Documenti di Didattica
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Series : OSR/I
Code No.
+nt.
s6lu2
+tssi Efi
Tq-YlE
rr{ qErs flerii
Candidates must write the Code on
the title page of the answer-book.
Roll No.
gksTqr+ttr+rqtTfuidt
o
o
o
o
I
Code number given on the right hand side of the question paper should be written on the
title page of the answer-book by the candidate.
Please check that this question paper contains 30 questions.
Please write down the Serial Number of the question before attempting it.
15 minutes time has been allotted to read this question paper. The question paper will be
distributed at 10.15 a.m. From 10.15 a.m. to 10.30 a.m., the students will only read the
question paper and will not write any answer on the answer-book during this period.
rqTFI"TfrTTl-q(+qrP,ffi)
CHEMISTRY (Theory)
fr?ttfu$qzt: 3 qoq
Time allowed:3 hours l
nrm{frT+vr:
(i) afiswatMt
(ii)
#forr ,:r*,'i r
tsdrwr*fdqz er+-d- I
qrqwadllsTrfrq*wif wsqhr n+ /
[P.T.O.
General Instructions
(v) Question numbers 28 to 30 are long-answer questions and carry 5 marlcs each.
(vi) tJse l-og Tables, if necessary. Use of calculators is not allowed.
1. da (sol) glh-+d Gel) trT \rs-qqtsqrtruTt |
2.
? I
Which reducing agent is employed to get copper from the leached low grade copper
ore ?
3.
Frq
dtrou
IUPAC
qFT
ftrdi
"l
cH.-9H-CHz-CHO
NH2
cH"-cH-cH2-cHo
,l
NHz
4.
rq oTr{tq{i tsq-qffiM.)
{t
q+{ qr efir*'qlqvftd
tt
s.
56 rq
lqDm
qr+
y{'Qffi{e' q{r} t
Tr tfv+*tq wr t}*
6.
Frq
q\ffi
s) {6fi
Ei^q{rfto,,,dr
*-mq
qqfsm dfsr+
56m2
'2
t
?
8.
ftE{ {*,d
s1ffi rn{
loqft +fi
gdwfrildrq{ETqqH sr*Trwne*dr t
State Henry's law. What is the effect of temperature on the
solubility of a gas in
liquid ?
r
(i)
fr1Fr+
oTFTTS @seudo)
(ii) ffi
(i)
(ii)
t.
sEq
tz.
srfi{pmur
(i)
(ii)
write
(ii)
(ii)
Hydraulic washing
Vapour phase refining
Frr ii + rer
(i)
qfi{PsqT
Gou
GcHz-
(ii)
s6tu2
GoH
GcHz
ffi*,
(i)
dfe6t
yilT{ firqrqf
(i) .
soc/2,
Peroxide,
- cH = cH, + 1191
lP.T.O.
13.
(i)
(ii)
f=rng'q+st{*ntftmmtiflEsffi\fi tsiY{orfuq^dd
nnBr
S*2
erftlmqltntr
l,
(a)
(b)
qil{ S srFltffir tt ft t
(i)
Which alkyl halide from the following pair is chiral and undergoes faster S*2
n,\^
reaction ?
Br
(a)
(ii)
(a)
(b)
14.
(b)
Inversion of configuration
Racemisation
qr {rsrqFr*,'{FM +} gn
*t
(i)
'gw
- {6fr
sr{qn qqf*uiT
s1H
ffiqq
tffi
g$ enc*r
or{qr
(ii) H2O, H2S, HrSe eilc H zT" -T6fr Ei' eTIrfi Hsfrr 3r1ur
Complete the following chemical equations':
(i)
(ii)
CarPr+ HrO -+
Cu + HrSOo(conc.)
OR
Arrange the following in the order of property indicated against each set :
(i)
(ii)
15.
- increasing
tt
acidic character.
Write the IUPAC name of the complex [Cr(NH3)aCl21+. What type of isomerism does
it exhibit ?
q+ riqr$
gs
itr
(Ne = 6.022
1023
ft1-t)
An element with density 11.2 gcm-3 forms a f.c.c. lattice with edge length of
Calculate the atomic mass of the element.
(Given : No = 6.A22x
t7
qei
A+
rr$
qren
B-
sTr+
A+
B_ A+ B_ A+
B-
B-
A+B-A+O
(0
sr
A+
B- A+
B-
l6rs cm.
mol-l)
B-
A+
1023
4x
Enr
A+ B- A+ B-
A+
B-
B_
B-
A+
A+B-A+O
A+
B_ A+ B- A+
B-
18.
(i)
(ii)
(iii)
qfrqftm s1F{+
fu
3Trurq
qlmrqr+fu'gtr+-A*rif
qqqm =
o.+s
256 g
+fl-r
Ksts*Elqr{
Gq= s.r2Kkg+n-rr.
inT5gof
56fit2
tP.T.O.
t9.
Fna eftk,qroTi*'A, B
(i)
cHrBrIg\
qkc+tr{rr+r(mrr}:
LiAHor
ffi
FTr{qfirqdrNHqrti t
(i) rT{*S:f,hmtffiqit,
(ii) \d+ffi orretiFItNnri,
(iii)
tF ?frr q1 Nl-trqrffi{qqqqqs
fsqcusrqFro
it
fud r;
(i) curnr-$ALiAHortffi.
NH, Br^+KOH CHC/"+NaOH
tii) CH3COOH-f A -j ----; B -----' - ---- ) C
OR
How will you convert the following
(i)
(i0
(iii)
AnilineintoN-phenylethanamide
(Write the chemical equations involved.)
20. (a)
FrE{
erfttx,,qr*m.rqAn
cH3cH2oH
HBr
ffi
, cHrcHrBr + Hro
cH3cH2oH
(b)
56nt2
HBr
, cHrcHrBr + Hro
21. wtftTr +
+dt q{
ts'irrr qr+ *-eqrra, \rs.q.m + BHT * zre ffiq fuqr fu.rr rilrif *}
ilflrEfiur s+{ qgrT rfr .rc Hrkr + qfi} +
sqrilq + qkd oti r yu gqq oi erftro qr+nt
eqr+ + ffi
qTq
tffis( +d H e*{ sfi
ffi qcit, erq
=ei+ Ed'*Tfif +
efu
fuqrfiam
"k*
s*,rrqRt
ra{r { o.m *'qd frt r q*+ u* i sor fuqr fu qr{r rfr s}
gtfuc + +ftr+ ryewrfiss.+ H qr rd,r rtoti
srrtff +{rqTsdr qgm-rfiilq.q$r} *.BiRt
r
(i)
onf enr
(iii)
wr t[-d*r
(ii) ffiq
s1{e qarer} t
siltrfi.Ft"ftrD wr
*i t t q+orqr+.eqrfiq t
All
(i)
(ii)
(iii)
XeF,
(ii)
BrF3
tlqa +1H
'rr-rr :'
23' (a)
fori
+ ffi
BlT
qErqT
r{ :tu} +
erftryilqur
fri *qtfi*
slgfi'-lts'g-trflur{H
(associated)
56tU2
[P.T.O.
(i)
Sb(V)
(i0
- pqs?r Blrs*rt
- Nqqe
slrcr*r
zS.
erfrrog+mt
(0
(ii)
(iii)
(i)
q5f6 + ffT{it
(ii) WPm.
(iii)
(i)
* ffi
firdrqqi q{r+
Gftdtcq Hr *e
ffi ry
q?15rr6' sT rIiT
flar}
*'em *'sq {
patient.
(ii)
(iii)
---+
So2(g; + Cl2G)
nftq sffisrqEq:
+T
rdtr
g{q/s-1
lrfiilqrfl{rg{r*T
0.4
100
0.7
ftniErqnskd*tki
(1og 4
=0.6021, log2=0.3010)
The following data were obtained during the first order thermal decomposition of
SO2C/2 at a constant volume :
sorC/r(s)
Experiment
Time/s-l
Total pressure/atm
0.4
100
0.7
56ltt2
27.
(i)
fuq f*aiffi st
qr+r
(i)
(ii)
(iii)
28. (a)
D-.Wts *'Br, wr
(i)
\-/ /
(ii)
(iii)
312
+HzN_ _oH
t_fO
H*,
cH3cooH
cl2lP
(i)
A;+ditsefudeltrre+q
(ii)
q}++m
o*{v}Erh
gNErT
(a)
er#q.norlarri:
(i)
t CH3CHo e*roffit
(,
qrq5-fEnffi{
(ii)
tretm
(iii)
(a)
{qr{
orBrhqr
213
(i)
(ii)
(iii)
(b)
*ffi
s{rtqfi
CEo
+H:N-oH H*,
cbtP
' z-
--+
compounds:
(i)
(ii)
OR
561u2
tP.T.O.
(a)
(i)
(i0
O)
29. (a)
(i)
(ii)
213
molar conductivity)
6r KC/ rrn di
o.oz fr6 1-t
+ KC/ + fumr{ +t {qretqmr et{ d6{ {qr*,iTr qfi$ftrd
KC/ futrq{ sl fqriame{r t.29 x 10-2 o-r cm-l d*
qrquT
rr
qiH
r 0.1
dfi
rr
gTqETT
(a) lrrt q;r *qF rqqerT (electrolysis) s'r !6f,T ffiq fut
q qqufrn q'{i +
H tffi+ W
I qEF
+m go2+ sryq$ *t cu
(a)
(i)
(ii)
(b)
Resistance of a conductivity cell filled with 0.1 mol L-l KCI solution is 100 Q.
KCI solution is
If the resistance of the same cell when filled with 0.02 mol
520 dr, calculate the conductivity and molar conductivity of 0.02 mol L-1 KC/
Cl-l cm-l.
solution. The conductivity of 0.1 mol L-l KC/ solution is 1.29 x
tr
lla
OR
(a)
(b)
State Faraday's first law of elecrolysis. How much charge in terms of Faraday is
required for the reduction of 1 mol of Cu2+ to Cu.
at298K:
F = 96500 C mol-l1
10
30. (a)
enq
q{r+
213
(b) qrqurflnrr*:
s[st{t
(i)
(ii)
3d
wI
q{rfdr
3d qd'cT
(iii) cf*
}t
=nq
fuii qt srfri-*-dq
sffi
srdtrTr(
eil{ Mn3+
+2
rq-d 6'{frr
sfu
ffi
t..'erff
t r .r tm
*it t
erYreii r
effi3uq
rqrqr
ffi yfirc t
MnOa+8[I++5e-+
(a)
(i)
(ii)
(b)
(i)
(ii)
(iii)
(0
(ii)
Which transition metal of 3d series has positive Eo(M2+6'4) value and why
(iii) Out of Cf+ and Mn3+, which is a stronger oxidizing agent and why ?
(iv) Name a member of the lanthanoid series which is well known to exhibit +2
oxidation state.
(v)
MnOa+8H++5e-+
56tU2
1I