Papercatalyser 10 August

XII / JEE MAINS PATTERN / 10.08.
2014
PART I PHYSICS
Straight Objective Type (+4, -1)
This section contains 30 multiple choice questions.
Each question has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.
1.
The current flowing through resistance of 2 ohm in the figure is 10
1.4 A
25
(A) 1.2 A
(B) 1.4 A
(C) 0.4 A
(D) 1.0 A
2.
A carbon resistor is marked with the rings coloured brown, black, green and gold. The resistance
(in ohm) is (A) 3.2 105 5 % (B) 1 106 10 % (C) 1 107 5 %
(D) 1 106 5 %
3.
For the circuit shown, the resistance in which the maximum heat is dissipated is 4
2
6
(A) 4
4.
12
(B) 2
(C) 6
(D) 12
If the switch S is closed in the circuit as shown in the figure, then current passed through it
is20V
5V
2
S
(A) 4.5 A
(B) 6.0 A
(C) 3.0 A
(D) zero
FOR ROUGH WORK
CatalyseREduventures (India) Pvt. Ltd.
XII / JEE MAINS PATTERN / 10.08.2014
5.
The power consumed by the 4V battery is

10V
4V
6
(A) 4 W
(B) 8 W
(C) 7 W
(D) cannot be calculated
6.
In an experiment to measure the internal resistance of a cell by potentiometer, it is found

that the balance point is at a length of 2 m when the cell is shunted by a 4 resistance and
at 3 m when cell is shunted by a 8 resistance. The internal resistance of cell is (A) 12
(B) 8
(C) 16
(D) 1
7.
A galvanometer having 30 divisions has a current sensitivity of 20 A/division. It has a resistance

of 25 . The value of resistance that should be connected to convert it into an ammeter of range 1
amp is (A) 0.15 in series
(B) 0.15 in parallel
(C) 0.015 in series
8.
(D) 0.015 in parallel
A potential difference of 220 V is applied across a rheostat of 12000 ohm. The voltmeter V
has a resistance of 6000 ohm and point C is at one fourth of the distance from A to B. The
error in the reading of voltmeter is approximately A
220V
C
V 6000
(A) 26%
9.
(B) 10%
(C) 40%
(D) 15%
The light bulbs A & B in the following circuits are identical. When the switch is closed -
12 V
(A) Intensity of bulb A increase

(C) Intensity of bulb B increase
12 V
12 V
(B) Intensity of bulb A decrease

(D) Nothing changes
FOR ROUGH WORK
10.
A source of constant potential difference is connected across a conductor having irregular

cross-section as shown in the figure P
Q
(A) electric field intensity at P is greater than that at Q

(B) rate of electrons crossing per unit area of cross-section at P is less than that at Q
(C) the rate of generation of heat per unit length at P is greater than that at Q
(D) mean kinetic energy of free electrons at P is greater than that at Q
11.
Find out the value of current through 2 resistance for the given circuit
10V
20V
10
5
2
(A) zero
12.
(B) 2A
(C) 5A
(D) 4A
In the circuit shown if point O is earthed, the potential of point X is equal to

2
X
5 10V
15V
2
5V
10V
5
5V
(A) 10 V
13.
(B) 15 V
(C) 25 V
(D) 12.5 V
The ammeter reading in the circuit of Fig. is 2V

10
A
1
6V
(A)
15
A
32
(B)
14
A
33
(C)
17
A
33
(D)
15
A
31
FOR ROUGH WORK
14.
A uniform wire of resistance 36 is bent in the form of a circle. The effective resistance
between A and B is (O is the centre of circle):
A
O
(A) 2.75
15.
(B) 3
30 B
(C) 33
(D) 36
Find the potential at point B 3A
(A) + 12 V
16.
9V
6V 2
A
(B) 12V
3
A
(D) 6 V
(C) +6 V
In the given diagram if VA VB is 23 V, then A
1
A
2V
2
A
1A
4V
4
A
3
3V
C
17.
(A) current through 1 resistance is 3 A
(B) current through 4resistance is 4 A
(C) both A and B are correct
(D) both A and B are incorrect
In the circuit shown current flowing from the battery is 4
(A)
18.
11
A
50
(B) 10 A
20 V
(C)
5
A
3
(D) Infinite current
A ball falling in a lake of 200m shows a decrease of 0.1 % in its volume. The bulk modulus
of elasticity of the material of the ball is (take g = 10 m/s2) (A) 109 N/m2
(B) 2 109 N/m2
(C) 3 109 N/m2
(D) 4 109 N/m2
FOR ROUGH WORK
19.
If two wires of same length and area of cross section A with Young modulus Y and 2Y
connect in series and one end is fixed on roof and other end with mass m. Make simple
harmonic motion, then the time period is (A) 2
m
YA
(B) 2
m
3YA
(C) 2
3m
2YA
(D) 2
m
2YA
20.
The mass of a lead ball is M. It falls down in a viscous liquid with terminal velocity V. The
terminal velocity of another lead ball of mass 8M in the same liquid will be (A) 64 V
(B) 4 V
(C) 8 V
(D) V
21.
Two solid spherical balls of radius r1 & r2 (r2 < r1), of density are tied up with a string and
released in a viscous liquid of lesser density and coefficient of viscosity , with the string
just taut as shown. The terminal velocity of spheres isr1
r2
22.
(A)
2 r22 g
( )
9
(B)
2 r12 g
( )
9
(C)
2 (r13 r23 ) ( ) g
9 r1 r2
(D)
2 (r13 r23 ) ( ) g
9 r1 r2
In a U-tube the radii of two columns are respectively r1 and r2. When a liquid of density
( = 0) is filled in it, a level difference of h is observed on two arms, then the surface
tension of the liquid is (A)
23.
ghr1r2
2(r2 r1 )
(B) hg (r2 r1)
(C)
h g (r2 r1 )
2
(D)
h g
2(r2 r1 )
The work done to get 'n' smaller equal size spherical drops from a bigger size spherical drop
of water is proportional to (A)
1
1
n 2/3
(B)
1
1
n1/3
(C) n1/3 1
(D) n4/3 1
FOR ROUGH WORK
24.
A closed cylinder of length '' containing a liquid of variable density (x) = 0 (1 + x) is

rotating about a vertical axis with an angular speed . Find the net force exerted by the
liquid on the axis of rotation. (Take the cylinder to be massless and A = cross sectional area
of cylinder, ignore the gravity)
A
1 1
(A) 0 A 2 3
1 2
(B) 0 A22
2 3
1 4
(D) 0 A22
2 3
2 2
(C) 0 A22
2
25.
Calculate the velocity with which the liquid gushes out of the 4 cm2 outlet, if the liquid
flowing in the tube is water and liquid in U tube has a specific gravity 12. Velocity of liquid
at point A is
20.2 m/s
2
v = (20.2) m / s A3 = 6cm
A
2 cm
A1 = 4cm2
A2 = 1cm2
8m/s
2 cm
= 12000 kg/m3
(A)2.5 m/s
26.
(B) 5.5 m/s
(C) 8 m/s
(D) 10 m/s
A given shaped glass tube having uniform area of cross-section is filled with water and is
mounted on a rotatable shaft as shown in Fig. If the tube is rotated with a constant angular
velocity , then A
(A) Water level in A will rise and fall in B

(C) Water level in B will rise and will fall in A
2L
(B) Water level in both A and B will rise

(D) Water level remains same in both A and B
FOR ROUGH WORK
27.
A wooden block, with a coin placed on its top, floats in water as shown in figure. The
distance and h are shown there. After some time the coin falls into the water. Then Coin
(A) decreases and h increases
(B) increases and h decreases
(C) both and h increase
(D) both and h decrease
28.
A block of wood floats in fresh water with two third of its volume submerged. In oil the
block floats with one fourth of is volume submerged. The density of oil is (A) 2666.7 kg/m3
(B) 5333.3 kg/m3
(C) 1333.3 kg/m3
(D) 3333.3 kg/m3
29.
A cubical sealed vessel with edge L is placed on a cart, which is moving horizontally with
an acceleration a as shown in figure. The cube is filled with an ideal fluid having density
d. The gauge pressure at the centre of the cubical vessel is
L
L
a
(A)
Ldg
2
(B)
Ld
(g + a)
2
(C)
Lda
2
(D)
Ld
(g a)
2
FOR ROUGH WORK
30.
The container is massless. Mass of liquid initially at t = 0 filled in the container is M. There
is a hole in the container as shown. If there is no friction between container and ground,
then -
(A) initial acceleration of system is less then g/2

(B) initial acceleration of system is equal to g/2
(C) initial acceleration of system is greater than g/2
(D) system remain at rest
END OF PHYSICS PORTION
FOR ROUGH WORK
PART II CHEMISTRY
31.
O
||
OH
CH3CCH3
P
C2 H5ONa
P + CH2(COOC2H5)2
Q
C2 H5ONa
Q
R
I . H3O II . Heat
S
R
The final product S is O
(A)
(B)
(C)
(D)
O
O
32.
1'
2'
3'
N
Monobro min ation
'A'
4'
Me
'Br' will be substituted in major product 'A' at (A) 1, 3

33.
(B) 2, 4
(C) 1', 3'
(D) 2', 4'
Which compound below is the product expected from the following reaction ?
O
CH3
OCCH3
( i ) LiAlH 4 , Et2O
( ii ) H 2O
H
O
CH3
(A)
CH3
OCCH3
OH
HO
OH
(B)
OH
(C)
CH3
CH3
OH
CH2OH
(D)
H
O
FOR ROUGH WORK
34.
Propenal principally undergo nucleophilic addition reaction because

(A) Conjugation leads to generation of carbocation
(B) Conjugation leads to formation of carbonion
(C) Presence of carbonyl group make double bond of alkene less reactive
(D) None of these
35.
The major product of following reaction is:

O
CF3CO3H
(A)
36.
O
O
(B) O
(C)
(D) None of above
NH 2OH
H 2O
TsCl

product.
Pentan-2-one
[A]
NH 4Cl
The final product (s) formed in the above reaction is:

(A) N-propyl ethanamide
(B) N-methyl propanamide
(C) Both
(D) None
37.
The major product of reaction :

Me
500C
is
OCEt
O
CHO
Me
(A)
(B)
CHO
38.
Me
Me
(C)
CHO
(D) None of above

CHO
The product formed in the reaction

O
PhN3
TiCl4
is -
O
N Ph
(A)
(B)
CONH2
NH2
(C)
(D)
FOR ROUGH WORK
10
39.
The major product of reaction

2 mol
Zn Hg
HCl
is -
(A)
(B)
(C)
O
40.
CH3CH = CH CH
HSCH2CH2SH
(D)
O
H2
Pt
O
H3O
MeI
PhLi
THF
gives major product (A) CH3CH = CHCPh
(B) CH3CH2CH2CHPh
41.
(C) CH3CH2CH2CMe
OH
(D) MeCH2CH2CPh
The appropriate reagent for the transformation O

CH2CH3
CH3
HO
HO
(B) NH2NH2, OH
(A) Zn(Hg), HCl

42.
(C) H2/Ni
Consider the following aryl alkyl ketones :

O
CCH3
CCH3
I.
II.
H3CO
H3C
CCH3
CCH3
III.
IV. CH3 CH
CH3
O2N
Friedel-Craft's acylation can be used to obtain.

(A) II, III and IV
(B) I, III and IV
(C) I, II and IV
43.
(D) NaBH4
(D) I, II and III
An optically active compounds (X) reacts with phenyl hydrazine to form phenylhydrazone
derivative. The compound X, gives a yellow precipitate of iodoform with I2 and NaOH. The
compound X is (A) CH3CH2CCH2CH3 (B) CH3CCH2CH CH3 (C) CH3C CH CH2CH3 (D) CH3CH CCH3
O
CH3
O CH3
CH3 O
FOR ROUGH WORK
11
44.
Consider the following reactions :

OH
(1) CH3MgBr + CH3COCH2COCH3 (CH3)2CCH2COCH3

O
OH
CH3
(2)CH3MgBr +
OH
(3) CH3MgBr + CH3COCH2CH2CH3 (CH3)2CCH2CH2CH3

(4) CH3MgBr + CH2 CH2 CH3CH2CH2OH
O
Which of the above products would be obtained after hydrolysis?

(A) (1), (4)
(B) (2), (3), (4)
(C) (2), (3)
(D) none of these
45.
Consider the following reaction :

O
1. LiAlH 4
CH3
2. H
Which of the following sets of isomers best represents the most stable conformations of the
two products?
(A) CH3
CH3
CH3
OH
(D) CH3
CH3
CH3
OH
H
OH
46.
H
H
(C)
OH
OH
(B) CH3
H
H
OH
H
OH
H
OH
CH3
H
Which one of the following is obtained when 4, 4-dimethyl cyclohexanone reacts with
N-bromo succinimide ?
CH3
(A) BrCH2
CH3
(B) CH3
CH3
(C) CH3
Br
Br
(D) All of the above
FOR ROUGH WORK
12
47.
Which of the following statements is false in case of equilibrium state

(A) There is no apparent change in properties with time
(B) It is dynamic in nature
(C) It can be attained from either side of the reaction
(D) It can be attained from the side of the reactants only
48.
A chemical reaction A
B is said to be in equilibrium when (A) Complete conversion of A to B has taken place
(B) Conversion of A to B is only 50% complete
(C) Only 10% conversion of A to B has taken place
(D) The rate of transformation of A to B is just equal to rate of transformation of B to A in
the system
49.
According to Law of Mass action, the rate of reaction is directly proportional to (A) molarities of the reactants
(B) normalities of the reactants
(C) molalities of the reactants
(D) mole fractions of the reactants
50.
In a chemical equilibrium, the equilibrium constant is found to be 2.5. If the rate constant of
backward reaction is 3.2 102, the rate constant of forward reaction is (A) 8.0 102
(B) 4.0 102
(C) 3.5 102
(D) 7.6 103
51.
Select the correct expression regarding the relation between KP and KC for the reaction
aX(g) + bY(g)
bZ(g) + aW(g) KC
(A) KP = KC(RT)a+b (B) KP =
(C) KP = KC RT
(D) KP = KC
( a b) 2
52.
Ksp of SrF2 (s) in water is 3.2 1011. The solubility of SrF2 (s) in 0.1 (M) NaCl solution is (A) 3.2 109 (M)
(B) 2 104 (M)
(C) 4 104 (M)
(D) slightly higher than 2 104 (M)
53.
What is the minimum pH required to prevent the precipitation of ZnS in a solution that is
0.01 M ZnCl2 and saturated with 0.10 M H2S ?
[Given Ksp = 1021, K a1 K a2 = 1020]
(A) 0
(B) 1
(C) 2
(D) 4
FOR ROUGH WORK
13
54.
Methyl amine in water has a weak basic property. This is explained by which of the
following equilibrium ?
C6 H 5 NH 3 + OH
(A) CH3NH3OH
CH3NH2OH
(B) CH3NH2 + 2H2O
+ H3O+
(C) CH3NH2 + H2O
55.
CH 3 NH 3 + OH (D) All of the above
Which of the following is/are soft bases ?

H2O, H , CO,CO2, C2H4, CN
(A) C2H4
(C) H, CN, CO, C2H4
(B) H ,CN, CO
(D) H, CO, CO2, C2H4
56.
Calcium lactate is a salt of weak organic acid and strong base represented as Ca (LaC)2 . A
saturated solution of Ca (LaC)2 contains 0.6 mole in 2 litre solution. pOH of solution is
5.60. If 90% dissociation of the salt takes place, then what is pKa of lactic acid ?
(A) 2.8 log (0.54) (B) 2.8 + log (0.54) (C) 2.8 + log (0.27) (D) None of these
57.
The value of Hsol. of BaCl2(s) and BaCl2. 2H2O (s) are a kJ and b kJ respectively. The
value of H Hydration of BaCl2 (s) is(A) b a
(B) a + b
(C) a b
(D) a b
58.
When two ideal liquids are mixed, the enthalpy of the system (A) Decreases
(B) Increase
(C) Remains unaffected
(D) May increase or decrease
59.
Select the correct order in the following :

(A) 1 erg > 1 joule > 1 cal
(C) 1 erg > 1 cal > 1 joule
60.
(B) 1 cal > 1 joule > 1 erg

(D) 1 joule > 1 cal > 1 erg
Which among the following is not a state function (A) Internal energy (B) Free energy
(C) Work
(D) Enthalpy
END OF CHEMISTRY PORTION
FOR ROUGH WORK
14
PART III MATHEMATICS

61.
(A) 0
62.
(B) 1
1 x2
1 y2
66.
(C) 2 xln x 1 ln x
1
, then the value of
x
(A) 0
(B) 3
x2 1
1 y2
(C)
(D)
y2 1
1 x2
m
, then
( x 2nx 1)
2
(C) m2 + n2 = 1
(B) m + n = 1
If y =
(D) xln x 2
dy
dx
1 y2
1 x2
(B)
If x sin ( + y) = sin y and y =

(A) m n = 1
65.
(B) xln x 1ln x
If 1 x 2 1 y 2 a( x y) , then
(A)
64.
(D) 2
The derivative of y xln x is

(A) xln x ln x
63.
dy
at x y 1 is
dx
(C) 1
If 2x 2 y 2 x y , then the value of
dy
1 y
dx
1 x4
(D) m = n
3 is equal to-
(C) 4
(D) 3
Let g : R R be a differentiable function satisfying g(x) = g(y) g(x y) x, y R and

g'(0) = a and g'(3) = b then g'( 3) is (A)
a2
b
(B)
a
b
(C)
b
a
(D) None of these
FOR ROUGH WORK
15
67.
d 2u
is
dx 2
(B) 2 cot x2 4x2 cosec2 x2
Let f(x) = sin x; g(x) = x2 and h(x) = log x. If u (x) = h (f (g (x))), then
(A) 2 cos3 x
(C) 2x cot x2
68.
(D) 2 cosec2 x
x y f ( x) f ( y )
Let f
for real values of x and y. If f (0) exist and equals 1 and
=
2
2
f(0) = 1, then f (2) is equal to(A) 1
69.
(B) non-existent
If f(x) = x +
(C)
1
2
(D) 12
x 2 x3
xn
+ .
, then f(0) + f (0) + f (0) + .. f .n times(0) is
1! 2!
(n 1)!
equal to
(A)
70.
71.
n(n 1)
2
(B)
If 3 sin(xy) + 4 cos (xy) = 5 then
If y =
tan
r 1
(A)
1
1 x2
(D)
n(n 1)(2n 1)
(C) 2 | x |
(D) None of these
(C) x/y
(D) x/y
dy
=
dx
(B) y/x
x
73.
n(n 1)
(C)
The differential coefficient of x |x| is (A) 2x

(B) 2x
(A) y/x
72.
n2 1
2
1
dy
then
is equal to2
1 r r
dx
(B)
1
1 (1 x) 2
(C) 0
(D) None of these
(C) 5 < x < 0
(D) e < x < 0
The solution set of f ' (x) > g' (x), where
1 2x+1
.5
and g(x) = 5x + 4x ln 5 is2
(A) x 0
(B) x > 0
f(x) =
FOR ROUGH WORK
16
74.
x x x .... ; where x > 0 then
If y =
(i)
1
,
2 y 1
(ii)
x
,
x 2y
Which of the above is/are correct ?

(A) only (i)
(C) only (i), (iii) & (iv)
75.
(B)
1
2
y
2x y
(B) only (i) & (iii)

(D) only (i), (ii) & (iii)
(C) 1
(B) 1
(C) 1/2
If g is the inverse of f and f (x) = sin x then g(x) =

(A) cosec (g (x))
(B) sin (g (x))
(C) cosec (g(x))
(D) none of these
(D) 1/ 2
(D) None
xc
where c is a constant, then when y is stationary, xy is equal to -
1 x2
(A) 1/2
(B) 3/4
(C) 5/8
(D) None
78.
If y =
79.
If f(x) = log x2 (nx) then f (x) at x = e is

(A) 0
80.
(iv)
If f(x) = cos [ x] x3 , 1 < x < 2 where [.] is the greatest integer then f ( 3 / 2 ) is
2
(A) 0
77.
1
,
1 4x
(iii)

If f(x) = cos x. cos 2x. cos 4x. cos 8x. cos 16x then f is4
(A)
76.
dy
is
dx
(B) 1
(C)
1
e
(D)
1
2e
3cos x 5sin x
, then dy is If y = cos1
34
dx
(A) 0
(B) 1
(C) 1
(D) none of these
FOR ROUGH WORK
17
81.
82.
If f(x) = (cosx + isinx)(cos3x + isin3x)..........

(A) n2f(x)
(B) n4f(x)
dy
3x 4
2
If y = f
is equal to
and f '(x) = tanx then
dx
5x 6
1
3x 4
(A) 2 tan

2
5 x 6 (5 x 6)
3 tan x 2 3
2
(B) f
tan x
2
5
tan
x
(C) tanx2
(D) None
83.
If f '(1)=2, g '( 2) = 4 then the derivative of f (tan x) with respect to g(sec x) at x = /4 is

(A)1
84.
(B)
(C)
2
2
(D) 2
The set of real values of x satisfying log1/2 ( x2 6 x 12) 2 is

(A) , 2
85.
(cos(2n1)x + isin(2n 1)x), then f (x) is equal to

(C) n2f(x)
(D) n4f(x)
(C) 4,
(B) [2, 4]
(D) None of these
If the sum of the roots of the quadratic equation ax2 bx c 0 is equal to the sum of the
squares of their reciprocals, then a / c, b / a, c / b are in
(A) A.P.
86.
(B) G.P.
(C) H.P.
(D) None of these
If every pair of the equations x2 px qr 0 , x2 qx rp 0, x2 rx pq 0, have a

common root, then the sum of three common roots is
(A)
87.
( p q r )
2
(B)
pqr
2
(C) ( p q r )
(D) p q r
(C) 3 a 3
(D) a 2
If the roots of x2 x a 0 exceed a, then

(A) 2 a 3
(B) a 3
FOR ROUGH WORK
18
88.
A ball is dropped from a height of 120 m rebounds (4/5)th of the height from which it has
fallen. If it continues to fall and rebound in this way. How far will it travel before coming to
rest ?
(A) 240 m
89.
(B) 140 m
(c) 1080 m
(D)
In an A.P. with first term 'a' and the common difference d (a, d 0), the ratio ' ' of the sum
of the first n terms to sum of n terms succeeding them does not depend on n. Then the ratio
a
and the ratio ' ', respectively are
d
(A)
1 1
,
2 4
(B) 2,
100
90.
The sum
k
k 1
(A)
4950
10101
1
3
1
,2
2
(C)
1 1
,
2 3
(D)
(C)
5151
10101
(D) None
k
is equal to
k 2 1
(B)
5050
10101
END OF TEST PAPER
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19

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