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16.03.2009
GOLD 25 g/L, codes: 13093, DPM 9005, FDS13093
1/6
Classification of the
pure substances
Symbols
S phrases
Classification of the
substances according
to their concentration
In the preparation, in
weight:
T+ R26/27/28
R32
N R50/53
T+, N
(1/2)-7-28-29-45-60-61
7%
T+ R26/27/28
1-7%
T R23/24/25
Xn R20/21/22
0.1-1%
N R50/53
25%
N R51/53
2.5-25%
R52/53
0.25-2.5%
-
OTHER SUBSTANCES WITH WORKPLACE EXPOSURE LIMITS: YES: ethylenediamine, less than 1 %, i.e. below the
minimal level defined in the directives.
Substances with the R33 phrase (if 1%) or with the R64 phrase (if 1%) or other sensitising substances (if 0.1%): NO.
OTHER INFORMATION: Gold content = 25 g/L.
________________________________________________________________________________________________
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16.03.2009
GOLD 25 g/L, codes: 13093, DPM 9005, Safety Data Sheet, document code: FDS13093
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16.03.2009
GOLD 25 g/L, codes: 13093, DPM 9005, Safety Data Sheet, document code: FDS13093
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Cyanides
(in CN) *
-
Hydrogen cyanide
(HCN) *
-
Gold compounds
Ethylenediamine
-
Average value
3
(8h) = 5 mg/m
PERSONAL PROTECTION
Provide a shower, a powerful tap and sink unit, an eye basin near the workplace and a protective breathing mask for
emergency interventions.
Respiratory protection: during brush plating, provide an effective inhaling of the sprays / vapours where they are
created and extraction out of the premises, and if insufficient, wear a filtering A2B2 cartridge (EN 405:2002 standard).
Hand protection: wear imperatively gloves (in latex or nitrile for example).
Eye protection: wear glasses with lateral protections or a facial screen. Do not wear contact lenses.
Skin protection: wear overalls and safety shoes.
For long-term and continuous uses, or according to the involved quantities of product or to the circumstances of work, it
can be appropriate to add:
a cyanide detection control system (permanent display or instant readings),
for emergency interventions: one or several protective breathing apparatus (complete airtight mask and compressed
air bottle), an oxygen bottle with mask, an emergency kit, the contents and use of which will be specified by the
company doctor. The hydroxocobalamine (B12 vitamin) is often recommended as antidote in case of cyanide
poisoning but presents an allergic shock risk. It must be administered by a resuscitating doctor in the minutes following
the accident. This product is available in pharmacies (Cyanokit 2.5 g for example).
Provide each operator with 2 separate clothing lockers or 1 locker with 2 compartments to allow him to separate non-work
clothes and work clothes.
Draw up a specific intervention plan in the event of an accident (with the company doctor, company safety managers, firstaid workers, external emergency services: ambulance, fire service, hospital, working together). Display the intervention
plan in the work unit.
Inform and train personnel relative to the risks, precautions to be taken and measures to be applied in the event of an
incident.
Hold intervention training sessions.
________________________________________________________________________________________________
service@dalicworld.com
16.03.2009
GOLD 25 g/L, codes: 13093, DPM 9005, Safety Data Sheet, document code: FDS13093
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No bioaccumulation.
service@dalicworld.com
16.03.2009
GOLD 25 g/L, codes: 13093, DPM 9005, Safety Data Sheet, document code: FDS13093
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FISHES - Lepomis macrochirus NOEC (57 days): < 0,005 mg/L - Salvelinus fontinalis NOEC (234 days): < 0,006 mg/L.
INVERTEBRATES - Gammares NOEC (83 days): < 0,01 mg / L - Asellus communis NOEC (112 j): < 0,01 mg / L
So the concentration without accute effects would be from 0,05 to 0,5 g /L.
Concentration without foreseeable effect for the environment: PNECfresh water = 0,114 g /L.
According to the directive 1999/45/EC, this solution must be classified with the N symbol: DANGEROUS FOR THE
ENVIRONMENT and with the R51-53 phrase because of its content in cyanide.
________________________________________________________________________________________________
13 - DISPOSAL CONSIDERATIONS
This product and water used for rinsing must not be thrown away notably because of their pH and cyanide contents. They
must be processed within the firm or destroyed by an approved organization without mixing with acids. Before, the
recovery of gold remaining in solution can be good.
Contaminated packaging if not re-used with the same product is also a special waste to be sent to an approved
organization for recycling or disposal.
Classification according to the commission directive 2000/532/EC of 3 May 2000 and its modifications (in particular
2001/118/EC, OJ L47). Use the mandatory documents to follow-up the waste products.
06 03 11*
15 01 10*
15 02 02*
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16.03.2009
GOLD 25 g/L, codes: 13093, DPM 9005, Safety Data Sheet, document code: FDS13093
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HEALTH SURVEILLANCE
Council Directive 98/24/EC of 7 April 1998 on the protection of the health and safety of workers from the risks related to
chemical agents at work
An appropriate health surveillance of workers must be carried out according to the risk.
For each worker who undergoes this health surveillance, individual health and exposure records are to be made and kept
up-to-date.
See also specific legislative and administrative, national or local provisions on the following topics:
occupational diseases,
health surveillance,