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Ferrofluids
Course InstructorDr. A.K.Vishwanath
Associate Professor
Contents
1.Introduction
2.Classifcation
Ionic ferrofluids(IFF)
Surfacted ferrofluids(SFF)
3.Stabilitiy of colloids
4.Properties
5.Synthesis
6.Applications
INTRODUCTION
A ferrofluid is a stable colloidal suspension of subdomain magnetic particles in a liquid carrier.
These colloidal are made of nanoscale ferromagnetic, or ferrimagnetic,
particles suspended in a carrier fluid (usually an organic solvent or H2O).
Each tiny particle is thoroughly coated with a surfactant to inhibit clumping.
It is a liquid which becomes strongly magnetized in the presence of a
magnetic field.
Ferrofluids usually do not retain magnetization in the absence of an
externally applied field and thus are often classified as
"superparamagnets" rather than ferromagnets.
Composition
The composition of a typical ferrofluid is about
5% magnetic solids,
10% surfactant &
85% carrier by volume.
Liquid Carrier
100
Magnetic particle
Surfactant
Classification of ferrofluids
according to the coating
Ionic ferrofluids(IFF)
Surfacted ferrofluids(SFF)
Ionic ferrofluids
Nanoparticles are electrically charged to keep the colloidal
system stable.
Surfacted ferrofluids
Formed by magnetic particles (usually magnetite, Fe3O4)
coated with surfactant agents (amphiphilic molecules, as
oleic acid and aerosol sodium di-2 ethylhexylsulfosuccinate) in order to prevent their aggregation.
Steric repulsion between particles acts as a physical barrier
that keeps grains in the solution and stabilizes the colloid.
72k T
D (
)
M
M- intensity of magnetization
1. Attractive interactions
Basically two main attractive interactions between magnetic particles in a
ferrofluid, the van der Waals-London and the dipole-dipole interactions.
The van der Waals-London interaction, UAw, between two spherical particles
of diameter D, separated by a distance r, is
A
2
2
4
[ 2
2 ln(
)]
2
6 4
U Aw
where = 2r/D
A - Hamaker constant ( 10-19J for ferrite particles) .
This is a short-range interaction and the attractive force increases with the
particles size.
U Ad
Where
0
r
r
[ 1.2 3( 1. )( 2 . )]
3
4r
r
r
2.Repulsive interactions
In ionic ferrofluids, long-range electrostatic interactions
give rise to repulsive interactions, which guarantee colloidal
stability.
Whereas in surfacted ferrofluids, there are steric repulsion
forces, of short range nature.
In case of IFF the interaction between two electrically charged
spherical particles of diameter D, separated by a distance r is
UR
D 2
0 r
exp[ (r D)]
Properties
Magnetically, a ferrofluid is perfectly soft.
Magnetic Characterizations
1.4500
L = 80 m
10 m
1.4450
1.4400
Ms = 0.68 emu/g
dH/dt = 10 Oe/s
= 1.557 m
1.4350
0
30
60
90
120
150
H (Oe)
180
210
240
270
Synthesis
Two basic steps in creating a ferrofluid:
synthesis of the magnetic solid, magnetite (Fe3O4)
suspension in water with the aid of a surfactant.
The magnetic particles must be of order 10 nm in diameterso that the thermal energy of the particles overcomes the
magnetic interactions between particles.
If size too large, magnetic interactions will dominate and the
particles will agglomerate.
Precipitation reaction
The magnetite synthesized by mixing FeCl2 and FeCl3 with
ammonium hydroxide (an aqueous solution of ammonia, NH 3)
FeCl3 + FeCl2 + NH3 + H2O = Fe3O4 + NH4Cl
Surfactant - tetramethylammonium hydroxide (N(CH3)4OH )
Tetramethylammonium
Cation (NH4+)
Electrostatic Repulsion
Interaction of the hydroxide ions (red) with the magnetite and the interactions of the
tetramethylammonium cations (blue and grey) with the water serving as the medium prevent
the magnetite nanoparticles (black) from interacting with each other through electrostatic
repulsion.
H2O
mixing
co-precipitate, Fe3O4
dextran
Fe3O4
Dextran
coating
centrifugal
gel filtration
chromatography
homogeneous water-based
Fe3O4 magnetic fluid
Application
1. Technological Application
i. Dynamic Sealing
ii. Heat Dissipation
iii. Internal and Viscous damper
2. BioMaterial Research
i. Magnetic colloids used to dope liquid crystals
ii. Doping of lyotropic liquid crystals with magnetic
particles
3. Medical Application
Magnetic drug targeting
Contrast enhancement for Magnetic Resonance Imaging
4. Art
Applications
Applications
Sealing Devices
The Ferrofluidic's rotary shaft seal uses a magnetic liquid
barrier to produce a seal which has very low drag torque and
a leakage rate which is too low to be measured.
Applications
High-pressure
High-pressure
region
MF
Low-pressure region
region
N
Magnets
Oil
Magnetic fluid
Applications
Heat transfer
Inertia Dampers
Applications
Applications
Medicine
In medicine, ferrofluids are used as contrast agents for
magnetic resonance imaging and can be used for cancer
detection. The ferrofluids are in this case composed of iron
oxide nanoparticles and called SPION, for
"Superparamagnetic Iron Oxide Nanoparticles.
The magnetic properties of the ferrofluids have resulted in the
development of systems which allow selective separation
of viruses, bacteria, concentration of therapeutic agents
at specific body sites; incorporation of magnetic particles into
preformed biologically active polymer gels allow use as
supports for affinity chromotography.
Art
REFEREnces
1. Ferrofluids- Properties andApplications
K Raj & R J Boulton,
2. en.wikipedia.org/wiki/Ferrofluid
3. www.ferrotec.com/technology/ferrofluid
4. Ferrofluids: Properties and Applications
C. Scherer and A. M. Figueiredo Neto
5. Synthesis of an Aqueous-Based Ferrofluid