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THE EFFECT
ON NO x
Department of Mechanical Engineering and Energy Studies, University College, Newport Road, Cardiff,
CF2 1TA United Kingdom
The problem of pollutant formation in swirling gas flames is a subject of current research
at Cardiff University. This paper concentrates on the influence of the levels of swirl on
the aerodynamics and NO x emissions at a constant load.
Measurements of mean temperature, local velocity and N O - - N O x concentrations were taken
for swirl numbers from .63 to 3.04. From these a net NO~ flow through sections of the
flame were calculated.
The flames have been classified into 4 broad groups dependent on the influence of the
recirculation zone on flame stabilization. These changes in flame type coincide with other
changes in the flow structure, as can be seen from the effects on the precessing vortex
core. A model based on well stirred and plug flow reactors is proposed for the flows.
The results highlight errors in interpretation that can occur by only considering the
concentration measurements. In order to establish the source of pollutants in a swirl combustor,
it is essential to consider the pollutant mass flow profiles.
The formation of NOx in these flows occur in the flame front. The recirculation zone,
despite its long residence times and moderate temperatures, does not contribute to NO x
formation.
Introduction
Experimental Combustors
82
~io
3-
ro II re
At
where
[Tangential Flow T
L
~ ~ w
_]
Experimental Techniques
The instantaneous velocities were measured by
dual beam laser anemometry. As the flame contained
areas of reversed flow direction, in addition to very
high turbulence, it was necessary to use frequency
shift to make the anemometer directionally sensitive.
By rotating the radial diffraction grating I used to
split the input laser beam, a frequency shift is
obtained between the two first order beams used
for the anemometer. The signal, collected from the
forward scattered light, was analysed using a counter
developed at Sheffield University, linked to a PDP
11/03 micro computer. 2
The flame was sampled with an aerodynamically
quenching quartz probe. As the flame temperatures
are relatively low, and in the light of previous work, a
it was felt unnecessary to adopt a more sophisticated
sampling system. The NO, NO~ concentrations were
r
re
Key
Contour
1
2
3
Z.
5
Sg
0.63
0.90
1.26
1.56
3.04
F I G . 2. R e v e r s e f l o w z o n e s .
, 'f' !l,lo
83
x
re
5
,li
N
', ,
$g =
0.90
re
Stream funct~n
u <10%
~( > 9 0 %
84
COMBUSTION GENERATED P O L L U T I O N
1.0
/
"
5
x
ce
re
&
//
9
Sg = 1.56
56
' II11,1
4
Stream function
Key
.....
_r
re
Temperature {K ) Contours
~ <10%
> 90%
Fic. 4. Top 'A' without injector (Sg = 1.56).
90%, indicating that the majority of the instantaneous velocity readings were negative). There is little
chemical reaction in this region and it contains
predominantly high temperature exhaust gas. The
contents of the r.f.z, which enters the combustor
diffuse rapidly outwards and mix with the isothermal
flow where they are quenched.
The area of unsteady flow (90% > 7 > 10%)
between the two most stable areas of the flow show
the distortion of the r.f.z, by the passage of a
precessing vortex core (PVC) discussed later. This
broadens the mean temperature gradients between
the high temperature r.f.z, and the isothermal swirling jet.
This is a type 'c' flame. The improved mixing,
particularly in the reaction zones, produces a blue
flame.
Further increasing Sg causes the reaction region
to occupy more of the recirculation zone. However
at Sg = 1.56, the fluctuating tail of reverse flow
(90% > 7 > 10%) extends beyond the visible flame
front (Fig. 4), and intermittently recirculates lower
temperature burnt gases into the centre of the reaction region, producing a quenching effect. Therefore, this is a type 'd' flame.
There is still some ignition of the gases in the
well stirred region where the swirling jet breaks
Pvlc.
2.C
Total flow
m3/min
10
[]
30
1 PVC
2 PVC
PVC with
I Domlr'cf't
No R.~Z
~r P','C
.~rese~t
~]
85
WSR 3
r.s
ws,
V,sofhe, , '
mixing
region
WSR 1
I
I
~ -
__<
FLOW IN
KEY:REGION
Mixing Region
WSR1
WSR 2
WSR 3
LOCATION
Forward swirling isothermal iet
Eye of Recirculotion zone
~reokdown region of swirling forward jet
Downstream slognation poinl of r f z
PLF 1
PLF 2
Stable r f z 1~>90%)
Exhaust flow
FIc. 6. a) Flow regions within a swirl combustor; b) Schematic model of swirl combustor.
86
TABLE I
Roles of p l u g f l o w a n d well stirred r e g i o n s
Sg
.63
.90
1.26
1.56
1.98
3.04
WSR 1
I n c r e a s i n g in size b u t
still p l a y s little part in
reactions.
I n c r e a s i n g in size. M a i n centre of
c o m b u s t o r reaction
WSR 2
S o m e reactions
M a i n reaction zone
WSR 3
Source o f ignition
M a i n reaction zone
Reaction
occurring
in this region
I n c r e a s i n g in size. R e c i r c u l a t i n g l o w
temperature exhaust gases
PLF 1
Small. U n s t a b l e
I n c r e a s i n g in size a n d
stability. C o n t a i n s h i g h
temp. exhaust gases
I n c r e a s i n g in size. C o n t a i n s s o m e of
t h e reaction
PLF 2
Majority o f c o m b u s t i o n
o c c u r s in this region
C o n t a i n s e x h a u s t gases
re
x/
re
k
/
i j;
10
lo
Sg = 1.56
Sg : .90
I
r_
re
(rag) 0.8
0.6
0"
0.2
O
x_
re
sg
1.2
9-
156
10
NOx
3.04
(rag) 0.8
0.6
Ol.
02
0
~.
t~
/(
1"0
87
5
re
SQ = 1.56
Sg ~ 0.90
0
___
..s
0
0
re
&
re
88
Conclusions
The flames produced by a swirl stabilized combustor, can be grouped into 4 types, dependent on
the influence of the recirculation zone on flame
stabilisation. The changes in flame type also coincide with other changes in flow structure, as can
be seen from the effects on the PVC. Of these, the
type 'c' flame, which produces a well stirred combustion in the recirculation zone, is the most satisfactory.
The most effective way of achieving this type
of flame is the quarl outlet (which enhances recirculation) with Sg = .63 (to minimise pressure losses).
A short parallel section is also essential to produce
a symmetrical flame. The use of a radial fuel injector
disturbs the continuous oscillations of PVC and
transforms it into random turbulence.
A model based on well stirred and plug flow
regions and the complete set of velocity, temperature
and gas concentration measurements, has been
proposed for the flow with combustion.
The NO~ concentration contours are similar to
those found by others. However, the results highlight
the errors in interpretation that can occur by only
considering the concentration measurements. In
view of this, it is felt that to establish the source
of pollutants in swirl combustor, it is essential to
consider the pollutant mass flow profiles.
The formation of NO x in this highly turbulent
combustion system is predominantly in the flame
front. The highest NO x output is with the turbulent
diffusion flame, type 'b' stabilised in the wake of
the recirculation zone. Although the results have
been presented primarily in terms of NOx, it should
be appreciated that NO is the main precursor of
NOx and that the rate of formation of NO is the
major influence on the amount of NO~ formed.
The moderate flame temperatures and the rapid
formation of NO, indicate that the NO is formed
via the 'prompt' mechanism. The reduction in NO,
NOx emissions by the change from a type 'b' to
a type 'c' is probably a result of better mixing prior
to combustion with the latter flame. This tends to
eliminate local imbalances of reactants which produce fuel rich regions of combustion.
The recirculation zone, despite elevated temperatures, does not appear to play a major role in the
formation of NO~. Although NO~ concentrations are
high and related to mean temperature, little, if any,
9.
Acknowledgments
10.
11.
REFERENCES
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gratings to laser anemometry'. AERE Report
R7886 1974, Harwell, UK.
2. NAIIM, S. 'An aerodynamic study of cyclonic
combustion with gaseous fuel'. Ph.D. Thesis,
University College Cardiff.
3. VINCE, I. M. 'Nitric oxide formation in flames'.
Ph.D. Thesis, Sheffield University UK, 1978.
4. SASPKAYA,T. 'An experimental investigation of
the vortex breakdown phenomena', US Naval
Postgraduate School. (NPS 59SL0071A) July
1970.
5. LtmCKEL,W. ANDFR1CHER, N. 'The characteristics
of swirl stabilised natural gas flames. Part 1:
Different flame types and their relation to flow
and mixing patterns', J. Inst. Fuel, June 1976.
pp. 103-112.
6. CLAyPOLE, T. C. AND SYRED, N. 'Coherent structures in swirl generators and combustors'. Paper
to be presented at ASME Fluids Engineering
Winter Annual Meeting 1980.
7. SrP,ED, N. AND BEEa, J. M. 'Effect of combustion
upon precessing vortex cores generated by swirl
combustors'. Proc. 14th Symposium (International) on Combustion 1972. pp. 537-550.
89
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