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y
nTransformers
a
Dissolved Gases-In-Oil From
p
m
e
e
n
i
ng
E
e
l
ob
C
g
n
ri
1
2014 Doble Engineering Company. All Rights Reserved
High
Temperature
About 700 C
g
n
i
r
ee
in
g
n
Ethane
E
e
l
ob
D
H
Ethylene
Acetylene
607 kJ/mole
H
H
H
720 kJ/mole
960 kJ/mole
3
le
b
o
D
e
n
i
g
En
C
g
n
eri
ny
a
p
om
Gas
Hydrogen
Carbon Monoxide
25
Hydrocarbons
le
b
o
D
MDL
Method B
(ppm)
MDL
Method C
(ppm)
ny
a
p
o0.6m
C
g
n
2 ri
0.09
e
e
in 1
0.04-0.06
20
MDL
Method
IEC 60567
(ppm)
Eng
2
10
0.2 1
ASTM D 3612
Method A - Vacuum extraction/GC Analysis
Method B - Stripper Column/GC Analysis
Method C - Headspace/GC Analysis
2014 Doble Engineering Company. All Rights Reserved
Acetylene Ethylene
Ethane
70
92
95
69
91
94
69
92
95
69
93
95 g
n
i
r
69
93
95
e
e
n
i
g
69
92En
95
e
l 91
b
68
94
o
D
68
92
95
69
93
95
68
92
94
H2
Methane
CO
Ethane
CO2
Ethylene
Acetylene
150.0
56.4
94.0
37.6
313.0*
37.6
37.6
152.7
57.1
96.6
37.8
324.3
37.5
34.6
ny
a
p
om
C
g
n
*CO includes about 50rippm in blank
e
e
n
i
ng
E
le
b
o
D
2
Historical Information
le
b
o
D
e
n
i
g
En
C
g
n
eri
ny
a
p
om
le
b
o
D
e
n
i
g
En
C
g
n
eri
ny
a
p
om
10
Partition Coefficients
Gas
Ostwald Coefficient
Oxygen
Nitrogen
Carbon Dioxide
Carbon Monoxide
Hydrogen
e
l
b
o
Methane
D
Ethane
Ethylene
Acetylene
in
g
n
E
g
n
i
r
ee
0.138
0.0745ny
a
p
m
Co0.900
0.102
0.0429
0.337
1.99
1.35
0.938
11
Gas Partitioning
Gas-in-Oil
ppm (vol/vol)
Gas
Estimated ppm
gas-in-gas
space**
Estimated %
gas-in-gas
space
ny
a
p
om
Oxygen
28,400
206,000
20.6
Nitrogen
59,000
792,000
79.2
Carbon Dioxide
1,000
1,110
0.11
Carbon Monoxide*
100
980
0.10
Hydrogen*
100
2,330
0.23
Methane*
100
297
0.03
Ethane*
100
50
0.01
Ethylene*
100
74
0.01
Acetylene*
100
107
0.01
*Combustible gases
**Estimated value under equilibrium conditions at 25C and 1 atm
le
b
o
D
e
n
i
g
En
C
g
n
eri
12
13
ny
a
p
om
C
g
n
i
Hydrogen, Carbon Monoxide,e(Methane
to lesser degree)
r
e
in
g
n
proportionally higherleinEclosed conservator than gas blanketed unit
ob
D
atmosphere in open conservator
slowly lost to
If leak in nitrogen blanketed unit, these gases decrease the most
out of the combustible gases
2014 Doble Engineering Company. All Rights Reserved
14
Rate of generation
ny
a
p
m
o
C
Rate of mechanical mixing mostinimportant
g
r
e
e
n
i
ng influencing factor
Presence of a gas lblanket
E
e
b
o
D
15
Gas Bubbles
Super-saturation of the oil with gas
ny
a
p
om
C
g insulation
n
Thermal decomposition of the cellulosic
i
r
e
e
n
i
ng
E
le
b
o
D
Vaporization of adsorbed moisture in the
cellulose (primary issue)
2014 Doble Engineering Company. All Rights Reserved
16
Oxygen
increase-leak
decrease-overheating
C
g
n
eri
e
n
consumed in chemical reactions
i
g
n
Nitrogen
E
e
l
ob
ny
a
p
om
17
ny
a
p
Key gases - Identification of type of Cproblem
om
g
n
i
r
e problem
e
n
Ratios -Identification ofntype
of
i
g
E
le
b
o
Trends - Whats
D new
Fingerprints - Typical gassing behavior for certain families
of transformers
2014 Doble Engineering Company. All Rights Reserved
18
CO
Methane
Ethane
Ethylene
DOBLE
100
250
100
60
100
*IEEE
100
101-700
701-1800
>1800
350
351-570
571-1400
>1400
120
121-400
401-1000
>1000
65
66-100
101-150
>150
ng C
IEC 60599
Typical
Range
50-150
ri
e
e
ngin
E
e
l
400-600ob 30-130
D
20-90
50
51-100
101-200
>200
Acetylene
5 ny
a
p
1
m
o
60-280
2-9
10-35
>35
2-20
(No OLTC)
60-280
(Communicating
OLTC)
CO2
TCG
--
610
2500
2500-4000
4001-10000
>10000
720
721-1920
1921-4630
>4630
3,800-14,000
19
501-1500
1501-2500
>2500
ny
a
p
MODERATE DECOMPOSITION
om - ESTABLISH
C
g
TREND
n
i
r
e
e
n
i
HIGHELEVEL
ng OF DECOMPOSITION - ESTABLISH
le
TREND
b
o
D
VERY HIGH LEVEL OF DECOMPOSITION
- IDENTIFY CAUSE
20
Combustibles, %
100
80
60
40
20
0
CO
le
b
o
D
Hydrogen
e
n
i
g
En
Methane
C
g
n
eri
Ethane
ny
a
p
om
Ethylene
Acetylene
21
Combustibles, %
100
80
60
40
20
0
CO
le
b
o
D
e
n
i
g
En
Hydrogen
Methane
C
g
n
eri
Ethane
ny
a
p
om
Ethylene
Acetylene
22
Combustibles, %
100
80
60
40
20
0
CO
le
b
o
D
e
n
i
g
En
Hydrogen
Methane
C
g
n
eri
Ethane
ny
a
p
om
Ethylene
Acetylene
23
Combustibles, %
100
80
60
40
20
0
le
b
o
D
CO
e
n
i
g
En
Hydrogen
C
g
n
eri
Methane
Ethane
ny
a
p
om
Ethylene
Acetylene
24
Combustibles, %
100
80
60
40
20
0
le
b
o
D
CO
Hydrogen
e
n
i
g
En
Methane
C
g
n
eri
Ethane
Ethylene
ny
a
p
om
Arcing
Heating Oil
PD
Heating Paper
Acetylene
25
1 - Arcing
0
1,100
79,000
9
33
7
510
8
9
80,676
57
le
b
o
D
e
n
i
g
En
2 - PD
1,700
3,000
110,000
43
440
6
8,400
2
0
123,591
2,191
C
g
n
eri
ny
a
p
om
3 - Thermal
540
2,300
87,000
1,300
420
160
2,000
810
2
94,532
3,232
26
le
b
o
Total combustible gas
D
540
1,300
420
160
2,000
810
2
e
n
i
g
En
3,232
TRANSFORMERS
2
3
1
69
400
2,300
6,800
180
0
C
g
n
eri
16
390
240
480
4,400
33
0
110
110
140
39
1,500
8
0
1,059
407
ny
a
p
om
2,950
Decreasing temperature
2014 Doble Engineering Company. All Rights Reserved
27
Ratio Methods
Advantages
quantitative
independent of oil volume
can be computer programmed
Disadvantages
e
n
i
g
En
C
g
n
eri
ny
a
p
om
28
Acetylene
Ethylene
Methane
Hydrogen
Ethylene
Ethane
Fault
<0.1
>0.1,<1.0
<1.0
Normal
<0.1
<0.1
<1.0
0.1-3.0
0.1-1.0
<0.1
<0.1
le
b
o
D
<0.1
m
o
C
ng >3.0
eeri
in
g
n
E
Low energy
y
n
pa PD
>0.1<1.0
1.0-3.0
>1.0
1.0-3.0
>1.0
>3.0
Arcing
Low temp
thermal
Thermal
<700C
Thermal
>700C
29
Methane
Hydrogen
Ethylene
Ethane
Fault
NS
<0.1
<0.2
PD
>1
0.1-0.5
>1
0.6-2.5
0.1-1
>2
NS
>1 (NS)
<0.1
<0.2
le
b
o
>1
D
>1
ny
a
p
om
D1 - Low energy
C D2 - High energy
g
n
eri
e<1
n
i
g
En
1-4
>4
T1 <300C
T2 >300C
<700C
Thermal
>700C
30
Overheating of Oil
GAS
Hydrogen
Methane
Carbon Monoxide
Ethane
Carbon Dioxide
Ethylene
Acetylene
y
pan
540
1,300
420
160
2,000
810
2
1
69
400
2,300
6,800
180
0
16
390
240
480
4,400
33
0
110
110
140
39
1,500
8
0
3,232
2,950
1,059
407
om
C
ng
ri
e
e
ngin
E
e
l
ob
TRANSFORMERS
2
3
31
Overheating of Oil
e
e
n
i
ng
Case 3: Overheating
150-200C
E
le
b
o
Doverheating <150C
Case 4: Slight
p
m
Co
32
CASE 3
Hydrogen
Methane
Carbon Monoxide
Ethane
Carbon Dioxide
Ethylene
Acetylene
le
b
o
D
650
81
380
170
g
n
i
r
2,000
e
e
n
i
Eng 51
270
CASE 7
76
6,000
36any
p
27,000
Com
4,400
120,000
1,700
1,602
154,812
33
Problems Detected
34
Important Ratios
Acetylene/Ethylene
<10% thermal problems
n electrical fault
a
> 10 but <20% thermal problems often developing
into
p
m
o
C
beginning of discharge activity
ng
>20% arcing
ri
e
e
ngin
E
e
l
ob monoxide
Carbon dioxide/Carbon
D
35
Important Ratios
Ethylene/Ethane
>4:1 indicative of heating of bare metal
n
a
<4:1 indicative of heating of paper-wrapped conductor
p
m
o
C
g
n that paper is involved even when
Not always correct, provides indication
i
r
e
carbon oxides are low ngine
E
e
l
ob paper overheated to increase carbon oxides
Sometimes notDenough
in large oil volume
above normal
Sometimes paper burned away at some point and little further
deterioration in paper
2014 Doble Engineering Company. All Rights Reserved
36
le
b
o
D
e
n
i
g
En
C
g
n
eri
ny
a
p
om
37
y
If CH4 = C2H4 = C2H2
pa=n100 ppm,
om
C
ng
le
b
o
D
ri
The
triangular
coordinates to use are:
e
e
n
i
Eng %CH4 = % C2H4 = % C2H2 = 100/ 300 = 33.3%,
and correspond to only one point in the Triangle.
38
le
b
o
D
N = Normal operation
T3 = Thermal faults
y T > 700C
n
a
p
T2 = Thermal
faults 300C < T < 700C
m
o
C
g = Fault T3/T2 in progress
X3
n
i
r
e X3 = Abnormal arcing D2
e
n
i
Eng
D1 = Abnormal arcing D1
: Normal operation; : Severe
coking; : Light coking; : Heating;
: Strong arcing D2; : Arcing D1
39
The Duval Triangle for Low Temperature Faults in Mineral Oil (H2, CH4 and C2H6)
Fault zones:
n
i
r
e
ine
ng
E
le
ob
D
40
The Duval Triangle for Low Temperature Faults in Mineral Oil (CH4, C2H6 and C2H4)
le
b
o
D
Fault zones:
PD = Corona Partial Discharges
S = Stray gassing of oil
O = Overheating,aTn<y250C
p
m
C = Carbonization
of paper T > 300C
o
C
gHigh temperature faults T > 700C
n
T3
=
i
r
e
e
n
i
Stray gassing can easily be distinguished
Eng
from the other low temperature faults.
: Corona partial discharges; : Stray
gassing at 120C; Stray gassing at
200C; : Hot spots with carbonization
of paper; : Overheating (T < 250C);
: faults T3 > 700C
41
Key gases
Fingerprints
le
b
o
D
e
n
i
g
En
C
g
n
eri
ny
a
p
om
42
ny
6
a
p
m
(GAS IN FTg C)o(7.48)(10 )
n
i
r
e
e
n
i
g
(GALLONS
OF OIL)
n
E
le
b
o
D
3
PPM
43
Gassing Rates
Arcing - active gassing needs to be monitored closely and
investigated to identify source
Usually more than two data points required and needs
to be over a
y
n
a
p
significant amount of time
m
o
C
g
n
i
r
Thermal and PD
e
e
in
g
n
<1 ppm per day - normal,
depending on loading, previous behavior, time
E
e
l
interval
ob
D
44
Transformer Fingerprints
GAS (PPM)
Hydrogen
Methane
Carbon Monoxide
Ethane
Carbon Dioxide
Ethylene
Acetylene
Initial
3 years later
Initial 3 years later
350
260
110
210
44
61
11 ny
13
a
p
670
650
520
630
m
o
26
25ng C
3
4
i
r
e
3000
1900
5000
3900
e
n
i
g
9En
5
8
10
e
---obl --
45
Transformer Fingerprints
GAS (PPM)
Initial 2 years later Initial 2 years later
Hydrogen
20
12
0
0
y
Methane
55
16
60 pan29
Carbon Monoxide
2
9
0om
0
C
g
Ethane
25
83erin
61
46
e
Carbon Dioxide
1900 ngin
1500
650
250
E
Ethylene
500
620
200
150
le
b
o
Acetylene
TRACE
0
0
D 1
46
Water
Electrolysis of free water + core steel + heat = hydrogen
+
y
n
a
p
oxygen
om
C
g
n
ri hydrogen
wet cellulose under PD yields
more
e
e
in
g
n
E
e
l
Silicone compounds,
ob organic polymers
D
hydrogen and CO
2014 Doble Engineering Company. All Rights Reserved
47
Cellulose Insulation
Shell form > CO2 than core form - due to mass
ny
a
p
Accidental CO2
om
C
g
n
i
r
CO2/CO : 3 -14 (Vitols)nginee
E
e
l
ob
CO2/CO Avg.
7:1
D
48
ny
a
p
om
C
g
n
ri duplicate sample and
e
Condition II - Possible Problem,
take
e
in
g
n
E of data, advise customer
investigate cause by
review
e
l
ob
D
Condition III
- Certain problem, manufacturer and customer
conference
HC = methane + ethane + ethylene
2014 Doble Engineering Company. All Rights Reserved
49
Condition I
Condition II
y
n
a
p
=>0.5<1.0 m
=>1.0
o
C
g
=>2.0<5.0
=>5.0
n
i
r
ee
<0.8
Hydrocarbon
<0.5
CO
CO2
<2.0
<20.0
le
b
o
D
Condition III
in
g
n
E
=>0.8<1.5
=>1.5
=>20.0<40.0
=>40.0
50
le
b
o
D
e
n
i
g
En
C
g
n
eri
ny
a
p
om
51
Methane
Carbon
Monoxide
Ethane
Utility Limits
13.8
2.3
34.5
2.3
Before Tests
After OA (TV)
After OA (HV)
After FA (HV)
12
After TV (FA)
After all Tests
Description
Carbon
Acetylene
ny
a
2.3
p
om
Comb
Gas
N/A
56
14
39
14
36
22
23
18
61
48
23
20
83
52
e
0l
b
o
D
e
11in
g
En
Dioxide
138
C22
g
n
eri
0
Ethylene
52
Conc.
(ppm)
Condition
Problem
0.92
Condition II
Possiblempa
o >0.8, <1.5
Problem
C
g
ny
n
i
r
e
e I No problem
Condition
0.34
n
i
g
n
E
e
l
b
o
Condition I
No problem
0.63
D
CO2
CO2/CO
2.54
Condition I
IEEE
Limits
No problem
OK
2014 Doble Engineering Company. All Rights Reserved
<0.5
<2.0
<20.0
>4, <10
53
Rate
(ppm/hr.)
Condition
IEEE
Problem
Limits
y
n
a
p
om ppm/hr.
C
Possible
g
n
Condition IIeri
1.7
e
Problem
n
i
g
n
E
e
l Condition I No problem
b
0.29
o
D
0
0
Condition I
Condition I
No problem
No problem
>0.8, <1.5
<0.5
<2.0
<20.0
54
Rate
(ppm/hr.)
1.83
Hydrogen
HC
CO
CO2
le
b
1.0
o
D
Condition
IEEE
Problem nLimits
y
a
p
om ppm/hr.
C
g
Certain
n
ri
Condition
III
e
e
Problem
n
i
g
En
Certain
Condition III
problem
>1.5
>1.0
1.7
Condition I
No problem
<2.0
4.2
Condition I
No problem
<20.0
55
Problem
e
n
i
g
En
C
g
n
eri
ny
a
p
om
56
Utility Limits
Before 2nd Heat Run
After OA (TV)
After OA (HV)
After FA (HV)
After FA (TV)
ny
a
p
13.8
N/A
N/A
2.3
34.5
2.3 m 138
2.3
o
C
g 0
n
i
2
4015
27263
0
10
51
0
r
e
e
in 12
g
n
2
6961
24224
0
0
41
0
E
e
l
b
o
4
5626
9
0
40
0
D 18934 0
N/A
12
14
13
7258
24675
17
56
21
8361
28775
20
81
24
57