ALL INDIAOPEN TEST (AIOT)

JEE ADVANCED

DATE : 05-05-2013

COURSE : JP, JF, JR & JCC

TARGET : JEE (ADVANCED)-2013

HINTS & SOLUTIONS

5.

PAPER-1
PART-I (Physics)

(B)

Sol

1.
(A)
Sol:
Let the elongation of the spring be x.
From the N.L.M. of the block
mg - kx = m (g - t)
kx = mt
or
k(l - l0) = mt
Differentiating w.r.t. time

Mass of sphere if its density was

Ycm =

dl
k m
dt

6 x 2 1 x 3
7

(B)

Sol:

a A / g a A / cm a cm / g

m t
g t dt
k 0

m
t2
gt
k
2

=
2.

m
V'
k

(C)

Sol. From the graph it can be seen that the max. value

60 0 .

is at

R
. a
2

would be 1 kg.

15
m
7

6.

k V V' m
V=

3R

Fx
R
2 F

2 I m

3 FR 2 F

4I
m

7.
(D)
Sol. From energy conservation w.r.t.
an observer in the trolley we have
From A to B
W mg + W ) = K.E.
mg2R + maRsin = 0

is max. when the rod Q is tangent on the circle

on which the ring attached to P moves.

a=

2g
sin

8.
(C)
Sol. F = shear strength x area on which shear stress acts
=

345 x 106 x 4 x 10 4

= 138000 N
= 13800 Kg
from the fig. d = 1 sec 60
= 2m
3.

(E)

4.

(B)
d

Sol. w =

9.
Sol

5
4 2 500
2

f dx f dy f dz
x

T =

Now

(B)
From the conservation of the energy we have ,
Initial internal energy= Dissociation energy + final internal energy

dx is positive since f > 0 and d > a

x

10.

(A)
( 4,2,1)

WE 2
Sol:
y

dy is negative since f > 0 ; e < b

y

dz is negative f < 0; f > c

z

xdx 2ydy 3dz = 3

( 3,3,1)

11.

(B)

Sol. Reading V2 =

w = + A1 + - A2 - A3

RESONANCE

3
5
2 2 T' + 3 2 T'
2
2

8000
= 100 T ; T = 4
21

= 2000 +

VR2 VC2 =

8 2 I 42 42
I = 2 Amp

I R 2 X C2

I 4 2

SOLAIOT050513 - 1

12.

(D)

PART-II (Chemistry)

Sol. V1 =

I R 2 XL XC
2

2 4 2 7 4

= 2x5

= 10 volt

24. Which is incorrect order of basic ..................

Sol. (C)
(A) NH3 is weaker acid than PH3 as NH bond is stronger than
PH bond. So NH2 is stronger base than PH2.
(B) H2O is a stronger base than H2S

13. (D)
Sol. Just after closing the switch, the
inductor will not allow current
Hence the equivalent circuit
will be as shown

i
14.
Sol

2R

(C) The ve charge is unstable on

Hence it is stronger base
(D) In pyrrole, the lone pair on nitrogen is delocalized for
aromaticity, hence weaker base.
(E) CO32 carry two units of negative charge, so it is stronger
base than HCO3 .

(A)
long after closing the switch the p.d.
across the inductor will zero

15.

(B)

16.
17.

(A)
(4)

Sol

t=

18.

(4)

5R

25. S1 : The intercept of a graph of PVm along Y-axis ..................

Sol. (A)
S1 :

T 2 I

4
4 pE

S1

Therefore the slits

and

S1

I=

S2
and

S2

distance

rCH4

4t 2
pE
2

are at the positons of brights.

will have same intensity. For

these slits Q is at the central line while the point P is at a

S3 :

=1

PVm = RT

rCD4

from the central line

19.

(5)

Sol

L= L T=

20.
Sol

(5)
Heat absorbed = heat released.

1 10 3 15 = 15 mm = 3x.

1
31.5 20 + 31.5 80 + 31.5 110
2

20

16

17.5 1

70
4

x=

mass of O2 used =

charge passed =

x
19.3

9375
100
1000

moles of Zn2+ finally =

Sol

4(2R)2 (1)T 4

1
1
4(R )2 ( )200 4
32
2

RESONANCE

1
1

= 0.25 103
2 2000

moles of Zn deposited = 0.75 103 =

moles of

involved =

3
103
4

3
103 2
4

x
19.3
3
103 2 96500 =

9375.
100 1000
4

22. (5)
Sol. In equilibrium, power released= power absorbed
or

2
1

= 103
2 1000

moles of Zn2+ initially =

(6)

mg 1 4 2(1)(2) cos(180 37)

1
3
16 +
32 = 4 + 24 = 28 g.
4
4

27. A current of 19.3 mA is passed for 9375 sec ..............

Sol. (A)
Let the current efficiency be x%.

m 540 + m 1 90

qE=

5
4

26. When 12g of carbon reacted with oxygen to form CO and CO2
...................
Sol. (E)
Let x mol of carbon converted into CO, then 1-x mole of C
converted into CO2.
x (25) + (1x) (95) = 77.5
25x + 95 95x = 77.5

17.5 = 70 x

Again P & Q are positions of brights

Intensities at these points will be equal.

P Vm
RT

Hence PVm approach RT when P O.

S2 : This statement is true when real gases are behaving
ideally.

Sol. Both the slits

21.

23. If enthalpy of formation of CH3CH3 (g), ......................

Sol.(B)
The enthalpy of formation per CH2 group = 5 kcal/mol.
Hence enthalpy of formation of C6H14 = 30 5 2 = 40 kcal/mol.

x = 80%.

SOLAIOT050513 - 2

28. On the basis of following reactions ....................

Sol. (A)
A = NaOH.
heat
NaOH + Al NaAlO2 + H2 (g)
NaOH + P4

heat

NaOH + NH4Cl

NaH2PO2 + PH3
34.

heat

...........................

NH3 + NaCl + H2O.

29.

anticlockwise. But both have equal area.

So heat = 0
U = 0
W = 0.

H
(CH3 )3 C CH C C H Pr oduct
isomerisat
ion
|
OH
(II)

(I)
Sol. (A)

H
(CH3 )3 C CH C C H
(CH3 )3 C CH C CH
|
|
OH

OH2

(I)

(CH3)3CCH=C= C H

Sol. (B)
(A) BC and DA are adiabatic process. So Ssys as well as Ssurr = 0
(B)During AB process, the entropy of system is increasing at
constant temperature. This is an isothermal expansion.
(C) The process BC is adiabatic ( S = 0) and it is compression
because temperature is increasing.
(D) The process is reversible process, Ssys = 0, Suniv = 0, so
Ssurr = 0
35. The element B can ...............
Sol. (B)
From the description, the ore is chromite ore FeCr2O4.
The orange compound is K2Cr2O7 which react with KCl and conc.
H2SO4 produce deep red vapours of chromyl chloride (CrO2Cl2).
CrO2Cl2 + H2SO4 H2Cr2O7
H2Cr2O7 + NaOH CrO42
CrO42 + Ba2+ BaCrO4

(CH3)3CCH=C= CH
|
OH
(CH3)3CCH=CCH=O
(II)
I and II both give +ve Tollens reagent.
I due to terminal alkyne.
II due to aldehydic group.
30. Diasteromers are possible for structural formula ...............
Sol. (B)
Geometrical isomers are always diasteromers.

(yellow)

The other element is the one which belongs to same group as.
Cr, i.e. either Fe or Al.
Also it belongs to 4th period. Hence, the element B is Fe.
36. The element B in its stable high oxidation state ..........................
Sol. (C)
The high oxidation state of iron is +3 and it gives blue color with
excess of K4[Fe(CN)6].
37. Compound (P) may ...............
Sol. (C)
38. Which is not correct ..................
Sol. (D)
NaCN

dil H SO

4
2

dil H2SO 4

31. Which of the following is a disacchharide which is ...............

Sol. (C)
(C) Only C is non reducing with -1,2 glycosidic linkage.
32. The following benzyl alcohols are reacted with HBr.
......................
Sol. (D)

33.

39. Coordination number of underlined or ....................

Sol. (7)
(i) 6

...................
(ii) 4

Sol. (C)
As can be understood from the question. The area enclosed in
the cyclic process in S Vs T diagram is heat.
In ABCDEFGA, one cycle is clockwise while the other is

RESONANCE

SOLAIOT050513 - 3

43. C4H8 (unsaturated hydrocarbons)

..........

(iii) CaSiO3
Sol. (6)

Hence the coordination number is 4.

(iv) Silicon Each Si is bonded to four silicon atoms.

CH2=CHC2H5

(v) Coordination Number is 2

(vi)

C.N. is 3.

(vii)

C.N. is 4.

Meso
CH3CH=CHCH3
trans

(viii)

C.N. is 3

(ix)

CN = 4

(x) PH4Cl

CN = 4

44. An aromatic hydrocarbon has molecular formula C 10 H 14 ,

...................
Sol. (9)
Atleast one benzylic hydorgen must be present. Therefore
possible isomers are :

40. How many of the following oxides are anhydrides ...............

Sol. (2)
(i) SO2 H2SO3 (dibasic)
(ii) P4O10 H3PO4 (tribasic)
(iii) NO2 HNO2 & HNO3 (monobasic)
(iv) CO2 H2CO3 (dibasic)
(v) Li2O LiOH (not an acid)
(vi) CO neutral
(vii) ClO2 HClO2 + HClO3 (monobasic)
(viii) Cl2O HOCl (monobasic)
(ix) I2O5 HO3 (monobasic)
Hence answer is 2.
41. 2 moles of a mixture of O2 and O3 is reacted with excess of
................
Sol. (6)
KI

I2
+
v.f = 2

O3
v.f = 2
moles
= x.
Na2S2O3

I2 + H2O + O2.
v.f = 2

1 48
100
1 48 1 32

3
60
100 = 60% Ans. =
= 6.
5
10

42. The number of completely filled orbitals in 29Cu ................

Sol. (9)
Cu 1s2 2s2
2p6
3s2 3p6 3d10 4s1
9
Nodes

Orbitals
So, 9.

RESONANCE

2
1

2
2
3 (but incompletely filled)
3
5

1
1

=
2
2
cos A (4 cos A 3) sin A (3 4 sin A

1
1

cos3A
sin3A

M=2

weight % of O3 =

sec A
cos ecA

Sol.
2
2

(1 4 sin A ) ( 4 cos A 1)

I + Na2S4O6

V = 1L
v.f = 1
eq of O3 = eq of I2 = eq of hypo
2x=2
x = 1 mole

PART-III (Mathematics)
45. (D)

1
1

sin15
cos15

A = 5
2

2 2
2 3
2 2

8
=
=

3 1 = 24
3

1
3

46. (D)
10

10

Sol. 2
r 1

r 1

8r 3

r 1

10

2r 1

r 1

10

(8r )

3
r 1

(210 1) 8.10.11

30 = 1023 + 440 30 = 1433

21
2

SOLAIOT050513 - 4

47. (B)
Sol. We have
1! . 2! . 3! 9! = (1)(12)(1 23) (1 29)
= 19 28 37 46 55 64 73 82 91 = 230 313 55 73.
The perfect square divisors of that product are the numbers of
the form 22a 32b 52c 72d
with 0 a 15, 0 b 6, 0 c 2, and 0 d 1. Thus there are
(16) (7) (3) (2) = 672 such numbers.

x
x3
Let g(x) =
+
50
100
1
3x2
g(x) =
+
> 0 x (0, 4]
50
100

y=

18
.
25

18
0, 25 x [0, 4]

3a . b

57 2

|b|
3 | a || b | cos =
25

| a |2

4 | b |2

A B , A B , A B
AB

sq. units

I>

1 1 4 2
4 1
+
5 3
5 3 5 3
upto

4! 3 3
3

4 1 1 1 4 2 2 4 1
+ +......
5 3 5 3 5 3 5 3

4
4 2
15

=
=
9
6 3
1
15
52. (C)

d2 y

cos x
dx
x

d y
Sol.

1.dx

/3

50. (A)

3a 5b . 2a b = 0

6 | a |2 5 | b |2 = 7a . b

Also ,
a 4b . b a = 0

dx 2
dx =
dy
dx

2x

x 2 1 dx

cos x
dx
x

dy

dx

dy
= n (x2 + 1)+n c
dx

/2

dx

2
2 (x + 1) = 2x

/6

<x<
; cosx < x
3
2

cos x
<1
x

Sol.

occurs

(P(( A B ) ( A B)))2 . P( A B ) +...... upto

cos x
>1
x

A B

P( A B ) P(( A B ) ( A B)). P( A B ) +

cosx > x

or

Alter :

sq. units
49. (B)

/6

57 2
|b|
25

41
P( A B )
4 2
53
=
=
=
=
4
1
1
2
6 3
P( A B ) P( A B)

53 53

CD

2
1
=
=
ACB =
.
CA
3
3
2

Thus area of smaller segment is =

19
43 2
57 2
| b | cos =
| b | cos =
25
5 43
25

Competition ends either if

Required probability

4
1 2 2
Area of sector ACB =
.2 .
=
sq. units
s
3
3
2

Sol. 0 < x <

Also

Events are A B,

x3
x

, simply represents the x-axis.

100 50

2
1 2
ACB =
.2 .sin
=
3
2

3a . b

Sol.

CA = CB = 2, CD = 1
cos =

51. (D)

[g(x)] = 0 x [0, 4].

Thus

4 | b |2

Thus g(x) is increasing in [0, 4].

Hence g(x)

1 2 4 2
6 2 5 2
|a| |b| = |a| + |b|
3
3
7
7
2
2
25 | a | = 43 | b |

48. (C)
Sol. Circle has (2, 1) as it's center and radius of this circle is 2.
Thus, if P(x, y) be any point on it. then x [0, 4]

g(0) = 0, g(4) =

| a |2

RESONANCE

dy
dy
= c(x2 + 1) c = 3 as at x = 0 ,
=3
dx
dx

dy
= 3(x2 + 1) y = x3 + 3x + 1
dx

/2

dx J <
6
/3

53. (D)
Sol. Let f(x) = x + cosx a
f(x) = 1 sinx 0 x R.
Thus f(x) is increasing in ( ,), as zero of f(x) don't for an
interval. f(0) = 1 a
For a positive root, 1 a < 0
a>1

SOLAIOT050513 - 5

54. (D)
Sol.

DE = (1, 1, 2 ) , AD = (0,2,0)

(r )(r ) = (r )(r 2)
= r2 + r + 1

| AD. ( AB DE) |
S.D. =

10

10

(r )(r ) = (r

r 1

r 1

cos

225

10

(r )(r ) = cos2= 1

AB DE =

r 1

55. (B)
Sol. Given equation represents a pair of straight line if

=2

5 5/2

12

5/2 8

1 1

2 j k

AD.( AB DE) = 4 2

8 =0
3

4 2
S.D. =

100 = 200
=2

| ( AB DE) |

r 1) = 450

56. (C)
Sol. The equation of 2nd degree is

Let

2 2

2 2 1

3
i
j
k
1 1 2
1 1 2

n1 ED EA =

2x2 10xy + 12y2 + 5x 16y 3 = 0

(2x 4y + 6) = 0 and

x 3y

1
=0
2

their point of intersection is 10 ,

2

1
=

57. (B)

58. (B)

n(2n 3n 13)
6

( n 2 n 1)

2 n 2 3 n 13
lim n
1
2
2( n 3 n 5)

Sol.

AB = (2,0,0)

RESONANCE

=m=n=

E(0,0,

2)

y 1

equations of line are

x 2 = y +1 = z 2 = r
Q (r + 2, r 1, r + 2)
Q Lies on the plane 2x + y + z = 9
2(r + 2) + (r 1) + (r + 2) = 9
4r + 5 = 9 r = 1
Q (3, 0, 3)

PQ =

n2 2

n 2
1
n n 1

OA = 2
AE2 = AO2 + OE2

1

3

x2

59. (C)
60. (B)
(Sol. 59-60)
Let A(1, 1,0), B(1, 1,0), C(1,1,0), D(1,1,0)

OE =

= cos1

2x + y + z = 9

= e3/2 e-1

4 = 2 + OE2

1
;
3

n ( n 2 3n 5)
3

lim
n

2 3 2 3

61. (3)

n(2n2 3n 13)

6
1
lim
n n(n 2 3n 5)

ADE and ABE then cos

| n1.n2 |
| n1 || n2 |
4

G(n) =

1 2

i (0 ) j(2 2 ) k (1 1)

g(n) = n2 + n + 1

(n 2 2)

If is acute angle between plane

n 1
=3+
[6 + (n - 2)2] = n2 + 2
2
f(n) = n2 + 2

F(n) =

n2 EA EB = 1 1 2

Sol.(57-58)
S = 3 + 6 + 11 + 18 + ...................
S=
3 + 6 + 11 + ....................+ tn
tn = 3 + (3 + 5 + 7 + 9 + .............. + (n - 1) terms

Similarly

i (2 2 ) j(0) k (2)

1 1 1 =

1/ 3

1/ 3

z2
=

1/ 3

62. (3)
Sol. Roots of the equation x2 + 3x + 5 = 0 are imaginary and equation
x2 + 3x + 5 = 0 and 3x2 + ax + c = 0 have a common root both
roots are common
a = 9, c = 15
a,b,c are in A.P.
b = 12

SOLAIOT050513 - 6

In radius of the ABC is

1
(9 )(12)
2
1
(9 12 15 )
2

= 2ab+1 ab + 6ac+1 3ac +

1 2a b 1
1 2 a c 1
+3
b 1
c 1

9 12
=3
36

63. (5)
Sol. Let coefficient of three consecutive term are nCr1, nCr , nCr+1
n

Now

c 1

Cr

7

1

C r 1

n + 1 = 8r
n

also

Cr 1

Cr

Let g(a) = 2ab+1 + 6ac+1 ab 3ac

n r 1 7

r
1

1
6a
2a b 1

+
+
b 1
c 1 b 1

g(a) = (2a 1) (bab1 + 3cac1)

g is greatest a = 1.
a0 = 1

..........(1)

35
nr

=5
7
r 1

PAPER-2

n = 6r + 5 ..........(2)
by (1) & (2) n = 23 and r = 3

PART-I (Physics)

n3

=5
4

1.

64. (4)
Sol. f(x + 3) = f(6 x 3)
f(3 + x) = f(3 x) f (3 + x) = f (3 x)
x = 3 f(6) = f (0) = 0
(x) = (f(x) f(x))
Let g(x) = f(x) f(x)
x=1
f (4) = f (2) = 0
x=2
f (5) = f (1) = 0
f (0) = f (1) = f (2) = f (3) = f (4) = f (5) = f (6) = 0
f (1) = f (2) = f (3) = f (4) = f (5) = f (6) = 0
0 < 1 < 1 < 2 < 2 < 3 < 3 < 4 < 4 < 5 < 5 <6 < 6
Rolle's (x) = 0 at least 12 = p

(C)

Sol. S =

2R sin

t
2

2.
(B)
Sol. Taking the wedge + insect as system and applying
Newtons II law in horizontal direction,

F=

65. (4)
Sol. Let

3.

x(x 1) + 2yz = ...............(1)

y(y 1) + 2zx = ...............(2)
z(z 1) + 2xy = ...............(3)
(2) (1) y2 x2 y + x + 2z(x y) = 0
(x y)(x + y 1 2z) = 0
Similarly (y z)(y + z 1 2x) = 0
(z x)(z + x 1 2y) = 0
Case -I x y z
x + y 1 2z = 0
y + z 1 2x = 0
z + x 1 2y = 0
Adding 3 = 0 contradiction
No solution
Case-II Any two are equal
x = y z (y z)(z 1 x) = 0,
z1x=0
z=x+1
(x y, y z, z x) = (0, 1, 1)
Similarly x y = z (1, 0, 1)
x y = z (1, 1, 0)
Three solutions
Case -III x = y = z (x y, y z, z x) = (0, 0, 0)
One solution
Total 4 solutions

V2

m
. cos M 0
R

(D)

Sol. For free surface

2 r 2
2g

Here h=5 cm and r=10 cm.

4.
(A)
Sol.

The mirror moves by DE=1 cm. From geometry DE=CE.Also

BA=DC= 2cm.Now if the wall is moved by 1 cm, the spot will
move further by 1cot37=4/3
5.
(A)
Sol:
Since the deviations caused by individual lenses are numeri-

66. (7)
1

Sol.

(a

3a c x b 3 x c ) dx +

(x

cally equal, and deviation = h / f we have

3 x c a b 3a c )

h1 h 2

fl
f2

from the figure it can be seen that h1>h2. f1>f2

b 1

c 1

1 a
ab1
1 a
ac 1

= (ab + 3ac) a b 1 3 c 1 + b 1 3 c 1

(ab + 3ac) (1 a)
= (ab + 3ac) (2a 1) +

6.

Sol.

(A)

Q2 1 2
LI
2C 2

LC

Q2
I2

1 2a b 1
1 2a c 1
+3
b 1
c 1

RESONANCE

3
c 1

SOLAIOT050513 - 7

and

1
I

LC Q

7.

(C)

8.

(A)

iR 1 R 2 2 x (2 4) 12

2
Q
2

9.
(A)
Sol. Since current is going out of the body,
i=

dq

dt
di
q
dt

Given

d 2q
dt 2

q=

q+

d 2q
0
dt 2

10.

i=

(ACD)

15.

(ABC)

16.

(A)

332 0
1000

332 5
332
1000
freflected
327

incident =

sec.

328
327
m ; reflected =
fincident
1000

i 332

r 328 .
17. (A) q,r,s ; (B) p,r,s ; (C) q,s
Sol. (A) Converging lens,

Q cos t

Q
1
1
3

; cos t
; sin t 1
2
2
4
2

14.

The min. time for the charge to become zero = T/4 =

(ABD)

fincident =

2
2 sec
T=

When q =

13.

Sol. fincident =

This is differential equation of SHM with

Let q =

ACD 6V ; DEA 6V

The equivalent circuit is as shown

VA + 6 - 2(2) = VD
VA + 2 = VD
VD - VA = 2 volt

3 Q 3

2
2

(q) Parallel beam will converge

(r) diverging beam may become parallel when object at focus.

(B)

11. (ABC)
Sol. Let the temperature of junction be t and let the heat currents be
H1, H2 & H3 H1 + H 2 + H3 = 0
0

40

H1

(s) diverging beam may converge when object is beyond focus

H2
t

H3
80

0 t 40 t 80 t

0
R
R
R
3t = 120
t = 40

Now, H2 =

12.

(B) Converging mirror

(p) parallel beam will converge

(r) diverging beam may become parallel if object is at focus

40 t
0
R
40
R

H1 =

H3 =

40
R

(AB)

Sol.

(s) diverging beam may diverge if object is within focus

(C) Diverging mirror

(q) parallel rays will diverge

RESONANCE

SOLAIOT050513 - 8

(C)

F B = vg = 2mg

(s) diverging rays will further diverge.

18. (A) p,q ; (B) r ; (C) p,q,s

Sol. (D) Figure shows the forces acting on the two blocks . As we
are looking for the maximum value of M / m, the equilibrium is
limiting . Hence , the frictional forces are equal to times the
corresponding normal forces.

Equilibrium of the block m gives

T = N1 and N1 = mg
which gives
T = mg

F B = vg = 2mg
(2mg) 2 (mg) 2 2mg mg 2

FB =

FR =

(mg)2 (mg)2 2(mg)(mg)

FR =

mg

mg

PART-II (Chemistry)
......(i)

T + N2 = Mg sin
Taking components normal to the incline

20. The wurtzite structure is described as hcp of S2 ions ................

Sol. (D)
B like S2
(making hcp)
A like Zn2+
(alternate tetrahedral void)
X
(alternate octahedral void)
no. of B in one unit cell = 6

= Mg cos

cos )
From (i) and (ii) , mg = Mg(sin cos )
or,

M/m =

.......(ii)

sin cos

If tan < , (sin

cos ) < 0 and the system will not

slide for any value of M/m.
19.

(A) p,r,s ; (B) r,s ; (C) r,s

Sol. ( A)

no. of A in one unit cell =

1
12 = 6
2

no. of X in one unit cell =

1
6=3
2

Formula
A6B6X3 A2B2X
A is in tetrahedral void, so, coordination number is 4.

X is in octahedral void, so, coordination number is 6.

when alternate tetrahedral voids are occupied, then centres of
6 A atoms lies on the edges of one unit cell.
21. Identify the incorrect ...................
Sol. (D)

(A) CH3CH=CH2
FB =

1
2

(D) r,s

Next, consider the equilibrium of the block M. Taking components parallel to the incline

These give T = Mg(sin

1
2

FB =

H
CH3 C H CH3

2 (2mg)

w.r.t. vessel
(B) CH3CH2CH3

(Conjugate acid of alkene).

H
CH3 CH2 CH2

Carbanion = Conjugate base of alkane).

(C) Carbocations are conjugate acids of very weak bases,
alkenes, so they are strong acids.
(D) Carbanions are conjugate bases of very weak acids, alkanes. So they are strong bases.
(B)

(A) p,r,s
F B = v(g + g) = 4mg

22. By which of the following processes, acidity ...............

Sol. (A)
(A) HgO + 4K + H2O

w.r.t. vessel

2KOH .
K2Hg4 +

basic
(B) Cu2+ + 4NH3
[Cu(NH3)4]2+
NH4+ + H2O
NH3 + H2O + H+
As NH3 is used up by Cu2+, More NH3 is produced by second
reaction, producing more H+.

(C) Al(OH)3 + NaOH

Na [Al(OH)4]

OH gets consumed, acidity increases.

(D) As a solution of weak acid is diluted, [H+] decreases.

(B) r,s

23. A chemical reaction 2NH3

N2 + 3H2 is .....................
Sol. (A)
Let the volume of He chamber become xL

40
x = 10 10
3

RESONANCE

SOLAIOT050513 - 9

x = 7.5L
volume of NH3 chamber = 10 + 2.5L
= 12.5L
If we assume that NH3 is undissociated, then its pressure P will
be
P 12.5 = 10 10
P=

27.

But NH3 has dissociated

N2 + 3H2
x
3x

8 - 2x + x + 3x =

2x =

x=

PN2

40
3

Sol.

8 + 2x =

8
3

PNH3

28 8

3
3

24. The following electrochemical cell is ...........

Sol. (D)
Cu | Cu2+(aq) || Ag+ (aq) | Ag.
E1 > 0.
(A) Due to NH3 addition, concentration of Ag+ decreases due
to complex formation. Hence, E decrease.
(B) Due to addition of HCl, Ag+ is consumed to form AgCl solid.
Concentration of Ag+ decreases. So, E decreases.
(C) Adding AgNO3 to anodic chamber result in direct reaction
between Cu and Ag+

25. Which of the following is incorrect regarding .................

Sol. (C)
(A) At concentration slightly lesser than CMC, all molecules are
present separatly.
Above CMC, they form micelles. Number of micelles is less than
no. of detergent molecules.
So concentration of micelles is less. Hence entropy decreases.
(B) Molecular masses of proteins are high as they are polymers.
Hence, for same mass of protein and urea in different solution,
concentration of urea will be more. So vapor pressure will be
more for protein solution. Also, this can be explained in terms of
entropy.
Entropy of urea solution is more than that of protein solution. So
its tendency to go in vapor phase is less.
(C) Entropy of pure solid solvent < entropy of pure liquid solvent.
< entropy of liquid solution
of non-volatile solute.
(D) Coagulation means combining together of colloid particles to
give precipitate. In this process, obviously entropy decreases.

Sol. (A)

PhCCH

OH

RESONANCE

H Br
| |
CH3 C CH CH3 CH3 C CH CH3
R 2O 2
|
|
CH2 CH3
CH2CH3
28. Write the basicity order of the following ....................
Sol. (C)
29. Consider the following reaction ...................
Sol. (D)
Br+ is not electrophilic.
30. An aqueous solution of iodine become ...............
Sol. (ABC)
2 + 2S2O32

+ S4O62

2 + Cl2 + H2O

O3 + Cl

NaO3 + Na

Br + 2 does not show reaction.

31. In a compound of Cl and F, the following ..............
Sol. (ACD)
In a compound of Cl and F, F is more electronegative and Cl is
central atom. So Cl has to be in positive oxidation state.
In ClF,
no d orbital is used in hybridisation
In ClF3, sp3d hybridisation takes place, it is polar (Tshape)
In ClF5, sp3d2 hybridisation takes place, it is polar (square pyramidal
shape)
32. Which of the following plots represent the correct ................
Sol. (AC)
For strong electrolytes
0
m= m b c
dilution =

1
.
concentrat ion

33. Which of the following hydrides react ...............

Sol. (ABC)
B2H6 + H2O
NH3 + H2O

NaOH(conc.),

HOCl

(P) ..................

HOCl

(C)

2 + NaOH

Cu2+ + 2Ag

More Cu2+ produced, hence E decreases.

(D) Adding NH3 in anodic chamber results in complex formation, [Cu(NH3)4 ]2+. Hence Cu2+ concentration decreases. So E
increases.

26. PhCCH

HBr

8
(8 ) 3
3
2
PH = 8 Kp = 8
= 3 64 = 192.
2

3

Cu + 2Ag+

O
O
|
||
H
EtMgBr
CH
3 C CH2 CH
CH3 C CH2 CH
3
3
|
Et

40
3

40
16
8=
3
3
8
.
3

Et
|
Me C CH Me ...................
|
|
H
Br

100
1000 40
=
=
= 8 atm
12.5
125
5

2NH3
8 - 2x

Me C Et
||
O

H3BO3 + H2

NH4OH

NaH + H2O

NaOH + H2

C2H6 + H2O

no reaction.

OH

34. Correct statement about peptide linkage in ............

Sol. (ABCD)
35. In which of the following reaction reactants ..............
Sol. (BCD)

SOLAIOT050513 - 10

36. (A) Ziesse's salt

................

Sol. (A) p,q,r ;

(B) s ;

(C) p

Sol. (A p,q,r,s) ; (B p,q,r) ; (C p,q)

(A) Ziese's salt = K [PtCl3 (C2H4)]. H2O
Pt2+

PART-III (Mathematics)

= 5d8 , coordination no. is 4.

39. (C)

So, it is a square planar complex.

Sol. The sum of series 84C4 + 6. 84C5 + 15. 84C6 + 20. 84C7 + 15. 84C8 + 6.
84

C9 + 84C10

= (84C4 + 84C5) + 5 (84C5 + 84C6) + 10 (84C6 + 84C7) + 10 (84C7 + 84C8) +

5 (84C8 + 84C9) + (84C9 + 84C10)
= 85C5 + 5. 85C6 + 10. 85C7 + 10 85C8 + 5 85C9 + 85C10
= (85C5 + 85C6) + 4 (85C6 + 85C7) + 6 (85C7 + 85C8) + 4 (85C8 + 85C9) + (85C9
Hence it contain plane of symmetry and C2 axis of symmetry. In
square planar complex,

x y 2 is used. As C is bonded, so it is

+ 85C10)
= 86C6 + 4. 86C7 + 6.86C8 + 4. 86C9 + 86C10
= 87C7 + 3. 87C8 + 3.87C9 + 87C10
= 88C8 + 2. 88C9 + 88C10

organometallic species.

= 89C9 + 89C10 =

(B) Wilkinson's catalyst = [RhCl(PPh3)3]

90

C10

40. (B)

Rh = 4d8 , coordination no. is 4. It is a square planar complex.

Sol. 5a2 + 2bc + 8b2 10ac + 25c2 = a2 + 6ab b2 + 17bc

4a2 + 9b2 + 25c2 = (2a) (3b) + 15bc + 10ac

(C) Nessler's reagent = alkaline K2Hg4.

(2a)2 + (3b)2 + (5c)2 = (2a) (3b) + (3b) (5c) + (5c) (2a)

[Hg4]2 = sp3 hybridisation.

Tetrahedral species, contain axis as well as plane of symmetry.
2a = 3b = 5c

37. (A) Zero order reaction ....................

a
b
c
=
=
= (say)
15 10
6

Sol. (A q,r) ; (B p,s) ; (C p,r,s)

(A) Zero order reaction rate is constant.
time taken to complete x% depend

cosA =

2
2
2
b 2 c 2 a 2 100 36 225
=
2(10 )(6 )
2bc

on initial amount.
so t1/2 also depend on initial amount.
concentration of product increases
=

linearly with time.

892
120 2

89
120

(B) First order reaction rate = k [A], so it increase on in

creasing concentration of reactant.

41. (D)

the time taken to complete x% of re

action is independent of concentration.

Sol. Equation of tangent y = 2x +

4a 2 b 2

the concentration of product increase

non-linearly with time.
(C) First order w.r.t.

passes (2, 0) 4 =

4a 2 b 2

each reactant in

rate = k [A]2 , so it increase on in

4a2 + b2 = 16

stoichiometric

creasing concentration of reactant

locus of (a, b) is 4x2 + y2 = 16

time taken to complete x% of reac

Area =

ratio = 2nd order

tion decrease on increasing reactant

1
(2)(4) = 2
4

concentration.
t1/2 depends on concentration.

42. (D)

graph of concentration of product

Sol. Apply Rolle's theorem on f(x), g(x) = ex f(x) and h(x) = ex f(x)

with time is non-linear.

43. (C)

38. (A)

RESONANCE

.......................

SOLAIOT050513 - 11

1 = a(1+x3) (3x3) 3b(1 + x3)2 3x6 . C

1 = 3a(x3 + x6) 3b(1 + x6 + 2x3) 3cx6
= 3b 3x6 (c + b + a) + x3 (3a 6b)
3b = 1, 3a 6b = 0, a + b + c = 0
Sol.
b =

(a1 + a2 + a3 + a4) = 21,

1
2
1
,a=
,c=
3
3
3

46. (D)

a5 + a3 + a6 + a7 = 21,
a1 + a2 + a3 + a4 + a5 + a6 + a7 = 35
a3 = 7, a1 + a2 + a4 = 14, a5 + a6 + a7 = 14
a1, a2 , a4 {2,4,8}, a5 , a6 , a7 {3,5,6}
or

Sol.

a1, a2 , a4 {3,5,6}, a5 , a6 , a7 {2,4,8}

Required number of ways = (3! 3!) + (3! 3!) = 72

L1
L2

M1 M2 M3

L3
L4

M4

M5

M6

44. (C)
Sol. First note that the area of the region determined by the triangle
4

topped by the semicircle of diameter 1 is

Required probability =

C1 3 C 2
6

C2

4
5

1 3 1 1
3 1
.
=

2 2
2 2
4
8

Alter : Required probability = 1 (no languages is common)

The area of the lune results from subtracting from this the area

=11

of the sector of the larger semicircle,

1 4
=
5
5

47. (D)

1
1
(1) 2
6
6

Sol.

sin1 x x a
I. represents the limiting case when a > 0.

So the area of the Iune is

3 1
1
3
1
=

4
8
6
4
24
Note that the answer does not depend on the position of the
lune on the semi-circle.
45. (C)

dx
Sol.

= a n
3 2

x 1 x
4

1 x 3
x

b
+

c
+

1 x3

+d

In this case, y = (a x) must pass through

Differentiating both sides, we get

1, .
2

1
4

x 1 x3

= a 1 a = 1 +
2
2

II. represents the limiting case when a < 0. In this case,

=a

1 x

x .3 x 1 x .3 x

x6

RESONANCE

3b
x4

3x .c

3 2

1 x

SOLAIOT050513 - 12

y = (x a) must pass through

1, .
2

48. (B)

+ ... +

cot n 2 cot n1 = cot n2 .
2
2

49. (AB)

sin

Sol. S =

2
3
9
sin
sin ....... sin
18
18
18
18

3
6
9

5
7
2
4
8

sin
sin

= sin 18 sin 18 sin 18 sin 18 sin 18 sin 18 sin

18
18
18

Sol.

sin

1+

3 1
6
1
sin
sin

18 4
18
4

3
1 1 1 3 1 3
. . .
. .
=
256
4 2 4 2 2 2

ak

ak
k 1 =
= k
2
r
2
2
k

2
2
2
2
+
+
+ ... +
a1 a 2
a3
an

= 1 + cosec

1 3
.
.1
2 2

C=

cos

2
3
8
cos
cos
.......cos
18
18
18
18

2 + cosec 3 + ... + cosec n 1
2
2
2

= cos 18 cos 18 cos 18 cos 18 cos 18 cos 18 cos 18 cos 18

sin
sin
2
2

cosec =
=

sin sin sin sin

2
2

3
256

S = C, S + C =

3
128

50. (AB)
Sol. The point of intersection of diagonals is (0, 0) and one vertex
A(2, 1)

cos sin
2
2

sin sin
2

sin cos
=

cot
2

= cot

1 +

2
22
23
2n
+
+
+ ... +
a1 a 2
a3
an

Vertex c is (2, 1) verties B & D are i(2 + i)

1 + 2i, 1 2i

B(1, 2) & D(1, 2)

Equation of the sides are x + 3y = 5, 3x y = 5.

51. (ACD)

=1+

cot 3 cot + cot 4 cot 3

4
2
2
2

RESONANCE

Sol. y = f (x) =

x2 1
2

x 1

2
=1

x 1

SOLAIOT050513 - 13

4x
( x 2 1) 2

f ' (x) =

x2

lim

x 0

lim

x0

a x 1 cos x

=1

1
2
1
1 cos x
a
ax

2
x

= 1 a = 4

53. (AC)
Sol. Equation of plane passing through A, B and D passes through C

2 2 5

x > 0, f is increasing and x < 0, f is decreasing (B) is true

range is [1, 1)

into

x 2 1

dx
A = 2 1 2

x
1

=4

(A) is false

hence A, B, C and D are coplanar

4. tan 1 x

= 4

1 0

=0

dx

x2 1

( 2) + 1 ( 2 + 5) = 0

2 + 3 = 0

= 2

3
2

for point of intersection of diagonals equation of AC is

Hence D is false

3
i

3
i

2k

j
+ (
+ 1 j + 0 k ) = 2 k +
r =

2
2

Minimum value is 1.
Hence C is false.
52. (BC)

Sol.

lim

x 0

equation of BD

dt
at
=1
bx sin x

since limit is of

2 = 3 4=

0
form
0

x 0 b

ax
1
1 ; xlim
0 a x b cos x
cos x

As x 0, Numerator 0 but Denominator

therefore b 1 = 0

3 1
, 2 Ans.
,
4 2

54. (BC)

x2

But limit exists and is equal to

5
4

point of intersection :

x2
lim

r = 2 i + 2 j 3 k + ( i + 2 j 4 k )

Sol Rough sketch for the function f(x) w.r.t. the sketch of f(x) can
be

(b 1)

b=1

a 0, otherwise limit will not exist.

RESONANCE

SOLAIOT050513 - 14

centre of circle NT as diameter is circumcentre of

For

Option (A) Graph of f(x) has zeroes at x = a, c, e so there are

triangle POT.
Let C(x1, y1) be centre

exactly three extrema for f(x).

Option (B) At x = b and x = d curvature of f(x) changes so there
are the point of inflection f(x).
Option (C) In the graph of f(x), for x (d,e) curvature is upward

2x1 = acos,

2y1 =

a2 b2
tan
b

so sign of f(x) should (+ve) or f(x) > 0.

Option (D) At x = e, local minima. so wrong.

a
2by1
, tan = 2
2 x1
a b2

sec =
55. Ans. (A) - (p), (B) - (p), (C) - (s)
Sol. (A)

Q P Q(x) has degree n 7n = 7n2

(B)

7n2

= 7 n = 1 Ans.

10 2013 1
10 33 1

a2
Locus is

(10 33 ) 61 1

4x 2

4b2 y 2

(a2 b2 )2

=1

(B) Points of intersection with coordinate axis

10 33 1

= (103360 + 103359 + 103358 +......+ 1)

unit digit = 1

(C)

2
m( 2 2 ( )
m 2 m
+
=
1 ( )
1 1

on y-axis put x = 0
y2 4y 12 = 0 y = 6, y = 2

(0, 6)(0, 2)

on x-axis put y = 0
x2 + x 12 = 0 x = 3, x = 4 (3, 0) (4, 0)

1
1
d1 d2 =
7 8 = 28 sq.units
2
2

area =

m (2m 3 8m 2 8m 2)
m2 m

now real roots

= 2(m2 3m + 1)

lim f ( x )
(C) For continuity at x = 1, we must have f(1) = x
1

D > 0 m < +1

Maximum value = 10

1 / nx

lim tan nx
x 1

56. Ans. (A) - (p), (B) - (q), (C) - (r)

Sol. (A) P(asec, btan)
T(acos, 0)

N 0,

tan nx 1
4

lim
nx
= e x 1

a2 b2
tan

lim

1 tan( nx ) (1 tan( nx ))
(1 tan( nx )).nx

e x 1

e x 1

lim

2. tan( nx )
1
.
nx
1 tan( nx )

= e2

Circle with NT as diameter passes through O and P

RESONANCE

SOLAIOT050513 - 15

57. Ans. (A) (r); (B) (p); (C) (s)

Sol. (A)

6 sin1

17
2
x 6x
=
2

6x

sin1 x

x2 6x +

x2 6x + 8 = 0

x = 2, 4

17
=
2 6

17
1
=
2
2

(B) Let f(x) = (1 x2013)1/2012

f

1(x)

= (1 x2012)1/2013

Hence

2012 1 x 2013 2013 1 x 2012 dx

=0

(C) Use De Moivre's theorem get the product of roots with + ve

real part

z = 2(1)1/6 = 2 cos

put m = 0

z1z2 =

4ei/6

or

e(11/6)i

2m
2m
isin

6
6

m = 5 for positive real part to get

= 4e2i = 4

RESONANCE

SOLAIOT050513 - 16