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Code: 10003, DPR 5070, document code: FDS10003
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Regulated substance
Classification of the
pure substance
S phrases
Classification of the
substance according to
its concentration (in %)
Concentration range in
the preparation
C R35
Xi R 36/38
< 5%
Substances with the R33 phrase (if 1%) or the R64 phrase (if 1%) or sensitising substances (if 0.1%): NO.
OTHER SUBSTANCES WITH WORKPLACE EXPOSURE LIMITS: NO.
OTHER INFORMATION: contains also quaternary ammonium salts.
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Code: 10003, DPR 5070, document code: FDS10003
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Sulphuric acid
3
Average value (8h) = 1 mg/m
3
Limit value (15 min) = 3 mg/m
(INRS file ND 2098)
Not applicable
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Code: 10003, DPR 5070, document code: FDS10003
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PERSONAL PROTECTION
Provide a shower, a powerful tap and sink unit and an eye basin near the workplace.
Respiratory protection: during brush electrolysis, provide as far as possible an inhaling of the sprays / vapours where
they are created and extraction out of the premises. Or work in a ventilated room and wear if necessary a filtering
FFP3 mask (EN 149:2001 standard).
Hand protection: wear gloves (in latex, nitrile, neoprene or PVC).
Eye protection: wear glasses with lateral protections or a facial screen. Do not wear contact lenses.
Skin protection: wear overalls and safety boots.
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9 - PHYSICAL AND CHEMICAL PROPERTIES
-
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Code: 10003, DPR 5070, document code: FDS10003
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Fish toxicity: leuciscus idus, EC/LC50 (96h) from 460 to 1000 mg/L.
Toxicity of daphnias: - daphnia magna, EC/LC50 (48h): 129 mg/L.
MOBILITY
The present species are very mobile in soils and dissolve quickly in water.
PERSISTENCE AND DEGRADABILITY
BIOACCUMULATION
Sulphuric acid has a weak bioaccumulative potential.
The involved ammonium salt is not bioaccumulative.
OTHER ADVERSE EFFECTS
No other information.
According to the applicable EC directives, it is not appropriate to apply theN symbol DANGEROUS FOR THE
ENVIRONMENT to this preparation.
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13 - DISPOSAL CONSIDERATIONS
This product and water used for rinsing must not be thrown away notably because of their acidity and their content in
metals after use. They must be processed within the firm or destroyed by an approved organization.
Contaminated packaging if not re-used with the same product is also special waste to be sent to an approved
organization for recycling or disposal.
Classification according to the commission directive 2000/532/EC of 3 May 2000 and its modifications (in particular
2001/118/EC, OJ L47). Use the mandatory documents to follow-up the waste products.
06 03 13* or Solid salts and solutions containing heavy metals
11 01 05*
Pickling acids
11 01 11*
Aqueous rinsing liquids containing dangerous substances
15 01 10*
Packaging containing residues of or contaminated by dangerous substances
As the volume of rinsing water is small, it can be added to the waste solutions.
NOTE: in addition to the community provisions, it can be specific legislative and administrative, national or local
provisions on this topic.
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14 - TRANSPORT INFORMATION
A.D.R. (road transport)
Corrosive liquid, acidic, inorganic, n.o.s., class 8, classification code C1, packaging group III, hazard label model n 8,
restricted quantities LQ7, hazard code n80, material code n 3264.
I.M.D.G. (sea transport)
Corrosive liquid, acidic, inorganic, n.o.s.*, UN N 3264, class 8, packaging group III, subsidiary risk: not applicable,
restricted quantities 5 L, stowing and separation: category A, far from houses, safety sheets F-A, S-B.
I.A.T.A. (air transport)
Corrosive liquid, acidic, inorganic, n.o.s.*, UN N 3264, class 8, subsidiary risk: not applicable, risk label: CORROSIVE,
packaging group III, Passenger and Cargo aircraft: packaging instructions 818, maximum quantity per package 5 L,
Cargo aircraft only: packaging instructions 820, maximum quantity per package 60 L, instruction IDC 8L.
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15 - REGULATORY INFORMATION
This safety data sheet has been established in accordance with the Corrigendum to Regulation (EC) n 1907/2006 of the
European Parliament and of the Council of December 18, 2006, OJ L136, 29.05.2007.
th
The preparation labelling has been established in compliance with the directive 67/548/EC (until the 29 adaptation:
directive 2004/73/EC of April 29, 2004) and the directive 1999/45/EC reviewed in last in January 23, 2006 by the
directive 2006/8/EC.
EC LABELLING:
Is not classified but contains at least one dangerous compound with a non regulated concentration (with regard
th
to the 67/548/EC directive until the 29 modification).
Safety data sheet available for professional user on request.
Aqueous acidic preparation containing in particular less than 5 % sulphuric acid.
S26: in case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S37/39: wear suitable gloves and eye/face protection.
HEALTH SURVEILLANCE
Council Directive 98/24/EC of 7 April 1998 on the protection of the health and safety of workers from the risks related to
chemical agents at work
An appropriate health surveillance of workers must be carried out according to the risk.
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Code: 10003, DPR 5070, document code: FDS10003
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For each worker who undergoes this health surveillance, individual health and exposure records are to be made and kept
up-to-date.
Other paragraphs in the French version of this safety data sheet summarize French rules regarding: