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4541/2
Chemistry
4541/2
October 2014
2 Hours 30 minutes
Name
: ____________________________
I/C No.
: ____________________________
Class
: ____________________________
FINAL EXAMINATION
SECONDARY
4
CHEMISTRY
Paper 2
2 HOURS 30 MINUTES
Prepared by
Checked by
Approved by
Section Question
B
C
Full
Mark
marks obtained
10
10
11
11
20
20
20
10
20
Total
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CONFIDENTIAL
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Section A
[60 marks]
Answer all questions in this section.
1 Diagram 1.1 shows the inter-conversion of the three states of matter, X, Y and Z of
water.
Diagram 1.1
(a) What type of particle is found in water?
............................................................................................................................................
.
[1 mark]
(b) Under the room temperature, at what temperature does ice change to water?
............................................................................................................................................
.
[1 mark]
(c) What is the physical state labelled Z?
............................................................................................................................................
.
[1 mark]
(d) When water changes from state Y to state Z, state the changes in:
(i)
The energy of the particles.
....................................................................................................................................
.
[1 mark]
(ii)
The forces of attraction between the particles.
....................................................................................................................................
.
[1 mark]
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(e) The smell of curry cooking in the kitchen spreads to the living room. Based on the
kinetic theory of matter, state the process involved. Explain your answer.
....................................................................................................................................
.
....................................................................................................................................
.
....................................................................................................................................
.
....................................................................................................................................
[3 marks]
2 (a) What is the meaning of empirical formula?
............................................................................................................................................
.
[1 mark]
(b) Diagram 2.1 shows the apparatus set up for two methods used to determine the
empirical formula of two compounds.
Diagram 2.1
(i)
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....................................................................................................................................
.
[1 mark]
(ii)
Why did you choose the method in 2(c)(i)?
....................................................................................................................................
.
[1 mark]
(iii)
When carrying out an experiment using Method I, why does the crucible
lid need to be opened once a while?
....................................................................................................................................
.
[1 mark]
(c) Diagram 2.2 shows the result for an experiment to determine the empirical
formula of lead oxide.
Mass of combustion tube
Mass of combustion tube + lead oxide
Mass of combustion tube + lead
= 64.00 g
= 117. 52 g
= 113.68 g
Diagram 2.2
Based on Diagram 2.3, determine the values of the following:
[Relative atomic mass: O = 16, Pb = 207]
(i)
Mass of lead
= ............................................................ g
[1
mark]
(ii)
= ........................................................... mol
[1
mark]
(iii)
Mass of oxygen
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= ............................................................ g
[1
mark]
(iv)
= ........................................................... mol
[1
mark]
(v)
= ..............................................................
[1
mark]
3 Table 3.1 shows the positions of some elements in the Periodic Table of Elements. P,
Q, R , S, T and U are not the actual symbols for these elements.
Element
P
Q
R
S
T
U
Group
1
17
18
1
13
17
Table 3.1
Period
2
2
2
3
3
3
(a) By using the letters in the Periodic Table of the Elements shown in Table 3.1,
answer the following questions.
(i)
Choose element that is an alkali metal.
........................................................................................................................
.
[1 mark]
(ii)
.
[1 mark]
(iii)
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........................................................................................................................
.
........................................................................................................................
.
[2 mark]
(b) Arrange S, T and U according to the decrease in size of the atom.
...........................................................................................................................................
.
...........................................................................................................................................
.
[1 mark]
(c) Which of the elements have the same chemical properties?
...........................................................................................................................................
.
...........................................................................................................................................
.
[1 mark]
[2 marks]
(ii)
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........................................................................................................................
.
........................................................................................................................
.
[1 mark]
(e) Write a chemical equation for the reaction between element P and oxygen.
...........................................................................................................................................
.
...........................................................................................................................................
.
[1 mark]
4 (a) Table 4.1 shows the proton number of three elements, X, Y dan Z. The letters used
do not represent the actual symbols of the elements.
Element
X
Y
Z
Proton number
6
12
17
Table 4.1
(i)
(ii)
Write the formula of the compounf formed between elements Y and Z.
....................................................................................................................................
.
[1 mark]
(iii)
Element X reacts with element Z to form a covalent compound with a
formula XZ4. State two physical properties of this covalent compound.
1. .................................................................................................................................
....................................................................................................................................
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2. .................................................................................................................................
....................................................................................................................................
.
[2 marks]
(iv) Draw the electron arrangement of the compound XZ4.
[2 marks]
(b) Table 4.2 shows some physical properties of two compounds, U and V.
Compound Melting point
(C)
Boiling point
(C)
Solubility in
water
800
1 420
Soluble
Solubility in
organic
solvent
Insoluble
-95
86
Insoluble
Soluble
Table 4.2
(i)
U: ................................................................................................................................
V: ................................................................................................................................
[2 marks]
(ii)
State the type of compound for U.
....................................................................................................................................
.
[1 mark]
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5 Diagram 5.1 shows the apparatus set up for the electrolysis of sodium nitrate solution
using carbon electrodes.
Diagram 5.1
(a)
What is the meaning of electrolysis?
....................................................................................................................................
.
....................................................................................................................................
.
[1 mark]
(b)
Write the formula of all the ions present in sodium nitrate solution.
....................................................................................................................................
.
[1 mark]
(c)
.
[1 mark]
(ii)
Explain your answer in (5)(b)(ii) in term of selective discharge of
ions.
........................................................................................................................
.
[1 mark]
(iii) Write the half equation for the reaction at the anode.
........................................................................................................................
.
[1 mark]
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(d)
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.
[1 mark]
(ii)
Write the half equation for the reaction at the anode.
........................................................................................................................
.
[1 mark]
(e)
Rosli discoveres his key which is made up of iron has rusted. By using the
knowledge on electrolysis, descibe breifly how he solves the problem.
....................................................................................................................................
.
....................................................................................................................................
.
....................................................................................................................................
....................................................................................................................................
.
....................................................................................................................................
....................................................................................................................................
.
[3 marks]
6 (a) Complete the blanks in the equations below.
(i)
6 HCl + 2Al (
) + (
(ii)
Na2CO3 + (
) 2NaCl + (
(iii)
2KOH + (
) K2SO4 + 2(
)
) + H2O
)
[3 marks]
(b) Sodium carbonate reacts with hydrochloric acid as represented by the equation
below.
Na2CO3 + 2HCl 2NaCl + H2O + CO2
(i)
Calculate the number of moles in 50.0 cm3 of 1.0 mol dm-3 sodium
carbonate.
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(ii)
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[2 marks]
Calculate the volume of 2.5 mol dm hydrochloric acid required to react
completely with 50.0 cm3 of 1.0 mol dm-3 sodium carbonate.
-3
[2 marks]
(c) Table 6.1 shows the pH values of four substance.
Substances
A
B
C
D
(i)
pH values
1
5
10
14
Table 6.1
.
[1 mark]
(ii)
.
[1 mark]
(iii)
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........................................................................................................................
.
[1 mark]
(iv)
.
[1 mark]
Section B
[20 marks]
Answer any one questions from this section.
7 (a) A student electrolysed an aqueous solution of copper (II) sulphate using carbon
electrodes.
(i)
(ii)
(b) Table 7.1 shows the products at the anodes of two electrolytic cells which use
different concentration of the same electrolyte. Carbon electrodes are used in both
cells.
Cell
I
II
(i)
Electrolyte
Sodium chloride, NaCl
(0.001 mol dm-3)
Sodium chloride, NaCl
(2.0 mol dm-3)
Table 7.1
Product at anode
Colourless gas
Greenish yellow gas
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[2 marks]
(ii)
Diagram 7.1
(i)
(ii)
Pair of metal
I
II
Cell voltage
1.10 V
1.56 V
Table 7.2
Negative
terminal
Zinc
Zinc
Use the information shown in Table 7.2 to calculate the voltage of the cell
shown in Diagram 7.1.
[2 marks]
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8 (a) Explain how you can determine the positions of element X, Y and Z in Table 8.1,
in the Periodic Table.
Element
X
Y
Z
Proton number
3
11
19
Table 8.1
[5 marks]
(b)
(c)
Section C
[20 marks]
Answer any one questions from this section.
.
9 Table 9.1 shows the electron arrangement of particle X, Y and Z.
Particle
Electron arrangement
2.8.1
2.8.4
2.8.7
Table 9.1
(a) (i)
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size.
[2 marks]
(ii)
X and Z
Y and Z
[8 marks]
(c) State three difference properties of the bonding of the compound P and
compound Q which shown in Diagram 9.1.
[6 marks]
Diagram 9.1
10 (a) What is meant by a weak base and a strong acid?
[2 marks]
(b) Different concentrations of alkaline solution will show different pH values.
Diagram 10.1 shows various concentration of sodium hydroxide solution.
0.1 mol dm -3
0.01 mol dm -3
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0.001 mol dm -3
0.0001 mol dm -3
[Please turn over
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Diagram 10.1
Describe one experiment to determine relationship between the concentration of
sodium hydroxide solution and the pH value.
[15 marks]
(c) State one property of alkali. Explain briefly the role of water which causes the
base to show its alkaline properties.
[3 marks]
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