Aiot Main Xii Syllabus Paper Code 0 19 01 2014 PDF

4.
If x1 and x2 are solutions for x in quadratic
PART-A
1
2
equation x 2 sin ! 1 x cos2 ! 0, then
SECTION - I
Straight Objective Type
This section contains 27 questions. Each
question has 4 choices (1), (2), (3) and (4) for
its answer, out of which ONLY ONE is correct.
maximum value of x12 x22 is equal to

(1) 2
(2) 3
9
4
(4) 4
(3)
1. Let P be a point on y = x2. If normal at P meets

parabola again at Q then minimum length of
PQ is
27
(1)
4
5. The mean and variance of a binomial

distribution are 30 and 5 respectively. The
probability of two successes is
3 3
(2)
2
(1)
(3) 2 3
875
6 34
(4) 18
(2)
2. A line L with slope 2 cuts parabola y2 = 8x to
875
2.6 34
form a chord. If mid-point of chord lies on x = 4

then equation of line L is
(3)
(1) y = 2x 6
(2) x = 2y 6
(3) 2x + y = 6
(4) x 2y = 6
875
636
34
5 1
6 6
(4) 36C2
3. If f(x) is a non constant differentiable function
x
such that (f(x)) 1947 =
1946
(f (t ))
1857
157
1947
(3) 0
then
6. The order of differential equation of family of

circles passing through intersection of
L 3x + 4y 7 = 0 and Sx2 + y22x2y + 1= 0
f(2014) =
(1)
dt ,
is
(2)
2013
2014
1857
(4)
1947
(1) 1
(2) 2
(3) 3
(4) 4
(SPACE FOR ROUGH WORK)
RESONANCE
AIOTXIIMAIN190114C0 - 1
7. Let ABCD be a square with A(0, 0), C(2, 2). If
10. The equation of plane through intersection of
M is mid point of AB and P is a variable point
the planes x + 2y + z 1 = 0 and
on BC. The smallest value of DP + PM is

(1) 13
(2)
(3) 2 3
(4) 1 + 2 2
2x + y + 3z 2 = 0 and perpendicular to plane

x + y + z = 1 is
2 5
(1) x + 4y 3z + 1 = 0
(2) x 4y + 3z 1 = 0
(3) x 4y + 3z = 0
8. An office employs thirty people. Five of them
(4) x + 4y 3z = 0
speak Sanskrit, Hindi, English. Nine speak

Sanskrit, English. Twenty speak Hindi of which
11. A man running round a race course notes that
twelve also speak Sanskrit. Eighteen speak
the sum of the distance of two flag posts
English. No one speak only Sanskrit. An

employee selected at random is known to
from him is always 10 meters and distance

between the flag posts is 8 meters. The area
speak either Hindi or English, the probability

that employee speaks only two of three
of the path he encloses in square meters is

(1) 15
languages is
(1) 14/15
(2) 7/15
(3) 1/6
(4) 5/6
(2) 12
(3) 18
(4) 8
9. ABC is vertical tower such that AB = BC = x.

Form the foot A of the tower, a horizontal line
12. Let H be a set of hyperbolas. If a relation R on

H be defined by
AQP is drawn. If the angle of elevation of the

point B from P is and that of C from Q is 2,
then AP, x, PQ are in
(1) A.P.
(2) G.P.
(3) H.P.
(4) None of these
R = {(h 1, h 2) : h 1, h 2 have same pair of

asymptotes, h1, h2 H}, then the relation R is
(1) reflexive and symmetric but not transitive
(2) symmetric and transitive but not reflexive
(3) reflexive and transitive but not symmetric
(4) Equivalence relation
RESONANCE
13. Let =
1 i 3
, and ,, 1, 2,.....,8 be
2
/6
16. Let I =
cos x
dx, J
x
/2
/3
cos x
dx . Which of
x
roots of equation x10 + ax + b = 0, where

i j, i j value of ( 1) ( 2).....( 8)
the following is CORRECT ?
=
(1) I <
, J<
6
6
(2) I >
, J<
6
6
(1) 90 2
(2) 10C2 2
(3) 10 + a
(4) 0
14. If A = {1, 2, 3, 4} then which of the following are
(3) I <
, J>
6
6
(4) I >
, J>
6
6
functions from A to itself ?

(1) f1 = {(x, y) : y = x + 1}
(2) f2 = {(x, y) : x + y > 4}
(3) f3 = {(x, y): x < y}
17. If x1 and x2 are the real and distinct roots of
(4) f4 = {(x, y) : x + y = 5}
ax2 + bx + c = 0, then
15. Let p be the statement "Ram races", q be the
statement "Ram wins". The statement
L im 1 sin ax 2 bx c
x x1
1
x x1
is equal to
~(p ~q) is :
(1) Ram does not race and Ram does not win.
(1) e x1 x2
(2) It is not true that Ram races or Ram does

(2) e x2 x1
not win.
(3) Ram does not race and Ram wins
a x x
(3) e 1 2
(4) It is not true that Ram races and Ram does

not win.
(4) ea x2 x1
RESONANCE
20. Number of acute angles such that
18. Let p,q be real numbers such that p q = 1

cos cos2 cos4 =
1
then
2
and 0 < p
(1) p +
1
1 2 1 3
1 2
p + p + ..... = q
q + q3
3
3
2
2
1
are
8
(1) 1
(2) 2
(3) 3
(4) 4
21. The smallest positive integer n such that

1 4
q + ....
4
11n 1 is divisible by 100 is :
1 2 1 3 1 4
1 2
(2) p
p + p
p +.... = q +
q
3
2
4
2
1 3
1 4
q +
q + ....
3
4
(1) 4
(2) 5
(3) 10
(4) 11
22. The integral curve of equation xdy ydx = ydy,

intersects the y-axis at (0, 1) and the line y = e
(3) p +
p3
q 2 q3
p2
q4
+
+ .... = q
3!
2! 3!
2!
4!
1
1 2
1 4
p + p3
p + ..... = q
3
2
4
q 2 q3 q 4
+ .....
2!
3!
4!
(1) 0
(2) 1
+ .....
(4) p
at (a, b). The value of a + b =
(3) 2e
(4) e
23. A variable line ax + by + c = 0, where a, b, c

are in A.P., is normal to a circle
/2
19.
x dx
1 sin x
(1) n2 + /4
(x )2 + (y )2 = , which is orthogonal to
circle x2 + y2 4x 4y 1 = 0. The value of
+ + is equal to :
(1) 3
(2) n2 /4
(2) 5
(3) 1 + /2 + n2
(3) 10
(4) n2
(4) 7
RESONANCE
24. Let A = [a ij ] 33 , B = [b ij ] 33 such that

a ij =a ji,b ij =b ji. W hich of the following is
SECTION - II
CORRECT ?
Reasoning Type
(1) AB is symmetric matrix
This section contains 3 reasoning type
(2) |A| = 0 and |B| 0
questions. Each question has 4 choices (1),
(3) If aij = bij for i < j then C = A + B is necessarily
(2), (3) and (4), out of which ONLY ONE is
an upper triangular matrix.
correct.
(4) If aij = bij for i < j and C = A + B, then |C| = |A|.

25. If
a i j k, b i j k, c i 2j k,
then
28. Let n 3. A list of numbers 0 < x1 < x2 < ... < xn

has mean and standard deviation . A new
a.a
a.b
a .c
list of numbers is made as follows : y1 = 0,
value of b . a b . b b . c =
c.a
c.b
y2 = x2, ....,yn1 = xn1, yn = x1 + xn. The mean
c .c
and the standard deviation of the new list are

(1) 16
(2) 24
(3) 256
(4) 144
and .
Statement-1 : and =
26. Number of sequences of a's and b's of length
20 having all consecutive a's or all consecutive
Statement-2 : Variance is independent of
b's or both are :
choice of origin while mean dependent on
(1)
20
C2
choice of origin.
(2) 2 20C2
(1) Statement -1 is True, Statement -2 is True;
(3) 20C2 + 2
Statement -2 is a correct explanation for
(4) 382
27. The equation of latus rectum of the rectangular
hyperbola xy = c2 is
(1) x y = 2c +
2 c, c > 0
(2) x + y = 2c + 2 2c, c 0
Statement -1
(2) Statement-1 is True, Statement-2 is True;
Statement-2 is NOT a correct
explanation for Statement-1
(3) Statement -1 is True, Statement -2 is False
(3) x + y = c +
2c, c 0
(4) Statement -1 is False, Statement -2 is True
(4) x + y = 2 2 c
RESONANCE
29. Statement- 1 : A vector in xy plane through
30. Let f(x) = sin x + cos x + tan x + sin1x + tan1x
origin and perpendicular to vector 4 i 3 j k

Statement- 1 : If p and q are maximum and
is parallel to (3 i 4j)
minimum values of f(x) then
Statement- 2 : A vector in plane of
pq
3
= sin1 + tan 1 +
2
4
non-colinear vectors a , b and perpendicular

to vector c is parallel to (a b) c .
Statement- 2 : If y = g(x) is strictly monotonic

increasing on x [a, b] then minimum value
of y is g(a) and maximum value of y is g(b).

Statement -1

Statement -1
(2) Statement-1 is True, Statement-2 is True ;

Statement-2 is NOT a correct explanation

Statement-2 is NOT a correct explanation
for Statement-1
for Statement-1

RESONANCE
32. A system of three large parallel conducting
PART-B
plates 1, 2 and 3 are shown in figure, charge

on middle plate is Q. Plate 1 and plate 3 are
SECTION - I
connected with conducting wire and switch S
and initially plate 1 and plate 3 are neutral. After
This section contains 28 multiple choice

questions. Each question has choices (1),
closing switch S which of the following option

is correct -
(2), (3) and (4) out of which ONLY ONE is

correct.
1
31. A solid sphere of mass 2 kg and density
2 Q
air
3
air
105 kg/m3 hanging from a string is lowered into

a vessel of uniform cross-section area 10 m2
b
S
containing a liquid of density 0.5 x 105 kg/m3,

until it is fully immersed. The increase in
pressure of liquid at the base of the vessel is
(Assume liquid does not spills out of the vessel
and take g = 10 m/s2)
(1) 2 N/m2
(2) 1N/m2
(1) Charge at right surface of plate 2 is
Qa
ab
(2) Magnitude of charge at right surface of
plate 1 is
Qb
ab
(3) 4 N/m2
(3) Total charge of the system is Q
1
(4)
N/m2
2
(4) All the above options are correct
RESONANCE
AIOTXIIMAIN190114C0- 7
33. A particle moves along a constant curvature

path between A and B (length of curve wire AB
is 100m) with a constant speed of 72 km/hr.
The acceleration of particle at mid point C of
35. A uniform solid sphere of mass m1 is placed

on the plank of mass m2 and the coefficient of
friction between the plank and sphere is If
the inclined plane is frictionless then frictional
curve AB is :
force on m1 is (Assume that the plank and

uniform solid sphere are released on the
inclined plane from rest)

C
vA
B
45
vB
m
1
m
(1) Zero
(2) 3.14 m/s
(3) 50.84 m/s2

(4) 50.84 km/hr2
34. The locus of all the points on the x - y plane
(1) parallel to the incline plane upwards.
about which the moment of inertia of the

uniform rod (axes perpendicular to xy-plane)
shown in figure, is same as that about axis
(2) parallel to the incline plane downwards.
perpendicular to rod and passing through point

O is :
(3) Zero
(4) 0 < f < m1gcos
(1) circle
(2) parabola
(3) straight line
(4) ellipse
RESONANCE
36. A massless piston connected to a spring of
37. In a damped oscillator the amplitude of
spring constant k fits smoothly inside an L

shaped fixed glass tube as shown in the figure.
vibrations of mass m = 150 grams falls by
1
e
The piston can slide without friction and without
times of its initial value in time t0 due to viscous
leakage of water. The cross sectional area of
forces. The time t0 and the percentage loss in
the tube is s and the density of the liquid is .
mechanical energy during the above time
If the system is slightly disturbed from its
interval t 0 respectively are (Let damping
equilibrium position then the angular frequency

of its small oscillations is: (m is the total mass
constant be 50 grams/s
(1) 6s,
e2 1
100
e2
(2) 3s,
e2 1
100
e2
(3) 6s,
e 1
100
e
(4) 3s,
e 1
100
e
of liquid and the liquid is ideal)
38. A circular coil is placed in a uniform but time

varrying magnetic field as shown in figure. Then
which of the following is correct statement :
(1)
2sg
+
m
k
m
(1) A variable current flows from 'A' to 'B' in the

(2)
sg
+
m
k
m
lower half of ring

(2) A variable current flows from 'B' to 'A' in the
lower half of ring
(3)
k 2sg
m
(3) A constant current flows from 'A' to 'B' in

the lower half of ring
(4) A constant current flows from 'B' to 'A' in
(4)
k sg
m
the lower half of ring

RESONANCE
39. The distance moved by the screw of a screw

gauge is 2 mm in four rotations and there are
42. A carnot refrigeration cycle absorbs heat at

270 K and rejects heat at 300 K. If the cycle is
50 divisions on its cap. When nothing is put

between its jaws, 30th division of circular scale
absorbing 1260 KJ/min at 270 K, then work
coincides with reference line, with zero of
required per second is :
circular scale lying above the reference line.
(1) 2.33 KJ/sec.
When a plate is placed between the jaws, main

scale reads 2 division and circular scale reads
(2) 4.66 KJ/sec.
20 division. Thickness of plate is :
(3) 1 KJ/sec.
(1) 1.5 mm
(2) 1.2 mm
(4) 4 KJ/sec.
(3) 1.4 mm
(4) 1.6 mm
40. Two stars at a distance 20 light years are

viewed through a telescope having a lens of
20 cm diameter. Then the minimum separation
of these stars for which they appears
distinguishable is ( = 6000 ) ) :
(1) 7.32 105 light years
43. The radius of the orbit of an electron in a

Hydrogen-like atom is 3 a0, where a0 is the Bohr
radius. Its orbital angular momentum is
3h
. It
2
is given that h is Plancks constant and R is
Rydberg constant. The possible wavelength,
when the atom de-excites is :
(4) None of these

41. A car is moving towards an approaching bike.
(1)
4
5R
(2)
4
9R
(3)
1
2R
Bike is moving with velocity 30 m/s. Frequency

of horn sounded by car is 100 Hz, while it is
observed by bike rider as 120 Hz. The actual
duration of horn is 6 sec. Find the time interval
for which the bike rider hears it. (Take velocity
of sound in air as 330 m/s)
(1) 5 sec
(2) 6 sec
(3) 7 sec
(4) Cannot be calculate with given information
(4) 32 R
RESONANCE
44. A particle leaves the origin at t = 0 with an initial
velocity v 3v 0 i . It experiences a constant
acceleration a 2a1i 5a2j . The time at which
46. Line PQ is parallel to y-axis and moment of

inertia of a rigid body about PQ line is given by
I = 2x2 12x + 27, where x is in meter and I is
in kg-m2. The minimum value of is :
the particle reaches its maximum x coordinate

is (a1, a2 & v0 are positive number)
3 V0
(1) 10a
2
3 V0
(2) 9a 5a
1
2
3 V0
(3) 2a
1
3 V0
(4) 2a 5a
1
2
(1) 27 kg m2
(2) 11 kg m2
45. A man beats drum at a certain distance from

a large mountain. He slowly increases the
(3) 17 kg m2
(4) 9 kg m2
rate of beating and finds that the echo is not

heard distinctly, when the drum beating is at
47. A ring of mass m and radius R is rolling without
the rate of 40 per minute. He moves by
sliding on a flat fixed horizontal surface, with a
80 meter towards the mountain and finds that
constant angular velocity. The angle between
the echo is again not heard distinctly, when
the velocity and acceleration vectors of a point
the rate of beating of the drum is 1 per
P on the rim of the ring at the same horizontal
second. What is the initial distance of the
level as the centre of the ring may be -
man from the mountain ?
(1) zero
(1) 120 m
(2) 90
(2) 240 m
(3) 135
(3) 270 m
(4) tan11/2
(4) 340 m
RESONANCE
48. In a series RC circuit shown in figure applied
50. A light inelastic thread passes over a small
voltage is 10 V and voltage across capacitor is
frictionless pulley. Two blocks of masses
found to be 8 V. Then voltage across R and

phase difference between current and applied
voltage respectively will be
m = 1 kg and M = 3 kg are attached with the

thread and heavy block rests on a surface. A
particle P of mass 1 kg moving upward with a
velocity 10 m/s collides with the lighter block
elastically at t = 0. (g = 10 m/s2). Choose the
incorrect option :
(1) 6V, tan-1 3
(2) 3V, tan-1 4

(3) 6V, tan-1 3

(4) 2V, tan-1(1)
49. The electric field of a plane electromagnetic

wave in vacuum is
8
Ey = 0.5 cos 2 10 t c V/m; Ez = Ex = 0.
Then select correct alternative.
(1) Direction of propagation of wave is along

+ve x-axis
(1) Velocity with which heavy block is jerked

into motion is 2.5 m/s
(2) Maximum height ascended by heavy block
after it is jerked into motion is 0.625 m
(3) Impulse of tension in jerk is 7.5 Ns
(2) Plane of polarization is x-y plane

(3) Amplitude of magnetic field is 1.66 109 T
(4) Time after which block again strikes the
(4) All of above
surface is 2.5 s
RESONANCE
51. In the circuit shown in figure, the current gain
54. A metallic uniform rod PQ is hinged at point P
= 100 for a npn transistor. The bias
and it can rotate about point P in vertical plane
resistance RB so that VCE = 5V is (VBE << 10 V)
and an infinite long wire AB having current i1 is

placed as shown in the figure. If the mass of
rod is m and length L, then the current i2 in rod
PQ such that it remains in equilibrium as
shown is (separation between P and current
carrying wire AB is very small) (consider gravity)
(1) 2 103
(2) 105
(3) 2 105
(4) 5 105
2mg
52. A point mass M is placed at a distance d
(1) i
01
mg
(2) 2 i
01
from infinite sheet. The magnitude of

gravitational flux through the sheet is :
(1) 2 GM
(2) 4 GM
(3) 3 GM
(4) GM
mg
(3) 4 i
01
mg
(4) i
01
55. Maximum deviation occurs in a prism of

53. The activity of radioactive sample is measured
refracting angle A1 and having critical angle of
as 9750 counts per minute at t = 0, and
its material as A2, when the angle of incidence
975 counts per minute at t = 5 minutes. The
is -
decay constant approximately is :

(1) 0.230 per minute
sin( A 1 A 2 )
1 sin A 2
(2) sin
sin
A
1
sin A 1
1
(1) sin

sin A
1
1
(3) sin sin A
2
sin( A 1 A 2 )
sin A 2
1
(4) sin
RESONANCE
56. Water, having positive ions of charge +e
57. A slightly conical wire of length L and radii a
dissolved in it with concentration c (Number of
and b is stretched by two forces each of
ions/volume), falls from a tube of cross

sectional area a with a speed v in a sieve
such that water is not retained in the sieve. The
value of
B. d integrated over the upper
magnitude F, applied parallel to its length in

opposite directions and normal to end faces. If
Y denotes the Youngs modulus, then the
extension produced is :
circular part of the sieve will be : [ B indicates

the magnetic field produced by Na+ ions and
d is along the tangent on the periphery of
circular part of the sieve].
FL
(1) (a 2 b 2 ) Y
circular upper part

FL
sieve
(2) (a 2 b 2 ) Y
(3)
FL
abY
(1) avce
(2) avce
(3) ace/v
(4) None of these
(4) /avce
RESONANCE
58. A drop of liquid of surface tension is in

between the two smooth parallel glass plates
held at a distance d apart from each other in
zero gravity. The liquid wets the plate so that
the drop is a cylinder of diameter D with its
59. Statement-1: For the situation shown in the

figure two monochromatic identical coherent
light sources produce interference pattern on
the screen. The intensity of minima nearest
to S1 is not exactly zero.
curved surface at right angles to both the plates.

Determine the force acting on each of the
plates from drops under the following
considerations.
Statement-2 : Minimum intensity is zero when
interfering waves have same intensity at the
location of super position.
Statement-2 is a correct explanation for
Statement-1.
(1)
D
2
(2)
2D
2

Statement-2 is NOT a correct explanation for
Statement-1
(3) Statement-1 is True, Statement-2 is False
(4) Statement-1 is False, Statement-2 is True
(3) zero
60. Statement-1 : Centre of gravity and centre
of mass have same physical meaning.
(4) None of these
Statement-2 : In uniform gravitational field,

centre of mass and centre of gravity are at
the same point.
SECTION - II
Reasoning Type
This section contains 2 reasoning type
questions. Each question has 4 choices (1),
(2), (3) and (4), out of which ONLY ONE is
correct.

Statement-2 is a correct explanation for
Statement-1.
Statement-2 is NOT a correct explanation for
Statement-1
(3) Statement-1 is True, Statement-2 is False
(4) Statement-1 is False, Statement-2 is True
RESONANCE
PART- C
Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24,
Al = 27, Si = 28, P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5,
Zn = 65, As = 75, Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]
SECTION
This section contains 30 questions. Each question has four choices (1), (2), (3) and (4) for its
answer, out of which ONLY ONE is correct.
61. A solution is prepared by urea and water. If mole

fraction of water is 0.8 in the solution. Find the
ratio of mass of urea & water.
62. Following graph shows the releation between
and C where is the osmotic pressure,

RT
T is temperature in K, R is gas constant and C

5
(1)
6
is molarity of solute. Given that solute Y neither

dissociates nor polymerises in solution. Identify
the incorrect statement
(i - Van't Hoff factor : M Molar mass).
(2)
6
5
(3)
1
1
(4)
4
1
(1) iX < 1 and iZ > 1

(2) iX > 1 and iZ < 1
(3) MABNORMAL MNORMAL
for Y & X
(4) MABNORMAL MNORMAL
for Y & Z
RESONANCE
63. For the electrons of oxygen atom, which of the
66. Which of the following statement is correct?
following statements is correct ?
(1) SS bond is present in H2S2O6.
(1) Zeff for an electron in a 2s orbital is the
(2) In peroxosulphuric acid (H2SO5) sulphur is
same as Zeff for an electron in a 2p orbital.

(2) An electron in the 2s orbital has the same
in +8 oxidation state.
(3) Copper powder along with Al2O3 and K2O
energy as an electron in the 2p orbital.
is used as a catalyst in the preparation of

NH3 by Habers process.
(3) Zeff for an electron in a 1s orbital is the

same as Zeff for an electron in a 2s orbital.
(4) Change in enthalpy is positive for the
(4) The two electrons present in the 2s orbital
preparation of SO3 by catalytic oxidation

of SO2.
have different spin quantum numbers (ms).

64. Decomposition of A follows first order kinetics
67. Steam undergoes decomposition at high

temperature as per the reaction
by the following equation.
H2O(g)
and after 10 minutes it is found to be 650 mm
The temperature at which equilibrium constant
of Hg. What is half-life of A ?
is unity is :
(Assume only A is present initially)

(1) 10 mins
(2) 5 mins
(3) 7.5 mins
(4) 15 mins
H2(g) +
1
O (g) ;
2 2
4A(g) B(g) + 2C(g)

If initially, total pressure was 800 mm of Hg
H = 200 kJ mol1, S = 40 kJ mol1.
(1) 3000 Kelvin
(2) 5000 Kelvin
(3) 5333 Kelvin
(4) 5 Kelvin
68. Pure PCl5(g) was placed in a flask at 2 atm

65. Consider the plane shown in the figure:
and left for some time at a certain temp. Where

the following equilibrium was established
PCl5 (g)
. A rock salt (NaCl) lattice is cut
PCl3 (g) + Cl2 (g)
Under the given condition, pure oxygen was

found to effuse 2.084 time faster than the
across this plane in which anions occupy fcc
equilibrium mixture then KP of the above
positions. It passes through centers of how
reaction is :
many cations?
(1) zero
(3) 6
(1)
2
3
(2)
3
2
(3)
4
5
(4)
5
2
(2) 4
(4) 12
RESONANCE
69. M(OH)x has Ksp = 4 x 1012 and solubility
73. In order to refine blister copper it is melted in

furnace and is stirred with green logs of wood
104 M. Hence x is :
(1) 1
(2) 2
(3) 3
(4) 4
. The purpose is:

(1) to expel the dissolved gases in blister
copper.
(2) to reduce the metallic oxide impurities with
70. Borax on heating strongly above its melting
hydrocarbon gases liberated from the
point melts to a liquid, which then solidifies to

a transparent mass commonly known as
wood.
.
(3) to bring the impurities to surface and oxidize

them.
borax-bead. The transparent glassy mass
(4) to increase the carbon content in the
consists of :
copper.
(1) sodium pyroborate
74. The incorrect statement among the following
(2) boric anhydride
is :
(3) sodium meta-borate
(1) beryllium oxide is amphoteric in nature
(4) boric anhydride and sodium metaborate
(2) solubility of sulphates of second group

elements decreases down the group
71. Which of the following is incorrect statement

(3) reducing power of hydride of alkali metal
regarding A = [Co(en)2Cl2]+ and
decreases down the group
B = [Co(NH3)4Cl2]+.
(1) A is more thermodinamically stable than B.
(4) Berylium has diagonal relationship with

alumunium
(2) A shows optical isomerism.

75. The e.m.f. of a cell corresponding to the
(3) A and B both are diamagnetic.
reaction
(4) A is outer orbital complex while B is inner
Zn + 2H+ (aq) Zn2+ (0.1M) + H2(g) (1 atm)
orbital complex.
is 0.169 volt at 25C. Calculate the pH of the

solution at the hydrogen electrode.
72. How many POH bond in pyrophosphoric acid:
EZn2+/Zn = 0.76 volt and EH+/H = 0

2
(1) Two
(2) Three
(1) 9
(2) 11.5
(3) Four
(4) One
(3) 10
(4) 10.5
RESONANCE
76. (I) V2O5, Cr2O3 are amphoteric oxides.
78. The equivalent conductance of 0.01 M solution
(II) Interstitial compounds are very reactive
of weak acid HA is 19.6 S cm2 eq 1. The
(III) In its higher oxidation states, manganese
equivalent conductance of the electrolyte at
forms stable compounds with oxygen and
infinite dilution 392 then pH of the solution will
fluorine.
be :
Correct statements amongs the following are(1) I, II
(2) II, III
(3) I, III
(4) I, II
(1) 2.3
(2) 5
(3) 3.3
(4) 4.7
79. In which of the following pairs the second one

77. Which of the following statements does not
is the stronger base than first ?
correct from the point of view of molecular

(1)
orbital?
(2)
(1) Be2 is not a stable molecule

(2) He2 is not stable but He+ is expected to exist
(3) Bond strength of N2 is maximum amongst
the homonuclear diatomic molecules
(4) The order of energies of molecular orbitals
(3)
(4) CH3NH2, CH3OH
80. When grignard reagent is treated with isopropyl
in O2 molecule is
formate followed by acid hydrolysis we get :
E(2s) < E(*2s) < E(2px) = E(2py) <
(1) Aldehyde
E(2pz) < E(*2px) = E(*2py) < E(*2pz)
(2) 2 alcohol
(3) 3 alcohol
(4) 1 alcohol
RESONANCE
81. Which of the following reactions report the

correct major products ?
I.
O
HCN
82.
NaNO2/H
LiAlH4
(P)
Major
AlCl
+ CH3CH2CH2Cl
Product P will be :
O
II.
aq. AgNO
(1)
(2)
(3)
(4)
83. An optically active aldotetrose which retains its

optical activity with aqueous Br2 but losses it
with conc. HNO3 has the following structure :
III.
Zn
(i)
IV.
CHO
CHO
H
OH
OH
CH2OH
CH2OH
CH3 CH2 CH2 OH

H
CHO
(iii)
CHO
(iv)
CH2OH
(1) I, III
(2) III, IV
(3) II, III, IV
(4) I, III, II
OH
(ii)
CH2OH
(1) i,ii
(2) i,iii
(3) ii, iii
(4) ii,iv
RESONANCE
84. Consider the following sequence of reaction :

PhCOOH
H2/Ni
86. The product of acid hydrolysis of P and Q can

be distinguished by :
D.
The final product D is :

(1) Benzonitrile
(2) Benzylamine
(1) Lucas reagent
(3) Aniline
(2) 2, 4DNP
(4) Benzamide
(3) Fehling solution
(4) NaHCO3
Et ONa / Et OH
85.
H SO /
4
2
[X]
The product [X] is :
87. In which of the following species, the

configuration at the starred atom is changed if
any change in configuration of neighbour atom
is carried out.
(1)
(1)
(2)
(2)
(3)
(3)
(4)
(4)
RESONANCE
88. Which of the following reagent can be used
90. Which of the following statement is incorrect :
for the given conversion :
(1)
is a Z - isomer
(1) LiAlH4
(2) Na / C2H5OH
(2)
has plane of symmetry and
(3) DIBAL-H
(4) NaBH4
89. CH2 = CH O CH3 + CH3OH
traces of HCl ( dry )
P (major)
The product "P" is/are :
centre of symmetry
(3) Only one conformation of ethylene glycol

(HOCH2CH2OH) has centre of symmetry
(4) The gauche form of meso tartaric acid is
chiral
(1) CH3OCH2CH2OCH3
(2) CH3CH=O + CH3OCH3
(3)
(4)
RESONANCE

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4.

If x1 and x2 are solutions for x in quadratic

equation x 2 sin ! 1 x cos2 ! 0, then

maximum value of x12 x22 is equal to

1. Let P be a point on y = x2. If normal at P meets

5. The mean and variance of a binomial

2. A line L with slope 2 cuts parabola y2 = 8x to

form a chord. If mid-point of chord lies on x = 4

such that (f(x)) 1947 =

6. The order of differential equation of family of

7. Let ABCD be a square with A(0, 0), C(2, 2). If

10. The equation of plane through intersection of

M is mid point of AB and P is a variable point

the planes x + 2y + z 1 = 0 and

on BC. The smallest value of DP + PM is

2x + y + 3z 2 = 0 and perpendicular to plane

8. An office employs thirty people. Five of them

speak Sanskrit, Hindi, English. Nine speak

11. A man running round a race course notes that

twelve also speak Sanskrit. Eighteen speak

the sum of the distance of two flag posts

English. No one speak only Sanskrit. An

from him is always 10 meters and distance

speak either Hindi or English, the probability

of the path he encloses in square meters is

9. ABC is vertical tower such that AB = BC = x.

12. Let H be a set of hyperbolas. If a relation R on

AQP is drawn. If the angle of elevation of the

R = {(h 1, h 2) : h 1, h 2 have same pair of

(SPACE FOR ROUGH WORK)

roots of equation x10 + ax + b = 0, where

the following is CORRECT ?

14. If A = {1, 2, 3, 4} then which of the following are

functions from A to itself ?

(2) It is not true that Ram races or Ram does

(4) It is not true that Ram races and Ram does

20. Number of acute angles such that

18. Let p,q be real numbers such that p q = 1

21. The smallest positive integer n such that

11n 1 is divisible by 100 is :

22. The integral curve of equation xdy ydx = ydy,

at (a, b). The value of a + b =

23. A variable line ax + by + c = 0, where a, b, c

24. Let A = [a ij ] 33 , B = [b ij ] 33 such that

(1) AB is symmetric matrix

This section contains 3 reasoning type

(2) |A| = 0 and |B| 0

questions. Each question has 4 choices (1),

(3) If aij = bij for i < j then C = A + B is necessarily

(2), (3) and (4), out of which ONLY ONE is

an upper triangular matrix.

(4) If aij = bij for i < j and C = A + B, then |C| = |A|.

28. Let n 3. A list of numbers 0 < x1 < x2 < ... < xn

list of numbers is made as follows : y1 = 0,

y2 = x2, ....,yn1 = xn1, yn = x1 + xn. The mean

and the standard deviation of the new list are

Statement-2 : Variance is independent of

b's or both are :

choice of origin while mean dependent on

(1) Statement -1 is True, Statement -2 is True;

Statement -2 is a correct explanation for

(4) Statement -1 is False, Statement -2 is True