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To:
pre-registration with the European Chemicals Agency of certain substances (as such, or contained in
preparations/mixtures to the extent where they are not covered by other more specific legislation, or, in
articles if substance is intended to be released during conditions of use) manufactured/used in, or
imported into, the European Economic Area (EEA) by December 1 2008; and
Subsequent registration of certain substances by specified deadlines, depending on the hazard profile
and/or annual manufacture, use or import volumes of the substance by the registrant in question.
Further information and guidance on the REACH Regulation can be found on the European Chemicals Agency
(ECHA) website (http://echa.europa.eu/home_en.asp).
Compliance with REACH is essential for the future marketing in the EEA of both M-I SWACO products and any of
your products which incorporate M-I SWACOs product(s). M-I SWACO is therefore dedicated to ensuring
effective REACH compliance for all M-I SWACO products placed on the EEA market whilst maintaining our
relationships with our customers and avoiding business interruption.
All of M-I SWACO chemicals used are either compliant with REACH requirements or are exempt from REACH
registration requirements either because they are listed in the relevant annex or covered under other legislation.
1|P a g e
Regarding your specific inquiry on the products, please see below answers:
Please note that the following products are considered exempt under REACH.
Product name
BARITE
Calcium Carbonate
MICA FINE
MICA MEDIUM
NUT PLUG FINE
KWIK-SEAL
MIKHART 0.35 0.7
MIKHART 130
MIKHART 10
MIKHART 10
MIKHART 65
NUT PLUG FINE
SUGAR
For the products below; please be assured that all the non exempt substances present in the product are REACH
compliant; non exempt substances will be registered by M-I SWACO or our upstream supplier.
Product name
KCL
KOH
XCD Polymer
Polypac UL
POLYPAC REGULAR
SODA ASH
BICARBONATE
DEFOAM X-EH
SOLTEX
LUBE 167
POTASSIUM CARBONATE
GLYDRIL MC
POLYPLUS LIQUID
SAFE SCAV NA
SAFE CIDE
SAFE COR
2|P a g e
We trust this satisfies your initial inquiry and we will keep you updated on any developments affecting supply to
your company.
For further questions regarding REACH, you can contact any member of our REACH Implementation Team at
REACH@miswaco.slb.com or send an email to csmith03@slb.com. You can also find more about our
commitment to REACH in the QHSE portion of the M-I SWACO website at
http://www.slb.com/services/miswaco/qhse/reach.aspx
Kind regards,
Chioma Smith
Chemical Regulatory Specialist
on behalf of the M-I SWACO REACH Compliance Team
3|P a g e
SDS No.
10201
Revision 5
Supersedes date 15-NOV-2011
DEFOAM-X* EH
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Defoamer.
M-I SWACO
A Schlumberger Company
Endeavour Drive
Arnhall Business Park, Westhill
Aberdeen AB32 6UF
Scotland UK
T = +44 (0)1224-742200
F = +44 (0)1224-742288
E-mail = MBXMSDS-EH@miswaco.slb.com
Not classified.
Not classified.
NC
Not classified.
Safety Phrases
2.3. Other hazards
Not Classified as PBT/vPvB by current EU criteria.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.2. Mixtures
WATER
60-100%
Classification (67/548/EEC)
Not classified.
1/ 6
SDS No.
10201
DEFOAM-X* EH
POLY(DIMETHYLSILOXANE)
5-10%
Classification (67/548/EEC)
Not classified.
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Composition Comments
The data shown is in accordance with the latest EC Directives.
SECTION 4: FIRST AID MEASURES
4.1. Description of first aid measures
Inhalation
Move the exposed person to fresh air at once. If respiratory problems, artificial respiration/oxygen. Get medical attention if any discomfort
continues.
Ingestion
Immediately give a couple of glasses of water or milk, provided the victim is fully conscious. Do not induce vomiting. Get medical attention
if any discomfort continues.
Skin contact
Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention promptly if symptoms occur after
washing.
Eye contact
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids.
Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
Inhalation.
This is unlikely to occur but symptoms similar to those of ingestion may develop.
Ingestion
May cause discomfort if swallowed.
Skin contact
Prolonged skin contact may cause redness and irritation.
Eye contact
May cause temporary eye irritation.
4.3. Indication of any immediate medical attention and special treatment needed
Get medical attention if any discomfort continues.
SECTION 5: FIREFIGHTING MEASURES
5.1. Extinguishing media
Extinguishing media
Water spray, foam, dry powder or carbon dioxide.
Unsuitable extinguishing media
Not known.
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products
When heated, vapours/gases hazardous to health may be formed.
5.3. Advice for firefighters
Special Fire Fighting Procedures
Containers close to fire should be removed immediately or cooled with water.
Protective equipment for fire-fighters
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
Wear protective clothing as described in Section 8 of this safety data sheet.
2/ 6
SDS No.
DEFOAM-X* EH
6.2. Environmental precautions
Do not allow to enter drains, sewers or watercourses.
6.3. Methods and material for containment and cleaning up
Stop leak if possible without risk. Dike far ahead of larger spills for later disposal. Absorb spillage with suitable absorbent material. Shovel
into dry containers. Cover and move the containers. Flush the area with water.
6.4. Reference to other sections
Wear protective clothing as described in Section 8 of this safety data sheet.
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for safe handling
Avoid spilling, skin and eye contact. Do not eat, drink or smoke when using the product.
7.2. Conditions for safe storage, including any incompatibilities
Store in tightly closed original container in a dry, cool and well-ventilated place. Protect from freezing and direct sunlight.
7.3. Specific end use(s)
The identified uses for this product are detailed in Section 1.2.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters
Ingredient Comments
No exposure limits noted for ingredient(s).
8.2. Exposure controls
Protective equipment
Engineering measures
Provide adequate general and local exhaust ventilation.
Respiratory equipment
No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air
contamination exists.
Hand protection
Use protective gloves made of: Rubber, neoprene or PVC.
Eye protection
Wear tight-fitting goggles or face shield.
Other Protection
Wear appropriate clothing to prevent any possibility of skin contact. Provide eyewash station.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Appearance
Liquid
Colour
Off-white
Odour
Slight odour.
Solubility
~ 100C
Relative density
6-8
Flash point
> 100C
10201
SDS No.
DEFOAM-X* EH
10.1. Reactivity
There are no known reactivity hazards associated with this product.
10.2. Chemical stability
Stable under normal temperature conditions and recommended use.
10.3. Possibility of hazardous reactions
Not known.
10.4. Conditions to avoid
Not known.
10.5. Incompatible materials
Materials To Avoid
Not known.
10.6. Hazardous decomposition products
When heated, vapours/gases hazardous to health may be formed.
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
Acute toxicity:
Acute Toxicity (Oral LD50)
> 2000 mg/kg
*Based on components
Aspiration hazard:
Not anticipated to present an aspiration hazard based on chemical structure.
Inhalation
Gas or vapour in high concentrations may irritate respiratory system.
Ingestion
May cause discomfort if swallowed.
Skin contact
Prolonged and frequent contact may cause redness and irritation.
Eye contact
Spray and vapour in the eyes may cause irritation and smarting.
Route of entry
No route of entry noted.
Target Organs
No specific target organs noted
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity
Contact M-I SWACO's QHSE Department for ecological information at env@miswaco.slb.com.
12.1. Toxicity
Acute Fish Toxicity
Not considered toxic to fish.
Acute Toxicity - Fish
LC50 > 100 mg/l
12.2. Persistence and degradability
Degradability
The product is not readily biodegradable.
4/ 6
10201
SDS No.
DEFOAM-X* EH
12.3. Bioaccumulative potential
Bioaccumulative potential
Bioaccumulation is negligible. LogPow < 3
12.4. Mobility in soil
Mobility:
Not determined.
12.5. Results of PBT and vPvB assessment
Not Classified as PBT/vPvB by current EU criteria.
12.6. Other adverse effects
None known.
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance with local authority requirements.
SECTION 14: TRANSPORT INFORMATION
General
The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,
ADR/RID).
14.1. UN number
Not applicable.
14.2. UN proper shipping name
Not applicable.
14.3. Transport hazard class(es)
Not applicable.
14.4. Packing group
Not applicable.
14.5. Environmental hazards
Environmentally Hazardous Substance/Marine Pollutant
No.
14.6. Special precautions for user
Not applicable.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.
SECTION 15: REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Uk Regulatory References
Chemicals (Hazard Information & Packaging) Regulations. Control of Substances Hazardous to Health Regulations 2002 (as amended)
Workplace Exposure Limits EH40.
EU Legislation
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive
1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive
76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.
Water hazard classification
WGK 1
5/ 6
10201
SDS No.
10201
DEFOAM-X* EH
15.2. Chemical Safety Assessment
International Chemical Inventories
Contact REACH@miswaco.slb.com for REACH information. Complies with the following national/regional chemical inventory requirements:
Australia (AICS), Canada (DSL / NDSL), China (IECSC), Europe (EINECS / ELINCS), Japan (METI / ENCS), Korea (TCCL / ECL), New
Zealand (NZIoC), Phillipines (PICCS), United States (TSCA).
SECTION 16: OTHER INFORMATION
Abbreviations and acronyms used in the safety data sheet
*a mark of M-I L.L.C.
Information Sources
Product information provided by the commercial vendor(s). Material Safety Data Sheet, Misc. manufacturers. LOLI. European Chemicals
Bureau - ESIS (European Chemical Substances Information).
Revision Comments
General revision. Compiled or Revised by Ewan MacLeod
Issued By
Bill Cameron
Revision Date
15-FEB-2012
Revision
Supersedes date
15-NOV-2011
SDS No.
10201
Not classified.
Disclaimer
MSDS furnished independent of product sale. While every effort has been made to accurately describe this product, some of the data are obtained from
sources beyond our direct supervision. We cannot make any assertions as to its reliability or completeness; therefore, user may rely only at user's risk.
We have made no effort to censor or conceal deleterious aspects of this product. Since we cannot anticipate or control the conditions under which this
information and product may be used, we make no guarantee that the precautions we have suggested will be adequate for all individuals and/or
situations. It is the obligation of each user of this product to comply with the requirements of all applicable laws regarding use and disposal of this
product. Additional information will be furnished upon request to assist the user; however, no warranty, either expressed or implied, nor liability of any
nature with respect to this product or to the data herein is made or incurred hereunder.
6/ 6
SDS No.
10759
Revision 6
Supersedes date 15-11-10
GLYDRIL* MC
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
M-I SWACO
A Schlumberger Company
Endeavour Drive
Arnhall Business Park, Westhill
Aberdeen AB32 6UF
Scotland UK
T = +44 (0)1224-742200
F = +44 (0)1224-742288
E-mail = MBXMSDS-EH@miswaco.slb.com
Classification (67/548/EEC)
Signal Word
Danger
Hazard Statements
H318
P280
P305+351+338
Precautionary Statements
1/ 6
SDS No.
10759
GLYDRIL* MC
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.1. Substances
GLYCOL ETHER MIXTURE
CAS-No.: 9004-77-7
60-100%
EC No.: 500-012-0
Classification (67/548/EEC)
Xi;R41.
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Composition Comments
The data shown is in accordance with the latest EC Directives.
SECTION 4: FIRST AID MEASURES
4.1. Description of first aid measures
Inhalation
Move the exposed person to fresh air at once. If respiratory problems, artificial respiration/oxygen. Get medical attention if any discomfort
continues.
Ingestion
Do not induce vomiting. If vomiting occurs, the head should be kept low so that stomach vomit doesn't enter the lungs. Risk of chemical
pneumonia after aspiration. Immediately give a couple of glasses of water or milk, provided the victim is fully conscious. Get medical
attention.
Skin contact
Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention promptly if symptoms occur after
washing.
Eye contact
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids.
Continue to rinse for at least 15 minutes and get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Inhalation.
This is unlikely to occur but symptoms similar to those of ingestion may develop. Gas or vapour in high concentrations may irritate
respiratory system.
Ingestion
Nausea, vomiting. Risk of chemical pneumonia after aspiration. If swallowed, especially in large quantities: Central nervous system
depression.
Skin contact
Prolonged skin contact may cause redness and irritation.
Eye contact
Irritation of eyes and mucous membranes. Splashes may cause serious eye damage.
4.3. Indication of any immediate medical attention and special treatment needed
Get medical attention if any discomfort continues.
SECTION 5: FIREFIGHTING MEASURES
5.1. Extinguishing media
Extinguishing media
Water spray, foam, dry powder or carbon dioxide.
Unsuitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products
Fire or high temperatures create: Vapours/gases/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2).
5.3. Advice for firefighters
Special Fire Fighting Procedures
Containers close to fire should be removed immediately or cooled with water. Do not use water jet as an extinguisher, as this will spread
the fire.
2/ 6
SDS No.
GLYDRIL* MC
Protective equipment for fire-figthers
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
Wear protective clothing as described in Section 8 of this safety data sheet.
6.2. Environmental precautions
Do not allow to enter drains, sewers or watercourses.
6.3. Methods and material for containment and cleaning up
Stop leak if possible without risk. Dike far ahead of larger spills for later disposal. Absorb spillage with suitable absorbent material. Shovel
into dry containers. Cover and move the containers. Flush the area with water.
6.4. Reference to other sections
Wear protective clothing as described in Section 8 of this safety data sheet.
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for safe handling
Avoid spilling, skin and eye contact. Keep away from heat, sparks and open flame.
7.2. Conditions for safe storage, including any incompatibilities
Store in tightly closed original container in a dry, cool and well-ventilated place.
7.3. Specific end use(s)
The identified uses for this product are detailed in Section 1.2.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters
Ingredient Comments
No exposure limits noted for ingredient(s).
8.2. Exposure controls
Protective equipment
Engineering measures
Provide adequate general and local exhaust ventilation.
Respiratory equipment
No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air
contamination exists. Chemical respirator with organic vapour cartridge.
Hand protection
For prolonged or repeated skin contact use suitable protective gloves. Butyl rubber. or Neoprene gloves are recommended.
Eye protection
Wear approved chemical safety goggles where eye exposure is reasonably probable.
Other Protection
Wear appropriate clothing to prevent any possibility of skin contact. Provide eyewash station.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Appearance
Liquid
Colour
Odour
Mild.
Solubility
> 200C
Relative density
Vapour pressure
10759
SDS No.
GLYDRIL* MC
Viscosity
<-12C
Inhalation
Gas or vapour may irritate respiratory system.
Ingestion
Gastrointestinal symptoms, including upset stomach. Nausea, vomiting. Central nervous system depression.
Skin contact
Prolonged contact may cause redness and irritation.
Eye contact
Irritating to eyes. Risk of serious damage to eyes.
Route of entry
Ingestion. Skin and/or eye contact.
Target Organs
Central nervous system Eyes
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity
Contact M-I SWACO's QHSE Department for ecological information at env@miswaco.com.
12.1. Toxicity
Acute Fish Toxicity
Not considered toxic to fish.
12.2. Persistence and degradability
Degradability
The product is expected to be biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential
The product does not contain any substances expected to be bioaccumulating.
12.4. Mobility in soil
4/ 6
10759
SDS No.
GLYDRIL* MC
Mobility:
Semi-mobile.
12.5. Results of PBT and vPvB assessment
Not Classified as PBT/vPvB by current EU criteria.
12.6. Other adverse effects
None known.
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance with local authority requirements.
SECTION 14: TRANSPORT INFORMATION
General
The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,
ADR/RID).
14.1. UN number
Not applicable.
14.2. UN proper shipping name
Not applicable.
14.3. Transport hazard class(es)
Not applicable.
14.4. Packing group
Not applicable.
14.5. Environmental hazards
Environmentally Hazardous Substance/Marine Pollutant
No.
14.6. Special precautions for user
Not applicable.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
The product has been assessed and contained in Chapters 17 and 18 of the IBC Code and the latest MEPC.2/Circular and is permitted to
be carried under Annex II of MARPOL and resolution A.673 (16) Offshore Supply Vessel Code. Ship Type:- 3. Pollution Category:- Z.
SECTION 15: REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Uk Regulatory References
Chemicals (Hazard Information & Packaging) Regulations. Control of Substances Hazardous to Health Regulations 2002 (as amended)
Workplace Exposure Limits EH40.
EU Legislation
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive
1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive
76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.
15.2. Chemical Safety Assessment
International Chemical Inventories
Contact REACH@miswaco.com for REACH information. Complies with the following national/regional chemical inventory requirements:
AICS, DSL / NDSL, IECSC, EINECS / ELINCS, METI ENCS, TCCL ECL, NZIoC, PICCS, TSCA,
SECTION 16: OTHER INFORMATION
Abbreviations and acronyms used in the safety data sheet
*a mark of M-I L.L.C.
General information
HMIS Health - 2 HMIS Flammability - 1 HMIS Physical Hazard - 0 J - Splash Goggles, Gloves, Synthetic Apron, Dust and Vapour
Respirator.
5/ 6
10759
SDS No.
10759
GLYDRIL* MC
Information Sources
Product information provided by the commercial vendor(s). Material Safety Data Sheet, Misc. manufacturers. LOLI. European Chemicals
Bureau - ESIS (European Chemical Substances Information). MARPOL 73/78. Marine Environment Protection Committee (MEPC)
Circulars. MEPC.2 MEPC 54/10/4. IBC Code. IMO Resolution A.673 (16), Guidelines for the Transport and Handling of Limited Amounts of
Hazardous and Noxious Liquid Substances in Bulk Offshore Support Vessels.
Revision Comments
General revision. Compiled or Revised by Ewan MacLeod
Issued By
Bill Cameron
Revision Date
06-09-11
Revision
Supersedes date
15-11-10
SDS No.
10759
Disclaimer
MSDS furnished independent of product sale. While every effort has been made to accurately describe this product, some of the data are obtained from
sources beyond our direct supervision. We cannot make any assertions as to its reliability or completeness; therefore, user may rely only at user's risk.
We have made no effort to censor or conceal deleterious aspects of this product. Since we cannot anticipate or control the conditions under which this
information and product may be used, we make no guarantee that the precautions we have suggested will be adequate for all individuals and/or
situations. It is the obligation of each user of this product to comply with the requirements of all applicable laws regarding use and disposal of this
product. Additional information will be furnished upon request to assist the user; however, no warranty, either expressed or implied, nor liability of any
nature with respect to this product or to the data herein is made or incurred hereunder.
6/ 6
SDS No.
10895
Revision: 3
Supersedes Date: 01-04-08
LUBE-167*
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
M-I SWACO
A Schlumberger Company
Endeavour Drive
Arnhall Business Park, Westhill
Aberdeen AB32 6UF
Scotland UK
T = +44 (0)1224-742200
F = +44 (0)1224-742288
E-mail = MBXMSDS-EH@miswaco.slb.com
Not classified.
Not classified.
NC
Not classified.
Safety Phrases
2.3. Other hazards
Not Classified as PBT/vPvB by current EU criteria.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.2. Mixtures
GLYCOL BLEND
30-60%
Classification (67/548/EEC)
Not classified.
30-60%
Classification (67/548/EEC)
Not classified.
1/ 6
SDS No.
10895
LUBE-167*
VEGETABLE OIL
10-30%
Classification (67/548/EEC)
Not classified.
The Full Text for all R-Phrases and Hazard Statements is Displayed in Section 16
Composition Comments
The data shown is in accordance with the latest EC Directives.
SECTION 4: FIRST AID MEASURES
4.1. Description of first aid measures
Inhalation.
Move the exposed person to fresh air at once. If respiratory problems, artificial respiration/oxygen. Get medical attention if any discomfort
continues.
Ingestion
Immediately give a couple of glasses of water or milk, provided the victim is fully conscious. Do not induce vomiting. Get medical attention
if any discomfort continues.
Skin Contact
Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention promptly if symptoms occur after
washing.
Eye Contact
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids.
Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
Inhalation.
This is unlikely to occur but symptoms similar to those of ingestion may develop.
Ingestion
May cause discomfort if swallowed.
Skin Contact
Prolonged skin contact may cause redness and irritation.
Eye Contact
May cause temporary eye irritation.
4.3. Indication of any immediate medical attention and special treatment needed
Get medical attention if any discomfort continues.
SECTION 5: FIREFIGHTING MEASURES
5.1. Extinguishing media
Extinguishing Media
Water spray, foam, dry powder or carbon dioxide.
5.2. Special hazards arising from the substance or mixture
Hazardous Combustion Products
When heated, vapours/gases hazardous to health may be formed.
Specific Hazards
Fire or high temperatures create: Vapours/gases/fumes of: Carbon dioxide (CO2). and Carbon monoxide (CO).
5.3. Advice for firefighters
Special Fire Fighting Procedures
Containers close to fire should be removed immediately or cooled with water.
Protective Measures In Fire
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
Wear protective clothing as described in Section 8 of this safety data sheet.
2/ 6
SDS No.
LUBE-167*
6.2. Environmental precautions
Do not allow to enter drains, sewers or watercourses.
6.3. Methods and material for containment and cleaning up
Stop leak if possible without risk. Dike far ahead of larger spills for later disposal. Absorb spillage with suitable absorbent material. Shovel
into dry containers. Cover and move the containers. Flush the area with water.
6.4. Reference to other sections
Wear protective clothing as described in Section 8 of this safety data sheet.
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for safe handling
Avoid spilling, skin and eye contact. Avoid inhalation of vapours and spray mists.
7.2. Conditions for safe storage, including any incompatibilities
Store in tightly closed original container in a dry, cool and well-ventilated place. Do not store near heat sources or expose to high
temperatures.
7.3. Specific end use(s)
The identified uses for this product are detailed in Section 1.2.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters
Ingredient Comments
No exposure limits noted for ingredient(s).
8.2. Exposure controls
Protective Equipment
Engineering Measures
Provide adequate general and local exhaust ventilation.
Respiratory Equipment
No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air
contamination exists. Chemical respirator with organic vapour cartridge.
Hand Protection
For prolonged or repeated skin contact use suitable protective gloves. Use protective gloves made of: Butyl rubber. or Neoprene.
Eye Protection
Wear approved chemical safety goggles where eye exposure is reasonably probable.
Other Protection
Wear appropriate clothing to prevent any possibility of skin contact. Provide eyewash station.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Appearance
Liquid
Colour
Light brown
Odour
Slight odour
Solubility
Disperses.
Relative Density
>10
8-10 @ 1%
10895
SDS No.
LUBE-167*
10.1. Reactivity
There are no known reactivity hazards associated with this product.
10.2. Chemical stability
Stable under normal temperature conditions and recommended use.
10.3. Possibility of hazardous reactions
Not known.
10.4. Conditions to avoid
Not known.
10.5. Incompatible materials
Materials To Avoid
Strong oxidising substances.
10.6. Hazardous decomposition products
Fire or high temperatures create: Vapours/gases/fumes of: Carbon dioxide (CO2). and Carbon monoxide (CO).
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
Inhalation
Gas or vapour in high concentrations may irritate respiratory system.
Ingestion.
May cause discomfort if swallowed.
Skin Contact
Prolonged and frequent contact may cause redness and irritation.
Eye Contact
Spray and vapour in the eyes may cause irritation and smarting.
Route of entry
No route of entry noted.
Target Organs
No specific target organs noted.
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity:
Contact M-I SWACO's QHSE Department for ecological information at env@miswaco.com.
12.1. Toxicity
Acute Fish Toxicity
Not considered toxic to fish.
12.2. Persistence and degradability
Degradability:
There are no data on the degradability of this product.
12.3. Bioaccumulative potential
Bioaccumulative Potential:
No data available on bioaccumulation.
12.4. Mobility in soil
Mobility:
Not known.
12.5. Results of PBT and vPvB assessment
Not Classified as PBT/vPvB by current EU criteria.
12.6. Other adverse effects
None known.
SECTION 13: DISPOSAL CONSIDERATIONS
4/ 6
10895
SDS No.
LUBE-167*
13.1. Waste treatment methods
Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance with local authority requirements.
SECTION 14: TRANSPORT INFORMATION
General
The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,
ADR/RID).
14.1. UN number
Not applicable.
14.2 UN Proper shipping name
Not applicable.
14.3 Transport hazard class(es)
Not applicable.
14.4. Packing group
Not applicable.
14.5. Environmental hazards
Environmentally Hazardous Substance/Marine Pollutant
No.
14.6. Special precautions for user
Not applicable.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.
SECTION 15: REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Uk Regulatory References
Chemicals (Hazard Information & Packaging) Regulations. Control of Substances Hazardous to Health Regulations 2002 (as amended)
Workplace Exposure Limits EH40.
EU Legislation
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive
1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive
76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.
Water Hazard Classification
WGK 1
15.2. Chemical Safety Assessment
International Chemical Inventories
Contact REACH@miswaco.com for REACH information. Complies with the following national/regional chemical inventory requirements:
AICS, DSL / NDSL, IECSC, EINECS / ELINCS, TCCL ECL, NZIoC, PICCS, TSCA,
SECTION 16: OTHER INFORMATION
Abbreviations And Acronyms Used In The Safety Data Sheet
*a mark of M-I L.L.C.
General Information
HMIS Health - 0 HMIS Flammability - 1 HMIS Physical Hazard - 0 J - Splash Goggles, Gloves, Synthetic Apron, Dust and Vapour
Respirator.
Information Sources
Product information provided by the commercial vendor(s). Material Safety Data Sheet, Misc. manufacturers. LOLI. European Chemicals
Bureau - ESIS (European Chemical Substances Information).
Revision Comments
General revision. Compiled or Revised by Ewan MacLeod
Issued By
Bill Cameron
Revision Date
19-05-11
Revision
Supersedes Date
01-04-08
SDS No.
10895
5/ 6
10895
SDS No.
10895
LUBE-167*
Risk Phrases In Full
NC
Not classified.
Disclaimer
MSDS furnished independent of product sale. While every effort has been made to accurately describe this product, some of the data are obtained from
sources beyond our direct supervision. We cannot make any assertions as to its reliability or completeness; therefore, user may rely only at user's risk.
We have made no effort to censor or conceal deleterious aspects of this product. Since we cannot anticipate or control the conditions under which this
information and product may be used, we make no guarantee that the precautions we have suggested will be adequate for all individuals and/or
situations. It is the obligation of each user of this product to comply with the requirements of all applicable laws regarding use and disposal of this
product. Additional information will be furnished upon request to assist the user; however, no warranty, either expressed or implied, nor liability of any
nature with respect to this product or to the data herein is made or incurred hereunder.
6/ 6
SDS NO.:
POLY-PLUS
APPLICATION
Flocculant
SUPPLIER
M-I SWACO.
Endeavour Drive
Arnhall Business Park
Westhill
Aberdeen AB32 6UF
Scotland UK
T = +44 (0)1224-742200
F = +44 (0)1224-742288
E-mail =
MBXMSDS-EH@miswaco.com
EMERGENCY TELEPHONE
(24 Hour) Europe +44 (0) 1235 239 670, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Middle
East and Africa +44 (0) 1235 239 671, Australia +61 2801 44558.
2 HAZARDS IDENTIFICATION
Not regarded as a health or environmental hazard under current legislation.
3 COMPOSITION/INFORMATION ON INGREDIENTS
Name
EC No.
CAS-No.
Content
Classification (67/548)
WATER
231-791-2
7732-18-5
30-60%
30-60%
10-30%
Xn;R65.
1-5%
Xn;R22. Xi;R41.
SYNTHETIC COPOLYMER
DISTILLATES (PETROLEUM), HYDROTREATED
LIGHT; KEROSINE - UNSPECIFIED
ETHOXYLATED FATTY ALCOHOL
265-149-8
64742-47-8
10086
SDS NO.:
POLY-PLUS
SPECIFIC HAZARDS
Fire or high temperatures create: Vapours/gases/fumes of: Oxides of: Carbon. and Nitrogen.
PROTECTIVE MEASURES IN FIRE
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
6 ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS
Wear protective clothing as described in Section 8 of this safety data sheet.
ENVIRONMENTAL PRECAUTIONS
Do not allow to enter drains, sewers or watercourses.
SPILL CLEAN UP METHODS
Stop leak if possible without risk. Dike far ahead of larger spills for later disposal. Absorb spillage with suitable absorbent material. Shovel
into dry containers. Cover and move the containers. Flush the area with water. In case of spills, beware of slippery floors and surfaces.
7 HANDLING AND STORAGE
USAGE PRECAUTIONS
Avoid spilling, skin and eye contact. Avoid inhalation of vapours and spray mists.
STORAGE PRECAUTIONS
Store in tightly closed original container in a dry, cool and well-ventilated place.
8 EXPOSURE CONTROLS/PERSONAL PROTECTION
INGREDIENT COMMENTS
Oil mist (mineral) workplace exposure limits are currently under review by legislative authorities. This workplace exposure limit (WEL)
standard is applicable to highly refined mineral oils and is provided as a guidance limit only LT. EXP = 5mg/m3 and ST. EXP = 10mg/m3.
PROTECTIVE EQUIPMENT
ENGINEERING MEASURES
Provide adequate general and local exhaust ventilation.
RESPIRATORY EQUIPMENT
No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air
contamination exists. Chemical respirator with organic vapour cartridge.
HAND PROTECTION
For prolonged or repeated skin contact use suitable protective gloves. Rubber gloves are recommended.
EYE PROTECTION
Wear approved chemical safety goggles where eye exposure is reasonably probable.
OTHER PROTECTION
Wear appropriate clothing to prevent any possibility of skin contact. Provide eyewash station.
9 PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Viscous liquid
COLOUR
Milky.
ODOUR
Hydrocarbon
RELATIVE DENSITY
pH-VALUE, DILUTED SOLUTION
FLASH POINT (C)
VAPOUR PRESSURE
VISCOSITY
POUR POINT (C)
2/ 4
10086
SDS NO.:
POLY-PLUS
MATERIALS TO AVOID
Avoid contact with oxidising agents.
HAZARDOUS DECOMPOSITION PRODUCTS
Fire or high temperatures create: Vapours/gases/fumes of: Oxides of: Carbon. and Nitrogen.
11 TOXICOLOGICAL INFORMATION
INHALATION
Gas or vapour in high concentrations may irritate respiratory system.
INGESTION
May cause discomfort if swallowed.
SKIN CONTACT
Prolonged and frequent contact may cause redness and irritation.
EYE CONTACT
Spray and vapour in the eyes may cause irritation and smarting.
12 ECOLOGICAL INFORMATION
ECOTOXICITY
Contact M-I SWACO's QHSE Department for ecological information at env@miswaco.com.
13 DISPOSAL CONSIDERATIONS
DISPOSAL METHODS
Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance with local authority requirements.
14 TRANSPORT INFORMATION
GENERAL
The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,
ADR/RID).
15 REGULATORY INFORMATION
RISK PHRASES
NC
Not classified.
NC
Not classified.
SAFETY PHRASES
UK REGULATORY REFERENCES
Chemicals (Hazard Information & Packaging) Regulations. Control of Substances Hazardous to Health Regulations 2002 (as amended)
Workplace Exposure Limits EH40.
EU DIRECTIVES
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive
1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive
76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.
INTERNATIONAL CHEMICAL INVENTORIES
Contact REACH@miswaco.com for REACH information. Complies with the following national/regional chemical inventory requirements:
AICS, DSL / NDSL, IECSC, EINECS / ELINCS, METI ENCS, TCCL ECL, NZIoC, PICCS, TSCA
16 OTHER INFORMATION
GENERAL INFORMATION
HMIS Health -1 HMIS Flammability - 1 HMIS Physical Hazard - 0 J - Splash Goggles, Gloves, Synthetic Apron, Dust and Vapour
Respirator.
INFORMATION SOURCES
Product information provided by the commercial vendor(s). Material Safety Data Sheet, Misc. manufacturers. Micromedex. European
Chemicals Bureau - ESIS (European Chemical Substances Information).
REVISION COMMENTS
General revision. Compiled or revised by Sandra McWilliam
ISSUED BY
Bill Cameron
REVISION DATE
24-08-10
3/ 4
10086
SDS NO.:
10086
POLY-PLUS
REV. NO./REPL. SDS GENERATED 8
SDS NO.
10086
Harmful if swallowed.
R65
R41
DISCLAIMER
MSDS furnished independent of product sale. While every effort has been made to accurately describe this product, some of the data are obtained from
sources beyond our direct supervision. We cannot make any assertions as to its reliability or completeness; therefore, user may rely only at user's risk.
We have made no effort to censor or conceal deleterious aspects of this product. Since we cannot anticipate or control the conditions under which this
information and product may be used, we make no guarantee that the precautions we have suggested will be adequate for all individuals and/or
situations. It is the obligation of each user of this product to comply with the requirements of all applicable laws regarding use and disposal of this
product. Additional information will be furnished upon request to assist the user; however, no warranty, either expressed or implied, nor liability of any
nature with respect to this product or to the data herein is made or incurred hereunder.
4/ 4
SDS No.
10844
Revision 6
Supersedes date 03-07-09
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
M-I SWACO
A Schlumberger Company
Endeavour Drive
Arnhall Business Park, Westhill
Aberdeen AB32 6UF
Scotland UK
T = +44 (0)1224-742200
F = +44 (0)1224-742288
E-mail = MBXMSDS-EH@miswaco.slb.com
Not classified.
Not classified.
NC
Not classified.
Safety Phrases
2.3. Other hazards
Not Classified as PBT/vPvB by current EU criteria.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.1. Substances
POLYANIONIC CELLULOSE
60-100%
Classification (67/548/EEC)
Not classified.
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Composition Comments
The data shown is in accordance with the latest EC Directives.
SECTION 4: FIRST AID MEASURES
1/ 6
SDS No.
10844
SDS No.
Engineering measures
Provide adequate general and local exhaust ventilation.
Respiratory equipment
No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air
contamination exists. Dust filter P2 (for fine dust).
Hand protection
For prolonged or repeated skin contact use suitable protective gloves. Use protective gloves made of: Nitrile. or Neoprene.
Eye protection
Wear approved chemical safety goggles where eye exposure is reasonably probable.
Other Protection
Wear appropriate clothing to prevent any possibility of skin contact. Provide eyewash station.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Appearance
Colour
White / off-white.
Odour
Odourless.
Solubility
Soluble in water.
Relative density
1.5 - 1.6 @ 25 C
Bulk Density
6.5 - 9.5 @ 1 %
> 230C
3/ 6
10844
SDS No.
Inhalation
Dust may irritate respiratory system or lungs.
Ingestion
May cause discomfort if swallowed.
Skin contact
Prolonged contact may cause redness, irritation and dry skin.
Eye contact
Particles in the eyes may cause irritation and smarting.
Route of entry
No route of entry noted.
Target Organs
No specific target organs noted
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity
Contact M-I SWACO's QHSE Department for ecological information at env@miswaco.com.
12.1. Toxicity
Acute Fish Toxicity
Not considered toxic to fish.
12.2. Persistence and degradability
Degradability
The product is slowly degradable.
12.3. Bioaccumulative potential
Bioaccumulative potential
The product is not bioaccumulating.
12.4. Mobility in soil
Mobility:
The product is soluble in water.
12.5. Results of PBT and vPvB assessment
Not Classified as PBT/vPvB by current EU criteria.
12.6. Other adverse effects
None known.
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance with local authority requirements.
Waste Class
EWC-Code: 16 03 06
4/ 6
10844
SDS No.
The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,
ADR/RID).
14.1. UN number
Not applicable.
14.2. UN proper shipping name
Not applicable.
14.3. Transport hazard class(es)
Not applicable.
14.4. Packing group
Not applicable.
14.5. Environmental hazards
Environmentally Hazardous Substance/Marine Pollutant
No.
14.6. Special precautions for user
Not applicable.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.
SECTION 15: REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Uk Regulatory References
Chemicals (Hazard Information & Packaging) Regulations. Control of Substances Hazardous to Health Regulations 2002 (as amended)
Workplace Exposure Limits EH40.
EU Legislation
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive
1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive
76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.
Water hazard classification
WGK 1
15.2. Chemical Safety Assessment
International Chemical Inventories
Contact REACH@miswaco.com for REACH information. Complies with the following national/regional chemical inventory requirements:
AICS, DSL / NDSL, IECSC, EINECS / ELINCS, METI ENCS, TCCL ECL, NZIoC, PICCS, TSCA,
SECTION 16: OTHER INFORMATION
Abbreviations and acronyms used in the safety data sheet
*a mark of M-I L.L.C.
General information
HMIS Health -1 HMIS Flammability - 1 HMIS Physical Hazard - 0
Information Sources
Product information provided by the commercial vendor(s). Material Safety Data Sheet, Misc. manufacturers. LOLI. European Chemicals
Bureau - ESIS (European Chemical Substances Information).
Revision Comments
General revision. Updated according to CLP. Compiled or Revised by Ewan MacLeod
Issued By
Bill Cameron
Revision Date
21-06-11
Revision
Supersedes date
03-07-09
SDS No.
10844
Not classified.
5/ 6
10844
SDS No.
10844
Disclaimer
MSDS furnished independent of product sale. While every effort has been made to accurately describe this product, some of the data are obtained from
sources beyond our direct supervision. We cannot make any assertions as to its reliability or completeness; therefore, user may rely only at user's risk.
We have made no effort to censor or conceal deleterious aspects of this product. Since we cannot anticipate or control the conditions under which this
information and product may be used, we make no guarantee that the precautions we have suggested will be adequate for all individuals and/or
situations. It is the obligation of each user of this product to comply with the requirements of all applicable laws regarding use and disposal of this
product. Additional information will be furnished upon request to assist the user; however, no warranty, either expressed or implied, nor liability of any
nature with respect to this product or to the data herein is made or incurred hereunder.
6/ 6
14.1.2011
Date of revision:
5.10.2011(CLP)
Page: 1 / 9
Product name:
POTASSIUM CARBONATE
COMPANY/UNDERTAKING
1.1
Product identifier:
Name:
Potassium carbonate
1.2
1.3
1.4
Annex I index:
Registration number:
01-2119532646-36-0010111nvcncn1111
Identification number:
61508195
Telefon:
Fax:
E-mail:
Web:
http://www. agchemigroup.eu
Skilled advisor:
Emergency phone:
14.1.2011
Date of revision:
5.10.2011(CLP)
Page: 2 / 9
Product name:
POTASSIUM CARBONATE
+420 2 2491 4575
Information concerning health risks acute poisoning of people
and animals only
Label elements:
Signal word
Standard hazard phrases
Precautionary statements
2.3
Xi - Irritant
Xi - Irritant
Further hazards:
Warning
H 315 Causes skin irritation
H 319 Causes serious eye irritation
H 335 May cause respiratory irritation
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P264: Wash with soap and water thoroughly after handling.
P280: Wear protective gloves/protective clothing/
eye protection/face protection.
P305+P351+P338: IF IN EYES: Rinse cautiously with water
for several minutes. Re-move contact lenses, if present and
easy to do. Continue rinsing.
P362: Take off contaminated clothing and wash before reuse.
P403+P233: Store in a well-ventilated place. Keep container
tightly closed.
Not applicable
Potassium carbonate
14.1.2011
Date of revision:
5.10.2011(CLP)
Product name:
POTASSIUM CARBONATE
Content (%):
CAS number:
EC (EINECS) number:
Index number:
Hazard:
Remark:
Page: 3 / 9
92,5 98,0 %
584-08-7
209-529-3
Not listed
Skin Irrit.2 H 315; Eye Irrit. 2 H 319; STOT Single Exp.3 H 335;
Xi R 36/37/38
-
For the full text of the H and R - Statements mentioned in this Section, see Section 16.
SECTION 4: FIRST AID MEASURES
4.1
In case of aspiration:
Rinse out with plenty of water with the eyelid held wide open. If
pain persists, call in ophthalmologist.
If swallowed:
4.2
4.3
5.2
5.3
14.1.2011
Date of revision:
5.10.2011(CLP)
Page: 4 / 9
Product name:
POTASSIUM CARBONATE
protecitive equipment and breathing apparatus.
The product is not flammable.
Personal precautions:
6.2
Environmental precautions:
6.3
6.4
7.2
7.3
Controlling parametres:
There is no specific emission limit set especially for this
Limits of exposition set by
substance
Govermental decree No.361/2007 Sb.:
14.1.2011
Date of revision:
5.10.2011(CLP)
Product name:
POTASSIUM CARBONATE
Substance name
(Component):
Carbonates of
alcaline metals
Page: 5 / 9
PEL = 5 mg/m3
CAS:
Producer announces treshold limit value for dust and power: 10 mg/m3
Recommended monitoring procedures: atmosphere or biological monitoring may be required to determine
the effec-tiveness of the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to European Standard EN 689 for methods for the
assessment of exposure by inhala-tion to chemical agents and national guidance documents for methods
for the determination of hazardous substances.
8.2
DNEL
No data available
PNEC
No data available
Exposition minimising:
Exposition minimising of workers:
After work wash the skin and take off contaminated clothes. Do
not eat, drink, smoke or take drugs during the work.
Respiratory protection:
Eye protection:
Tight-fitting goggles.
Hand protection:
Additional information:
Environment protection:
Odour or smell:
Odourless
pH (at 20 C):
891 C
Not applicable
No data available
Solubility in water:
110 g/L 20 C
14.1.2011
Date of revision:
5.10.2011(CLP)
Product name:
POTASSIUM CARBONATE
Flammability:
9.2
Page: 6 / 9
Not flammable
Relative density:
Bulk density:
750 kg/m3
Additional information:
No data
Reactivity:
No
10.2
Chemical stability:
Stable
10.3
No possible reactions
10.4
Conditions to avoid:
Humidity
10.5
Incompatible materials:
Acids
10.6
Under normal conditions of storage and use the product does not
decompose.
Skin corrosion/irritation:
No data available
Carcinogenicity:
No data available
Reproductive toxicity:
No data available
No data available
Aspiration hazard
No data available
Inhalation, skin/eyes,ingestion
14.1.2011
Date of revision:
5.10.2011(CLP)
Page: 7 / 9
Product name:
POTASSIUM CARBONATE
No other information.
Toxicity:
Fish:
Algae:
No data
Invertebrates:
Bacteries:
No data
Soluble in water, increases pH
12.3
12.4
Soil mobility:
No data
12.5
12.2
12.6
Not applicable
14.5
14.2
14.3
Not applicable
Not applicable
Not applicable
Not applicable
14.1.2011
Date of revision:
5.10.2011(CLP)
Page: 8 / 9
Product name:
POTASSIUM CARBONATE
14.4
14.6
14.7
14.8
Bulk transportation according to appendix II MARPOL 73/78 and decree IBC: No data
Regulation concerning safety, health and environement / specific legal regulations concerning the product
or mixture:
In the Czech republic:
Law 356/2003 Sb., and respective implementing regulations
Law 102/2001 Sb., in valid version
Law 185/2001 Sb., in valid version
see 44a of the Law 258/2000 Sb., Part 8 section (6); (8); (9) and (10)
Regulation EU 1907/2006 (REACH)
Regulation EU 1272/2008 (CLP)
15.2
Not applicable
15.5
Further regulations:
This substance is not SVHC and is not listed in the Annex XIV or
XVII of REACH Regulation
14.1.2011
Date of revision:
5.10.2011(CLP)
Product name:
POTASSIUM CARBONATE
Page: 9 / 9
Version:2
Potassium chloride
Date: 20-06-2011
Supersedes: 04-07-2008
OA00130
1.
1.1.
Product identifier
: Potassium chloride
1.2.
Relevant identified uses of the substance or mixture and uses advised against
1.2.1.
Country
NETHERLANDS
Address
2.
Hazards identification
2.1.
2.1.1.
Emergency number
+31 30 274 88 88
P.O. Box 1
3720 BABilthoven
Not classified
2.1.2.
Not classified
2.1.3.
Label elements
2.2.1.
No labelling applicable
2.2.2.
No labelling applicable
2.3.
Other hazards
3.
Composition/information on ingredients
3.1.
Substances
Name
Product identifier
Classification according to
Directive 67/548/EEC
Potassium chloride
(CAS No.)7447-40-7
~ 98
Not classified
(EC no)231-211-8
Name
Product identifier
Classification according to
Regulation (EC) No.
1272/2008 [CLP]
Potassium chloride
(CAS No.)7447-40-7
~ 98
Not classified
(EC no)231-211-8
Mixtures
Not applicable
20-06-2011
EN (English)
1/4
Potassium chloride
Safety Data Sheet
according to Regulation (EC) No. 1907/2006
4.
4.1.
After inhalation
: Dust of the product, if present, may cause respiratory irritation after an excessive inhalation
exposure. Seek medical attention if ill effect or irritation develops. Remove the victim into fresh
air.
After swallowing
: Rinse mouth.
4.2.
Inhalation
Skin contact
Eye contact
4.3.
5.
Firefighting measures
5.1.
Extinguishing media
6.
6.1.
6.1.1.
Protective equipment
6.1.2.
Environmental precautions
: Contain and collect as any solid. Prevent entry to sewers, ground and public waters.
7.
7.1.
Technical measures
: No special requirements.
Storage
7.3.
8.
8.1.
Control parameters
20-06-2011
EN (English)
2/4
Potassium chloride
Safety Data Sheet
according to Regulation (EC) No. 1907/2006
8.2.
Exposure controls
- Hand protection
: Wear gloves.
- Eye protection
: Safety glasses with side guards should be worn to prevent injury from airborne particles and/or
other eye contact with this product.
- Skin protection
- Respiratory protection
: Approved dust or mist respirator should be used if airborne particles are generated when
handling this material.
9.
9.1.
Appearance
: Solid.
Physical state
: Solid
Colour
: White.
Odour
: Odourless.
pH value
: 5,4-8,6 (5%)
Melting point
: 770 C
Boiling point
: 1420 C
Density
: 1987 kg/l
Water solubility
: 340 g/kg
9.2.
Other information
10.
10.1.
Reactivity
Chemical stability
Conditions to avoid
Moisture.
10.5.
Incompatible materials
11.
Toxicological information
11.1.
12.
Ecological information
12.1.
Toxicity
Bioaccumulative potential
Mobility in soil
EN (English)
3/4
Potassium chloride
Safety Data Sheet
according to Regulation (EC) No. 1907/2006
13.
Disposal considerations
13.1.
Additional information
: After last use, the packing should be totally empty and closed.
14.
Transport information
15.
Regulatory information
15.1.
Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1.
EU-Regulations
National regulations
Remediation Efforts
15.2.
16.
Other information
Further information
: The contents and format of this MSDS are in accordance with regulation (EC) no. 1907/2006 of
the European Parliament and Council of 18 December 2006 concerning the registration,
evaluation, authorisation and restriction of Chemicals (REACH). Appendix Of the raw materials
in chapter 3 at moment of reporting of this material safety data sheet, chemical safety reports
have not been registered in the scope of regulation (EC) no. 1907/2006.
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be
construed as guaranteeing any specific property of the product.
20-06-2011
EN (English)
4/4
Page : 1
Revision nr : 3
Date : 23 / 3 / 2009
Supersedes : 30 / 5 / 2006
CA25041
Label 8 : Corrosive
substance.
C : Corrosive
Trade name
Use
Company identification
Emergency phone nr
2. HAZARDS IDENTIFICATION
: Corrosive.
Hazards identification
Other information
Value(s)
50 to 100 %
CAS
1310-58-3
EG
215-181-3
EC index
019-002-00-8
Classification
Xn; R22
C; R35
- Skin contact
- Eye contact
- Ingestion
5. FIRE-FIGHTING MEASURES
Flammable class
Extinguishing media
- Suitable extinguishing media
: Not combustible.
: Use extinguishing media appropriate for surrounding fire.
Page : 2
Revision nr : 3
Date : 23 / 3 / 2009
Supersedes : 30 / 5 / 2006
CA25041
: Water
: Evacuate unnecessary personnel.
Stop release.
: S36 : Wear suitable protective clothing.
Use self-contained breathing apparatus
:
:
:
:
:
:
Flakes.
White.
Odourless.
14 (56g/l)
2.04
360
Page : 3
Revision nr : 3
Date : 23 / 3 / 2009
Supersedes : 30 / 5 / 2006
CA25041
: 1200
: 112
:
:
:
:
Harmful if swallowed.
Severe skin irritant.
Severe irritation
Severe eye irritant.
: 1813
: 8
: II
Page : 4
Revision nr : 3
Date : 23 / 3 / 2009
Supersedes : 30 / 5 / 2006
CA25041
: 80
: UN1813 POTASSIUM HYDROXIDE, SOLID, 8, II
: No.
: F-A, S-B
Symbol(s)
Contains
: Corrosive.
: EG : 215-181-3
Potassium hydroxide
: R22 : Harmful if swallowed.
R35 : Causes severe burns.
: S1/2 : Keep locked up and out of reach of children.
S26 : In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
S36/37/39 : Wear suitable protective clothing, gloves and eye/face protection.
S45 : In case of accident or if you feel unwell, seek medical advice immediately (
show the label when possible).
R Phrase(s)
S Phrase(s)
DISCLAIMER OF LIABILITY The information in this MSDS was obtained from sources which we believe are reliable. However, the
information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling,
storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we
do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with
the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the
product is used as a component in another product, this MSDS information may not be applicable.
End of document
SDS No.
11326
Revision 7
Supersedes date 16-05-11
SAFE-SCAV* NA
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Oxygen Scavenger
M-I SWACO
A Schlumberger Company
Endeavour Drive
Arnhall Business Park, Westhill
Aberdeen AB32 6UF
Scotland UK
T = +44 (0)1224-742200
F = +44 (0)1224-742288
E-mail = MBXMSDS-EH@miswaco.slb.com
Xi;R36. R31.
Irritant
Risk Phrases
R31
R36
S25
S26
Safety Phrases
In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
1/ 6
SDS No.
11326
SAFE-SCAV* NA
AMMONIUM BISULPHITE
CAS-No.: 10192-30-0
40-70%
EC No.: 233-469-7
Classification (67/548/EEC)
Xi;R36.
R31.
WATER
CAS-No.: 7732-18-5
30-60%
EC No.: 231-791-2
Classification (67/548/EEC)
Not classified.
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Composition Comments
The data shown is in accordance with the latest EC Directives.
SECTION 4: FIRST AID MEASURES
4.1. Description of first aid measures
Inhalation
Move the exposed person to fresh air at once. If respiratory problems, artificial respiration/oxygen. Get medical attention if any discomfort
continues.
Ingestion
Immediately give a couple of glasses of water or milk, provided the victim is fully conscious. Get medical attention if any discomfort
continues.
Skin contact
Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention promptly if symptoms occur after
washing.
Eye contact
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids.
Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
Inhalation.
This is unlikely to occur but symptoms similar to those of ingestion may develop.
Ingestion
May cause discomfort if swallowed.
Skin contact
Prolonged skin contact may cause redness and irritation.
Eye contact
May cause temporary eye irritation.
4.3. Indication of any immediate medical attention and special treatment needed
Get medical attention if any discomfort continues.
SECTION 5: FIREFIGHTING MEASURES
5.1. Extinguishing media
Extinguishing media
Water spray, foam, dry powder or carbon dioxide.
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products
When heated, vapours/gases hazardous to health may be formed.
Specific hazards
Fire or high temperatures create: Oxides of: Sulphur. Ammonia or amines. and Nitrous gases (NOx).
5.3. Advice for firefighters
2/ 6
SDS No.
SAFE-SCAV* NA
Special Fire Fighting Procedures
Containers close to fire should be removed immediately or cooled with water.
Protective equipment for fire-figthers
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
Wear protective clothing as described in Section 8 of this safety data sheet.
6.2. Environmental precautions
Do not allow to enter drains, sewers or watercourses.
6.3. Methods and material for containment and cleaning up
Stop leak if possible without risk. Dike far ahead of larger spills for later disposal. Absorb spillage with suitable absorbent material. Shovel
into dry containers. Cover and move the containers. Flush the area with water.
6.4. Reference to other sections
Wear protective clothing as described in Section 8 of this safety data sheet.
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for safe handling
This product slowly releases sulphur dioxide in contact with air. Ventilate well, avoid breathing vapours. Use approved respirator if air
contamination is above accepted level. Avoid spilling, skin and eye contact.
7.2. Conditions for safe storage, including any incompatibilities
Store in a cool and well-ventilated place. Store in closed original container at temperatures between 5C and 30C.
7.3. Specific end use(s)
The identified uses for this product are detailed in Section 1.2.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters
Name
STD
SULPHUR DIOXIDE
WEL
TWA - 8 Hrs
1 ppm
2.6 mg/m3
STEL - 15 Min
1 ppm
Notes
2.6 mg/m3
Engineering measures
Provide adequate general and local exhaust ventilation.
Respiratory equipment
Respiratory protection must be used if air contamination exceeds acceptable level. Use respiratory equipment with gas filter, type K.
Hand protection
Use protective gloves made of: Butyl rubber. Neoprene. or Nitrile.
Eye protection
Wear approved chemical safety goggles where eye exposure is reasonably probable.
Other Protection
Wear appropriate clothing to prevent any possibility of skin contact. Provide eyewash station.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
3/ 6
11326
SDS No.
SAFE-SCAV* NA
Appearance
Liquid
Colour
Odour
Pungent. Sulphur.
Solubility
105C
Relative density
<1
Vapour pressure
18 mmHg 20C
N/A
11326
SDS No.
SAFE-SCAV* NA
12.2. Persistence and degradability
Degradability
The product is biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential
The product does not contain any substances expected to be bioaccumulating.
12.4. Mobility in soil
Mobility:
Mobile.
12.5. Results of PBT and vPvB assessment
Not Classified as PBT/vPvB by current EU criteria.
12.6. Other adverse effects
None known.
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance with local authority requirements.
SECTION 14: TRANSPORT INFORMATION
General
The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,
ADR/RID).
14.1. UN number
Not applicable.
14.2. UN proper shipping name
Not applicable.
14.3. Transport hazard class(es)
Not applicable.
14.4. Packing group
Not applicable.
14.5. Environmental hazards
Environmentally Hazardous Substance/Marine Pollutant
No.
14.6. Special precautions for user
Not applicable.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.
SECTION 15: REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Uk Regulatory References
Chemicals (Hazard Information & Packaging) Regulations. Control of Substances Hazardous to Health Regulations 2002 (as amended)
Workplace Exposure Limits EH40.
EU Legislation
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive
1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive
76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.
Water hazard classification
WGK 3
15.2. Chemical Safety Assessment
5/ 6
11326
SDS No.
11326
SAFE-SCAV* NA
International Chemical Inventories
Contact REACH@miswaco.com for REACH information. Complies with the following national/regional chemical inventory requirements:
AICS, DSL / NDSL, IECSC, EINECS / ELINCS, METI ENCS, TCCL ECL, NZIoC, PICCS, TSCA,
SECTION 16: OTHER INFORMATION
Abbreviations and acronyms used in the safety data sheet
*a mark of M-I L.L.C.
General information
HMIS Health - 3 HMIS Flammability - 0 HMIS Physical Hazard - 1
Information Sources
Product information provided by the commercial vendor(s). Material Safety Data Sheet, Misc. manufacturers. LOLI. European Chemicals
Bureau - ESIS (European Chemical Substances Information).
Revision Comments
Classification updated. Compiled or Revised by Ewan MacLeod
Issued By
Bill Cameron
Revision Date
23-06-11
Revision
Supersedes date
16-05-11
SDS No.
11326
R36
Irritating to eyes.
H319
Disclaimer
MSDS furnished independent of product sale. While every effort has been made to accurately describe this product, some of the data are obtained from
sources beyond our direct supervision. We cannot make any assertions as to its reliability or completeness; therefore, user may rely only at user's risk.
We have made no effort to censor or conceal deleterious aspects of this product. Since we cannot anticipate or control the conditions under which this
information and product may be used, we make no guarantee that the precautions we have suggested will be adequate for all individuals and/or
situations. It is the obligation of each user of this product to comply with the requirements of all applicable laws regarding use and disposal of this
product. Additional information will be furnished upon request to assist the user; however, no warranty, either expressed or implied, nor liability of any
nature with respect to this product or to the data herein is made or incurred hereunder.
6/ 6
SDS No.
10707
Revision 8
Supersedes date 13-07-11
SAFE-CIDE*
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Biocide
M-I SWACO
A Schlumberger Company
Endeavour Drive
Arnhall Business Park, Westhill
Aberdeen AB32 6UF
Scotland UK
T = +44 (0)1224-742200
F = +44 (0)1224-742288
E-mail = MBXMSDS-EH@miswaco.slb.com
Classification (1999/45/EEC)
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
2.2. Label elements
Contains
2,2',2''-(HEXAHYDRO-1,3,5-TRIAZINE-1,3,5-TRIYL)TRIETHANOL
Signal Word
Danger
Hazard Statements
H302
H317
H330
Harmful if swallowed.
May cause an allergic skin reaction.
Fatal if inhaled.
P280
P310
P501A
Precautionary Statements
1/ 7
SDS No.
10707
SAFE-CIDE*
Supplementary Precautionary Statements
P261
P363
P405
60-100%
EC No.: 225-208-0
Classification (67/548/EEC)
T;R23.
Xn;R22.
R43.
2-AMINOETHANOL
CAS-No.: 141-43-5
1-5%
EC No.: 205-483-3
Classification (67/548/EEC)
C;R34
Xn;R20/21/22
1-5%
EC No.: 200-573-9
Classification (67/548/EEC)
Xn;R22.
Xi;R36.
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Composition Comments
The data shown is in accordance with the latest EC Directives.
SECTION 4: FIRST AID MEASURES
4.1. Description of first aid measures
Inhalation
Move the exposed person to fresh air at once. If respiratory problems, artificial respiration/oxygen. Get medical attention if any discomfort
continues.
Ingestion
Do not induce vomiting. Immediately give a couple of glasses of water or milk, provided the victim is fully conscious. Get medical
attention.
Skin contact
Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention.
Eye contact
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids.
Continue to rinse for at least 15 minutes. Get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
2/ 7
SDS No.
SAFE-CIDE*
Inhalation.
Toxic by inhalation.
Ingestion
Harmful if swallowed.
Skin contact
May cause sensitisation by skin contact.
Eye contact
May cause temporary eye irritation.
4.3. Indication of any immediate medical attention and special treatment needed
Get medical attention if any discomfort continues.
SECTION 5: FIREFIGHTING MEASURES
5.1. Extinguishing media
Extinguishing media
Water spray, foam, dry powder or carbon dioxide.
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products
When heated, vapours/gases hazardous to health may be formed.
Specific hazards
Fire or high temperatures create: Vapours/gases/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2). Nitrous gases (NOx).
Sulphurous gases (SOx).
5.3. Advice for firefighters
Special Fire Fighting Procedures
Containers close to fire should be removed immediately or cooled with water.
Protective equipment for fire-fighters
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
Wear protective clothing as described in Section 8 of this safety data sheet.
6.2. Environmental precautions
Do not allow to enter drains, sewers or watercourses.
6.3. Methods and material for containment and cleaning up
Stop leak if possible without risk. Dike far ahead of larger spills for later disposal. Absorb spillage with suitable absorbent material. Shovel
into dry containers. Cover and move the containers. Flush the area with water.
6.4. Reference to other sections
Wear protective clothing as described in Section 8 of this safety data sheet.
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for safe handling
Avoid spilling, skin and eye contact. Avoid inhalation of vapours and spray mists.
7.2. Conditions for safe storage, including any incompatibilities
Store in tightly closed original container in a dry, cool and well-ventilated place.
7.3. Specific end use(s)
The identified uses for this product are detailed in Section 1.2.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters
Name
STD
2-AMINOETHANOL
WEL
TWA - 8 Hrs
1 ppm
2,5 mg/m3
STEL - 15 Min
3 ppm
7,6 mg/m3
Notes
Sk
10707
SDS No.
SAFE-CIDE*
8.2. Exposure controls
Protective equipment
Engineering measures
Provide adequate general and local exhaust ventilation.
Respiratory equipment
Wear suitable respiratory protection. A minimum of a chemical respirator with organic vapour cartridge should be worn. If there are
conditions in which this triazine containing product produces a vapor, a chemical respirator with A1 +Formaldehyde and P2 particulate
pre-filter combination would be required.
Hand protection
Chemical resistant gloves required for prolonged or repeated contact. Use protective gloves made of: Nitrile. or Neoprene.
Eye protection
Wear approved chemical safety goggles where eye exposure is reasonably probable.
Other Protection
Wear appropriate clothing to prevent any possibility of skin contact. Provide eyewash station.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Appearance
Liquid
Colour
Odour
Characteristic.
Solubility
>100C
Relative density
Vapour pressure
9.5-11.5 @ 1%
Viscosity
1850mPas @ 20C
Flash point
68C
>200C
10707
SDS No.
SAFE-CIDE*
Toxicological information
This product may contain or release trace amounts of formaldehyde. The International Agency for Research on Cancer (IARC) has
classified formaldehyde as a Group 1carcinogen(limited evidence in humans, sufficient evidence in animals). exposure to formaldehyde
has been linked to adverse reproductive effects in some human and animal studies. In other reproductive studies, however, no adverse
effects were noted. (Meditext). Formaldehyde may also cause skin and respiratory sensitisation (allergic reaction).
Acute toxicity:
Acute Toxicity (Oral LD50)
1400 mg/kg Rat
Acute Toxicity (Inhalation LC50)
0.371
mg/l 4h. Method - Aerosol.
Aspiration hazard:
Toxic by inhalation.
Inhalation
Toxic by inhalation.
Ingestion
Harmful if swallowed.
Skin contact
May cause sensitisation by skin contact.
Eye contact
Irritating to eyes.
Route of entry
No route of entry noted.
Target Organs
No specific target organs noted
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity
Contact M-I SWACO's QHSE Department for ecological information at env@miswaco.com.
12.1. Toxicity
Acute Fish Toxicity
Not considered toxic to fish.
Acute Toxicity - Fish
LC50 96 hours > 100 mg/l Brachydanio rerio (Zebra Fish)
> 100 mg/l
EC 50, 48 Hrs, Daphnia, mg/l
IC 50, 72 Hrs, Algae, mg/l
10-100 mg/l
5/ 7
10707
SDS No.
SAFE-CIDE*
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance with local authority requirements. This material
and its container must be disposed of as hazardous waste.
SECTION 14: TRANSPORT INFORMATION
14.1. UN number
UN No. (ADR/RID/ADN)
2810
UN No. (IMDG)
2810
UN No. (ICAO)
2810
TOXIC LIQUID, ORGANIC, N.O.S. (2, 2', 2"-(hexahydro -1, 3, 5-triazine -1, 3, 5-triyl) triethanol)
6.1
ADR/RID/ADN Class
IMDG Class
6.1
ICAO Class/Division
6.1
Transport Labels
TOXIC
6
14.4. Packing group
ADR/RID/ADN Packing group
II
II
II
F-A, S-A
2X
60
(D/E)
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.
SECTION 15: REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Uk Regulatory References
Chemicals (Hazard Information & Packaging) Regulations. Control of Substances Hazardous to Health Regulations 2002 (as amended)
Workplace Exposure Limits EH40.
6/ 7
10707
SDS No.
10707
SAFE-CIDE*
EU Legislation
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive
1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive
76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.
15.2. Chemical Safety Assessment
International Chemical Inventories
Contact REACH@miswaco.com for REACH information. Complies with the following national/regional chemical inventory requirements:
Australia (AICS), Canada (DSL / NDSL), China (IECSC), Europe (EINECS / ELINCS), Japan (METI / ENCS), Korea (TCCL / ECL), New
Zealand (NZIoC), Phillipines (PICCS), United States (TSCA).
SECTION 16: OTHER INFORMATION
Abbreviations and acronyms used in the safety data sheet
*a mark of M-I L.L.C.
General information
HMIS Health - 3 HMIS Flammability - 1 HMIS Physical Hazard - 0 J - Splash Goggles, Gloves, Synthetic Apron, Dust and Vapour
Respirator.
Information Sources
Product information provided by the commercial vendor(s). Material Safety Data Sheet, Misc. manufacturers. LOLI. European Chemicals
Bureau - ESIS (European Chemical Substances Information).
Revision Comments
Classification updated. The following sections have been revised: 11, Compiled or revised by Sandra McWilliam
Issued By
Bill Cameron
Revision Date
01-11-11
Revision
Supersedes date
13-07-11
SDS No.
10707
Causes burns.
R20/21/22
R22
Harmful if swallowed.
R36
Irritating to eyes.
R37
R43
R23
Toxic by inhalation.
Harmful if swallowed.
H312
H314
H317
H319
H330
Fatal if inhaled.
H332
Harmful if inhaled.
H335
Disclaimer
MSDS furnished independent of product sale. While every effort has been made to accurately describe this product, some of the data are obtained from
sources beyond our direct supervision. We cannot make any assertions as to its reliability or completeness; therefore, user may rely only at user's risk.
We have made no effort to censor or conceal deleterious aspects of this product. Since we cannot anticipate or control the conditions under which this
information and product may be used, we make no guarantee that the precautions we have suggested will be adequate for all individuals and/or
situations. It is the obligation of each user of this product to comply with the requirements of all applicable laws regarding use and disposal of this
product. Additional information will be furnished upon request to assist the user; however, no warranty, either expressed or implied, nor liability of any
nature with respect to this product or to the data herein is made or incurred hereunder.
7/ 7
SDS No.
11302
Revision 7
Supersedes date 10-Feb-2011
SAFE-COR*
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Corrosion inhibitor.
M-I SWACO
A Schlumberger Company
Endeavour Drive
Arnhall Business Park, Westhill
Aberdeen AB32 6UF
Scotland UK
T = +44 (0)1224-742200
F = +44 (0)1224-742288
E-mail = MBXMSDS-EH@miswaco.slb.com
Xi;R36. R52/53.
Irritant
Risk Phrases
R36
R52/53
Irritating to eyes.
S25
S26
Safety Phrases
S60
In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
This material and its container must be disposed of as hazardous waste.
1/ 6
SDS No.
11302
SAFE-COR*
WATER
60-100%
Classification (67/548/EEC)
Not classified.
EC No.: 272-712-1
Classification (67/548/EEC)
Xi;R36.
R52/53.
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Composition Comments
The data shown is in accordance with the latest EC Directives.
SECTION 4: FIRST AID MEASURES
4.1. Description of first aid measures
Inhalation
Move the exposed person to fresh air at once. If respiratory problems, artificial respiration/oxygen. Get medical attention if any discomfort
continues.
Ingestion
Immediately give a couple of glasses of water or milk, provided the victim is fully conscious. DO NOT induce vomiting. Get medical
attention immediately.
Skin contact
Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention promptly if symptoms occur after
washing.
Eye contact
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids.
Continue to rinse for at least 15 minutes and get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
Inhalation.
This is unlikely to occur but symptoms similar to those of ingestion may develop.
Ingestion
May cause discomfort if swallowed.
Skin contact
Prolonged skin contact may cause redness and irritation.
Eye contact
May cause severe irritation to eyes.
4.3. Indication of any immediate medical attention and special treatment needed
Get medical attention if any discomfort continues.
SECTION 5: FIREFIGHTING MEASURES
5.1. Extinguishing media
Extinguishing media
Water. Carbon dioxide (CO2).
Unsuitable extinguishing media
Not known.
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products
When heated, vapours/gases hazardous to health may be formed.
5.3. Advice for firefighters
2/ 6
30-60%
SDS No.
SAFE-COR*
Special Fire Fighting Procedures
Containers close to fire should be removed immediately or cooled with water.
Protective equipment for fire-fighters
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
Wear protective clothing as described in Section 8 of this safety data sheet.
6.2. Environmental precautions
Do not allow to enter drains, sewers or watercourses.
6.3. Methods and material for containment and cleaning up
Stop leak if possible without risk. Dike far ahead of larger spills for later disposal. Absorb spillage with suitable absorbent material. Shovel
into dry containers. Cover and move the containers. Flush the area with water.
6.4. Reference to other sections
Wear protective clothing as described in Section 8 of this safety data sheet.
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for safe handling
Avoid spilling, skin and eye contact. Avoid inhalation of vapours and spray mists.
7.2. Conditions for safe storage, including any incompatibilities
Store in tightly closed original container in a dry, cool and well-ventilated place. Suitable containers: Mild steel.
7.3. Specific end use(s)
The identified uses for this product are detailed in Section 1.2.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters
Ingredient Comments
No exposure limits noted for ingredient(s).
8.2. Exposure controls
Protective equipment
Engineering measures
Provide adequate general and local exhaust ventilation.
Respiratory equipment
No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air
contamination exists. Chemical respirator with organic vapour cartridge.
Hand protection
Use protective gloves made of: Rubber, neoprene or PVC.
Eye protection
Wear splash-proof eye goggles to prevent any possibility of eye contact.
Other Protection
Wear appropriate clothing to prevent any possibility of skin contact. Provide eyewash station.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Appearance
Liquid
Colour
Dark. Amber.
Odour
Slight odour.
Solubility
Soluble in water.
3/ 6
11302
SDS No.
SAFE-COR*
Initial boiling point and boiling range
>100C
Relative density
1.03-1.05 @ 20 C
>10.2
Flash point
4/ 6
11302
SDS No.
SAFE-COR*
Acute Toxicity - Fish
LC50 96 hours > 45 mg/l
*Aquatic species (calculated data following Dir. 1999/45/CE)
Acute Toxicity - Aquatic Invertebrates
EC50 48 hours > 100 mg/l Daphnia magna
12.2. Persistence and degradability
Degradability
The product is not readily biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential
No data available on bioaccumulation.
12.4. Mobility in soil
Mobility:
The product is soluble in water.
12.5. Results of PBT and vPvB assessment
Not Classified as PBT/vPvB by current EU criteria.
12.6. Other adverse effects
None known.
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance with local authority requirements.
SECTION 14: TRANSPORT INFORMATION
General
The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,
ADR/RID).
14.1. UN number
Not applicable.
14.2. UN proper shipping name
Not applicable.
14.3. Transport hazard class(es)
Not applicable.
14.4. Packing group
Not applicable.
14.5. Environmental hazards
Environmentally Hazardous Substance/Marine Pollutant
No.
11302
SDS No.
11302
SAFE-COR*
Uk Regulatory References
Chemicals (Hazard Information & Packaging) Regulations. Control of Substances Hazardous to Health Regulations 2002 (as amended)
Workplace Exposure Limits EH40.
EU Legislation
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive
1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive
76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.
15.2. Chemical Safety Assessment
International Chemical Inventories
Contact REACH@miswaco.slb.com for REACH information. Complies with the following national/regional chemical inventory requirements:
Australia (AICS), Canada (DSL / NDSL), China (IECSC), Europe (EINECS / ELINCS), New Zealand (NZIoC), United States (TSCA).
SECTION 16: OTHER INFORMATION
Abbreviations and acronyms used in the safety data sheet
*a mark of M-I L.L.C.
General information
HMIS Health - 2 HMIS Flammability - 1 HMIS Physical Hazard - 0 J - Splash Goggles, Gloves, Synthetic Apron, Dust and Vapour
Respirator.
Information Sources
Product information provided by the commercial vendor(s). Material Safety Data Sheet, Misc. manufacturers. LOLI. European Chemicals
Bureau - ESIS (European Chemical Substances Information).
Revision Comments
Compiled or Revised by Ewan MacLeod Classification updated.
Issued By
Bill Cameron
Revision Date
31-Jan-2012
Revision
Supersedes date
10-Feb-2011
SDS No.
10031
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R36
Irritating to eyes.
H412
Disclaimer
MSDS furnished independent of product sale. While every effort has been made to accurately describe this product, some of the data are obtained from
sources beyond our direct supervision. We cannot make any assertions as to its reliability or completeness; therefore, user may rely only at user's risk.
We have made no effort to censor or conceal deleterious aspects of this product. Since we cannot anticipate or control the conditions under which this
information and product may be used, we make no guarantee that the precautions we have suggested will be adequate for all individuals and/or
situations. It is the obligation of each user of this product to comply with the requirements of all applicable laws regarding use and disposal of this
product. Additional information will be furnished upon request to assist the user; however, no warranty, either expressed or implied, nor liability of any
nature with respect to this product or to the data herein is made or incurred hereunder.
6/ 6
SafetyDataSheetinaccordancewithAnnexIIofRegulationEC1907/2006(REACH),
Regulation(EC)1272/2008andRegulation(EC)453/2010
Product
:SODIUMCARBONATE
REACHRegistrationNumber
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
:IssueNo.02,dated10012011
PageNumber
:Page1 of27
1.IDENTIFICATIONOFTHESUBSTANCE/MIXTUREANDOFTHECOMPANY/UNDERTAKING
1.1ProductIdentifier
ProductName
ChemicalName
AlternativeName
ChemicalFormula
CASNumber
ECNumber
IndexNumber
1.2Relevantidentifieduses
:SODIUMCARBONATE
:Sodiumcarbonate
: Disodiumcarbonate,sodaash
:Na2CO3
:497198
:2078388
: 011005002
: glassproduction; intermediatein chemicalsproduction;water
treatmentchemicals;washingandcleaningproducts;other
industrial,professionalandconsumeruses.Exposurescenarios
coveringusescanbefoundintheAnnex
1.2.1Usesadvisedagainst
1.3CompanyDetails
CompanyName
Address
Telephone
1.4EmergencyTelephoneNumber
EmergencyNumber(24hours)
: noneidentified
:TataChemicalsEurope
:WinningtonLane
:MondHouse
:Northwich
:Cheshire
:CW84DT
:+44(0)1606724000
:+44(0)1606781353
:www.tatachemicals.com/europe
:msdstce@tatachemicals.com
:+44(0)1606781000
2. HAZARDS IDENTIFICATION
2.1Classificationofthesubstance
2.1.1ClassificationaccordingtoRegulation(EC)1272/2008[CLP/GHS]
Classification:EyeIrritant2
2.1.2ClassificationaccordingtoDirective67/548/EEC
Classification:Irritatingtoeyes
2.2Labelling
2.2.1LabellingaccordingtoRegulation(EC)1272/2008[CLP/GHS]
HazardPictograms:
SignalWord
HazardStatements
H319
:Warning
:Causesseriouseyeirritation
SafetyDataSheetinaccordancewithAnnexIIofRegulationEC1907/2006(REACH),
Regulation(EC)1272/2008andRegulation(EC)453/2010
Product
:SODIUMCARBONATE
REACHRegistrationNumber
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
:IssueNo.02,dated10012011
PageNumber
:Page2 of27
Precautionary
Statements:
P264
P280
P305+P351+P338
P337+P313
:Washhandsandfacethoroughlyafterhandling
:Wearprotectivegloves/protectiveclothing/eyeprotection/faceprotection
:IFINEYES,rinsecautiouslywithwaterforseveralminutes,removecontact
lenses,ifpresentandeasytodo.Continuerinsing
:Ifeyeirritationpersists:Getmedicaladvice/attention
2.2.2LabellingaccordingtoDirective67/548/EEC
Symbol
RiskPhrases:
R36
SafetyPhrases:
S2
S22
S24
:Xiirritant
:Irritatingtoeyes
:Keepoutofthereachofchildren
:Donotbreathedust
:Avoidcontactwithskin
2.3Otherhazards
ThesubstancedoesnotmeetthecriteriaforPBTorvPvBaccordingtoAnnexXIIIoftheREACHRegulation
EC1907/2006(aninorganicsubstance)
Nootherhazardsidentified
3.COMPOSITION/INFORMATIONONINGREDIENTS
3.1Substance
Mainconstituent
Formula
Purity%w/w(typical)
>99.0
Sodiumcarbonate
Na2CO3
IMPURITIES
Noimpuritiesrelevantforclassificationandlabelling
CASNumber
497198
ECNumber
2078388
4.FIRSTAIDMEASURES
4.1Descriptionoffirstaidmeasures
Generaladvice
Noknowndelayedeffects
Followinginhalation
Removetofreshair,keepwarmandatrest
Ifsymptomspersist,seekmedicalattention
Followingskincontact
Removecontaminatedclothingandwashbeforereuse
Washoffwithsoapandwater
Ifsymptomspersist,seekmedicalattention
Followingeyecontact
Removecontactlensesifpresent
Irrigateeyethoroughlywitheyewashsolutionorcleanwaterforatleast15minutes
SafetyDataSheetinaccordancewithAnnexIIofRegulationEC1907/2006(REACH),
Regulation(EC)1272/2008andRegulation(EC)453/2010
Product
:SODIUMCARBONATE
REACHRegistrationNumber
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
:IssueNo.02,dated10012011
PageNumber
:Page3 of27
Eyelidsshouldbeheldawayfromtheeyeballtoensurethoroughrinsing
Ifeyeirritationpersistsseekmedicalattention
Afteringestion
DONOTinducevomiting
Washoutmouthwithwaterandgiveplentyofwatertodrink(atleast300ml.)
Obtainmedicaladviceifnecessary.
5.FIREFIGHTINGMEASURES
5.1ExtinguishingMedia
5.1.1Suitableextinguishingmedia
Useextinguishingmeasuresthatareappropriatetolocalcircumstancesandthesurroundingenvironment
5.1.2Unsuitableextinguishingmedia
None
5.2Specialhazardsarisingfromthesubstanceormixture
None
5.3Adviceforfirefighters
Nospecialprecautionsrequired
6.1PersonalPrecautions
6.1.1Fornonemergencypersonnel
Keepdustlevelstoaminimum
Wearsuitableprotectiveequipment(seeSection8)
6.2EnvironmentalPrecautions
Preventuncontrolleddischargesintotheenvironment(rivers,watercourses,sewersetc.)
Avoidanymixturewithanacidintosewer/drains(CO2gasformation)
6.3Methodsforcontainmentandcleanup
Inallcasesavoiddustformation
Usevacuumsuction,orshovelintobags
Collectasmuchaspossibleinasuitablecleancontainer,preferablyforreuse,otherwisefordisposal(See
Section13)
6.4Referencetoothersections
Formoreinformationonexposurecontrols/personalprotectionordisposalconsiderations,pleasesee
section8and13
7.1PrecautionsforSafeHandling
7.1.1Protectivemeasures
Keepdustlevelstoaminimum
Ensureadequateventilation
Wearprotectiveequipment(seeSection8.2)
Keepawayincompatiblematerials
7.1.2Adviceongeneraloccupationalhygiene
Goodpersonalandhousekeepingpracticestobeused
Nodrinking,eatingorsmokingattheworkplace
7.2Conditionsforsafestorage,includinganyincompatibilities
Storeinadryplace
SafetyDataSheetinaccordancewithAnnexIIofRegulationEC1907/2006(REACH),
Regulation(EC)1272/2008andRegulation(EC)453/2010
Product
:SODIUMCARBONATE
REACHRegistrationNumber
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
:IssueNo.02,dated10012011
PageNumber
:Page4 of27
Storeinoriginal,closedandcorrectlylabelledcontainer
Storeawayfromincompatiblematerials
8.EXPOSURECONTROLS/PERSONALPROTECTION
8.1ControlParameters
8.1.1OccupationalExposureStandards
NotlistedbyH&SE(GuidanceNoteEH40)orACGIH
RecommendedLimits:WEL10mg/m3(totaldust)(8hrTWA)
4mg/m3(respirabledust)(8hrTWA)
8.1.2DNELs/PNEC
Exposureroute
ofrelevance
Inhalation
DNELs(localeffects)
Workers
Longterm
Acute
Generalpopulation
Longterm
10mg/m3
Acute
PNEC:
ThelowestL(E)C50valueis>100mg/l(48hEC50is200mg/lindaphnids(Ceriodaphniasp)).Thereforesodiumcarbonate
neednotbeclassifiedaccordingtoDirective67/548/EECandEUClassification,LabellingandPackagingofSubstances
andMixtures(CLP)Regulation(EC)No.1272/2008
EnvironmentalClassificationisnotwarranted
8.2ExposureControls
8.2.1Appropriateengineeringcontrols
provideappropriateexhaustventilationatplaceswheredustisformed
applytechnicalmeasurestocomplywiththeoccupationalexposurelimits
8.2.2Personalprotection
8.2.2.1Eye/faceprotection
weareye/faceprotectionratedtoprotecteyesagainstdust(EN166)eg.safetyeyeshieldswithdust
protection,gogglesorfacevisor
8.2.2.2Handprotection
wearsuitablechemicalresistantprotectivegloves,thatcomplywiththespecificationofECDirective
89/686/EECandtherelatedstandardEN374.Suitablematerials,Neopreneornaturalrubber
8.2.2.3Skin/bodyprotection
dustimperviousprotectivesuit
rubberorplasticsafetyboots
8.2.2.4Respiratoryprotection
inthecaseofhighdustlevelswearsuitablerespiratoryprotectiveequipmenteg.dustmaskor
respirator,that
conformtonational/internationalstandard,EN143.RecommendedfiltertpeP2
8.3EnvironmentalExposureControls
containanyspillage
avoiddischargestotheenvironment
disposeofanyrinsewaterinaccordancewithlocalandnationalregulations
9.PHYSICALANDCHEMICALPROPERTIES
9.1InformationonBasicPhysicalandChemicalProperties
SafetyDataSheetinaccordancewithAnnexIIofRegulationEC1907/2006(REACH),
Regulation(EC)1272/2008andRegulation(EC)453/2010
Product
:SODIUMCARBONATE
REACHRegistrationNumber
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
:IssueNo.02,dated10012011
PageNumber
:Page5 of27
Appearance
Odour
Odourthreshold
pH
Melting/freezingpoint
Boilingpoint
Flashpoint
Evaporationrate
Flammability
Upperflammabilitylimit
Lowerflammabilitylimit
Vapourpressure
VapourDensity
Relativedensity
Watersolubility
Partitioncoefficient
Autoignitiontemperature
Decompositiontemperature
Viscosity
Explosiveproperties
Oxidisingproperties
:whitepowder
:odourless
:noinformationavailable
:>11(saturatedsolution,studyresult,OECDGuideline105)
:851oc(publisheddata)
:notapplicable(meltingpoint>300oc)
:notapplicable(inorganicsubstance)
:notapplicable(meltingpoint>300oc)
:nonflammable(studyresult,EUMethodA.10))
:nonflammable
:nonflammable
:notapplicable (inorganicsubstance,vapourpressurenegligible)
:notapplicable
:2.52@20oc(studyresult,EUMethodA.3)
:212.5g/l@20oc(studyresult,OECDGuideline105)
:notapplicable(inorganicsubstance)
:nonflammable
:notinformationavailable
:notapplicable (solid)
:nonexplosive(voidofchemicalgroupsassociatedwithexplosive
properties)
:nonoxidising (basedonthechemicalstructureofthesubstanceand
theoxidationstateoftheconstituentelement)
10.STABILITYANDREACTIVITY
10.1Reactivity
Decomposesbyreactionwithstrongacidstoevolvecarbondioxide
10.2ChemicalStability
Stableunderrecommendedstorageconditions(seeSection7)
10.3Possibilityofhazardousreactions
None
10.4ConditionstoAvoid
Contactwithacidsunlessundercontrolledconditions
Exposuretomoisture
10.5Incompatiblematerials
Finelydividedaluminium
10.6Hazardousdecompositionproducts
None
11.TOXICOLOGICALINFORMATION
11.1InformationonToxicologicalEffects
SafetyDataSheetinaccordancewithAnnexIIofRegulationEC1907/2006(REACH),
Regulation(EC)1272/2008andRegulation(EC)453/2010
Product
:SODIUMCARBONATE
REACHRegistrationNumber
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
:IssueNo.02,dated10012011
PageNumber
:Page6 of27
Toxicityendpoints
Acutetoxicity
Irritation/
corrosion
Sensitisation
Repeateddose
toxicity
Detailsoftheeffectsassessment
Oral
: LD50 ,rat2800 mg/kgbw
Dermal
:LD50 ,rabbit >2000 mg/kgbw
Method:EPA16CFR1500.40
Inhalation
:LC50 ,rat 2300mg/m3 air
Method:basedonOECD Guideline
403
Valuesexceedthecutofflimitof2000mg/kgestablishedbyEUDirective67/548/EECandEU
Classification,LabellingandPackagingofSubstancesandMixtures(CLP)Regulation(EC)No.
1272/2008
Classificationforacutetoxicity: isnotwarranted
Eyeirritation
Skinirritation
Respiratoryirritation
:irritatingMethod:OECDGuideline405
:notirritatingMethod:OECDGuideline404
:notirritating Basedonavailabledata
ClassificationforEyeirritancy:Xi,R36(irritatingtoeyes)accordingtoDirective
67/548/EEC
:Category2,H319(causesseriouseyeirritation)
accordingtoCLPRegulation(EC)1272/2008
ClassificationforSkinirritancy:isnotwarranted
ClassificationforRespiratoryirritancy :isnotwarranted
Nodataavailableonthesensitisation ofsodiumcarbonate.
Sodiumcarbonateisconsiderednottohaveanysensitisingproperties,basedonthephysiological
roleofbothitsconstituentionsanditslongtermhistoricalandwidedispersiveuseinindustrial
processesandconsumerproducts.
Classificationforsensitisation:isnotwarranted
Mutagenicity
Invitro Theavailableinvitrotests(SOSchromotestwithsodiumcarbonateandAmestestwith
sodiumbicarbonate)werenegative.Furthermoresodiumbicarbonateisnaturallypresentincells
andboththestructureofsodiumbicarbonateandsodiumcarbonatedonotindicateagenotoxic
potential.Therefore,thereisnoreasontoevaluatethepotentialgenotoxicityofsodiumcarbonate
furtherandnogenotoxiceffectsareexpected.
Classificationformutagenicityisnotwarranted
Classificationforrepeateddosetoxicity: isnotwarranted
SafetyDataSheetinaccordancewithAnnexIIofRegulationEC1907/2006(REACH),
Regulation(EC)1272/2008andRegulation(EC)453/2010
Product
:SODIUMCARBONATE
REACHRegistrationNumber
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
:IssueNo.02,dated10012011
PageNumber
:Page7 of27
Toxicityendpoints Detailsoftheeffectsassessment
Carcinogenicty
Nodataavailableforcarcinogenicityofsodiumcarbonate.Althoughthesubstancehasawideand
varieduse,therearenoindicationsthatitcaninducehyperplasia,preneoplasticlesionsoris
mutagenic.Therefore,acarcinogenicitystudyisconsideredunnecessary
Classificationforcarcinogenicityisnotwarranted
Reproductive
toxicity
Fertlity :
Nodataavailable
Developmentaltoxicity:
InaccordancewithSection1ofREACHAnnexXI,testingdoes
notappearscientificallynecessary,asthesubstancewill
usuallynotreachthefoetusorthemaleandfemale
reproductiveorganswhenexposedorally,dermallyorby
inhalation,asitdoesnotbecomeavailablesystemically.As
such,itisconsiderednotusefultoperformareproduction
study
ClassificationforreproductivetoxicityaccordingtoRegulation(EC)1272/2008isnotrequired
12.ECOLOGICALINFORMATION
12.1Toxicity
12.1.1Acute/shorttermtoxicitytofish
LC50(96h)forfreshwaterfish:300mg/l
12.1.2Chronic/longtermtoxicitytofish
Studyscientificallyunjustified,sodiumcarbonatedissociatesreadilyintosodiumandcarbonateionsinan
aquaticenvironment.Bothionsoriginallyexistinnature,andtheirconcentrationsinsurfacewaterare
dependentonvariousfactors,suchasgeologicalparameters,weatheringandhumanactivities.Therefore,
thereisacontinuoussourceofbothionsintotheenvironmentandhavebeenmeasuredextensivelyin
aquaticecosystems
12.1.3Acute/shorttermtoxicitytoaquaticinvertebrates
EC50(48h)forfreshwaterinvertebrates:200227mg/l
12.1.4Chronic/longtermtoxicitytoaquaticinvertebrates
Studyscientificallyunjustified,sodiumcarbonatedissociatesreadilyintosodiumandcarbonateionsinan
aquaticenvironment.Bothionsoriginallyexistinnature,andtheirconcentrationsinsurfacewaterare
dependentonvariousfactors,suchasgeologicalparameters,weatheringandhumanactivities.Therefore,
thereisacontinuoussourceofbothionsintotheenvironmentandhavebeenmeasuredextensivelyin
aquaticecosystems
12.1.5Acutetoxicitytoalgaeandaquaticplants
Studyscientificallyunjustified,sodiumcarbonatedissociatesreadilyintosodiumandcarbonateionsinan
aquaticenvironment.Bothionsoriginallyexistinnature,andtheirconcentrationsinsurfacewaterare
dependentonvariousfactors,suchasgeologicalparameters,weatheringandhumanactivities.Therefore,
thereisacontinuoussourceofbothionsintotheenvironmentandhavebeenmeasuredextensivelyin
aquaticecosystems
12.1.6Toxicitytosoilmacroorganisms
InaccordancewithREACHAnnexXIastudyisnotrequiredasinwatersodiumcarbonateisdissociatedinto
sodiumandcarbonateions,bothofwhichwillnotadsorbonparticulatematter.Furthermore,exposureof
thesoilcompartmentisunlikely
12.1.7Toxicitytoterrestrialplants
InaccordancewithREACHAnnexXIastudyisnotrequiredasinwatersodiumcarbonateisdissociatedinto
sodiumandcarbonateions,bothofwhichwillnotadsorbonparticulatematter.Furthermore,exposureof
thesoilcompartmentisunlikely
SafetyDataSheetinaccordancewithAnnexIIofRegulationEC1907/2006(REACH),
Regulation(EC)1272/2008andRegulation(EC)453/2010
Product
:SODIUMCARBONATE
REACHRegistrationNumber
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
:IssueNo.02,dated10012011
PageNumber
:Page8 of27
12.2Persistenceanddegradeability
Inwater
Insoil
Insediment
:Notapplicable(quicklydissociates)
:Notapplicable(inorganicsubstance)
:Notapplicable(inorganicsubstance)
12.3BioaccumulativePotential
Notbioaccumulative(inorganicsubstancethatinwaterdissociatesintosodiumandcarbonateions,which
donotaccumulateinlivingtissues)
12.4MobilityinSoil
Ifsodiumcarbonateisemittedtosoilitcanescapetoatmosphereascarbondioxide,precipitateasametal
carbonate,formcomplexesorstayinsolution
12.5ResultsofPBTandvPvBAssessment
AccordingtoAnnexXIIIofREACHRegulationinorganicsubstancesdonotrequireassessment
12.6OtherAdverseEffects
Nootheradverseeffectsareidentified
13.DISPOSALCONSIDERATIONS
13.1WasteTreatmentMethods
Ifrecyclingorreuseisnotpracticable,disposeofincompliancewithlocalornationalregulations
Neutralisewithacidundercontrolledconditions
Dilutewithplentyofwater
Packaging:
Wherepossible,recyclingispreferredtodisposalorincineration
Cleancontainerwithwater,disposeofrinsewaterinaccordancewithlocalornationalregulations
Mustbeincineratedinaregisteredincinerationplantwithpermitfromthelocalauthorities
14.TRANSPORTINFORMATION
Sodiumcarbonateisnotclassifiedashazardousfortransport
14.1UNNumber
Notregulated
14.2UNpropershippingname
Notregulated
14.3Transporthazardclass
LandTransport
InlandWaterwayTransport
SeaTransport
AirTransport
:ADR/RID
:ADN
:IMO/IMDG
:ICAOTI/IATADGR
Notrestricted
Notregulated
Notregulated
Notregulated
15.REGULATORYINFORMATION
15.1Safety,healthandenvironmentalregulations
Waterhazardclass:WGK1,VwVwS(Germany)
TSCAInventory:Listed
15.2Chemicalsafetyassessment
AChemicalSafetyAssessment/Report(CSA/CSR)hasbeenundertakenonsodiumcarbonate
16.OTHERINFORMATION
16.1Indicationofchanges
Section1changeofcompanyname,logoandcontactdetails
SafetyDataSheetinaccordancewithAnnexIIofRegulationEC1907/2006(REACH),
Regulation(EC)1272/2008andRegulation(EC)453/2010
Product
:SODIUMCARBONATE
REACHRegistrationNumber
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
:IssueNo.02,dated10012011
PageNumber
:Page9 of27
IssueNo.:02Revision01DateofIssue:10012011supercedesIssueNo.2DateofIssue:10012011
16.2Abbreviationsandacronyms
WEL
ACGIH
TWA
DNEL
NOEC
PBT
vPvB
PNEC
ADR
RID
ADN
:Workplaceexposurelimit
:AmericanConferenceofIndustrialHygiene
:TimeWeightedAverage
:Derivednoeffectlevel
:NoObservedEffectConcentration
:Persistent,Bioaccumulative,Toxic
:veryPersistent,veryBioaccumulative
:PredictedNoEffectConcentration
:EuropeanAgreementConcerningtheInternationalCarriageofDangerousGoodsbyRoad
:InternationalRuleforTransportofDangerousSubstancesbyRail
:EuropeanAgreementconcerningtheInternationalCarriageofDangerousGoodsbyInland
Waterway
IMO/IMDG :InternationalMaritimeOrganization/InternationalMaritimeDangerousGoodsCode
ICAO/IATA :InternationalCivilAviationOrganization/InternationalAirTransportAssociation
OECD
:OrganisationofEconomicCooperationandDevelopment
SIDS
:ScreeningInformationDataSet
16.3Keyliteraturereferencesandsourcesofdata
DataistakenfromtheChemicalsafetyreport(CSR)and/orOECDSIDSreportforsodiumcarbonate
16.4FurtherInformation
16.4.1Theaboveinformationdescribesexclusivelythesafetyrequirementsoftheproductandisbasedonourpresent
dayknowledge.Theinformationisintendedtogiveyouadviceaboutthesafehandlingoftheproductnamed
inthissafetydatasheet,forstorage,processing,transportanddisposal.Theinformationcannotbetransferred
tootherproductsorinthecaseofprocessing,theinformationonthissafetydatasheetisnotnecessarily
valid.
Toourbestpresentknowledgetheinformationgiveniscorrectandcompleteasofthedateofthisdocument
andisgiveningoodfaithbutwithoutwarranty,eitherexpressedorimplied,nordoweacceptanyliabilityin
relationtothisinformationoritsuse.ThisversionoftheSDSsupercedesallpreviousversions.
16.4.2AnytradenamesreferencedinthisdocumentareregisteredtrademarksofTataChemicalsEuropeLimited
ANNEXTOEXTENDEDSAFETYDATASHEET(eSDS):
Page1113ExposureScenario1(ES.1)SodaashManufacturingofsodiumcarbonate
Page1416ExposureScenario2(ES.2)SodaashGlassproduction
Page1719ExposureScenario3(ES.3)SodaashFormulation
Page2025ExposureScenario4(ES.4)SodaashOtherindustrialandprofessionaluse
Page2628ExposureScenario5(ES.5)SodaashConsumeruse
SafetyDataSheetinaccordancewithAnnexIIofRegulationEC1907/2006(REACH),
Regulation(EC)1272/2008andRegulation(EC)453/2010
Product
:SODIUMCARBONATE
REACHRegistrationNumber
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
:IssueNo.02,dated10012011
PageNumber
:Page10 of27
ExposureScenarioforcommunication:
ES1:Manufacturingofsodiumcarbonate
0.Generalinformation
ESidentifier
Versionno
Revisiondate
EC#
CAS#
ES1
01
28.10.2010
2078388
497198
1. Use descriptors
Manufacturingofsodiumcarbonate
Marketsector:SU3(Industrialuses)
Sectorofuse:SU8(Manufactureofbulk,largescalechemicals)
Environment:(EnvironmentalReleaseCategory)Manufactureofsubstances
ERC1
Worker(ProcessCategoryPhrase)
Useinclosedprocess,nolikelihoodofexposure
PROC1
Useinclosed,continuousprocesswithoccasionalcontrolledexposure
PROC2
Useinclosedbatchprocess(synthesisorformulation)
PROC3
Useinbatchandotherprocess(synthesis)whereopportunityforexposurearises
PROC4
Transferofsubstanceorpreparation(charging/discharging)from/tovessels/largecontainersatnondedicated
facilities
PROC8a
Transferofsubstanceorpreparation(charging/discharging)from/tovessels/largecontainersatdedicated
facilities
PROC8b
Transferofsubstanceorpreparationintosmallcontainers(dedicatedfillingline,includingweighing)
PROC9
Potentiallyclosedprocessingoperationswithminerals/metalsatelevatedtemperature
PROC22
Processes,tasks,activitiescovered
Manufacturing,maintenance,loading,packaging,samplingandmonitoring.
2.Conditionsofuseaffectingexposure
2.0DefaultProductCharacteristics
Physicalformofproduct/article
Solid
Volatility
Notrelevant
Dustiness
Medium(PROCs1,2,3,4,8a,8b,9)
Low(PROC22)
2.1.Controlofenvironmentalexposure:
ManufactureofsubstancesERC1
SafetyDataSheetinaccordancewithAnnexIIofRegulationEC1907/2006(REACH),
Regulation(EC)1272/2008andRegulation(EC)453/2010
Product
:SODIUMCARBONATE
REACHRegistrationNumber
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
:IssueNo.02,dated10012011
PageNumber
:Page11 of27
Amountsused
Annualsitetonnage(tonnes/year):upto1500000.
Frequencyanddurationofuse
Continuous
Othergivenoperationalconditionsaffectingenvironmentalexposure
Notapplicable.
Technicalandorganizationalconditionsandmeasures
Seesection8ofSafetydatasheet.
Conditionsandmeasuresrelatedtomunicipalsewagetreatmentplant
Wastewaterstreamsfromsodiumcarbonateproductionsitescontaininorganicsubstancesandarethereforenottreatedin
sewagetreatmentplants.
Conditionsandmeasuresrelatedtoexternaltreatmentofwaste
In Chapter 2.3.5 of the Reference Document on Best Available Techniques for the Manufacture of Large Volume Inorganic
Chemicals Solids and Others Industry(EC, 2007) two types of solid waste, generated during themanufacturing of sodium
carbonate,arediscussed.Bothtypesofsolidwasteoriginatefromrawmaterialsandtheconcentrationofsodiumcarbonate
inthesolidwasteisnegligible.Forthisreasonspecificwasterelatedmeasuresarenotneeded.
AdditionalgoodpracticeadvicebeyondtheREACHCSR(ChemicalSafetyReport)
Seesections6and13ofSafetyDataSheet
2.2.Controlofworkersexposure
ValidforPROCs1,2,3,4,8a,8b,9,22.
Amountsused,frequencyanddurationofuse
Amountsused
NotRelevant
ParameterdoesnotinfluenceexposureestimationsforthisES
Frequencyanddurationofuse
Daily8h/day
Technicalandorganizationalconditionsandmeasures
Seesection8ofSafetyDataSheet.
Ensureworkersaretrainedtominimizeexposures.
AdditionalgoodpracticeadvicebeyondtheREACHCSR(ChemicalSafetyReport)
Seesections7and8ofSafetyDataSheet
3.Exposureestimationandreferencetoitssource
3.1Environmentexposureestimationandreferencetoitssource
ThetablebelowgivesthesummaryoftheenvironmentexposureestimationmadeintheChemicalSafetyReport,referringto
DocumentonBestAvailableTechniquesfortheManufactureofLargeVolumeInorganicChemicalsSolidsandOthers
Industry.
Compartments
Measuredrelease(kg/d)
Explanation/sourceofmeasureddata
Aquatic
Negligible
ReferenceDocumentonBestAvailableTechniques(EC,2007)
Air(direct)
2.2118
Soil(directonly)
Negligible
ReferenceDocumentonBestAvailableTechniques(EC,2007)
SafetyDataSheetinaccordancewithAnnexIIofRegulationEC1907/2006(REACH),
Regulation(EC)1272/2008andRegulation(EC)453/2010
Product
:SODIUMCARBONATE
REACHRegistrationNumber
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
:IssueNo.02,dated10012011
PageNumber
:Page12 of27
3.2Workersexposureestimationandreferencetoitssource
TheECETOCTRAtoolhasbeenusedtoestimateworkplaceexposuresunlessotherwiseindicated.
Productionofsodiumcarbonate:longtermexposureconcentrationstoworkers
Exposure
Explanation/sourceofmeasureddata
Routesofexposure concentrations
(Characteristics,Duration,Frequency,OCandRMMdescribedabove)
3
(mg/m )
Modeledexposuredata
Dermalexposure
Notrelevant
Noassessmentfordermalexposurebecauseofnolocalskineffectsandno
systemicavailabilityafterdermalcontact.
Inhalationexposure
0.01
ECETOCTRAV2.PROC1
0.5
ECETOCTRAV2.PROC2
ECETOCTRAV2.PROC3
ECETOCTRAV2.PROC4
ECETOCTRAV2.PROC8a
ECETOCTRAV2.PROC8b
ECETOCTRAV2.PROC9
ECETOCTRAV2.PROC22
Measuredexposuredata
Inhalationexposure
7.9
Anextensiveset(intotal:698observations)ofworkerexposuredatafrom4
sitesthatmanufacturesodiumcarbonate.Measurementsarerepresentative
foraworkdayof8hours.
4.GuidancetoDUtoevaluatewhetherheworksinsidetheboundariessetbytheES
4.1Environment.
NotApplicable:thisscenariodoesnotconcernDU.
4.2Health.
NotApplicable:thisscenariodoesnotconcernDU.
SafetyDataSheetinaccordancewithAnnexIIofRegulationEC1907/2006(REACH),
Regulation(EC)1272/2008andRegulation(EC)453/2010
Product
:SODIUMCARBONATE
REACHRegistrationNumber
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
:IssueNo.02,dated10012011
PageNumber
:Page13 of27
Substance:SodiumCarbonate;EC:2078388;CAS:497198
ExposureScenarioforcommunication:
ES2:Glassproduction
0.Generalinformation
ESidentifier
Versionno
Revisiondate
EC#
CAS#
ES2
01
28.10.2010
2078388
497198
1.Usedescriptors
GlassProduction
Marketsector:SU3(Industrialuses)
Sectorofuse:SU3(Industrialuses)
Environment:(EnvironmentalReleaseCategory)Industrialuseresultinginmanufactureof
anothersubstance(useofintermediates)
ERC6a
Worker(ProcessCategoryPhrase)
Useinclosedprocess,nolikelihoodofexposure
PROC1
Useinclosed,continuousprocesswithoccasionalcontrolledexposure
PROC2
Useinclosedbatchprocess(synthesisorformulation)
PROC3
Useinbatchandotherprocess(synthesis)whereopportunityforexposurearises
PROC4
Transferofsubstanceorpreparation(charging/discharging)from/tovessels/largecontainersat
nondedicatedfacilities
PROC8a
Transferofsubstanceorpreparation(charging/discharging)from/tovessels/largecontainersat
dedicatedfacilities
PROC8b
Potentiallyclosedprocessingoperationswithminerals/metalsatelevatedtemperature
PROC22
Openprocessingandtransferoperationswithminerals/metalsatelevatedtemperature
PROC23
Handlingofsolidinorganicsubstancesatambienttemperature.
PROC26
Processes,tasks,activitiescovered
Manufacturing,maintenance,loading,packaging,samplingandmonitoring.
2.Conditionsofuseaffectingexposure
2.0DefaultProductCharacteristics
Physicalformofproduct/article
Solid
Volatility
Notrelevant
SafetyDataSheetinaccordancewithAnnexIIofRegulationEC1907/2006(REACH),
Regulation(EC)1272/2008andRegulation(EC)453/2010
Product
:SODIUMCARBONATE
REACHRegistrationNumber
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
:IssueNo.02,dated10012011
PageNumber
:Page14 of27
Dustiness
Medium(PROCs1,2,3,4,8a,8b,26)
High(PROCs22and23)
MixtureArticleConcentration
ForPROCs1,2,3,4,8a,8band26theneatsubstanceistakenintoaccount,becausetheneatsubstanceistransferred
totheprocess.
Percentageof525%sodiumcarbonateinthemixtureduringthemeltingprocessisassumed.
2.1.Controlofenvironmentalexposure:
Useasintermediate:industrialuseresultinginmanufactureofanothersubstance.
Amountsused
Upto200000tonnes/year.
Frequencyanddurationofuse
Continuous.
Othergivenoperationalconditionsaffectingenvironmentalexposure
TheimpactofglassmanufacturingontheenvironmenthasbeendescribedextensivelyintheReferenceDocumenton
Best Available Techniques in the Glass Manufacturing Industry (EC, 2001). The document was established in the
contextoftheEUDirectiveonIntegratedPollutionPreventionandControl(Directive96/61/EC).
Technicalandorganizationalconditionsandmeasures
Seesection8ofSafetyDataSheet.
Incaseofdustformation,usefiltertoreduceatmosphericemissions.
Conditionsandmeasuresrelatedtomunicipalsewagetreatmentplant
Wastewaterstreamsoftheglassindustrydonotcontainsodiumcarbonateasitisstoredincoveredsilosandnot
linkedtointernalsewagesystems.Forthisreasonanemissionassessmentforthesewagetreatmentplantisnot
neededfortheindustrialenduseofsodiumcarbonateintheglassindustry.
Conditionsandmeasuresrelatedtoexternaltreatmentofwaste
Nospecificwasterelatedmeasuresaretobedefined.
AdditionalgoodpracticeadvicebeyondtheREACHCSA
Seesections6and13ofSafetyDataSheet
2.2.Controlofworkersexposure
ValidforPROCs1,2,3,4,8a,8b,9,22,26.
Amountsused,frequencyanddurationofuse
Amountsused
NotRelevant
Parameterdoesnotinfluenceexposureestimationsfor
thisES
Frequencyanddurationofuse
Daily8h/day
Technicalandorganisationalconditionsandmeasures
Seesection8ofSafetyDataSheet
AdditionalgoodpracticeadvicebeyondtheREACHCSR(ChemicalSafetyReport)
Seesections7and8ofSafetyDataSheet
3.Exposureestimationandreferencetoitssource
3.1Environmentexposureestimationandreferencetoitssource
SafetyDataSheetinaccordancewithAnnexIIofRegulationEC1907/2006(REACH),
Regulation(EC)1272/2008andRegulation(EC)453/2010
Product
:SODIUMCARBONATE
REACHRegistrationNumber
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
:IssueNo.02,dated10012011
PageNumber
:Page15 of27
ThetablebelowgivesthesummaryoftheenvironmentexposureestimationmadeintheChemicalSafetyReport,
referringtoDocumentonBestAvailableTechniquesintheGlassManufacturingIndustry(EC,2001).
Compartments
Measuredrelease
(kg/d)
Explanation/sourceofmeasureddata
Aquatic
Negligible
ReferenceDocumentonBestAvailableTechniques(EC,2001)
Air(direct)
Negligible
ReferenceDocumentonBestAvailableTechniques(EC,2001)
Soil(directonly)
Negligible
ReferenceDocumentonBestAvailableTechniques(EC,2001)
3.2Workersexposureestimationandreferencetoitssource
TheECETOCTRAtoolhasbeenusedtoestimateworkplaceexposuresunlessotherwiseindicated.
Glassproduction:longtermexposureconcentrationstoworkers
Routesofexposure
Estimated
exposure
concentrations
(mg/m3)
Explanation/sourceofmeasureddata
(Characteristics,Duration,Frequency,OCandRMMdescribedabove)
Dermalexposure
Notrelevant
Noassessmentfordermalexposurebecauseofnolocalskineffectsandno
systemicavailabilityafterdermalcontact.
0.01
0.5
1
5
5
5
1
1
ECETOCTRAV2.PROC1
ECETOCTRAV2.PROC2
ECETOCTRAV2.PROC3
ECETOCTRAV2.PROC4
ECETOCTRAV2.PROC8a
ECETOCTRAV2.PROC8b
ECETOCTRAV2.PROC22a
ECETOCTRAV2.PROC23a
Inhalationexposure
PROC26isnotforeseeninECETOCTRAbutitinvolvesactivitieswhicharedescribedbyPROC8aand8b.Thereforethe
calculationwithPROC8aand8bcoversPROC26.
4.GuidancetoDUtoevaluatewhetherheworksinsidetheboundariessetbytheES
4.1Environment.
PredictedexposuresarenotexpectedtoexceedtheDNELwhentheRiskManagementMeasures/Operational
ConditionsoutlinedinSection2areimplemented.
4.2Health.
PredictedexposuresarenotexpectedtoexceedtheDNELwhentheRiskManagementMeasures/Operational
ConditionsoutlinedinSection2areimplemented.
SafetyDataSheetinaccordancewithAnnexIIofRegulationEC1907/2006(REACH),
Regulation(EC)1272/2008andRegulation(EC)453/2010
Product
:SODIUMCARBONATE
REACHRegistrationNumber
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
:IssueNo.02,dated10012011
PageNumber
:Page16 of27
Substance:SodiumCarbonate;EC:2078388;CAS:497198
ExposureScenarioforcommunication:
ES3:Formulation
0.Generalinformation
ESidentifier
Versionno
Revisiondate
EC#
CAS#
ES3
01
28.10.2010
2078388
497198
1.Usedescriptors
Formulation
Marketsector:SU3(Industrialuses)
Sectorofuse:SU10(Formulation[mixing]ofpreparationsand/orrepackaging(excludingalloys))
Environment:(EnvironmentalReleaseCategory)Formulationofpreparations
ERC2
Worker(ProcessCategoryPhrase)
Useinclosedprocess,nolikelihoodofexposure
PROC1
Useinclosed,continuousprocesswithoccasionalcontrolledexposure
PROC2
Useinclosedbatchprocess(synthesisorformulation)
PROC3
Mixingorblendinginbatchprocessesforformulationofpreparationsandarticles(multistage
and/orsignificantcontact)
PROC5
Transferofsubstanceorpreparation(charging/discharging)from/tovessels/largecontainersat
nondedicatedfacilities
PROC8a
Transferofsubstanceorpreparation(charging/discharging)from/tovessels/largecontainersat
dedicatedfacilities
PROC8b
Transferofsubstanceorpreparationintosmallcontainers(dedicatedfillingline,including
weighing)
PROC9
Productionofpreparationsorarticlesbytabletting,compression,extrusion,pelletisation
PROC14
Useaslaboratoryreagent
PROC15
Processes,tasks,activitiescovered
storage,materialstransfers,mixing,maintenance,samplingandassociatedlaboratoryactivities.
2.Conditionsofuseaffectingexposure
2.0DefaultProductCharacteristics
Physicalformofproduct/article
Volatility
Solid
Notrelevant
Dustiness
Medium
MixtureArticleConcentration
Notrelevant:forexposureestimationtheneatsubstanceistakenintoaccount,becausetheneatsubstanceisaddedto
theformulationprocess.
SafetyDataSheetinaccordancewithAnnexIIofRegulationEC1907/2006(REACH),
Regulation(EC)1272/2008andRegulation(EC)453/2010
Product
:SODIUMCARBONATE
REACHRegistrationNumber
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
:IssueNo.02,dated10012011
PageNumber
:Page17 of27
2.1.Controlofenvironmentalexposure:
Formulationofpreparations ERC2
SPERC(AISE,2010E)arealsoused(http://www.aise.eu/reach/exposureass_sub4.htm).
Amountsused
Upto5000tonnes/year
Frequencyanddurationofuse
Continuous
Othergivenoperationalconditionsaffectingenvironmentalexposure
Seesections8and13ofSafetyDataSheet
Technicalandorganizationalconditionsandmeasures
Incaseofdustformation,usefiltertoreduceatmosphericemissions.
Conditionsandmeasuresrelatedtomunicipalsewagetreatmentplant
ControlthepHoftheliquideffluentiftheeffluentissenttoSTP.
Conditionsandmeasuresrelatedtoexternaltreatmentofwaste
Nospecificwasterelatedmeasuresaretobedefined.
AdditionalgoodpracticeadvicebeyondtheREACHCSA
Seesections6and13ofSafetyDataSheet
2.2.Controlofworkersexposure
ValidforPROCs1,2,3,5,4,8a,8b,9,14,15.
Amountsused,frequencyanddurationofuse
Amountsused
NotRelevant
Parameterdoesnotinfluenceexposureestimationsforthis
ES
Frequencyanddurationofuse
Daily8h/day
Technicalandorganisationalconditionsandmeasures
Seesection8ofSafetyDataSheet
AdditionalgoodpracticeadvicebeyondtheREACHCSR(ChemicalSafetyReport)
Seesections7and8ofSafetyDataSheet
3.Exposureestimationandreferencetoitssource
3.1Environmentexposureestimationandreferencetoitssource
ThetablebelowgivesthesummaryoftheenvironmentexposureestimationmadeintheChemicalSafetyReportandin
SpecificEnvironmentalReleaseCategories(SPERC)(AISE,2010):
Compartments
Measuredrelease
(kg/d)
Explanation/sourceofdata
Aquatic
Negligible
Air(direct)
2.7
SpecificEnvironmentalReleaseCategories(SPERC)(AISE,2010)
Soil(directonly)
Negligible
SpecificEnvironmentalReleaseCategories(SPERC)(AISE,2010)
SafetyDataSheetinaccordancewithAnnexIIofRegulationEC1907/2006(REACH),
Regulation(EC)1272/2008andRegulation(EC)453/2010
Product
:SODIUMCARBONATE
REACHRegistrationNumber
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
:IssueNo.02,dated10012011
PageNumber
:Page18 of27
Formulation:longtermexposureconcentrationstoworker
Routesofexposure
Dermalexposure
Inhalationexposure
Estimated
exposure
concentrations
(mg/m3)
Notrelevant
Explanation/sourceofmeasureddata
(Characteristics,Duration,Frequency,OCandRMMdescribedabove)
Noassessmentfordermalexposurebecauseofnolocalskineffectsandno
systemicavailabilityafterdermalcontact.
0.01
ECETOCTRAV2.PROC1
0.5
ECETOCTRAV2.PROC2
ECETOCTRAV2.PROC3
ECETOCTRAV2.PROC4
ECETOCTRAV2.PROC5
ECETOCTRAV2.PROC8a
ECETOCTRAV2.PROC8b
ECETOCTRAV2.PROC9
ECETOCTRAV2.PROC14
0.5
ECETOCTRAV2.PROC15
4.GuidancetoDUtoevaluatewhetherheworksinsidetheboundariessetbytheES
4.1Environment.
PredictedexposuresarenotexpectedtoexceedtheDNELwhentheRiskManagementMeasures/Operational
ConditionsoutlinedinSection2areimplemented.
4.2Health.
PredictedexposuresarenotexpectedtoexceedtheDNELwhentheRiskManagementMeasures/Operational
ConditionsoutlinedinSection2areimplemented.
SafetyDataSheetinaccordancewithAnnexIIofRegulationEC1907/2006(REACH),
Regulation(EC)1272/2008andRegulation(EC)453/2010
Product
:SODIUMCARBONATE
REACHRegistrationNumber
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
:IssueNo.02,dated10012011
PageNumber
:Page19 of27
Substance:SodiumCarbonate;EC:2078388;CAS:497198
ExposureScenarioforcommunication:
ES4:Otherindustrialandprofessionaluses
0.Generalinformation
ESidentifier
Versionno
Revisiondate
EC#
CAS#
ES4
01
28.10.2010
2078388
497198
1.Usedescriptors
1.1Industrialenduses
Marketsector:SU3(Industrialuses)
Sectorofuse:Norestriction(SUs020,23,24)
Environment:(EnvironmentalReleaseCategory)
Formulationofpreparations
ERC4
Industrialuseresultingininclusionintoorontoamatrix
ERC5
Industrialuseresultinginmanufactureofanothersubstance(useofintermediates)
ERC6a
Industrialuseofreactiveprocessingaids
ERC6b
Industrialuseofprocessregulatorsforpolymerisationprocessesinproductionofresins,rubbers,
polymers
ERC6d
Industrialuseofsubstancesinclosedsystems
ERC7
Worker(ProcessCategoryPhrase)
Useinclosedprocess,nolikelihoodofexposure
PROC1
Useinclosed,continuousprocesswithoccasionalcontrolledexposure
PROC2
Useinclosedbatchprocess(synthesisorformulation)
PROC3
Useinbatchandotherprocess(synthesis)whereopportunityforexposurearises
PROC4
Sprayinginindustrialsettingsandapplications
PROC7
Transferofsubstanceorpreparation(charging/discharging)from/tovessels/largecontainersat
nondedicatedfacilities
PROC8a
Transferofsubstanceorpreparation(charging/discharging)from/tovessels/largecontainersat
dedicatedfacilities
PROC8b
Transferofsubstanceorpreparationintosmallcontainers(dedicatedfillingline,including
weighing)
PROC9
SafetyDataSheetinaccordancewithAnnexIIofRegulationEC1907/2006(REACH),
Regulation(EC)1272/2008andRegulation(EC)453/2010
Product
:SODIUMCARBONATE
REACHRegistrationNumber
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
:IssueNo.02,dated10012011
PageNumber
:Page20 of27
Rollerapplicationorbrushingofadhesiveandothercoating
PROC10
Treatmentofarticlesbydippingandpouring
PROC13
Useaslaboratoryreagent
PROC15
Lubricationathighenergyconditionsandinpartlyopenprocess
PROC17
Greasingathighenergyconditions
PROC18
HandmixingwithintimatecontactandonlyPPEavailable
PROC19
Potentiallyclosedprocessingoperationswithminerals/metalsatelevatedtemperature.The
processtemperatureishigherthanthemeltingpoint(Highfugacity)
Openprocessingandtransferoperationswithminerals/metalsatelevatedtemperature.The
processtemperatureishigherthanthemeltingpoint(Highfugacity)
Handlingofsolidinorganicsubstancesatambienttemperature
PROC22
PROC23
PROC26
Processes,tasks,activitiescovered:
Manufacturing,mixing,maintenance,loading,packaging,samplingandmonitoring.
ERC8a
Widedispersiveindooruseofreactivesubstancesinopensystems
ERC8b
Widedispersiveindooruseresultingininclusionintoorontoamatrix
ERC8c
Widedispersiveoutdooruseofprocessingaidsinopensystems
ERC8d
Widedispersiveoutdooruseofreactivesubstancesinopensystems
ERC8e
Widedispersiveoutdooruseresultingininclusionintoorontoamatrix
ERC8f
Widedispersiveindooruseofsubstancesinclosedsystems
ERC9a
Widedispersiveoutdooruseofsubstancesinclosedsystems
ERC9b
Worker(ProcessCategoryPhrase)
Useinclosedprocess,nolikelihoodofexposure
PROC1
Useinclosed,continuousprocesswithoccasionalcontrolledexposure
PROC2
SafetyDataSheetinaccordancewithAnnexIIofRegulationEC1907/2006(REACH),
Regulation(EC)1272/2008andRegulation(EC)453/2010
Product
:SODIUMCARBONATE
REACHRegistrationNumber
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
:IssueNo.02,dated10012011
PageNumber
:Page21 of27
Useinbatchandotherprocess(synthesis)whereopportunityforexposurearises
PROC4
Transferofsubstanceorpreparation(charging/discharging)from/tovessels/largecontainersat
nondedicatedfacilities
PROC8a
Transferofsubstanceorpreparation(charging/discharging)from/tovessels/largecontainersat
dedicatedfacilities
PROC8b
Transferofsubstanceorpreparationintosmallcontainers(dedicatedfillingline,including
weighing)
PROC9
Rollerapplicationorbrushingofadhesiveandothercoating
PROC10
Nonindustrialspraying
PROC11
Treatmentofarticlesbydippingandpouring
PROC13
Useaslaboratoryreagent
PROC15
HandmixingwithintimatecontactandonlyPPEavailable
PROC19
Processes,tasks,activitiescovered
Manufacturing,mixing,maintenance,loading,packaging,samplingandmonitoring.
2.Conditionsofuseaffectingexposure
2.0DefaultProductCharacteristics
Physicalformofproduct/article
Volatility
Dustiness
Solid
Notrelevant
Medium(PROCs1,2,3,4,8a,8b,9,15,19)
High(PROCs22and23)
2.1.Controlofenvironmentalexposure:
Industrialenduses:ERC4,ERC5,ERC6a/6b/6d,ERC 7.
Professionalenduses:ERC8a/8b/8c/8d/8e/8f;ERC9a/9b.
Amountsused
Industrialuseupto100000tonnes/year.
Professionalusemuchlower
Frequencyanddurationofuse
Uptocontinuous.
Othergivenoperationalconditionsaffectingenvironmentalexposure
Seesections8and13ofSafetyDataSheet
Technicalandorganizationalconditionsandmeasures
Incaseofdustformation,usefiltertoreduceatmosphericemissions.
Conditionsandmeasuresrelatedtomunicipalsewagetreatmentplant
ControlthepHoftheliquideffluentiftheeffluentissenttoSTP.
Conditionsandmeasuresrelatedtoexternaltreatmentofwaste
Nospecificwasterelatedmeasuresaretobedefined.
AdditionalgoodpracticeadvicebeyondtheREACHCSR(ChemicalSafetyReport)
SafetyDataSheetinaccordancewithAnnexIIofRegulationEC1907/2006(REACH),
Regulation(EC)1272/2008andRegulation(EC)453/2010
Product
:SODIUMCARBONATE
REACHRegistrationNumber
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
:IssueNo.02,dated10012011
PageNumber
:Page22 of27
Seesections6and13ofSafetyDataSheet
2.2.Controlofworkersexposure
ValidforPROC14,7,8a,8b,9,10,11,13,15,17,18,19,22,23,26.
Amountsused,frequencyanddurationofuse
NotRelevant
Parameterdoesnotinfluenceexposure
estimationsforthisES
Amountsused
Frequencyanddurationofuse(ExposureFrequencyDuration)
Operationalconditions Process
Industrial
Professional
relatedtotheduration
Category
(DataField)
(DataField)
ofuse
PROC1
Lessthan15min/day
PROC2
Lessthan15min/day
>4hours/day(liquid
PROC3
mixture)
PROC4
>4hours/day
>4hours/day(liquid
PROC7
mixture)
PROC8a
15min/dayto1hour/day
PROC8b
15min/dayto1hour/day
Durationofexposureper
>4hours/day(liquid
PROC9
dayatworkplace[forone
mixture)
worker]
PROC10
>4hours/day
PROC11
>4hours/day
PROC13
15min/dayto1hour/day
PROC15
15min/dayto1hour/day
>4hours/day(liquid
PROC17
mixture)
>4hours/day(liquid
PROC18
mixture)
PROC19
15min/dayto1hour/day
PROC26isnotforeseeninECETOCTRAbutitinvolvesactivitieswhicharedescribedbyPROC8aand8b.Thereforethe
calculationwithPROC8aand8bcoversPROC26.
Technicalandorganisationalconditionsandmeasures
Seesection8ofSafetyDataSheet.
AdditionalgoodpracticeadvicebeyondtheREACHCSR(ChemicalSafetyReport)
Seesections7and8ofSafetyDataSheet
3.Exposureestimationandreferencetoitssource
3.1Environmentexposureestimationandreferencetoitssource
Winnington Lane, Northwich, Cheshire, CW8 4DT, United Kingdom
Tel +44 (0) 1606 72400 Fax +44(0) 1606 781353 www.tatachemicals.com
SafetyDataSheetinaccordancewithAnnexIIofRegulationEC1907/2006(REACH),
Regulation(EC)1272/2008andRegulation(EC)453/2010
Product
:SODIUMCARBONATE
REACHRegistrationNumber
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
:IssueNo.02,dated10012011
PageNumber
:Page23 of27
ThetablebelowgivesthesummaryoftheenvironmentexposureestimationmadeintheChemicalSafetyReport:
Compartments
Measuredrelease(kg/d)
Aquatic
Negligible
Air(direct)
Smallreleasesmightbepossible
Soil(directonly)
Negligibleinallcasesexceptagriculturaluse
Maxapplicationuseratesofsodaashascoformulantinplantprotection
products:Professionalagricultural:0.0126kg/ha(tier1defaultuserate:1
kg/ha)
3.2Workersexposureestimationandreferencetoitssource
TheECETOCTRAtoolhasbeenusedtoestimateworkplaceexposuresunlessotherwiseindicated.
Routesofexposure
Dermalexposure
Explanation/sourceof
measureddata
(Characteristics,Duration
Frequency,OCandRMM
describedabove)
Industrial
estimated
exposure
concentrations
(mg/m3)
Professionalestimated
Exposureconcentrations
(mg/m3)
Notrelevant
Notrelevant
Nolocaleffectsandnosystemic
availabilityafterdermalcontact
PROC1
0.01
PROC2
0.5(solid)
PROC3
PROC4
1(solid)
5
PROC7
PROC8a
0.022
5
Inhalationexposure
PROC8b
PROC9
PROC10
PROC11
PROC13
PROC15
PROC17
PROC18
PROC19
5(solid)
5(solid)
5(solid)
0.022(liquid
mixtureonly)
0.022(liquid
mixture)
5
0.0044(liquid)
0.001(solid)
0.044(liquid)
0.1(solid)
0.044(liquid)
0.044(liquid)
5(solid)
0.088(liquid)
1(solid)
0.088(liquid)
0.044(liquid)
0.44(liquidmixtureonly)
0.44(liquidmixtureonly)
0.088(liquidmixtureonly)
0.088(liquidmixtureonly)
PROC22
PROC23
Professionalagriculturalwith
solidmixture,outdoor,noPPE
(ECPAOWBTier1:defaultuse
rate)
1
1
0.088(liquid)
1(solid)
0.142(solid)
PROC26isnotforeseeninECETOCTRAbutitinvolvesactivitieswhicharedescribedbyPROC8aand8b.Thereforethe
calculationwithPROC8aand8bcoversPROC26.
4.GuidancetoDUtoevaluatewhetherheworksinsidetheboundariessetbytheES
SafetyDataSheetinaccordancewithAnnexIIofRegulationEC1907/2006(REACH),
Regulation(EC)1272/2008andRegulation(EC)453/2010
Product
:SODIUMCARBONATE
REACHRegistrationNumber
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
:IssueNo.02,dated10012011
PageNumber
:Page24 of27
4.1Environment.
PredictedexposuresarenotexpectedtoexceedtheDNELwhentheRiskManagementMeasures/Operational
ConditionsoutlinedinSection2areimplemented.
4.2Health.
PredictedexposuresarenotexpectedtoexceedtheDNELwhentheRiskManagementMeasures/Operational
ConditionsoutlinedinSection2areimplemented.
SafetyDataSheetinaccordancewithAnnexIIofRegulationEC1907/2006(REACH),
Regulation(EC)1272/2008andRegulation(EC)453/2010
Product
:SODIUMCARBONATE
REACHRegistrationNumber
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
:IssueNo.02,dated10012011
PageNumber
:Page25 of27
Substance:SodiumCarbonate;EC:2078388;CAS:497198
ExposureScenarioforcommunication:
ES5:Consumeruse
0.Generalinformation
ESidentifier
Versionno
Revisiondate
EC#
CAS#
ES5
01
28.10.2010
2078388
497198
1.Usedescriptor
Consumeruse
Marketsector:SU21Consumeruses:Privatehouseholds(=generalpublic=consumers)
Sectorofuse:SU21Consumeruses:Privatehouseholds(=generalpublic=consumers)
Environment:
EnvironmentalReleaseCategory:ERC8a/b/c/d/e/f;ERC9a/b.
ProductCategory(PC):Norestriction(fromPC0toPC40)
ProcessCategory:Notapplicable
Processes,tasks,activitiescovered
Cleaningactivities
2.Conditionsofuseaffectingexposure
2.0DefaultProductCharacteristics
Physicalformofproduct/article
Volatility
Dustiness
Solidordissolvedinwater
Notrelevant
Mediumforpowdereddetergents,lowfor
householdsoda
MixtureArticleConcentration
Laundrydetergentsandsurfacecleaners:30%
Machinedishwashingtablets:45%
Householdsoda(puresodiumcarbonatedecahydrate):37%contentofsodiumcarbonate
Surfacecleaningsprays:10%
Aircareproducts:5%(PC3)
Furniture,floorandleathercare:10%(PC31)
2.1.Controlofenvironmentalexposure:
ConsumeruseERC8a/b/c/d/e/f;ERC9a/b.
Amountsused
Notrelevantastheexposureisestimatedtobenegligible
Frequencyanddurationofuse
Notrelevantastheexposureisestimatedtobenegligible
Othergivenoperationalconditionsaffectingenvironmentalexposure
SafetyDataSheetinaccordancewithAnnexIIofRegulationEC1907/2006(REACH),
Regulation(EC)1272/2008andRegulation(EC)453/2010
Product
:SODIUMCARBONATE
REACHRegistrationNumber
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
:IssueNo.02,dated10012011
PageNumber
:Page26 of27
Seesections8and13ofSafetyDataSheet
Technicalandorganizationalconditionsandmeasures
Seesection8ofSafetyDataSheet
Conditionsandmeasuresrelatedtomunicipalsewagetreatmentplant
Seesection13ofSafetyDataSheet
Conditionsandmeasuresrelatedtoexternaltreatmentofwaste
Seesection13ofSafetyDataSheet
AdditionalgoodpracticeadvicebeyondtheREACHCSR(ChemicalSafetyReport)
Seesections6and13ofSafetyDataSheet
2.2.Controlofconsumersexposure
Amountsused,frequencyanddurationofuse
Amounts used
Householdsoda:37g/l(worstcase)
Householdsoda:onetimeperweek(frequency)and5min
(duration)(worstcase)
Technicalandorganisationalconditionsandmeasures
Keepoutofreachofchildrenandavoidcontactwitheyes.Incaseofcontactwitheyes,rinseimmediatelywithplentyof
waterandseekmedicaladvice.
AdditionalgoodpracticeadvicebeyondtheREACHCSR(ChemicalSafetyReport)
Seesections7and8ofSafetyDataSheet
3.Exposureestimationandreferencetoitssource
3.1Environmentexposureestimationandreferencetoitssource
ThetablebelowgivesthesummaryoftheenvironmentexposureestimationmadeintheChemicalSafetyReport,
referringtoHERA(2005a)andtoSpecificEnvironmentalReleaseCategories(SPERC)(AISE,2010).
Compartments
Measuredrelease(kg/d)
Explanation/sourceofmeasureddata
Aquatic
Negligible
HERA(2005a);seesection9.5.2.3.2
Air(direct)
Negligible
SpecificEnvironmentalReleaseCategories(SPERC)(AISE,2010)
Soil(directonly)
Negligible
SpecificEnvironmentalReleaseCategories(SPERC)(AISE,2010)
3.2Consumersexposureestimationandreferencetoitssource
ExposureshavebeencalculatedwiththesoftwaretoolREACT(ReachExposureAssessmentConsumerTool)
Longtermdermalexposuretoconsumers:
Productcategory
Ingredientfractionby
weight
Estimateduptakevalue
(mg/kgbwperday)
Laundryregular(AISEC1,PC35),Powder
0.3
1.56E02
Laundryregular(AISEC1,PC35),Liquid
0.3
2.29E02
SafetyDataSheetinaccordancewithAnnexIIofRegulationEC1907/2006(REACH),
Regulation(EC)1272/2008andRegulation(EC)453/2010
Product
:SODIUMCARBONATE
REACHRegistrationNumber
:012119485498190018
IssueNumber
: 02 Revision01
IssueDate
:01042011
Supercedes
:IssueNo.02,dated10012011
PageNumber
:Page27 of27
Laundrycompact(AISEC2,PC35),Powder
0.3
1.60E02
Laundrycompact(AISEC2,PC35),Liquid/Gel
0.3
2.29E02
Laundryadditives(AISEC4,PC35),LiquidBleach
0.3
2.21E02
HandDishwashing(AISEC5,PC35)
0.3
3.12E04
Surfacecleaners(AISEC7,PC35),Gel
0.3
4.29E02
ThenegligibleinhalationhasbeenconfirmedforthelaundrywashingscenarioreportedbyHERA(2005a).
4.GuidancetoDUtoevaluatewhetherheworksinsidetheboundariessetbytheES
4.1Environment.
PredictedexposuresarenotexpectedtoexceedtheDNELwhentheRiskManagementMeasures/Operational
ConditionsoutlinedinSection2areimplemented.
4.2Health.
PredictedexposuresarenotexpectedtoexceedtheDNELwhentheRiskManagementMeasures/Operational
ConditionsoutlinedinSection2areimplemented.