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barrel.
The feed section conveys the polymer pellets from the hopper to the screw channel,
preheats and compacts them, and transports them down the channel. In the
compression section the pellets are molten and compacted. In the metering section the
polymer melt is homogenized, pressure is generated and the melt is pumped out of the
extruder and through the die, ideally at a uniform temperature, pressure and flow rate.
Note that the channel depth between the screw and the barrel, H, varies along the length
of the extruder, becoming smaller from the feed throat to the die. In the compression
section, the channel depth between the screw and the barrel decreases gradually to
further compact the pellets, expel air trapped between them, improve heat transfer, melt
the polymer and accommodate the density change of the material upon melting. In the
metering section, the channel depth is again constant, but smaller than in the feed
section, so that the melt can be pressurized before being pumped out through the die.
Figure 2 shows the pressure profile along the length of the extruder and the die. At the
base of the screw, near the hopper, the pressure is atmospheric. The pressure
increases along the length of the screw and reaches a maximum at the end of the screw
that meets the die. The pressure drops across the die section, and once again returns to
atmospheric pressure at the point where the extrudate exits the die. For effective
extrusion, three points are important. First, the polymer should be completely molten
before it reaches the die. Second, the temperature within the die should be low enough
to prevent degradation of the polymer. Third, the pressure generated within the extruder
must be sufficiently large to be capable of pushing the molten polymer through the die.
Figure 3 is a diagram showing the geometry of an extruder screw, and Table 1 contains
values for the geometry of the screw and die used in this lab.
Table 1: Values for some geometric parameters of extruder screw and die
(1)
The explanations of all symbols used in the equations are provided in Table 2.
Table 2: Operating variables and coefficients for extruder characteristic equation
and are geometric factors that are constant for a given screw/barrel combination.
They can be calculated from the geometry of the system (see also Figure 3) using the
following expressions:
(2)
(3)
Details of the assumptions and derivation of equations (1) to (3) are given in MortonJones (1989), Osswald (1998) and Baird and Collias (1995). Polymer melts fall into a
category of fluids that exhibit shear thinning behaviour. This means that their apparent
viscosity decreases with increasing shear rate. To estimate the viscosity of the polymer
melt, we can use an empirical equation called the power law model:
= m n 1
(4)
DN
(5)
Flow of the polymer melt through the tubular die used in this lab can be modeled using
an equation that incorporates the power law model for the polymer melt viscosity
(Osswald, 1998):
(6)
Notice that equation (1) and equation (6) are expressions for the volumetric flow rate (Q)
of the polymer melt through the extruder and the die (respectively) as functions of the
change in pressure. If we assume that the pressure at the start of the metering section
is atmospheric, and the pressure at the die outlet is also atmospheric, then the pressure
rise in the metering section of the extruder will equal the pressure drop in the die (so P
will be the same for the extruder and for the die). Now, for a given extruder-die
combination at a fixed screw speed N we could predict the operating point (Pop, Qop) by
solving equations (1) and (6) in the two unknowns. However, an easier way to solve
these equations is to use a graphical method. Equation (1) can be used to generate a
plot of Q vs. P for the extruder, called the screw characteristic curve, and equation
(6) can be used to generate another plot of Q vs. P for the die, called the die
characteristic curve. The intersection point (Pop, Qop) of the two curves is the
predicted operating point of the extruder/die combination.
Characteristic screw-die curves, such as the one shown in Figure 4 can be generated
experimentally by measuring the die pressure (P) and flow rate (m3/s or kg/h) as a
function of screw rotation speed (N) and type of die. Alternatively the theoretical
characteristic screw-die curves can be constructed using equations (1)-(6) above.
W =
P
R die
2L die
(7)
It can also be expressed in terms of the flow inside the die as:
3n + 1 4Q
w = m
3
4
n
R die
(8)
The phenomenon of melt flow instabilities, or sharkskin, which appears when the shear
stress at the wall exceeds the value of 0.14 MPa, is a significant problem, preventing
high production rates in extrusion processing and imposes the upper limit of shear stress
for extrusion.
4. Deliverables
Your plant has recently received a million-dollar order for an underground piping system
for water transportation, made of polyethylene. Your group has been assigned the task
of conducting some preliminary experiments on a small scale equipment, so that the
operation can be scaled-up accordingly. Currently there are two types of polyethylene
available in the Process Development (PD) lab of your company that you can use for
your tests. Initially it has been suggested that a low density polyethylene grade LDPE
Petrothene NA960000 by LyondellBasell is suitable for this task. The flow curve of this
material measured in the PD lab is provided in section 5.
1. The small laboratory scale extruder is to be used for pilot runs for preliminary
determinations of operating conditions. Generate screw-die characteristic curves similar
to the ones shown in Figure 4, using equations (1)-(6). Design a set of experiments to
obtain experimental data points, which you can compare with the theoretical predictions.
How do the experimental operating points compare to the theoretical ones?
2. Previous investigations done in the PD lab have found that the model outlined above
is inadequate, since it overpredicts the pressure values. Malfunction of the pressure
transducer has been ruled out. Leakage flow over the flights has been cited as a
possible reason for the discrepancy. Leakage flow occurs when the clearance between
the screw flight and the barrel is not negligible. The amount of leakage flow rate, QL,
must be subtracted from the total flow rate shown in equation (1) and can be estimated
by:
QL =
P
2D 2 3
tan
L
12e
(9)
Viscosity (Pa s)
100000
10000
1000
PetrotheneLDPE
PetrotheneLLDPE
100
0.1
10
100
1000
Figure 5: Viscosity vs. shear rate at 190C for the two polyethylenes
7. Safety
Safety glasses and hardhats must be worn at all times in the pilot plant. The extrudate is
at extremely high temperatures immediately after leaving the die, so thermally insulated
safety gloves MUST be worn when sampling the polymer and handling it. The extruder
and die are also at a high temperature, so caution should be taken to avoid skin contact
with it. If the exiting stream becomes blocked, the exit pressure can quickly increase to
unsafe levels. Accordingly, operators must not stand in front of the die during extruder
operation. MSDS sheets should be read in order become familiarized with all dangers of
the materials. Degradation temperatures should be avoided as polyethylene may
decompose, or crosslink, thus plugging the extruder.
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References
1. Baird, D.G. and Collias, D.I. Polymer Processing Principles and Design,
Butterworth-Heinemann, Boston, 1995.
2. Middleman, S. Fundamentals of Polymer Processing, McGraw-Hill, New York,
1977.
3. Morton-Jones, D.H. Polymer Processing, Chapman and Hall, London, 1989.
4. Muccio, E.A. Plastics Processing Technology, ASM International, 1994.
5. Osswald, T.A. Polymer Processing Fundamentals, Hanser Publishers, Munich,
1998.
6. Tadmor, Z. and Gogos, C.G. Principles of Polymer Processing, Wiley, New York,
1979.
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