Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
A large proportion of the oil and gas in the Middle East is contained in carbonate reservoirs,
including several supergiant fields. The traditional techniques for developing and assessing
clastic reservoirs are less effective or even counter-productive in carbonate rocks.
Geoscientists need a clear understanding of their reservoirs because predictions about
future behaviour can only be based on current performance and an understanding of the
mechanisms controlling that performance.
In this article, Roy Nurmi and Eric Standen investigate the new nuclear magnetic
resonance (NMR) technology, and the fresh insights it offers into the complexities of
carbonate reservoirs and pore systems. The logging of borehole NMR in Kuwait has
provided a wealth of new data on the geological and production potential of
complex carbonate reservoirs.
With important contributions from: Ahmed A Latif and Dogan Sungur of Kuwait
Oil Company, along with Ian Stockden of British Petroleum and Chanh Cao
Minh of Schlumberger Middle East, whose SPE paper 37771 for the
recent Middle East Oil Show (MEOS) in Bahrain is featured
in this article.
28
Western E
urope
South America
and Caribbean
North
America
Asia
Eastern
Europe
Africa
Australasia
Types of microporosity
id outer laye
Oo
r
In pore-filling
calcite mud
Pelletal grain
with microporosity
ore-filling
en p
cry
we
t
st
Be
s
al
Microporous
ooid
Initial particle
Mould
ro
Solution-enlarged
mould
g
re
s
s
iv
Vug
e
s
o
lu
ti
o
n
29
CARBONATES CLASSIFIED
Most carbonate rocks are formed from
accumulations of skeletal fragments the remains of carbonate-secreting animals and plants. Although the animals
are better known to geologists, it is the
plants, particularly blue-green and red
algae, which, as a major food source for
marine micro-organisms, control the
distribution of carbonate sediments.
Numerous methods for carbonate
rock classification have been proposed
over the past 40 years. The most
widely accepted method, devised by
R.J. Dunham in 1962, concentrates on
the features which control porosity and
permeability, i.e. grain-matrix relationships and mud content (figure 2.6).
Wackestone
Less than
10 % grains
More than
10 % grains
Packstone
Grainsupported
Grainstone
Boundstone
Crystalline
Lacks mud
and is grainsupported
Original
components
were bound
together
Depositional
texture not
recognizable
Mud-supported
Contains mud, clay and fine silt-size carbonate
Original components not bound together during deposition
Boundstone
Grainstone
Grainstones are grain-supported carbonates containing less than 10% lime
mud. With very little mud blocking
the pore space, grainstones often
2000
Rock type
pu
md
Good reservoir
grainstone
25 2000
5
N
4
Ap
pa
ren
tp
ro g
0.50
re s
siv
3 Ch
alk smal
l p o res
ed
on
ec
-res
e r v o i r r oc k
50.0
100
erv
o ir g
r a in sto
500
re a
se
in
po
re
siz
es
2
es
Hg pressure (psia)
0.05
Mudstone
Reservoir
grainstone with
25
micropores or
isolated macropores
500
25
10
Heterogeneous
pore size
distribution
25
50
Non-effective pores 25
0.1
50
% Hg saturation of pore volume
0
0
Fig. 2.7: The relationship between effective pore throat radii and pore volume for some typical
reservoir types (grainstones, wackestones and chalks) with a non-reservoir rock for comparison.
All of these sediments could be encountered in the same carbonate sequence.
30
Open littoral
Open reef-shoals
Fore-reef
transition zone
Open basin
(a) Ramp
Back-reef shoals
Reef wall
Reef talus
slope
Fore-reef
shoals
Fore-reef
transition
zone
Fore-reef basin
Reef boundstones
Fig. 2.8: Carbonates can be deposited in a wide range of marine environments. They typically occur in sequences which can be characterized as
ramp (a) or reef shelf (b) settings. Low-energy environments, such as the back reef shoals, which are protected from wave and current action, are
characterized by higher concentrations of lime mud while clean rocks with high original permeabilities are found in high-energy zones at the
shoreline or around the main reef wall. If the basin area associated with either of these sections generates hydrocarbons the oil and gas should
migrate up the structure (green arrow) into the porous carbonate rocks.
Packstone
Mudstone
Wackestone
31
Microporous dolomite
Ooids with micropores
within particles and also
intergranular pores
30 pu
50 ft.
Depth
micropore
grain
32
micrite
crystal
x2560
x385
10m
x38.5
100m
1000m
Water
Water
Moved hydrocarbon
Moved hydrocarbon
Oil
(PU)
Oil
0.0
25.0
0.0
Porosity
Calcite
Diff. Caliper
Perfs
1:200ft
Bound fluid
0.25 -20
(IN)
Dolomite
20
Anhydrite
Irreducible water
Moved oil
X900
Residual oil
Residual oil
Fig. 2.11: Some zones which appear to contain too much water for cost-effective oil production actually produce dry oil because
all of the water in the zone is irreducible (i.e. bound in the rocks micropores). Modified from M. Petricola and H. Takezaki
(1996) Nuclear Magnetic Resonance: It Can Minimize Well Testing. SPE 36328 7th ADIPEC Conference.
In the Middle East, the potential problems associated with microporosity first
became apparent as a result of difficulties with wells in the Lower Cretaceous
Thamama Group. Predictions about oil
or water production, based on logderived saturation calculations, were
consistently incorrect because irreducible fluids in non-effective micropores were being included in porosity
calculations (figure 2.11).
Younger rocks have more micro
porosity (figure 2.12) than their older
counterparts. The Tertiary carbonate
reservoirs of Egypt and India are more
likely to be affected by microporosity
than the deep Permian Khuff carbonate
reservoirs of the Arabian peninsula. This
probably reflects the ease with which
micropores can be closed by overburden pressure following deep burial.
33
Fig. 2.13: Scanning electron micrograph showing rhombs of dolomite growing over crystals
of calcite which contain high concentrations of magnesium.
34
(a)
Supratidal
hypersaline
pond
Sealevel
Hypersaline
marine water
Beach
ridge
Evaporative
dolomite
crusts
Freshwater
lens
Intense evaporation
(b)
Tidal flat
Sealevel
Lake
Seepage
Reflux
Porosity (%)
0
10
20
30
40
50
Depth (km)
3
> 75% dolomite
4
Area of
dolomitization
Fig. 2.14:
Dolomitization
involves the
movement of
magnesium-rich fluids
through carbonate
rocks. The details of
dolomite formation
are unclear, but two
possible mechanisms
are (a) precipitation
around hypersaline
ponds as a result of
marine and meteoric
water mixing and (b)
seepage reflux where
seawater seeping into
supratidal lakes is
subjected to intense
evaporation and
gypsum precipitation
which raises the
Mg/Ca ratio in
solution.
Several mechanisms have been proposed to account for dolomitization (figure 2.14). One critical aspect of the
process wherever it occurs is that
dolomite preferentially replaces mudsized particles rather than the sand-sized
grains in the original limestone.
Consequently, the best oil and gas reservoirs are seldom found in (mud-free)
rocks with high primary permeability.
In intertidal and subtidal environments permeable units such as skeletal
and oolitic limestones display secondary
(leached) porosity that has converted
moulds into irregular vugs and fractures
into solution channels. If dolomitization
occurs at this stage the calcium ions
Fig. 2.15: Compaction in dolomites is
typically less than in limestones, so
although dolomites start with lower
porosity at the surface they retain reservoir
levels of porosity to greater depths.
35
(a) deposition
(b) compaction
When sediment is deposited the intergranular pores are almost always considerably smaller, on average, than the rock
particles. Burial makes the situation
worse as compaction and cementation
combine to reduce pore size (figure
2.17). If no major phase of cementation
occurs, intergranular carbonate pores
generally remain well-connected until
pressure solution effects at great depth
close them completely.
Intraparticle pores are usually independent of the effective pore system and
may be preserved to greater depths. They
are also very variable: their maximum
size is limited only by the dimensions of
the rock grains. Intraparticle porosity may
occur as several small pores within a rock
particle or as microporosity spread
throughout a grain (see figure 2.2).
(d) fracturing
Permeability (md)
1000
(e) leaching
of cement
100
(f) leaching
of grains
(c) cementation
10
15
30
45
Porosity (%)
Macropores
(visible)
Classes
Megapore
Mesopore
Units
mm
microns
large
>4
>4000
small
4000
large
1/2
500
small
1/16
62.5
Micropore
(individually invisible to naked eye)
36
Examination
Outcrop
core
Core,
hand-lens
thin section
SEM,Hg
capillary
Borehole
imagery
CMR log
CMR log
00
=1
ter
me
rtic
le
dia
iam
Pa
Moldic grainstone
Pa
Lim cks
e to n
m es
ud ,
300
r=
ete
eter
=
rtic
le d
Pa
diam
Par
ticle
Leac
hed
10
500
l roc
k
meta
els in
chan
n
100
G
dia rain
m sto
et ne
er
de , po
cli re
nin
g
1000
Permeability (md)
r<
ete
Vuggy dolomite
Wackestone
m
dia
lk p
ha
th c
li
cco
Co
0.1
ore
Wackestones
Mudstones
0.01
0
10
20
30
Porosity (%)
Compaction
and cementing
Fractures
Leaching
Wellbore
CMR
measurement
volume
1" x 1" x 6"
37
38
West Kuwait
Kuwait City
The Gulf
Minagish
Umm-Gudair
Jurassic
Upper
Middle
Lower
Tithonian
Hith
Kimmeridgian
Gotnia
Oxfordian
Callovian
Callovian
Bajocian
Bathonian
Bajocian
Dharuma
Toarcian
Marrat
Najmah
Sargelu
Upper middle
Rhaetian
Carnian
Ladinian
Anisian
Lower Triassic
Upper Permian
Scythian
Tatarian
Sudair
Permian
Kazanian
Khuff
Upper
Triassic
Minjur
Jilh
Fig. 2.22: The Jurassic reservoirs of West Kuwait, in the Najmah, Sargelu and Marrat formations,
are complex carbonate sequences. Production-related decisions about these units are never
simple, so they provide a perfect test for any new logging technique.
x430
Predicting permeability
x450
x470
x490
Fig. 2.23: This example is taken from the Najmah Formation. Beneath the fault at X450, there is
a packstone-wackestone series that grades into mudstone (as indicated by the decreasing poresize trend in the CMR). DSI permeability values are affected by the mudstone laminations and
are incorrect. The CMR-derived porosity value is correct.
Fig. 2.24: This
example from the
Marrat Formation.
shows that in the
lower part of the
sequence porosity
decreases upwards,
but this change is
accompanied by a
permeability
increase. The CMR
tool (track 2)
identifies pore size
distributions, helping
to explain this
apparent anomaly.
39
60
40
20
0
20
40
60
Key:
Reef
Shelf carbonate
Deep carbonate
40
80
Pore apertures
(Hg-injection data)
50 p.u.
100
60
40
Whole pores
(image data)
20
0
100.0
Micropores
-?-
1.0
10.0
Diameter (microns)
Depth
0.1
Mesopores
(a)
0.1
1.0
10.0
100.0
Pore size (microns)
Pore size distribution (similar to CMR T2)
41