, 2 and 3 alcohols.
16.
[A] : (CH3)2CHCH2OH
[B] : CH3CH(CH3)COOH
[D] : (CH3)3C OH
19.
XII Chemistry
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[Ans. : (A)
20.
(B)
CH3CH2OH
(C)
CH3CHOHCH3
(D)
CH3COOH
(E)
CH3COCH3
Phenol, C6H5OH when it first reacts with concentrated sulphuric acid, forms
Y.Y is reacted with concentrated nitric acid to form Z. Identify Y and Z and
explain why phenol is not converted commercially to Z by reacting it with
conc. HNO3.
[Ans. :
Phenol is not reacted directly with conc. HNO3 because the yield of picric
acid is very poor]
21.
22.
Ethoxybenzene
(b)
121
2methoxy2methylpropane
XII Chemistry
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