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Solid: A solid is a state of matter in which the constituting particles are arranged very closely. The
constituent particles can be atoms, molecules or ions.
Properties of solids:
o They have definite mass, volume and shape.
o Intermolecular distances are short, and hence, the intermolecular forces are strong.
o Their constituent particles have fixed positions and can only oscillate about their mean positions.
o They are incompressible and rigid.
Classification on the basis of the arrangement of constituent particles:
o Crystalline solids: The arrangement of constituent particles is a regular orderly arrangement.
Examples: Iron, copper, diamond, graphite
o Amorphous solids: The arrangement of constituent particles is an irregular arrangement.
Examples: Glass, plastics, rubber
Polymorphic forms or polymorphs: The different crystalline forms of a substance are known as
polymorphic forms or polymorphs. Examples: Graphite and diamond.
Constituent
Particles
Molecul
ar
solids
1. Nonpolar
Molecules
2. Polar
3.
Hydrog
en
bonded
Ionic
solids
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Ions
Bonding/
Attractive
Forces
Dispersion
or London
forces
Examples
Physical
nature
Electrical
conductivity
Melting
point
Soft
Insulator
Very low
Dipole
dipole
interactions
Hydrogen
bonding
HCl, solid
SO2, solid
NH3
H2O (ice)
Soft
Insulator
Low
Hard
Insulator
Low
Hard but
brittle
Insulators
in solid
state but
conductors
in molten
state and
High
Coulombic
or
electrostatic
NaCl,
MgO, ZnS,
CaF2
Metallic
solids
Positive
ions in a
sea of
delocalised
electrons
Covalen Atoms
t or
network
solids
Metallic
bonding
Hard but
malleabl
e and
ductile
Covalent
bonding
SiO2
(quartz),
SiC, C
(diamond),
AlN
Hard
in aqueous
solutions
Conductors
in solid
state as
well as in
molten
state
Insulators
C (graphite)
Soft
Conductor
(exception)
Fairly
high
Very
high
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Types of voids:
o Tetrahedral voids: This type of void is formed at the centre when four spheres are joined in the
form of a tetrahedron.
o Octahedral void: This type of void is surrounded by six spheres.
In hcp or ccp arrangement, octahedral and tetrahedral voids are present. The number of octahedral
voids present in a lattice is equal to the number of close-packed particles. The number of tetrahedral
voids is twice the number of octahedral voids.
Example: If the number of close-packed particles = n
Number of particles present in octahedral voids = n
Number of particles present in tetrahedral voids = 2n
Packing efficiency is the percentage of total space occupied by constituent particles (atoms, molecules
or ions)
Packingefficiency=
Radius ratio in an octahedral void: For an atom to occupy an octahedral void, its radius must be 0.414
times the radius of the sphere.
r
= 0.414
R
Radius ratio for tetrahedral void: For an atom to occupy a tetrahedral void, its radius must be 0.225
times the radius of the sphere.
r
= 0.225
R
Density of a unit cell is same as the density of the substance.
Relationship between radius of constituent particle (r) and edge length(a):
o Simple cubic unit cell: a = 2r
o Face-centred unit cell: a 2 2 r
4r
o Body-centred unit cell: a =
3
Volume of a unit cell = (edge length)3 = a3
o Simple cubic unit cell: Volume = (2r)3
o Face-centred unit cell: Volume (2 2 r)3
4r 3
)
o Body-centred unit cell: Volume = (
3
Number of atoms in a unit cell (z):
o Simple cubic unit cell: z = 1
o Face-centred unit cell: z = 4
o Body-centred unit cell: z = 2
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zM
a3.NA
Crystal defects are basically irregularities in the arrangement of constituent particles.
Defects are of two types:
o Point defects: Point defects are the irregularities or deviations from ideal arrangement around a
point or an atom in a crystalline substance.
o Line defects: Line defects are the irregularities or deviations from ideal arrangement in entire rows
of lattice points.
Density of unit cell=
Interstitial defect
A crystal is said to have an
interstitial defect when some
constituent particles (atoms or
molecules) occupy an interstitial
site.
This results in increase in density
of the substance.
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Solids can also be classified into three types based on their electrical conductivities:
o Conductors: The solids with conductivities ranging between 104 and 107 ohm1m1 are called
conductors.
o Insulators: These are solids with very low conductivities ranging between 1020 and 1010
ohm1m1.
o Semi-conductors: These are solids with conductivities in the intermediate range from 106 to 104
ohm1m1.
Band theory: A metal is characterised by a band structure. The highest filled band is called a valence
band, and the lowest unoccupied band is called a conduction band. The gap between the two bands
is called the forbidden band.
o In conductors, the valence band and the conduction band overlap.
o In insulators, the forbidden gap is very large, and the electrons are unable to excite to the
conduction band.
o In semiconductors, the forbidden gap is small. Therefore, some electrons may jump to the
conduction band and show some conductivity. Electrical conductivity of semiconductors increases
with rise in temperature, because more electrons can jump to the conduction band.
Types of semiconductors:
o Intrinsic: These are semiconductors in which the forbidden gap is small. Only some electrons may
jump to the conduction band and show some conductivity. They have very low electrical
conductivity. Examples: Silicon, germanium
o Extrinsic: When an appropriate impurity is added to an intrinsic semiconductor. Their electrical
conductivity is high.
Doping: The process of adding an appropriate amount of suitable impurity to increase the conductivity
of semiconductors.
p-type semiconductors
They are formed when silicon is
doped with an electron-deficient
impurity like group 13 elements.
The increase in conductivity is
due to the positively charged
holes.
Transistors: They are made by sandwiching a layer of one type of semiconductor between two layers
of the other type of semiconductor. npn and pnp types of transistors are used to detect or amplify radio
or audio signals.
1216 compounds: These compounds are formed by the combination of group 12 and group 16
compounds. They possess an average valency of 4. Examples: ZnS, CdS, CdSe and HgTe
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1315 compounds: These compounds are formed by the combination of group 13 and group 15
compounds. They possess an average valency of 4. Examples: InSb, AlP and GaAs.
Every substance has some magnetic properties associated with it. The origin of these properties lies
in the electrons. Each electron in an atom behaves like a tiny magnet. Its magnetic moment originates
from two types of motions (i) its orbital motion around the nucleus and (ii) its spin around its own axis.
On the basis of magnetic properties, substances can be classified into five categories:
o Paramagnetic: These are substances which are weakly attracted by the magnetic field. It is due to
presence of one or more unpaired electrons.
o Diamagnetic: Diamagnetic substances are weakly repelled by a magnetic field. Diamagnetism is
shown by those substances in which all the electrons are paired and there are no unpaired
electrons.
o Ferromagnetic: These are substances which are attracted very strongly by a magnetic field.
o Antiferromagnetic: They have equal number of parallel and antiparallel magnetic dipoles resulting
in a zero net dipole moment.
o Ferrimagnetic: They have unequal number of parallel and antiparallel magnetic dipoles resulting in
a net dipole moment.
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