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SCHOOL OF TECHNOLOGY
Environmental department
Course:
Evaluation:
Period:
Academic
year:
Environmental
Engineering
Unit:
Exam
Teacher:
Normal
Year:
2010/2011
Date:
Artur Figueirinha
3
5
Semester:
November
2012
Potentiometric method
(Grans plot)
Sample (g)
Sample (g)
Grans equation
28,1875
7,30
28,5781
Y = 3,875x106X +
4,324x107
28,2010
7,35
26,0120
Y = 4,175x106X +
4,324x107
27,9899
7,23
28,5090
Y = 3,975x106X +
4,195x107
a) Briefly explain how you would obtain the data for tracing the Grans plot.
%acidity =
acetic acid ( g )
x100
sample mass ( g )
4. The following
owing chart resulted in a condutimetric titration of chloride present in
50.00 ml of a water sample with a standard solution of silver nitrate 0.001986 M. Based
on the data obtained, calculate the concentration of chlorides in the water sample
expressing the result in mg NaCl / liter. (2,9 mg NaCl / liter).
a)
b)
c)
X Xt
x1 x2 t S acum
tS
N
N1 + N 2
N1 N 2
MA(H) = 1.00794
MA(Ag) = 107.868
MA(Cl) = 35.4527
MA (O) = 15.9994
MA(N) = 14.00674
MA (C) = 12.0107
MA(Cd) = 112.41
MA (S) = 32.066
MA (Ca) = 40.078
MA(Na) = 22.990