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2
The heat evolution generated by the grinding, how
ever, means an increased tendency to formation of ferric
3,478,073
PREPARATION OF ANHYDROUS FERRQUS
FUMARATE
'
10115.
6,263/66
1 Claim
avoided.
The present invention is further illustrated by the fol~
lowing example.
EXAMPLE I
63.8 g. (0.550 mole) of fumaric acid were added while
stirring in small portions over a period of about 30 min
utes to an air-free suspension of 0.515 mole of ferrous
hydroxide in 700 ml. of water at a temperature of 95 to
100 C. The substance thus formed was ?ltered off hot
and washed with 200 ml. of water at about 50 C. The
product was dried overnight at 105 C. 80.7 g. of anhy
-d-
0.1%.
The suspension of ferrous hydroxide was prepared in
situ by adding while stirring 42.5 g. of 97% NaOH
( 1.03 mole) dissolved in 100 m1. of water to a solution of
143 g. (0.515 mole) of ferrous sulphate
grinding.
60
3,478,073
3
Substance B: Two populations, one of 2-5,u and one of
TABLE 2
10-40;/..
Time
required
-~-
120 hours
Original
moisture
content
percent
by weight '
Substance:
A ..................... _ _
B ..................... _.
C ..................... ..
52
0.310
0. 349
64
0. 399
0. 423
75
52
0. 467
1. 64
0. 478
1. 80
64
2. 65
2. 70
75
52
2. 91
0. 474
2. 97
0. 521
64
0. 698
0. 718
75
52
0. 778
0. 106
0. 818
0. 127
0. 542
64
75
0. 219
0. 287
0. 232
0. 306
0. 344
64
0. 374
0. 372
0. 515
52
0. 903
0. 898
64
1. 02
1. O0
1. O3
1. 03
minutes
minutes
1. 8
4. 1
11
17
11
5
8. 2
>25
>25
>25
>25
12
100
89
93
71
80
100
0 215
E ..................... _ .
75
2,848,366
8/1958
1,432,757
FOREIGN PATENTS
2/1966 France.
OTHER REFERENCES
1. 18
after 25
minutes
0. 350
D ____________________ __
F ..................... ..
dissolved
RH 60 hours
Percent
substance
Substance:
Percent
95% of
substance substance
Increase in moisture
content in percent
by weight after-
for
50% 0
dissolving dissolving
TABLE 1
Time
required
for