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Series : OSR/I
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Code number given on the right hand side of the question paper should be written on the
title page of the answer-book by the candidate.
Please check that this question paper contains 30 questions.
Please write down the Serial Number of the question before attempting it.
15 minutes time has been allotted to read this question paper. The question paper will be
disfibuted at 10.15 a.m. From 10.15 a.m. to 10.30 a.m,, the students will only read the
question paper and will not write any answer on the answer-book during this period.
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CHEMISTRY (Theory)
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Timeallowed:3hours
t MaximumMarks:7O
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(i)
wtlsw efqqzii
(ii)
erqr*
(v)
(vi)
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lP.T.O.
General Instructions
(v)
1.'qfl
i[
{H
Give one example each of 'oil in water' and 'water in oil' emulsion.
2.
foqfaaWns*qiw*sirg.t*ir{stHfu+Hqiq+ qqq'{*,,srnrq}rfuqrqmrt?
Which reducing agent is employed to get copper from the leached low grade copper
ore ?
3.
frTq
oi{
[co(en)r]3+
4.
rq dFIfi.Hr IUPAC
{-IT
ImK+
cHr-cH-cHr-COOH
I
OH
Write the IUPAC name of the compound.
cHr-cH-cHr-COOH
I
OH
5.
Eq oTrqtqti 6*rn-emuHiy +
st{ rn qftrm'qru{vflE t r
6.
56tUt
xr di t' r
7.
fiffi dffi
q+
qr+{ Tr*
C6H5NH2,
8.
d +qi
st'il ii + frt{ qI
EreT
ii
ffi
t}or
tt
9.
ll.2
gcm-3
(Na = 6'022
1023
ff
{ HEr
2
fr6-t;
10. qfi M
A+ B- A+ BB-OB-A+BA+B-A+0A+
B- A+ B- A+
(i)
(ii1
ffi :
A+
B_
Es fum Enr
(ii) Es iq
+{
tx-w)
HT
tr
A+ B- A+ BB-OB-A+B_
A+B-A+0A+
B- A+ B- A+
A+
B-
(i)
(ii)
(iii)
$fltfi
IP.T.O.
n.
dtrr
rTHr
6t 75 g ffi{
futr.
t2.
sil{{s*l*tttrofuqtsdr fttrd
gof
3.
aflItrqr *'
*q
(order)
ett E{r*t
srTurErfi
ftfui t
14.
urEeif
(i)
*.yilqr *t
=f*
(*)
'
(i0 altffifrfti
Outline the principles behind the refining of metals by the following methods
Zone refining method
(i)
(ii)
15.
ga
Chromatographicmethod
q-ssfipn{r+dr{"if e} Trr *t
CarPr+ HrO ->
(i)
(ii) Cu + HrSOo{utO ->
g[?rdlT
fiTE{
(i)
(ii)
'1w
(i)
(i0
C\Pz+ HrO -+
Cu + HrSOo(conc.) -+
OR
Arrange the following in the order of property indicated against each set :
(i) HF, HCr, HBr, HI - increasing bond dissociation enthalpy.
(ii) H2O, H2S, HrSe, HrTe - increasing acidic character.
16.
tt
fud
Write the IUPAC name of the complex [Cr(NH)aCl21+. What type of isomerism does
it exhibit ?
L7
. (i)
(ii)
fua
gr t qir qr tka
nnBr
(a)
Frrr ftxftrqt
(i)
i-ifl{ststiT
a;
{ s*t *r s*z { t
nA \n
reaction ?
Brl
(ii)
(a)
(i)
(ii)
(b)
(a)
(b)
18. frq {
Br
Inversionofconfiguration
Racemisation
o_ou
qtritd
so%,
31q1q6t
O-cHz-cH:cH'+1*'
i{{fir
ffi'
Draw the structure of major monohalo product in each of the following reactions
(i)
(ii)
O-ou
GcHz
s9c4
'
Peroxide'
ulq qruT q{
Nt +
qftNilsrur
+ fu+ qqio.{ur
O)
(c)
S6lUt
tp.T.O.
(i)
(i0
qfrH
XeOFo
H2so4
2t.
flqr{+'ERor
(0
PC/3
(ii)
HC/
frfiri
(covalent)
(i)
(ii)
(iii)
22.
fury
The two O-O bond lengths in the ozone molecule are equal.
sOrC/r(e)---+
itFrrr gfi5} ,{Iqt 6g :
SO2(g) + C/2(B)
rqTTT
IITrt/s-1
Ftraqrqrdqrilrgfr
r00
0.4
0.7
+rflFniq,,qfi$ftrd+tH
(1og 4 =
---+
SO2( 91
frst
+ Cl2G)
Experiment
Time/s-1
Total pressure/atm
0.4
100
0.7
23.
(i)
edqq Hqq
+H
gi
En+
24.
Wq
(asparrame) mr
*'qi
{H
ortr$Efui
tro'rftflqm
(i)
(ii)
(iii)
(i)
F*q frErirr
(iii)
(iii)
tr
HI
*t
+.+
qintrt
(i)
(ii)
25.
sqrcrur
n-t*ilq
q?n
I q6 flsqr
tt fre-or
tt
r
r6ts *t {rfir }
qry*1
il wr
3
HI gives
it
+ &ii w +s'Hrr qr+ *'sqrfr, \rs'q'd + BTrt + T6 fiTUiq fuqr t*,'q6 ialril si
qkflERuT eil{ q${r tfr qr
+ ftif + gqtTlq t qt{d qtt r Eu rSqqr q+ erftrs. ulTI*
"FTrfisr
ffir+ + fu+ sdl'+ ESt q.if *'qrq flqffir{ +d H oilr Edli qM H qdt, eqq
qA dt r qct urit + yur tsqr fu q5r r* fti
5-sr-rqTtf etk Miza {fit { $rrs +
gtkotrs++Hq6teTrfir*.+q?if q,rfult-rfi r
raTrftar
(0
orii rro wr rt
(ii) ffi
Erdrq
rri
{g?rqr NFftqg
* srr t
Hr d+ S r q+*rtroe+etur
(condensation)
frfrq{ t
After the ban on plastic bags, students of one school decided to make the people aware
of the harmful effects of plastic bags on environment and Yamuna River. To make the
awareness more impactful, they organized rally by joining hands with other schools
and distributed paper bags to vegetable vendors, shopkeepers and departmental stores.
All students pledged not to use polythene bags in future to save Yamuna River.
'
(i)
(ii)
(iii)
56lut
!P.T.O.
srftfuqr +t ffdEfu
ffi
(b)
(i) cHrnrI$eLiA&,nffic
(ii) cH3cooH+L o Brr+KoHr, CHC/r+NaoH
A
ETSr{T
fql{qfig+{er$Hqr(,t t
(i)
rrtnffimrtFr*rtt,
(ii) q+iEq,,oIRttF'I*ffi{,
(iii)
tFffihmr
N-ffi{'qqqr{sii,
ffi
r;
(i)
cHrBr KCN>R
LilHor"ffi"
(i)
(ii)
(iii)
AnilineintoN-phenylethanamide
(Write the chemical equations involved.)
56lllt .,)
28. (a)
fiTqqqistqfr{rqrtffi:
(i) dtrd fu{{qrdffidr (Limiting molar conductivity)
2,3
SNTET
(a) N
ii
ur
s{qErfrrfr
q,{+
+ftr+
ffi
Wq?st
qs'dm
et onqsqqmr &fr t
gu2+
Effi qt Cu
(a)
Ei"u = +2.71V,
(i)
(ii)
O)
F = 96500 C mol-l1
Resistance of a conductivity cell filled with 0.1 mol L-r KC/ solution is 100 O.
KC, solution is
If the resistance of the same cell when filled with 0.02 mol
520 d2, calculate the conductivity and molar conductivity of 0.02 mol I;1 KCI
solution. The conductivity of 0.1 mol L-l KC/ solution is 1.29 x 10-2 (l-1 cm-I.
I;l
OR
(a)
State Faraday's
O)
at298K
F = 96500 C mol
1]
2,rr
O) qrorleri:
qq{t
56tU1
[P.T.O.
(i)
3d q,l' *'nq
*il q{rfdr r
sT
flr
.rr
tsr
(ii) 3d q{ or q*q qr {iffi'qur srq Eo(M2+[vI) s'r ffinrrs-qFr rEl-fri t etk eii z
(iii)
(iv) d++rggqri*'ssntrsrilqkr**
+2
effi3qm
rrytErffi*'Hyfirct
(v) w{qtfi{q*}Trrft1H:
MnOa+8H++5e----+
(a)
(,
(ii)
(b)
(0
(i0
(iii)
?
?
(i)
(i0
(iii)
(iv)
(v)
which transition metal of 3d series has positive E"(M2+714) value and why ?
Out of Cr3+ and Mn3*, which is a sffonger oxidizing agent and why
MnOa+8H++5e---+
30. (a)
rq s{futsqroTt61ryme ftrri
(i)
(ii)
Ctro
2 C6H5CHO +
312
-H.N_oH H*,
qrq
. NaOH
----+
(i)
(ii)
sre {r$qt{s'Tfti"r
++d-ons$ki;+{+.sirr{
nit+Ft stTsiH{
OPFTT
56tUt
10
ful
(a) w+-*,nqfui'
(i)
t curcno erftm.fuqrvftm t
(i0 ffi,FT +16n { olqtffim erra erftr*-mrfi {FT rtm t
(b) B*1 ;1wnt s{fuf{rqrcTf +'ffi ttrflqFffi qtsr,r ffi
(i) qriF-tser{ sTrlqgr
HCN
(ii) Nm{qr{
(ii1
(a)
+M sfirt*ur
213
(i) (-)-o
+H2N_oH H:
\,_J
(ii) 2 C6H'CHO + conc. NaOH->
(iio cH3cooH cl2lP
(b)
>
compounds:
(i)
(ii)
OR
(a)
(i)
(ii)
(b)
(ii) Aldolcondensation
(iii) Cannizzaroreaction
56tUt
11