Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
PRODUCTION
by
Moses Gideon Akpabio
NTNU
Norwegian University of
Science and Technology
JULY, 2012
Acknowledgement
This piece of work would not have been possible without the help and contributions of
others. I hereby seize this opportunity to appreciate these people for their assistance
whenever I found myself in doubt of what to do and how to do it.
My profound gratitude goes to my supervisor, Professor Jon Steinar Gudmundsson for his
understanding and assistance on defining this project work, his guidance, and all useful links
he sent to me while here in Nigeria that have make this final result possible. I also appreciate
the way he accepted me as his student, his advice and answers to all of my questions. I
equally acknowledge the support of Associate Professor Pal Skalle as well as the Norwegian
government for sponsoring the EnPE/NORAD programme.
I also appreciate my friends and colleagues, especially Mr. Samson Imoh, and others, whose
suggestions and inputs have enhanced my motivation in finishing this project work.
However, I acknowledge the works of several authors as well through which I have gained a
lot of new ideas for this project work.
I deeply appreciate the creator of the universe for His mercies, love and for this wonderful
opportunity. And, my Parent and siblings are well acknowledged for their respective
contributions to my life.
ii
Abstract
Subsea production of oil and gas is always faced with the potential problem of hydrates
formation which causes pipeline blockage, damage of pipeline fittings, and other related
problems. A reliable method that has the ability to predict hydrate formation conditions
during the production process, and transmission is thus needed. It is important to ensure
safe operations.
In this work, water concentration estimation for the conditions prevailing at the reservoir,
the wellhead and the receiving terminal on land are evaluated analytically based on
theoretical approach. As an example, a natural gas stream from Nigeria with pipeline as a
transmission medium is used. The temperature profile and pressure profile along this
pipeline have also been used as an input in the evaluation of hydrate formation. Also, a
hydrate inhibition strategy with MEG is considered. Results show that the flow is within the
hydrates forming region, since the temperature is below 20 oC and pressure, above 100 bara.
Water concentration estimation provides useful information which can assist in prevention
of hydrate formation as gas flows through a pipeline. The temperature profile and pressure
profile also provide useful information for the management or controlled of hydrates
formation as the temperature and pressure data can indicate the thermodynamic conditions
that favours hydrates formation.
iii
Table of Contents
Title
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Acknowledgement. .
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Abstract.
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Table of Contents.
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List of Tables. .
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List of Figures. .
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1. Introduction.
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8. Conclusion. .
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Nomenclatures.
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References.
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List of Tables
Table 1: Typical Natural Gas Components. .
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Table 2: Three common hydrate unit crystal structures.
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Table 3: Summary of Applications, Benefits & Limitations of Chemical Inhibitors.
Table 4: Water Content of gas at different conditions.
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Table A1: Sour gas correction factor constants.
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Table A2: Constants in LGE equation. .
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Table A3: Natural Gas Reservoir, Production & Pipeline Parameters.
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Table A4: Natural Gas Stream Composition from Nigeria, with modification.
Table A5: Temperature Profile Data. .
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Table A6: Pressure Profile Data.
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List of Figures
Figure 1: Natural Gas Typical Molecule.
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Figure 2: Hydrate Plug Removed from a Gas Pipeline.
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Figure 3: Host molecules (water) and guests (Gas). .
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Figure 4: Schematics of Structure I, II and H Gas Hydrates. .
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Figure 5: Phase Diagram Showing the Conditions under which Hydrates form.
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Figure 6: Conceptual representation of hydrate formation in an oil-dominated system.
Figure 7: MEG Reclamation Process Schematics. .
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Figure 8: Temperature variation along pipeline.
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Figure 9: Steady-State flow (pressure) in gas pipeline.
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Figure 10: Steady-State Temperature Profile.
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Figure 11: Steady-State Pressure Profile.
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Figure A1: Water contents of natural gases. .
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Figure A2: Pressure-temperature Curves for Predicting Hydrate Formation
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Figure A3: Natural Gas Heat Capacity of 0.60 and 0.65 Specific Gravity.
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vi
1. Introduction
Natural gas is rapidly growing in global importance both as a primary energy source and as a
feedstock for the downstream industry. The increase of natural gas in the energy matrix all
over the world has posed a strong demand on offshore exploration and production. Natural
gas consumption has constantly continued to increase from 50 % of the oil consumption in
1950 to 98 % in 1998 (Chapoy 2004). This growth is being driven by a number of economical,
ecological and technological factors together with an overall increasing energy demand
because it is environmentally cleaner than oil and coal.
Natural gas demand is increasing steadily and considering pipeline among other means of
transporting oil and gas, there is guaranteed delivery from the wellhead to processing plant
and from there to the consumers and which also assures lower maintenance costs. It is
therefore important to operate an offshore pipeline system free of hydrate formation risks.
However, it is worthy to note that subsea pipelines represent at least 25 % of the total
project cost and this is one of the reasons for the flow assurance studies (Nava et al. 2011).
The past decade has seen the oil and gas industry moving towards deep-water exploration
and production, with over 10,000 feet of water depth (Mehta et al. 2001), where pressures
and temperatures are ideal for hydrate formation. This has brought new challenges for
hydrate prevention in transportation of natural gas in subsea environment.
Hydrate formation in offshore pipelines is a major problem that arises due to temperature
drop and other thermodynamic changes as hydrocarbons are produced. As temperature
drops or decreases, the solubility of water in gas decreases and the water vapour condense.
The precipitated water molecule causes hydrate to form with hydrocarbon molecules such
as methane. The formation of hydrates can lead to clogging of pipeline, higher pressure
losses, flow rate reduction, and other problems. The removal of hydrate plugs in subsea
production systems as well as transmission systems poses safety concern and can lead to
loss of time and costly repair work. For these reasons, the formation of hydrates in subsea
gas transmission pipelines should be prevented effectively and economically to guarantee
that the pipeline operates normally.
The main objective of this project is to study flow assurance of a natural gas produced from
a subsea environment. A pipeline transmission system of natural gas stream from subsea to
shore (receiving terminal on land) is considered, using a natural gas stream composition
from Nigeria as an example.
In order to avoid hydrate formation in the pipeline system during transmission, my focus is
on analyzing the temperature profile and pressure profile in a steady-state production
conditions along the pipeline. These will provide information on temperature and pressure
data along the pipeline as well as indicating if hydrates will form. Water vapour content of
natural gas is also analyzed for conditions prevailing at the reservoir, wellhead, and at the
receiving terminal. Hydrates formation prevention with Mono-Ethylene-Glycol (MEG), and
an inhibitors rate required to prevent hydrates formation are also analyzed. The inhibitor is
to reduce the dew point temperature of water vapour in the gas flow below operating
temperature and thus, decreasing the risk of hydrate formation.
These will be computed analytically based on the theoretical approach. This project is a case
study based on a specific steady-state defined production case. The production data is
provided in the Appendix, Table A3.
The results will be analysed to identify if the pipeline has the potentials of forming hydrates
as the temperature and pressure drop along the pipeline and to analyse the inhibitors that
could be used to prevent hydrates from blocking the pipeline.
Figure 1: Natural Gas Typical Molecule: Models of molecules of oxygen (O2), water (H2O), methane (CH4) and
carbon dioxide (CO2) (Sanchez 2010).
Natural gas also contains impurities or contaminants that have to be removed before it can
be used as a consumer fuel after its extraction from the reservoir. These impurities include
acid gases, such as hydrogen sulfide (H2S), carbon dioxide (CO2), mercaptans (methanethiol
CH3SH, and ethanethiol C2H5SH), nitrogen (N2), helium (He), and water vapor (H20).
Sometimes, mercaptans are kept or added for safety reasons (Sanchez 2010). However, a
typical composition of natural gas is given in Table 1.
Non - Hydrocarbons
Components
Methane
Ethane
Propane
Mole %
70 - 98
1 -10
Trace - 5
Components
nitrogen
Carbon dioxide
Hydrogen sulphide
Mole %
Trace - 15
Trace - 20
Trace - 20
Butane
Trace - 2
Helium
Up to 5 (non usually)
Pentane
Trace - 1
Hexane
Trace - 0.5
Heptane+
Trace
In the reservoir, oil and natural gas normally coexist with water. Water comes as the wetted
phase and from the sub-adjacent aquifer. The presence of water also causes crystallization
of salts after hydration due to salt concentration increase (when water is consumed).
Furthermore, when gas is produced offshore, the separation of liquid fractions and the
removal of water are not always carried out before the production flow is sent into
pipelines. Consequently, the unprocessed well gas stream coming from a production field
can contain water and light hydrocarbon molecules (methane, ethane, propane and other
components). Given the correct temperature and pressure conditions (particularly large
temperature gradients which leads to higher pressure), can lead to hydrate formation during
transport through pipelines.
transport natural gas. In Europe, even though the British discovered natural gas in the
middle of the 17th century, it was until the late 18th century (around 1785) that they started
trading natural gas obtained from coal seams for lighting of houses and streets (Rojey et al.
1994).
An intriguing factor that caused a faster expansion of the use of natural gas around the
world in the last decade of the 19th century was the fact that many cities began replacing
their gas lamps with electric lamps. Thus, the gas industry was required to look for new
markets, perhaps far away from their usual customers (Sanchez 2010).
Natural gas had been clearly extinguished by electricity. However, at that time the real
problem was certainly the lack of a pipeline infrastructure to transport and distribute natural
gas, as well as the lack of facilities to store it (Chapoy 2004).
Figure 2: Hydrate Plug Removed from a Gas Pipeline, Zarinabadi et al. 2011.
located within the lattice, Makogon (1997) and Sloan (1998). Gas hydrates which are
crystalline ice-like solids are formed from water and a range of lower molecular weight
molecules, typically methane, ethane, and propane. The water molecules are referred to as
the host molecules and the other compounds which stabilize the crystal are called, the
guest molecules. The hydrate crystals have complex, three-dimensional structures in which
the water molecules form a cage and the guest molecules are entrapped in the cages as
shown in Figure 3.
Figure 3: Host molecules (water) and guests (Gas), Zarinabadi et al. 2011.
There are three known hydrate structures referred to as structures I, II and H (abbreviated as
sI, sII and sH) as contained in Pickering et al. 2001. The schematics of the three different
structures are presented in Figure 4.
Structure I hydrates contain 46 water molecules per 8 gas molecules giving a hydrate
number of 5.75. The water molecules form two small dodecahedral voids and six large tetradecahedral voids. The sizes of the voids are relatively small meaning that the guest
molecules are restricted in size to essentially methane and ethane (Pickering et al. 2001).
Structure II hydrates contains 136 water molecules per 24 gas molecules giving a hydrate
number of 5.67. The water molecules form 16 small dodecahedral voids and 8 large
hexakaidecahedral voids. The larger voids are able to accommodate molecules including
propane, isobutane, cyclopentane, benzene and others. However, while the larger cavities
can accommodate larger molecules, the structure is only stable if small help molecules are
available to fill the smaller lattice cavities (Pickering et al. 2001).
Structure H hydrates contains 34 water molecules for every 6 gas molecules giving a hydrate
number of 5.67. The structure has three cavity sizes with the largest cavity able to
accommodate larger molecules than both sI and sII. Once again, stability is only possible in
the presence of smaller help molecules such as methane or nitrogen (Pickering et al. 2001).
Table 2 lists the properties of the three common unit crystals.
Table 2: The three common hydrates unit crystal structures. Nomenclature: 51264 indicate a water
cage composed of 12 pentagonal and four hexagonal faces. The numbers in squares indicate the
number of cage types. For example, the structure I unit crystal is composed of two 5 12 cages, six
51262 cages and 46 water molecules. (Sloan Jr., 2003)
Cavity
Small
Large
Small
Large
Small
512
51262
512
51262
512
16
4.33
3.91
4.73
24
20
Description
Number of cavities per unit
cell
Average cavity radius ()
II
2
3.95
Coordination number
20
46
136
28
medium
Large
435663
51262
3.91
4.06
5.71
20
20
36
34
Figure 5 presents a hydrate formation diagram in the pressure-temperature plane. The right
hand region covers pressures and temperatures at which hydrates are thermodynamically
unstable and is therefore hydrate free as indicated. In the hydrates region, the degree of
sub-cooling is sufficient such that hydrates form spontaneously, Estefen et al. 2005.
Figure 5: Phase Diagram Showing the Conditions under which Hydrates will form (Estefen et al. 2005).
Gas hydrates form in the water phase from gas molecules dissolved in that phase.
Consequently, H2S and CO2 increase the temperature at which hydrates will form since they
are more soluble in water than most hydrocarbons. Turbulence producing conditions (for
example: orifice meters, reduced port valves) enhance the formation of hydrates during
flow. However, hydrates also form under static conditions.
Factors that contribute to the initiation of hydrate formation include:
Degree of sub-cooling hydrates may not begin to form immediately upon reaching
the hydrate point. As much as 5C to 10C of sub-cooling is needed to form the first
seed crystals of hydrates;
Furthermore, once crystallization has begun, time is needed for the crystals to agglomerate
(clump) and actually block the flow (CAPP 2007). In other word, hydrates formation is a
transient process. Also, the exact hydrate formation point depends on the composition of
the fluids involved; gas composition and water as well as brine composition. In Figure 6, the
conceptual representation of hydrate formation is shown schematically as temperature
drops along a pipeline with time in oil dominated system, though this project focuses on gas
system. It starts with a shell and then grows up to a hydrate plug (Sloan et al. 2009).
Figure 6: Conceptual representation of hydrate formation in an oil-dominated system. Sloan et al. 2009.
(1983); Robinson and Ng (1986); and Ng et al. (1987). The following are the thermodynamic
ways to prevent the hydrate formation:
1. Reducing the water concentration from the system.
2. Operating at temperatures above the hydrate-formation temperature for a given
pressure by insulating the pipelines or applying heat.
3. Operating at pressures below the hydrate-formation pressure for a fixed
temperature.
4. Adding inhibitors such as salts, methanol, and glycols to inhibit the hydrate formation
conditions and shift the equilibrium curve to higher pressure and lower temperature.
11
12
Table 3: Summary of Applications, Benefits & Limitations of Chemical Inhibitors (Pickering et al. 2001)
Thermodynamic Hydrate
Inhibitors
Anti-Agglomerants
Inhibitors
1. Multiphase
2. Gas & Condensate
3. Crude oil?
1. Multiphase
2. Condensate
3. Crude oil
1.
2.
3.
4.
5.
1.
2.
3.
4.
5.
Applications
1. Multiphase
2. Gas & Condensate
3. Crude oil
Benefits
1.
2.
3.
4.
Lower OPEX/CAPEX
Lower volume (<1wt. %)
Environmentally friendly
Non toxic
Tested in gas system
Lower OPEX/CAPEX
Lower volume (<1wt. %)
Environmentally friendly
Non toxic
Wide range of subcooling
Limitations
1.
2.
3.
4.
5.
6.
Higher OPEX/CAPEX
High volumes (10-60wt. %)
Toxic / hazardous
Environmentally harmful
Volatile losses to vapour
Salting out
1.
2.
3.
4.
5.
6.
1. Time dependency?
2. Shutdowns?
3. Restricted to lower water
cuts
4. System specific testing
5. Compatibility
6. Limited experience
7. No predictive models
Reliable solution;
Closed loop;
Corrosion protective;
No gas plant or refinery contamination;
Environmentally friendly, non-toxic, non-flammable;
Qualified technology.
In a closed loop system, Rich MEG arriving at the production unit must be regenerated to
Lean MEG quality, 90-95 weight % MEG, before being re-injected at the subsea producers
(Estefen et al. 2005). The full reclamation of MEG process is illustrated in Figure 7.
14
15
He also asserts that the main advantage of empirical or semi empirical correlations and
charts is the availability of data input and the simplicity of the calculations, while most of the
available thermodynamic models could be installed on laptop computers.
Using empirical or semi empirical correlations and charts, Mohammadi et al. 2005 puts
that, as long as the gas gravity of the mixture is closed to that of methane, and temperature
is not too high, the effect of gas composition (in other word, gas gravity) can be ignored. He
added that for lean and sweet natural gases containing over 70 mol percent methane and
small amounts of heavy hydrocarbons, the effect of composition can be ignored and the
water content can be assumed as a function of temperature and pressure.
However, a detailed discussion on different methods with some conditions on which they
provide high accuracy can be found in the some of these literatures: Mohammadi et al.
(2005), Carroll (2002), Song et al. (1982), and others. In addition, accurate determination of
water content of sour natural gases therefore requires a careful study of the existing
literature information and available experimental data. In most cases, using additional
experimental data is the best way to verify the model based predictions (Bahadori et al.
2009).
16
( )
( )( )
( )]
(2)
Steady-state flow and heat exchange (no problem variable is dependent on time);
Physical properties for the mixture and the structure are independent on
temperature and pressure;
Only mixture temperature variation in the longitudinal direction is considered;
Mixture is idealized homogeneous, that is, single phase flow;
One dimensional heat transfer.
(5)
) (
(6)
19
where Tu = Tsea, and setting in for constant outside temperature, this result in the following
simplification:
(7)
The cooling from outside of the pipeline corresponds to the cooling of the fluid flowing
inside the pipeline, thus resulting in the relationship:
(
( )
(8)
(9)
and
( )
(10)
Therefore, to determine the outlet temperature in each of the segment, the equation can be
re-arranged thus:
(
(11)
The temperature, T2 is the outlet temperature for each pipeline segment with an inlet
(wellhead) temperature T1. Equation (11) was then used in computation of temperature
variation along this pipeline.
The specific heat capacity Cpg was estimated by interpolating through the heat capacity chart
(Moshfeghian 2009), as a function of temperature and specific gravity and at constant
pressure. The heat capacity chart is provided in the Appendix, Figure A3.
(16)
21
Assuming that there is no elevation (that is, the pipeline is horizontal), then the pressure
drop is mainly due to friction losses between the pipe wall and the fluid. Then, total pressure
drop of compressible fluids (gas) due to friction in horizontal pipe was surveyed from the
expression given below, Gudmundsson (2011):
(
( )
(17)
The natural logarithm term is quite small and can be ignored, Gudmundsson (2011).
Simplifying for P2 yields:
(18)
(19)
22
Considering flow through a horizontal pipe segment of length, L, in Figure 9, the upstream
pressure P1 and a downstream pressure P2, (P1 P2) represents the driving force that causes
the flow and the longer the pipe length for a given pressure the larger the pressure drop.
However, iteration was performed on the pipeline diameter to obtain a reasonable pipe
diameter that will ensure flow with less pressure drop. Thus, subsequent sub-sections
discuss these important dependent parameters and variables.
5.3.1.2 Density
This is dependent upon the system pressure, gas compressibility and temperature. Recall
that an ideal gas law is given by:
And, density:
.
Therefore, density relationship can also be mathematically expressed as:
(21)
where p, T, and z = system pressure, temperature, and compressibility respectively,
Mw = gas molecular weight, and
23
R = gas constant.
5.3.1.3 Velocity
Considering a pipe segment; the velocity of the flowing gas changes with density and the
pipes internal diameter. It is also a function of fluid rate (q) along the pipe which is given as:
;
and,
And, combining these equations and simplifying for velocity, gas velocity was then
determined using the expression below:
(22)
where m = mass flow rate of the fluid,
A = pipeline cross sectional area.
5.3.1.4 Viscosity
The dynamic viscosity of a fluid is a unique function of fluid composition, pressure and
temperature. As the gas flows in the pipeline, the viscosity changes with change in
temperature and pressure.
In this work, the Lee-Gonzales-Eakins (LGE) correlation was used, (Gudmundsson 2011 and
Jeje et al. 2004), and it has the following form:
(
(23)
where:
24
where:
) )
y = reduced-density parameter, (it is the product of a van der Waals co-volume and
density), was obtained by solving the expression below:
( )
with
( )
(
(
)
)(
)
where Tpr and Ppr = pseudo reduced temperature and pressure respectively.
[( )
(25)
25
(26)
(27)
The inhibitors constant of MEG used in this analysis was 1222, and molecular weight of the
MEG was 62.00 kg/kmol, (Gudmundsson 2010).
The following assumptions were however made that:
The dew point depression is given as the difference between the hydrate formation
temperature and the final terminal temperature. Hydrate formation temperature was
determined using the pressure-temperature curve (GPA Handbook). This chart is provided in
the Appendix, Figure A2.
Water mass rate was determined as the product of gas mass rate and mol fraction of water
condensed expressed as:
26
(28)
Where mg = mass rate of gas and
xw = mol fraction of water.
However, the mass rate of hydrate inhibitor required was estimated as the product of mass
rate of water and the mol fraction of the inhibitor. This is expressed as:
mMEG = mwxMEG
(29)
27
Water
Content
mg/Sm3
Pressure
bara
Temperature
o
C
Sour Gas
Correction
Factor
Reservoir
290.00
90.00
0.9785
3495
Wellhead
200.00
80.00
0.9855
3063
Terminal
113.34
17.59
0.9932
374
Conditions
The water vapour condensed out of the gas phase at the wellhead is 432.67 mg/Sm3 and at
the receiving terminal at shore, it is 2689.04 mg/Sm3. However, the difference between the
water content at reservoir condition and the water condensed at the receiving terminal,
amounts to the quantity of water that needs to be removed or prevented from forming
hydrates. The total value of condensed water at the receiving terminal is approximately 806
mg/Sm3 which is high enough to cause hydrates formation with the presence of other
28
favourable conditions. It is necessary to control the water content of gas to ensure safe
operation of gas pipeline.
70.0
60.0
Temperature, T(oC)
50.0
40.0
30.0
20.0
10.0
0.0
0
20000
40000
60000
80000
100000
120000
Distance, L(m)
Figure 10: Steady-State Temperature Profile
The result of this analyzes points out that the fluid is within hydrate forming region
(temperature) when compared to the theoretical or necessary conditions (less than 21 oC)
29
that favours hydrate formation. The pipeline is exposed to the cooling sea current, thus the
gas inside the pipeline is cooled down to temperatures that favour hydrate formation.
In steady state operation, the production fluid temperature decreases as it flows along the
pipeline due to heat transfer through pipe walls. This steady state temperature profile from
the produced fluid can be used to identify the flow rates and insulation preference that can
keep the system above the critical minimum temperature during production.
Thermal analysis of a typical subsea production system, which predicts the temperature
profile along the flowline, is one of the most important steps in the subsea layout design
(Vianna et al. 2009). However, heat transfer analysis of the pipeline systems is of great
importance for the prediction and prevention of hydrate formations. Accurate knowledge of
the temperature field in the equipment combined with the knowledge of the critical
temperature values for solid deposit formations must be adequately evaluated in order to
ensure continued production at desired levels for profitability.
30
Pressure, P (bara)
140.0
120.0
100.0
80.0
60.0
40.0
20.0
0.0
0
20000
40000
60000
80000
100000
120000
Distance, L (m)
Figure 11: Steady-State Pressure Profile
31
32
8. Conclusion
Produced natural gas stream from the reservoir is always saturated with water. One of the
problems associated with the transmission of this fluid especially in offshore / subsea
environments to shore through pipeline is the formation of hydrates. Thus, the important
parameters and factors that favour hydrate formation must be understood if hydrates are to
be controlled or managed.
Water content estimation of a natural gas stream at the reservoir, wellhead and the
receiving terminal conditions is one of the important parameters that must be understood if
successful operations of pipeline transmission systems are to be ensured. The estimated
amount of water vapour condensed was 803.23 mg/Sm3.
In the thermal analyzes, the initial wellhead temperature was 80 oC and the arrival
temperature is 17.59 oC giving rise to a total temperature drop of 62.41 oC. Thus, the gas
flow is not out of hydrate forming region as the terminal arrival temperature was below 20
o
C.
The pressure profile analyzes also results in a total pressure drop of 86.66 bara, with the
arrival pressure of 113.34 bara. The initial wellhead pressure was 200 bara, thus arrival
pressure also reflects pressure above 100 bara, a condition which also favours hydrates
formation.
Based on the fact that this flow is not out of hydrate forming conditions, MEG was
considered for the prevention of hydrate plug formation. The total amount of hydrate
inhibitor (MEG) required to prevent hydrate formation was estimated to be 798.35
tonne/day. Consequently, it is important to identify first the potentials of hydrate formation
in a pipeline system and then plan on the necessary prevention strategy for safe operations.
33
Nomenclature
MEG
CAPEX
OPEX
P1
P2
A
f
z
R
T1
T2
din
Tf
QMEG
L
g
Tr
Pr
g
Tc
Pc
CO2
Mw
m
Cp
H2S
TLMTD
U
xg
THIs
KHIs
Fsour
To
Po
yw_sour
yw_sweet
=
=
=
=
=
=
=
=
=
=
=
=
=
=
=
=
=
=
=
=
=
=
=
=
=
=
=
=
=
=
=
Mono-Ethylene-Glycol
Capital Expenditure
Operational Expenditure
Upstream or Inlet Pressure (bara)
Downstream or outlet Pressure (bara)
Cross sectional Area of pipeline (m2)
Friction factor
Gas compressibility factor
Gas constant (J/kmol.K)
Upstream or Inlet temperature ( oC)
Downstream or outlet temperature (oC)
Pipeline internal diameter (m)
Gas flowing temperature (oC)
MEG flow rate (tonne/day)
Pipeline Length (m)
Gas viscosity (cp)
Reduced temperature
Reduced pressure
Gas density (kg/m3)
Critical temperature (K)
Critical pressure (MPa)
Carbon dioxide
Molecular weight (kg/kmol)
Mass rate (kg/s)
Heat capacity (J/kg.K)
Hydrogen Sulfide
Logarithmic mean temperature difference (K)
Overall heat transfer coefficient (W/m2.K)
Gas mass fraction (kg/kmol)
Thermodynamic hydrate inhibitors
Kinematics hydrate inhibitors
=
=
=
=
=
=
=
L
BC
q
K
=
=
=
=
35
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40
Appendix A
Table A1: Sour gas correction factor constants, (Mohammadi et al. 2005)
Mohammadi et al.
Constants
C1
0.03185
C2
C3
0.01538
-0.02772
Reservoir Pressure
PR
290
bara
Wellhead Pressure
Pwh
200
bara
Reservoir Temperature
TR
90
Wellhead Temperature
Twh
80
Seawater temperature
Tsea
10
Dwh
150
3.50E+07
Sm3/day
din
600
mm
Pipeline Length
Pipeline Overall Heat Transfer Coefficient
L
U
120
10
km
W/m2.k
Pipeline Roughness
35.10
microns
C
C
C
41
Figure A1: Water contents of natural gases, Mcketta and Wehe Chart (GPA Handbook).
42
Figure A2: Pressure-temperature Curves for Predicting Hydrate Formation Temperature (GPA
Handbook).
43
Figure A3: Natural Gas Heat Capacity of 0.60 and 0.65 Specific Gravity (Moshfeghian, 2008)
44
Table A4: Natural Gas Stream Composition from Nigeria, with slight modification
Source: Development of petrochemicals from natural gas (methane), Maina, N.S., 2005 (Dept. of
Chemical Engineering, Ahmadu Bello University, Nigeria)
(Original)
(Modified)
Component Symbol
Mol
Percent
Mol
fraction
Component Symbol
Mol %
Mol
fraction, zi
Methane
C1
91.25
0.9125
Methane
C1
90.01
0.9001
Ethane
C2
3.61
0.0361
Ethane
C2
5.35
0.0535
Propane
C3
1.37
0.0137
Propane
C3
2.46
0.0246
i-Butane
i-C4
0.31
0.0031
i-Butane
i-C4
0.31
0.0031
n-Butane
n-C4
0.44
0.0044
n-Butane
n-C4
0.38
0.0038
i-Pentane
i-C5
0.16
0.0016
i-Pentane
i-C5
0.21
0.0021
n-Pentane
n-C5
0.17
0.0017
n-Pentane
n-C5
0.2
0.002
Hexane
C6
0.27
0.0027
C6
0.05
0.0005
Heptane+
C7+
2.42
0.0242
Hexane
Heptane
plus
C7+
0.57
0.0057
CO2
Nitrogen
N2
0.04
0.0004
H2S
CO2
0.14
0.0014
N2
H2S
0.28
0.0028
100
100
Carbon
dioxide
Hydrogen
Sulphide
Nitrogen
Total
Carbon
dioxide
Hydrogen
Sulphide
Total
45
Segment Pipeline
Number Segment
dL
#
m
1
0
2
100
3
200
4
300
5
400
6
500
7
600
8
700
9
800
10
900
11
1000
12
1100
13
1200
14
1300
15
1400
16
1500
17
1600
18
1700
19
1800
20
1900
21
2000
43
4200
1190
118900
1191
119000
1192
119100
1193
119200
1194
119300
1195
119400
1196
119500
1197
119600
1198
119700
1199
119800
1200
119900
1201
120000
Pipeline
Temperature
Ti
o
C
80.000
79.871
79.741
79.612
79.484
79.355
79.227
79.099
78.971
78.843
78.716
78.589
78.462
78.335
78.209
78.083
77.957
77.831
77.706
77.581
77.456
74.763
17.747
17.733
17.718
17.704
17.690
17.676
17.661
17.647
17.633
17.619
17.605
17.591
46
119200
119300
119400
119500
119600
119700
119800
119900
120000
17.704
17.690
17.676
17.661
17.647
17.633
17.619
17.605
17.591
0.7597
0.7598
0.7599
0.7600
0.7600
0.7601
0.7602
0.7603
0.7604
115.775
115.662
115.549
115.435
115.321
115.207
115.093
114.978
114.862
9.7262
9.7357
9.7452
9.7548
9.7644
9.7741
9.7838
9.7936
9.8034
Constants
5.188
5.188
5.189
5.189
5.190
5.190
5.191
5.191
5.192
5.193
5.193
5.194
5.194
5.195
5.195
1.293
1.293
1.293
1.293
1.293
1.293
1.293
1.292
1.292
1.292
1.292
1.292
1.292
1.292
1.292
128.905
128.859
128.813
128.767
128.721
128.676
128.630
128.585
128.539
128.494
128.449
128.404
128.359
128.314
128.269
5.520
5.520
5.520
5.520
5.520
5.520
5.520
5.521
5.521
1.219
1.219
1.219
1.219
1.219
1.219
1.219
1.219
1.219
106.249
106.244
106.239
106.233
106.228
106.223
106.217
106.212
106.207
Haaland's
Total
Outlet
Reynolds Friction
Pressure
Pressure
Drop
Viscosity Number Factor
P2
dPT
Re
fH
mPa.s
bara bara
0.0196 34399147 0.0108 200.00 0.00
0.0196 34395012 0.0108 199.92 0.08
0.0196 34397808 0.0108 199.84 0.16
0.0196 34400597 0.0108 199.76 0.24
0.0196 34403379 0.0108 199.68 0.32
0.0196 34406153 0.0108 199.60 0.40
0.0196 34408921 0.0108 199.52 0.48
0.0196 34411681 0.0108 199.44 0.56
0.0196 34414434 0.0108 199.36 0.64
0.0196 34417180 0.0108 199.28 0.72
0.0196 34419919 0.0108 199.20 0.80
0.0196 34422650 0.0108 199.13 0.87
0.0196 34425375 0.0108 199.05 0.95
0.0196 34428094 0.0108 198.97 1.03
0.0196 34430805 0.0108 198.89 1.11
0.0158
0.0158
0.0158
0.0158
0.0158
0.0158
0.0158
0.0158
0.0158
42701098
42722431
42743828
42765288
42786813
42808401
42830054
42851772
42873556
0.0108
0.0108
0.0108
0.0108
0.0108
0.0108
0.0108
0.0108
0.0108
114.19
114.08
113.98
113.87
113.77
113.66
113.55
113.45
113.34
47
85.81
85.92
86.02
86.13
86.23
86.34
86.45
86.55
86.66
B. Calculation Procedure
I present here the calculation procedures of the various inputs used in this work for the
evaluation of hydrates formation and prevention, but the equations with the important
parameters are discussed in the empirical correlations and calculation methods section. The
natural gas composition data was first obtained and other necessary data provided in
Appendix A, and then the formulas to be used was decided for the calculations of the
needed values.
For water vapour estimation at different conditions, the equivalent hydrogen sulfide was
first determined and it was used for the calculation of the sour gas correction factor. Sweet
gas water content was determined using Mcketta-Wehe chart, and the water content of the
gas was then estimated as the product of the sweet gas water content and the sour gas
correction factor.
For temperature drop, I needed to calculate the specific gravity of the gas using the
molecular weight and the pseudocritical properties of the gas compositions. I further on to
calculate the mass rate of the gas at standard conditions and the temperature profile along
the pipeline was then calculated.
I continued on the pressure drop along the pipeline. The gas compressibility was calculated
using reduced temperature and pressure, and it is highly dependent on pressure and
temperature of the system. I further calculate the density, velocity, viscosity, Reynolds
number, friction factor, and then outlet pressure for each pipes segments. And, finally the
total pressure drop along the pipeline.
Finally, for the prevention of hydrate formation using MEG, I first determined hydrate
depression point. From the percentage of water condensed, water mass rate was
determined, and with the estimated amount of MEG, the required quanity of inhibitor (MEG)
at the wellhead to prevent hydrate formation and blockage of pipeline during transmission
was estimated.
48