EDMS 45084199 Dated 12/30/2009 Incident T120404 #2 SRU Malfunction on 12/23/2009

http://edms.deq.louisiana.gov/app/doc/view.aspx?doc=45084199
automatic safety shutdown reported as result of apparent malfunction in the SRU
main burner - 2.6 hours event estimated emissions 3,090 pounds SO2

EDMS 44922598 Dated 12/16/2009 Incident T119999 #2 SRU Malfunction on December 9

2009
http://edms.deq.louisiana.gov/app/doc/view.aspx?doc=44922598
automatic safety shutdown reported as result of apparent malfunction in the SRU
main burner flame detectors - 6.5 hours and resulted in SO2 emissions estimated at
10,800 pounds

EDMS 45084186 Dated 12/29/2009 Incident T120412 Dec 24 2009 300 barrel crude oil
spill at Tank 250-1
http://edms.deq.louisiana.gov/app/doc/view.aspx?doc=45084186
on December 24 2009 at approximately 00:30 hours. Estimated spill 300 bbl; release
to air 9.3 bbl; release to ground 50.7 bbl....conducted air monitoring....and
detected no VOC and benzene levels. There was no impact to waterways.

EDMS 44926543 dated 12/21/2009 Incident T120104 Dec 14 2009 storage tank cover
collapsed
http://edms.deq.louisiana.gov/app/doc/view.aspx?doc=44926543
31,274 pounds of VOC's and 616 pounds of benzeneOn December 14 2009 there was a
release of 10,967 barrels of gasoline to the roof of Tank 200-1( state hazmat Dec
14 2009 storage tank roof collapsed. ) For approximately 2.8 hours until the tank
was pumped down to its lowest level, initial estimated emissions are 31,274 pounds
of VOC's and 616 pounds of benzene.

EDMS 44922633 Dated 12/18/2009 T120127 December 13 2009 diesel oil release into
neighborhood canal.
http://edms.deq.louisiana.gov/app/doc/view.aspx?doc=44922633
No quantity of diesel released nor benzene or VOC emissions reported. On December
11 2009 Murphy was forced to open Outfall 003 due to prolonged rains. also reports
on December 13 2009 Murphy Oil made a discovery of oil in a neighborhood canal.
Murphy Oil discovered a release of diesel-like oily water on the 20 arpent canal,
reported by Murphy Oil as ""presumably from Outfall 003"".The refinery storm water
outfalls on page two of the flowchart indicates emergency outfall 003 due east of
the Collin's Pipeline area. Collin's Pipeline is a joint venture of EXXON-Houston
and Murphy Oil Meraux. To the west of Collin's Pipeline area is the municipal
storm drainage pipe which released the diesel oil into the neighborhood canal,
named 20 arpent canal, where it intersects Jacob Drive. It is unclear at this time
how the diesel oil entered the municipal storm water system. There is no quantity
of diesel released nor benzene or VOC emissions reported.
Residents have requested water, soil and air sample results from Louisiana Dept of
Environmental Quality. It is unclear if any samples were taken by the state
department.During the same time Murphy Oil Tank 250-2 was scheduled for a cleanout
with use of a temporary, portable diesel fuel tank EDMS 44548567.

EDMS 43986164 Dated 10/26/2009 Incident T118824 Oct 19 2009 crude oil spill tank
250-1
http://edms.deq.louisiana.gov/app/doc/view.aspx?doc=43986164
130 barrel crude oil spill Tank 250-1 on Oct 19 2009 released to air 12/4 bbl;
released to ground 11.6 bbl; estimated emissions 3.91 benzene; 3907 pounds VOC's
(Residents called both Murphy Oil and LDEQ to come to the neighborhood about high
level of chemical's present; both refused. Murphy reports their subcontractors
were monitoring the air).
EDMS 44138747 dated 11/13/2009 Incident T119342 Oct 14 2009 FCCU leak (Late Report
- also Benzene emissions rescinded EDMS 44922731 Dated 12/10/2009)
http://edms.deq.louisiana.gov/app/doc/view.aspx?doc=44138747
http://edms.deq.louisiana.gov/app/doc/view.aspx?doc=44922731
Cat Craker Unit leak releases 44,000 pounds hydrocarbons with 155 pounds benzene
from Oct 14 - 17 2009 --- leak at upper manway in #2 FCCU Reactor (Cat Cracker or
Hydrocracker) --Application of steam to disperse the vapors. First attempt to
repair the leak failed on Oct 15 2009 and leak apparently worsened. Specialty
group arrived Oct 16 2009 to measure the manway and access the leak. On Oct 17
2009, as Murphy awaited that repair, the leak worsened, so Murphy shut down the
FCCU as a safety precaution. The vendor installed the clamp on Oct 18 2009. The
leak was estimated to have lasted 74.5 hours from approximately 09:00 hrs on Oct
14 2009 to 11:300 hrs on Oct 17 2009 when the unit was shut down.Estimated
hydrocarbon emissions 44,000 pounds with 155 pounds of benzene. Murphy Oil
rescinded notification of benzene release Dec 10 2009. Murphy reported to the
National Response Center that this event resulted in the release of benzene in
excess of the 10 pounds reportable quantity. Murphy Oil provides Dec 10 2009
update to rescind benzene release notification citing CERCLA 101(14) for exemption
from reporting benzene emissions.

EDMS 43622670 Dated 10/05/2009 Incident T118251 #2 TGT Bypbass 09'/27/2009

http://edms.deq.louisiana.gov/app/doc/view.aspx?doc=43622670
automatic safety shutdown of #2 SRU apparently due to hydrocarbon breakthrough
into the unit. Event 4.2 hours; SO2 emissions estimated at 159 pounds - below
reportable.