PEPERIKSAAN AKHIR TAHUN 2014

SKIMA JAWAPAN KIMIA TINGKATAN 4

KERTAS 1
1C
6A
2B
7A
3C
8A
4D
9B
5B
10D

11A
12B
13A
14B
15D

16A
17D
18A
19C
20D

21D
22D
23B
24A
25A

26D
27D
28A
29C
30B

31C
32B
33A
34B
35D

36D
37A
38C
39B
40C

41D
42B
43A
44D
45D

4A6
47A
48C
49B
50A

KERTAS 2
ANSWER
1(a)(i) Total number of proton and neutron in an atom.
(ii) 18
(iii)
P

MARKS
1
1
2

2.8.2

(iv) 20

(b) Refer graph

5
Total: 10

2 (a)(i) No. of moles = 6.0/24 = 0.25 mol

No. of molecules = 0.25 x 6.02 x 1023 = 1.505 x 1023
(ii) Mass = mol x RMM = 0.25 x 44 = 11 g

(b)(i) Chemical formula that shows the simplest ratio for each element in a
compound.
(ii) Magnesium: 2.4 g
Oxygen: 1.6 g
(iii) 1:1
(iv) MgO
(v) Copper is a less reactive metal than hydrogen in the reactivity series.
(vi) To allow oxygen to enter the crucible for complete combustion.
3 (a)(i) Atoms of an element which have the same number of proton but different
number of neutron.
(ii) To estimate the age of fossils and artifacts

1
2
1
1
1
1
Total: 10
1
1

(b) Proton

(c) 4

(d) 612 P [A: proton number, Z: nucleon number]

(e)(i) 2Mg + O2
(ii)
Mg

2
3

2MgO
2+

2O

Total: 10
4 (a) [Shows the direction on the diagram: Zinc rod

Copper rod]

(b) Zinc

1
1

(c) Chemical energy

Electrical energy

(d) Copper ion, Cu2+

(e)(i) Copper ions from X solution discharged to become copper atoms and
deposited at copper rod.
(ii) Cu2+ + 2e
Cu

(f)(i) The reading of the voltmeter is greater.

(ii) The distance between Mg and Cu in the reactivity series is greater than that
between Zn and Cu.

1
2

(g) Zn + Cu2+

Zn2+ + Cu

Total: 10
5(a) P: 2.8.2

Q: 2.4

(b)(i) Ionic compound

(ii) Atom P donates 2 electrons, atom R receives 2 electrons
(iii) No, because there are no freely moving ions in solid state.

1
2
2

(c)(i)

2
R

(ii) Molecules in a covalent compound are bonded with weak molecular forces
of attraction. Thus less energy required to break the bond.

2
Total: 10

6(a)(i) S
(ii) The higher the pH value, the higher the concentration of hydroxide ion,
OH- which indicates the strongest alkaline solution.
(b)(i) Neutralisation
(ii) Phenolphtalein // methyl orange
(iii) Pink to colourless // yellow to orange
(iv) H+ + OHH2O

1
2

1
1
1
1

(c)(i)

M1V1 = M2V2
(0.1)(0.5) = M2 (20.0)
M2 = 0.5 / 20
= 0.025 moldm-3

(ii) No.ofmol= 0.1 moldm-3 / 0.5 dm-3No.of ions = 0.2mol x6.02x1023

before dilution = 0.2 mol
= 1.204x1023

No.ofmol=0.025 moldm-3 /20.0 dm-3No.of ions = 1.25x10-3x6.02x1023

after dilution = 1.25 x 10-3mol
= 7.525x1020
Total: 10
7(a)(i) 2.5
(ii) Group 15 because the number of valence electron is 5. In Period 2 because
the number of shell-filled with electrons is 2.
(b)(i) - big and bright flame is produce
- explosion occur
(ii) 2Rb + 2H2O
2RbOH + H2
(iii) During handling the Group 1 metals, avoid direct contact with skin.

1
4

2
2
1

(c)(i)
Covalent compound
C2H5OH
C6H14

Covalent compound (C6H14)

Ionic compound
MgO
NaCl
(ii)
Physical
Ionic compound (MgO)
properties
Melting point and Ions are attracted by a
boiling point
strong electrostatic force
of attraction. More energy
required to overcome the
forces thus the melting and
boiling points are high.
Electrical
conductivity

In molten or aqueous
states, ions are freely
moving thus can conduct
electricity.

Molecules are bonded with

weak molecular forces of
attraction. Less energy
required to break the bond
thus the melting and boiling
points are low.
There are no freely moving
ions in all states thus cannot
conduct electricity.
Total: 20

8(a)(i) Q: 2.7
R: 2.4
(ii) Number of neutron = 10,

Number of electron = 9

2
2

(b) Both Q and R are non-metal elements.

The reaction forms a covalent compound through the sharing of electron.
Atom R with electron arrangement 2.4 has 4 valence electrons, thus need 4
more electrons to achieve octet electron arrangement.
Atom Q with electron arrangement 2.7 has 7 valence electrons, thus need one
more electron to achieve octet electron arrangement.
One atom R contributes 4 electrons, while 4 atoms Q contribute one electron
each in the sharing. The compound formed is RQ4

(c) Group 1
When going down the group, the number of shell increases.
The distance between nucleus and valence electron increases.
Thus the strength of nucleus to attract electrons decreases down the group.
The reactivity increases as elements have a higher tendency to lose electron
due to weaker attractive forces from the nucleus.

Group 17
When going down the group, the number of shell increases.
The distance between nucleus and valence electron increases.
Thus the strength of nucleus to attract electrons decreases down the group.
The reactivity decreases as elements have a lower tendency to gain electron
due to weaker attractive forces from the nucleus.
Total: 20
9(a)(i)
2
Glass cover
Gas jar
Bromine gas

(ii)

2
Bromine gas
Gas jar

(iii) Procedures:
- A few drops of liquid bromine were placed into a gas jar. The gas jar
immediately covered and set aside for a few minutes.
- Another gas jar containing air was inverted on top of the gas jar which
contained bromine vapour, Br2
- The cover between the two jars was removed. The apparatus was set
aside for a few minutes and observation was recorded.
- Wear glove when handle bromine gas.
- Activity carried out in a fume chamber.

(iv) Bromine gas contains discrete particles which possess high kinetic energy.
The particles are moving freely as the spaces between particles are further
apart.
(b) Materials and apparatus
- boiling tube, beaker, thermometer, tripod stand, retort stand and clamp,
Bunsen burner, wire gauze, stopwatch, conical flask.

Diagram:
2

I.

Heating of naphthalene

II.

Cooling of naphthalene

Procedure

I. Heating of naphthalene
1. A boiling tube was filled with naphthalene to a depth 3 cm and a
thermometer was put into it.
2. The boiling tube was suspended in a beaker half-filled with water using a
retort stand and a clamp. The level of naphthalene in the boiling tube
below the level of water in the beaker.
3. The water was heated and the naphthalene was stirred slowly with the
thermometer until the temperature of the naphthalene reached 90oC.
II. Cooling of naphthalene
1. The boiling tube in ( I) was removed from the water bath. The outer
surface of the boiling tube was dried and immediately it was put into a
conical flask. The naphthalene was stirred continuously.
2. The temperature of the naphthalene was recorded at half-minute intervals
until the temperature dropped to about 60oC.
Result
Time/s
Temperature/oC

2
0
90

30
86

60
82

90
78

120
78

150
78

180
75

210
72

240
60

Total:20
5

10 (a). The stages in Contact Process:

10

I Production of sulphur dioxide

Suphur is heated in dry air to produce sulphur dioxide
S + O2

SO2

II Production of sulphur trioxide

Sulphur dioxide is further oxidized by oxygen over vanadium(V) oxide, V2O5
catalyst to produce sulphur trioxide at a temperature of 450 to 500oC.

2SO2

V2O5
+ O2
2SO3
o
450 - 500 C
1 atm

III Production of sulphuric acid

Sulphur trioxide is dissolved in concentrated sulphuric acid to form oleum,
H2S2O7
SO3 + H2SO4

H2S2O7

Oleum is then diluted with appropriate amounts of water to form sulphuric acid in
a large scale.
H2S2O7

+ H2O

2H2SO4

(b) Experiment to show the hardness of the alloy compared to its pure metal.
Apparatus set up:

10

Procedure:
1. A steel ball is stuck to a brass block using cellophane tape.
2. A weight of 1 kg is hung at a height of 50 cm from the top of the brass
block.
3. The weight is released so that it falls on the metal ball.
4. The diameter of depression formed on top of the brass block is measured
using a metre ruler and the measurement is recorded in Table 9.5
5. Steps 1 to 4 are repeated twice on different spots on the brass block to
obtain an average of the diameter
6. The experiment is repeated using a pure copper block.
Tabulation of data:
Type of
Block
Brass
Copper

Diameter of depression
2

Average
diameter (mm)

Total: 20

KERTAS AMALI
ANSWER
1.
Titration
Initial burette
reading (cm3)
Final burette
reading (cm3)
Volume of P2
used (cm3)

(a)

MARKS
7

1
50.0

2
50.0

3
24.4

24.2

24.3

49.0

25.8

25.7

24.6

( 25.8 + 25.7 + 24.6) / 3 = 25.4 cm3

(b) (i) NaOH + HCl

NaCl + H2O

2
4

(ii) MHCl = 1.0 moldm-1

VHCl = 25.4 cm3
nHCl = (1.0) (25.4) / 1000
= 0.0254 mol

From equation, 1 molHCl required 1 molNaOH

So, 0.0254 molHCl requires 0.0254 molNaOH
MNaOH = 0.0254 mol / 0.025 dm3
= 1.0 moldm-3
(c) Pink to colourless

(d) When HCl is added slowly into NaOH solution mixed with
phenolphthalein, the pink solution turns colourless shows that the mixture
has neutralized.

(e) 12.7 cm3 (half of the volume of HCl)

2
Total: 20

2
Pair of electrodes
Magnesium and
copper
Metal X and
copper
Iron and copper
Metal Y and
copper
Aluminium and
copper

Potential
difference (V)
1.4

Negative terminal
of the cell
Magnesium

1.0

Metal X

0.5

Iron

0.1

Metal Y

0.2

Aluminium

Arrangement of metals:

Copper, Magnesium, metal X, Iron, Aluminium, metal Y

Total : 10