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ABSTRACT
Cohen, A.D., Raymond, R. Jr., Ramirez, A., Morales, Z. and Ponce, F., 1989. The Changuinola
peat deposit of northwestern Panama: A tropical, back-barrier, peat(coal)-forming environ-
ment. In: P.C. Lyons and B. Alpern (Editors), Peat and Coal: Origin, Facies, and Depositional
Models. Int. J. Coal Geol., 12: 157-192.
A large ( > 82 km 2), thick ( > 8 m), low-ash, low-sulfur peat deposit has formed on the north-
western coast of Panama. Its low ash and low sulfur contents can be attributed partly to: (1)
doming; (2) the occurrence of a relatively continuous, marine-blocking, beach-barrier shoreline
feature; and (3) leaching of the mineral matter. This deposit is roughly rectangular in shape and
oriented with its longest axis parallel to the beach-barrier shoreline. It would produce an economic
coal bed that is bright and finely banded in its thickest central region and more coarsely banded
at its margins. Its northwestern margin would be characterized by interfingering of coal with
sandstone and siltstone of the Changuinola River flood plain, whereas its southeastern boundary
would be characterized by truncation of the upper part of the seam by marine to brackish shales,
siltstones, and carbonates that were derived from Almirante Bay.
Total sulfur was found to be very low (less than 0.2% dry wt.) except in a few places. In these
rare cases, nearly all of the sulfur was pyritic and the total sulfur content was anomalously high
( > 14% ). Although the general tendency was for total sulfur to increase wherever the deposit was
influenced by marine conditions, one case was found where sulfur was high at the base of an inland
freshwater peat core, which suggests either a "hidden" marine influence or the need for some new
mechanism to explain sulfur enrichment in such an anomalous case.
Differences in inherent fixed carbon contents and calorific values due to changes in peat type
and analytical uncertainties tended to mask seamwide trends in these parameters. However, fixed
carbon contents and calorific values showed a slight tendency to increase with depth (especially
if plotted for single peat types).
Vitrinite reflectance within the hypothetical Changuinola coal bed would be expected to in-
crease as follows: (1) toward the margins of the deposit; (2) toward the bottom and top of the
bed; and (3) toward stream channels or tidal inlets.
INTRODUCTION
The primary objective of this research was to assess the potential for the
Changuinola peat deposit of Panama to be used as a fuel for an electrical power
plant. This assessment was completed in 1987 (see Cohen et al., in press, a).
A secondary objective of this research was to gather information that would be
useful in developing a model to predict the characteristics of coal seams that
formed in tropical, back-barrier settings similar to that of the Changuinola
deposit. The results of this secondary objective are reported in this paper.
4% on a dry weight basis over the entire deposit and less than 2.5% ash through
its central region), and very low in sulfur (less than 0.2% over most of the
deposit except for its seaward edges).
".'L
s f" ~ .":i:'~.
L-~,
AS DEL TORO
: :::..: -
BAHIA ALMIRANTE
. - . - ,pA ,e
Fig. 1. Location of sampling sites and sectional profiles, Changuinola Peat Deposit, Changuinola,
Panama.
82045 , 82015 ,
9030: .j' -~,._.~ COSTA R,CA ~. . . . . . . . . . . . . . . . ~ nECEm
k" T., '~I , ~ ~ ~ MIOCENE
9°10
nola (Fig. 1 ). The peat has formed on top of recent unconsolidated sediments
behind (and roughly parallel to) a beach-barrier that extends continuously to
the southeast for about 10 km (Fig. 1 ). Bordering the deposit on the southwest
are the foothills of a mountain range composed of Upper Cretaceous to Eocene
sandstone, shale, and volcanic rocks (Fig. 2 ). Miocene rocks of the Gatun For-
mation outcrop in the low hills closest to the peat deposit and may extend
beneath the unconsolidated Quaternary clastics on which the peat deposit has
developed. These Miocene rocks consist of shale, mudstone, sandstone, coals,
conglomerate, and pyroclastic rocks (Fig. 2 ).
Bahia Almirante (Almirante Bay) borders the deposit to the southeast. Pre-
liminary sampling in the bay near the deposit suggests that remnants of the
peat deposit may have been buried in places beneath the bay sediments by a
transgression of the sea after the peat had formed.
The vegetational and drainage patterns displayed on the aerial photographs
suggest that this deposit is domed in the center. However, the precise surface
geometry has not yet been determined by surveying.
METHODS
Field methods
Laboratory methods
A
NTE
Fig. 3. Isopachous map of the peat deposit at Changuinola, Panama. Peat thickness (cm).
(SW) (NE)
o" :.; ".; :'.~V,:::" o'.-.;.. : 7 - ~ . ".~-~..,,...~.-~: ......... ..... . . . . .. "..,: .~BARR ER, ..., o',,'," ,,
A A'
Fig. 4. Schematic diagram illustrating cross sectional geometry and surface vegetation, Changui-
nola peat deposit, Panama.
Fig. 5. Surface vegetation covering the Changuinola peat deposit. A. Aerial view looking inland (SW) from the Caribbean sea to the mountains
(coincident with A-A' in Fig. 1 ). Note that the treeless central region coincides with the area of thickest peat. B. Closer aerial view of the surface
vegetation in the central region showing the dominance of herbaceous ~egetation and the presence of occasional shrub hammocks. C. Closer vie~
of the surface. Note the scattered clumps of sedges, grasses, and ferns and occasional bare patches where the peat surface is exposed. D. Close-up
of typical surface vegetation in the central region. Dominant plants here are sedges, grasses, ferns, Sagittaria (arrow head plant ). and Spha~mu~i
(peat moss). Insect-eating plants, such as stmdews (Drosera) and bladderworts (Utricutaria), are a~so present.
165
B B'
(NW) (SE)
RIO BAHIA
;HANGUINOLA ALMIRANTE
BDT-5 BDT-20 BDT-14 ~ BDT-3 I
Fig. 6. Schematic longitudinal section (B-B') of the Changuinola peat deposit (not to scale).
covering this wetland region occurs where this primarily freshwater wetland
contacts Bahia Almirante (Fig. 6).
~
MAR i t ..... ~ MAR
ARIBE l ~"~ CARIBE
/
(A) (B)
MAR MAR
CARIBE
, CARIBE
~¢'b.Oel:
+.o~ CQ~<C,'
\
,'OLA0 ~ \.
(c) (o)
E ~ .......................
~--~ OF FRESHWATER PEAT
(E) • CORELOCATIONS
Fig. 7. Hypothetical development of the Changuinola peat deposit. A. Formation of Rio Chan-
guinola Delta and Bahia Changuinola. B. Transgressing sea erodes delta and forms Changuinola
split. C. Restriction of entrance to Bahia Almirante by spit extension. D. Further restriction of
entrance to Bahia Almirante and beginning of freshwater peat formation. E. Most recent marine
transgression begins reopening of entrance to Bahia Almirante and widening of the bay. F. Present
geomorphology of Changuinola area and occurrence of peat.
167
As
A
(SW) (NE)
BDT-1
BDT-22 BDT-20 BDT-12
0.
60' t
t
/
120, i
180,
240
/
/
JY
.,: . ////
3OO
a F
B
(NW) (SE)
BDT-5 BDT-20 BDT- 14 BDT-3
RIO
s ~ / BAHIA
CHANGUINOLA
~ // ~ ALMIRANTE
iii/i/11~
DEPTH / /
(cm) 420- \ \ ~\ / /
480- \ \ /I /
\ \ /
540" ', \ I /
600- \ "\ \ /
660. \~\, /
720.
780.
84C
Fig. 8. Sectional profiles A-A' and B-B' through Changuinola peat deposit showing peat types.
BDT-3, which occurs near the edge of the deposit at its boundary with Bahia
Almirante.
The freshwater swamp-forest peat was found in all areas and was especially
persistent in mineral-rich places such as the base of most cores and toward the
Fig. 9. Petrographic/botanical characteristics of peats from the Changuinola peat deposit, Panama. Scale-- 200 #m.
A. Typical swamp-forest peat showing woody fragments and darkened debris.
B. Typical sedge-grass-fern peat showing sedge roots.
C. Sagittaria-dominated peat showing characteristic root anatomy (BDT-18, 250-300 cm).
D. Fern-dominated peat showing fern root and darkened debris (BDT-13,500-550 cm).
E. Nymphaea-dominated peat showing large concentration of fiber and light color (BDT- 13, 945-950 cm).
F. Typical Rhizophora (mangrove) peat showing dominance of roots.
~D
Fig. !0. Petrographic/botanicalcharacteristicsof peats from the Changuinola deposit,Panama.
A. Sphagnum-dominated peat (BDT-13,500-550 cm).
B. Insect (mite) exoskeleton (BDT-14, 0-50 cm).
C. Fecal pelletsamong sedge roots (BDT-18, 0-50 cm).
D. Freshwater sponge spiculesshowing silicadissolution (BDT-12, 780-805 cm).
E. Charcoal and mineral-rich zone near the base of core BDT-22 (780-805 cm).
F. Mineral-rich zone at base of core BDT-13, (945-950 cm) showing siliceous mineral matter and pyrite (FeS2) crystals.
~=~
172
edges of the deposit (Fig. 8). Note the interfingering of this peat type with the
Rio Changuinola flood-plain sediments at the northwestern edge of the deposit
and also its presence as a surface layer at the northeastern and southeastern
edges of the Changuinola peat deposit. This peat type is a diverse mixture of
freshwater swamp trees, shrubs, and vines with ferns and tropical broadleaf
herbaceous plants as common associates. Palm debris (probably Raphia) was
also encountered occasionally in this peat (but only near the surface ).
The most commonly occurring peat types (sedge-grass-fern and Sagittaria
et al. ) represent freshwater, open-marsh settings characterized by very shallow
water and ephemeral dry periods (see Fig. 5C ). The Sagittaria-dominatedpeat
type represents slightly wetter conditions than does the sedge-grass-fern type.
Even wetter conditions (i.e., areas of ponded water) are represented by the
presence of a Nymphaea-dominated peat type. Note that this peat type never
occurs near the tops of any cores (within less than 1.5 m of the surface), which
suggests that persistent deep water conditions (ponds) have been rare in this
region in recent times. Because we have no radiocarbon dates from this area
at present, we do not know the length of time represented by 1.5 m of peat.
However, radiocarbon dates from a peat deposit in Costa Rica (Cohen et al.,
1985) indicate an approximate rate of peat sedimentation of 1 m per 800 yr.,
which suggests that persistent ponds have probably not existed within the
Changuinola peat-forming area for the last 1200 years. Radiocarbon dates for
the Changuinola peats will be obtained in future years.
Note that, except for the layer of sedge-grass-fern peat at the top of cores
22, 20, 12, and 14 (central region) and the persistent (but often thin) layer of
freshwater swamp-forest peat at the base of most all cores, correlation of peat
types between cores is virtually impossible at this core spacing (roughly 2-2.5
km apart). However, the variability of these sequences within each core indi-
cates that the vegetational community that produced each peat layer did not
cover a very large area nor did it last for very long in any one area.
Typical microscopic characteristics of each peat type are shown in Figures
9 and 10. Additional petrographic characteristics are illustrated graphically in
Figures 11 to 13. Figure 11 shows the frequency at which samples of each peat
type fall into one of the three fiber categories of the ASTM classification sys-
tem (i.e., "fibric", "hemic", or "sapric", ASTM, 1987). These fiber categories
generally represent the degree of decomposition of plant tissues composing a
peat (that is, the more fibers, the less decomposition ). Because too few samples
of mangrove or transitional peat were encountered, these types were not in-
cluded on the graphs.
The three peat types are shown from left to right in order of increasing per-
sistence of standing water (Fig. 11 ). Note that fibric peat increases from left
to right and sapric peat decreases from left to right. Thus, swamp-forest peat
samples (which form under drier conditions) usually are more decomposed
than Nymphaea-Sagittaria peats (which form under wetter conditions).
173
SAMPLES 40-
30- ,,,- ?:S~
20-
10-
I¢'1~
F HS FHS
[]
FHS
[-g..~
FHS
Fig. 11. Fiber frequency of peat samples from Changuinola, Panama. Fiber determined micro-
scopically as area %. F = Fibric (greater than 67% ); H = Heroic (34-67%); S = Sapric (less than
34% ).
SAMPLES 5o- j
40- -~
30-
20-
10-
% 70-,
OF
SAMPLES i
m
2o-4 IH~lllmm i I III1~
Proximate analysis
A A'
(SW} (NE)
BDT-22 BDT-20 BDT-12 BDT-1
120
180
4201J
(cm)
480-
~ 7% 93~
540,
600
660
720
780
S40 , , , , , , , , , , , i , i , , , , , , ,
10 20 3O 10 2O 3O 10 20 30 10 20 30
S'
B (SE)
(NW)
660
72O
780 , , , , , , , ,
840
10 20 3O 10 2O 3O 10 2O 3O 10 20 3O
% ASH (DRY WT.)
RIO CHANGUINOLA BAHIA ALMIRANTE
4
Fig. 14. Sectionalprofiles A-A' and B-B' showingash content of cores with depth, Changuinola,
Panama.
might explain this offset. Furthermore, the sources of the inorganic materials
that produced these peaks are still unknown. If, for example, the source is
windblown inorganics (e.g., volcanic ash), then this material could have been
deposited at all elevations on a domed (i.e., curved) surface at the same time.
On the other hand, note that ash percentage increases slightly in both peaks
from core BDT-22 to core BDT-20. This would indicate that these inorganics
might have come from the northeast (ocean side), suggesting (but not prov-
ing) a marine origin for these inorganics. It is also possible that a tributary of
176
the Rio Changuinola once existed to the north of core BDT-12. This river
would have flowed roughly parallel to the beach-barrier shoreline feature that
now bounds the swamp on its north side. In addition to being a source of in-
organics, any existing streams would have been natural conduits allowing
brackish water to penetrate this area as the sea level rose. Nearness to one of
these streams could also explain the marine (mangrove) high-ash, high-sulfur
peat that occurs at the base of core BDT-3, because this peat does not exist a
short distance away (at BDT-24).
Figure 15 shows ash content plotted against peat type for the Changuinola
peat deposit. As might be expected, the mangrove peat has the highest ash
content because it probably formed at the edges of a brackish stream channel
or next to the bay. Of the freshwater types, the swamp-forest (woody) peat
type has the highest ash content because the vegetation that produces it tends
to be more competitive in mineral-rich environments.
The very low total ash content of the peat in the central portions of this
deposit (e.g., BDT-20 ) is especially significant with regard to the origin of low-
ash coals. Note that, although the petrographic analyses indicate the presence
of peat types that should contain significant amounts of authigenic silica (e.g.,
12.
(10-12)
ASH
CONTENT
(% DRY WT.) 6
(1-25) 12-12)
(1-17)
(1-13) ,': --'2.':
,, i L, -!
.-,.:) :.,
Fig. 15. Averages and ranges of ash content for each peat type, Changuinola, Panama.
177
grass-sedge phytoliths and sponge spicules), only a rare, degraded and pitted
siliceous fragment was encountered. This evidence would seem to suggest that
this mineral matter was leached from these low-ash zones, because the living
plants that produced these peats are the same types as those that we had ashed
previously from other areas and were found to contain more than 10% ash. For
a more detailed description of the potential for leaching of mineral matter from
peats to produce a low-ash coal, see Kosters and Bailey {1986) and Cohen et
al. (1987a).
A A'
(SW) (NE)
BDT-22 BOT-20 BDT-12 BDT-1
0
---- f_. . . . . .
120
180
240
DEPTH 36O
(cm) 420
540
600
66O "~
< Basal Sand
720 K
78o
840
~
. . . . . . . , , , , ,
2"
, , , . . . . , , , i , , i , • ,
25 29 33 37 25 29 33 37 25 29 33 37 25 29 33 37
MTS OCEAN
B g'
(NW) (SE)
BDT-5 BDT-20 BDT-14 BDT-3
120
~41
40
DEPTH 300360~ % ~ "'----------------
(cm) 420
840 I . . . . . . . . . ~ , I . . . . , . . . . . . . . .
25 29 33 37 25 29 33 37 25 29 33 37 25 29 33 37
Fig. 16. Sectional profiles A-A' and B-B' showing fixed carbon (daf) with depth, Changuinola,
Panama.
Calorific value
The average calorific value for 62 samples of peat from the Changuinola
deposit was 10,000 Btu/lb (dry) with a range of 8,824-11,310. Calculated on
an ash-free basis, these values exhibited an average of 10,375 and a range of
9,456-11,541 Btu. Figure 20 shows Btu/lb (dry), for sectional profiles A-A'
and B-B'. For these profiles, no significant differences in vertical or lateral
179
(39-41 )
39.
>~'j'-,
38
,-J ,/._
(28-41 ) (32-39)
36
FIXED (31-38) ,,,;,.,
CARBON 35"
J ~ (27-40) ."
, , : o,
.....
,o : . °
(WT% daf) 34
- • • :.,
'.o. -.,
- 5 - - . ,
":..:.:.
33.
. o ° : .
. ° .
,° . ,°
: ° . = .
32. ,• °°
. . . . , L ,21 ~/I
. , l : o
° • •
• °•
,'~,-.',.,-~ : ,. , _o . o
31 ~,;,; < ~ .,~ ....... : o , : o
• _o o.
.° • ,-
• • °
• , ;.*** ;
30 . . . . , "" -I,, I
Fig. 17. Averages and ranges of fixed carbon (daf) for each peat type, Changuinola, Panama.
trends were revealed by plotting calorific value on either a dry basis or a dry,
ash-free basis so that Figure 20 is sufficient to represent either case.
Note that in the thicker central portion of the Changuinola deposit (BDT-
22, -20, and -14), the calorific value: (1) tends to be slightly lower at the top
of the core; (2) increases gradually with depth (but with numerous fluctua-
tions ); and (3) decreases abruptly at the base of the cores, where the ash con-
tent goes up. On the other hand, cores BDT-12 and -3, which are closer to the
deposit edge and thus thinner, look similar to the lower portions of cores BDT-
22, -20, and -14, (i.e., they have relatively high calorific values throughout their
length, and they tend to decrease abruptly at the base or where ash content
increases). As previously noted, these trends cannot be accounted for entirely
by increasing or decreasing mineral matter content, even though a general
trend toward decreasing calorific value with increasing ash exists for all the
samples {Fig. 21 ). It is more likely that these trends reflect variations in peat
types (i.e., chemical differences in original plant source ingredients) as well as
differences in ash content. These differences may also be affected by the geo-
graphic positions of the core sites relative to the geometry of the deposit (e.g.,
180
120~ ~0 O O
$
1804
240.
300-
DEPTH 360"
(cm) 420" S °
480"
540
600- • i s
6604
720"
780-
i
840:
900 j
96O
45-
Fig. 19. Fixed carbon content (daf) versus ash content for all peat and nonpeat samples from
Changuinola, Panama.
A At
(SW) (NE)
BDT-22 BDT-20 BDT-12 BDT-1
0-
60-
120-
NO ANAL.
180-
DEPTH 24o-
:300-
(cm) ~0-
420 -
480-
540 -
600-
660-
720 -
780-
840 i i i i i ! t i i ! ! ! ; i ! i , i I ; , i i ,
}000 9000 1 0 0 0 0 1 1 0 0 0 8 0 0 0 9000 100001100080009000 100(X~ 11000 80009000 10000 11000
B B'
(NW) (SE)
BDT-5 BDT-20 BDT-14 BDT-3
o.
60o
120-
18o-
DEPTH 24o-
(cm) 3oo-
360"
420 ~
480"
540.
800.
720 o
780.
Fig. 20. Sectional profiles A-A' and B-B' showing calorific value (dry) with depth, Changuinola,
Panama.
taining or ash-free basis for all peat samples (Fig. 22), no particular trend is
evident. On the other hand, Figure 23 shows calorific value (daf) versus depth
for two of the peat types. These two types were the only ones that exhibited
any relationship between calorific value and depth (i.e., a slight tendency to-
ward increasing calorific value with depth).
182
~1 500~
o
oooi t.
BTU/LB 10000. • •
(DRY)
9500. ~De°O• oo
9000~ • • •
eDo
8500~
8000! l
7500 I •
6 I0 14 18 22 26 30
ASH CONTENT (W T % d r y )
11500-
1100~ ~e:dL
5~ °
10,500- OiI •
10,000- iloo ° °o • | •
BTU/LB Oo
9ooo-~
85004
80001
7500f
ASH CONTENT (W T % d r y)
Fig. 21. Average calorific value versus ash content for Changuinola peat samples.
Calorific value (dry) plotted against fixed carbon (dry) (Fig. 24A) illus-
trates no particular relationship between these two parameters, even if plotted
for individual peat types. Even on an ash-free basis for both parameters (Fig.
24B ), no obvious trends are evident. Figures 25A and 25B show calorific value
(daf) versus fixed carbon (daf) for individual peat types. The unusual circum-
stance is that (except for a few data points) swamp-forest peats show a slight
trend toward increasing Btu with decreasing fixed carbon, whereas all other
peat types tend toward increasing Btu with increasing fixed carbon content.
183
0-
• • 0
0
o
0 *
• O
DEPTH ¢ ,
(cm) 0 •
I, t0*
• 0
O
7~.
~ 0
• SWAMP-FOREST PEAT
o SEDGE-GRASS-FERN PEAT
• SAGITTARIA ET AL PEAT
* NYMPHAEA ET AL PEAT
o
• o
0 •
lOO o ° ~
• ,o•
0
• 0
800. 00
9oo
s~oo ~o ~oo , o.'soo 115oo 11~
BTU/LB. (DRY, ASH-FREE)
Fig. 22. Average calorific value versus depth for Changuinola peat samples.
Sulfur content
Figure 26 shows total sulfur contents of the Changuinola peats along sec-
tional profiles A-A' and B-B'. Total sulfur contents in the central, thicker por-
tions of the deposit (BDT-22 and -20) are very low, averaging about 0.15%
184
CJ!
!0C,-
&
200-
DEPTH 300-
(cm) 400- &
500- A,
600~
700~
i
8004
900 j
95(30 10.()00 10,500 11,000 11.500
BTU/LB. (DRY, ASH-FREE)
• SAGITTARIA ET AL P E A T
* NYMPHAEA ET AL P E A T
Fig. 23. Average calorificvalue (daf) versus depth for two of the Changuinola peat types.
(dry weight). Note that average sulfur contents tend to increase toward the
Caribbean Sea (SW-NE) and toward Almirante Bay (NW-SE), with the
highest values being near the brackish bay rather than near the more saline
sea. These relationships of sulfur to marine conditions are consistent with those
observed in many other coastal peat deposits of the world, for example, in
southern Florida (Cohen et al., 1984).
The dramatically higher total sulfur values encountered below about 180 cm
in core BDT-3 reflect the presence of brackish and marine mangrove peats
(see previous petrographic/botanical descriptions and Fig. 7 ). Mangrove peat
has the highest average sulfur and ash content of any peat type (compare Figs.
27 and 15), with swamp-forest peat having the next highest (but significantly
lower) average concentrations of both sulfur and ash.
Because freshwater peat can be secondarily enriched in sulfur by either over-
lying marine peats or by intrusion of marine water from either above or below
(Cohen, 1968; Altschuler et al., 1983; Cohen et al., 1984 ), the somewhat higher
total sulfur contents of certain freshwater peat samples (e.g., BDT-14,750 cm )
may have resulted from one of these secondary enrichment phenomena. On
the other hand, sulfur isotope and petrographic analyses for the basal, high-
sulfur peat from one of the inland freshwater cores (Raymond et al., 1987)
indicate the lack of any marine influence at that site.
Abundant pyrite was observed petrographically within the basal mangrove
peat of core B D T - 3 and within the freshwater, swamp-forest peat of core PB-
185
(A)
37 C:m
36 0 eJ:3 • o 0
0
FIXED
o o ~ oa~m•
CARBON
WT.%
DRY
• 00 O
30
29
28
27
26 0
25
85OO ~o 9~00 ,06o0 ,o~00 11600 1,~oo
BTU/LB. (DRY)
(B) ,4.1,
40. • O
39.
38- OO O4c • O
37. • • ~ o• * o•
FIXED 35.
CARBON 34-
WT.O/o • :# ~0
DRY,ASH-FREE 3 3
32- O O
31- ap O
30- • r-1
29-
28-
27- O
26-
25 i , i , ,
8500 90 0 9500 10000 10500 11000 11500
Fig. 24. Average calorific value versus fixed carbon content for Changuinola peats, Panama.
( • = swamp-forest, ~ sedge-grass-fern, • = Sagittaria et al., ~ = N y m p h a e a et al. ).
4 (on the Caribbean edge of the deposit). Abundant pyrite was also observed
by scanning electron microscope in the basal samples of core BDT-23 and to a
lesser extent at the base of core BDT-14. This suggests that most, if not all, of
these peaks in total sulfur content probably are due to the presence of the
mineral pyrite. The rest of the total sulfur (occurring in relatively low quan-
tities throughout this deposit) is probably organic sulfur.
(A}
4t
4O
39 • SWAMP-FOREST
PEAT
38! 00
37~
S6~
ss~
FIXED 34 ~ @0
CARBON 33q
% DRY,
32~
ASH-FREE
30 ~
28~
28~
274
26 '
(B)
41 l •SEDGE-GRASS-FERN O
391 PEAT
&SAGITTARIAET AL O • O
37 PEAT (~ O O
35 O E~ •
FIXED "] • •
CARBON 33t I~
% DRY OO
ASH-FREE 31 ,~ O
4 o
27 []
25
8500 9()00 95100 10000 10,~'00 11000 11500
BTUILB. (DRY, ASH-FREE)
Fig. 25. Averagecalorificvalue versusfixed carboncontentfor Changuinolapeats, Panama.
A A t
(sw) (NE)
BDT-22 BDT-20 BDT-12 BDT-1
jJ
~asal Sand
DEPTH
(cm) :26(~] ~ and Layer
"ot ~.
~(~t ~:> ~-BasalSand
~2o t
:20 .as= .Sand s... s.o . . . . . . .
B B'
(NW) (SE)
120
-,-1 5%
180
240 Casal Sand
~ 4.9%
x,J.7%
DEPTH
(cm)
~ 6.3%
6.6%
14.9%
48O
540
6OO
720
780
Basal Sand * - Basal Sand
84O , , • i , , ,
0.1 0.3 0.5 0.1 0.3 0.5 0.1 O3 0.5 0.1 03 0.5 07
Avg.= 0.12 Avg.= 0.15 Avg. = 0.24 Avg. = 4.08
Fig. 26. Sectional profiles A-A' and B-B' showingtotal sulfur content versus depth, Changuinola,
Panama.
(6.3-7.7)
7.0
t
0.4*
,(! •
(0.2-1.7)
(o.i -0.6)
0.3-
|
4
AVERAGE • (0.1-0.3)
:.:.-.-
,2'2(';~
TOTAL ,, 4 ,o -o 0 ,;, p -
SULFUR 0.2- (0.1-0.3) ! :::..:::,
,i .,.,. . .:. oo
(WT % dry)
: : ',:" - . : - '72:,'~
.~ ',::_:::
. . . . .
,'..,.,%
•..: ,.o o.,
i o-° °-o
:;'92;'~?,,',~
c ]~,~..v..'.4:,,
SWAMP SEDGE- SAGITTARIA NYMPHAEA RHIZOPHORA
FOREST GRASS- ET AL E T At_ (MANGROVE)
{WOODY! FERN
lier discussion of sulfur) and a very small amount of cristobalite within various
horizons of core BDT-23.
Acidity (pH)
TABLE 1
BDT-21 BDT-3
has probably had some brackish water intrusion) and brackish to marine man-
grove peat (with very high sulfur and ash) toward the base. The pH is lower
throughout this core than in BDT-21 and is especially low in the basal man-
grove peat, where most of the sulfur is in the form of the mineral pyrite. The
low pH values may not represent conditions during peat formation but may be
an artifact of later pyrite oxidation. This would perhaps be a phenomenon
similar to that which produces "acid mine water" from pyrite-rich coal beds.
CONCLUSIONS
ACKNOWLEDGEMENTS
This work was funded by a grant from the U.S. Agency for International
Development, by a grant from the U.S. Department of Energy (Office of Basic
Energy Sciences), by the National Science Foundation (EAR 82-01088), and
191
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