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Activated carbons obtained from rice husk exhibit low specific surface areas when physical activation is
applied due to its high silica content. The purpose of this work was to improve textural parameters of powdered
activated carbons obtained from rice husk. To avoid the negative influence of the raw material ash content,
a leaching step was included in the preparation process. Hydrofluoric acid, in two concentrations (25 and 50
wt %), was used as leaching agent and applied in different stages of the process. Physical activation using
water vapor as activating agent was applied. Specific surface area and porosity were evaluated from nitrogen
adsorption data. When a leaching step was included, specific surface area values between 700 and 1200 m2/g
were obtained. These values are higher than that corresponding to the activated carbon prepared from rice
husk not treated with acid (290 m2/g). Pore size distribution depends on the step sequence of the preparation
process and on the HF concentration.
Introduction
Almost any carbonaceous material, with high carbon content
and low proportion of inorganic components, can be used as
precursors for the preparation of activated carbons.1 Many
agricultural solid wastes have traditionally been used as raw
materials for this purpose, among them coconut shell,2 olive
stones,3 eucalyptus wood,4 and corn cob.5 The increase of
agricultural activity produces large volumes of solid wastes that,
in many cases, become potential environmental contaminants.
Rice constitutes the base of diet for a great part of humanity.
Rice husk waste represents 20% of rice production and grows
up to many tons per year. Even though it has been used for
land filling and fuel or biogas production, new technical
applications have been explored in the last years.6,7
The major constituents of rice husk are cellulose, lignin, and
mineral components. The content of each of them depends on
rice variety, climatic conditions, and even the geographic
localization of the culture. When rice husk is subjected to
combustion at moderate temperature, an amorphous ash is
obtained; a 95% white silica powder could be produced after
calcination at 700 C for 6 h.6 Many authors have concluded
that rice husk is an excellent source of amorphous silica of high
purity appropriate to produce silicium, silicium nitride, silicium
carbide, or magnesium siliciure.8 As a consequence it constitutes
a non-traditional raw material for the ceramic industry.
As a result of its high cellulose and lignin content, rice husk
can be used as the raw material to prepare activated carbons,
which are known to be highly complex porous structures, with
high values of specific surface area (ssa) and porous sizes mainly
in the range of micropores. They are obtained by two different
processes: the physical or thermal activation and the
chemical activation. In the former carbonization is followed
by char activation; in the second one, carbonization and
* Author to whom correspondence should be addressed. E-mail:
nestor@fq.edu.uy. Tel: +598 2 9248352. Fax: +598 2 9241906.
Ind. Eng. Chem. Res., Vol. 47, No. 14, 2008 4755
Scheme 1. Experimental Scheme and Sample Identification
Table 1. Ultimate Analysis for Rice Husk and Derived Products (%,
Dry Basis, Ash Free) and Ash Content (%, Dry Basis)
sample
Oa
ash
rice husk
C
CA
CAL50
CAL25
CL50A
CL25A
CL50
CL25
L50CA
48.3
85.7
83.1
95.0
83.7
75.7
86.0
89.1
83.5
90.0
6.8
1.0
0.5
0.0
0.4
0.6
0.5
0.9
1.1
0.6
0.5
3.1
1.9
4.2
1.5
1.2
1.2
3.0
2.9
1.6
0
0
0
0
0
0
0
0
0
0
44.4
10.2
14.5
0.8
14.4
22.5
12.3
7.0
12.5
7.8
17.2
43.2
68.4
1.0
0.0
1.0
1.1
0.0
0.8
0.0
By difference.
sample
YT (wt %)
VT (cm3/g)
VDR (cm3/g)
C
CL25
CL50
CA
CL25A
CL50A
CAL25
CAL50
L50CA
41.0
23.4
23.2
24.3
14.1
12.1
6.9
6.9
11.8
16
170
160
290
750
820
1030
1180
950
0.07
0.18
0.17
0.25
0.54
0.60
0.98
1.09
0.46
0.06
0.05
0.12
0.31
0.35
0.39
0.50
0.39
4756 Ind. Eng. Chem. Res., Vol. 47, No. 14, 2008
Ind. Eng. Chem. Res., Vol. 47, No. 14, 2008 4757