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Suggested Problems
Serway: Physics for Scientists and Engineers with Modern Physics, 8th edition.
Eastop: Applied Thermodynamics for Engineering Technologists, 5th edition.
1) Specific Heat, Latent Heat
Serway 20.14, 20.16, 20.17, 20.18, 20.19, 20.20, 20.51, 20.63
(Note: Constants in Tables 20.1 (p.569), 20.2 (p.573)).
2) Ideal Gases: State Equation
Serway 19.21,19.24,19.25,19.27,19.29,19.34,19.54,20.69
(Note: Molar mass from Periodic Table, Appendix C. Values of R and k in p.555)
3) Work, First Law of Thermodynamics for a Closed System
Serway 20.24, 20.25, 20.27, 20.38, 20.13
4) Ideal Gases: Heat Capacities, Enthalpy, Quasi-static Processes
Serway
21.15
Isochoric: 21.14
Isobaric: 21.17, 20.33
Isothermal: 20.31
Adiabatic: 21.19, 21.23, 21.24, 21.71
Polytropic: 21.53
21.51
Eastop
2.10, 2.12
Isochoric: 3.1
Isobaric: 3.3
Isothermal: 3.5, 3.7
Adiabatic: 3.8, 3.9, 3.10
Polytropic: 1.5, 3.11, 3.12
(Note: For air, r = 0.287 kJ/ kg K, cp = 1.005 kJ/ kg K, cv = 0.718 kJ/ kg K,
= 1.4.)
5) Thermodynamic Cycles, Second Law of Thermodynamics: Entropy, Heat Engines and Refrigerators
Serway
Cycles: 22.30, 22.35, 22.57, 22.62, 22.67
Entropy: 22.37, 22.38, 22.40
HE&R: 22.11, 22.19, 22.28, 22.59, 22.60, 22.61
Eastop
Entropy: 4.5, 4.7, 4.12, 4.15, 4.18
HE&R: 5.1, 5.2
6) Heat Transfer by Conduction
Serway 20.42, 20.45, 20.49
(Note: Thermal conductivities in Table 20.3 (p.584).)
Eastop 16.1.
7) Steam Tables, Quasi-static Processes with Steam, Steady Flow Equation
Additional Exercises
1
Question 1.1. A lead bullet initially at 30 C just melts upon striking a target. Assuming that
all of the initial kinetic energy of the bullet goes into the internal energy of the bullet to raise its
temperature and melt it, calculate the speed of the bullet upon impact. (clead = 0.128 kJ/ kg K,
Tmelting = 327C, Lmelting = 24.7 kJ/ kg) [Ans: 353.31 m/s]
Question 1.2. If 500 g of molten lead at 327 C is poured into a cavity in a large block of ice
at 0 C, how much of the ice melts ? [Ans: 100 g]
Question 1.3. A 200 g piece of ice at 0 C is placed in 500 g of water at 20 C. The system is
in a container of negligible heat capacity and is isolated from its surroundings.
a) What is the final equilibrium temperature of the system ? [Ans: Tf = 0 C]
b) How much of the ice melts ? [Ans: 126 g]
Question 1.4. A well-insulated bucket contains 150 g of ice at 0 C.
a) If 20 g of steam at 100C is injected into the bucket, what is the final equilibrium temperature of the system ? [Ans: Tf = 5.09C]
b) Is any ice left afterward ? [Ans: No]
Question 1.5. How many calories must be supplied to 60 g of ice at 10 C to melt it and
raise the temperature of the water to 40 C ? [Ans: 7.48 kcal]
Question 1.6. What is the amount of vapour at 130 C that is needed to heat up 200 g of
water and its glass container (100 g) from 20 to 50 C ? (cvapour = 2.01 kJ/ kg C, cglass =
0.212 kJ/ kg C, Lvapour = 2.26 kJ/ kg, cwater = 4.18 kJ/ kg C)
2
Question 3.1. The initial state A of a certain amount of a monoatomic ideal gas is P1 = 5 bar,
V1 = 3 L, and its final state B is P2 = 2 bar, V2 = 6 L.
a) Find the change in internal energy of the ideal gas from states A to B. [Ans: UAB =
450 J]
b) Find the quasi-static work done and the net heat absorbed by this system in each of the
following processes which take the system from state A to state B:
i) The system is expanded from its original to its final volume, heat being added to
maintain the pressure constant. The volume is then kept constant, and heat is
extracted to reduce the pressure to 2 bar. [Ans: W = 1500 J, Q = 1050 J]
ii) The volume is increased and heat is supplied to cause the pressure to decrease linearly
with the volume. [Ans: W = 1050 J, Q = 600 J]
Question 3.2. Two containers of volume V1 = V2 = V are connected by a small tube with a
valve. Initially, the valve is closed and the two volumes contain monoatomic gas at pressures
P1 and P2 , and temperatures T1 and T2 respectively. After the valve is opened, what will be the
final pressure and temperature inside the joint volume ? (Neglect heat lost from the system).
P1 + P2
T1 T2 (P1 + P2 )
[Ans: Pf =
, Tf =
]
2
P1 T2 + P2 T1
V,P 1,T
V,P 2,T
Question 4.1. The change in temperature of a certain amount of a diatomic gas with flexible
bond when it absorbs a quantity of heat Q at constant volume is Tv . When the same amount
of gas absorbs the same amount of heat Q at constant pressure, the change in temperature is
Tv
. [Ans: 9/7]
found to be Tp . Find
Tp
Question 4.2. [Isobaric process]
Heat in the amount of 500 J is supplied to 2 mol of an ideal diatomic gas.
a) Find the change in temperature if the pressure is kept constant. [Ans: 8.6 K]
b) Find the work done by the gas. [Ans: 143 J]
c) Find the ratio of the final volume of the gas to the initial volume if the initial temperature
is 20 C. [Ans: 1.03]
d) Find the change in enthalpy of the gas. [Ans: 500.503]
Question 4.3. [Isobaric] 100 mol of a monoatomic gas is cooled at constant pressure such
that its volume is reduced by 3%. If the original temperature of the gas is 24 C, find:
a) The final temperature of the gas. [Ans: 288.09 K]
b) The heat capacity at constant pressure. [Ans: 2078.5 J/K]
c) The heat lost by the gas. [Ans: 18.52 kJ]
d) The work done. Is it done on or by the gas ? [Ans: 7.407 kJ (on the gas)]
Question 4.4. [Isothermal process]
Two moles of a diatomic ideal gas are compressed isothermally from 18 to 8 L. In the process,
170 calories escape from the system. Determine the amount of work done by the gas, the change
in internal energy, and the initial and final temperature of the gas. (Note: 1 cal = 4.184 J ).
[Ans: U = 0, W = 711.28 J, Q = 711.28 J, Tf = 52.75K ]
Question 4.5. [Adiabatic process]
An ideal gas at a temperature of 20 C is compressed quasi-statically and adiabatically to half
its original volume. Find the final temperature if the molar specific capacitances are:
a) cv = 23 R [Ans: 465.1K ]
b) cv = 52 R [Ans: 386.6K ]
Question 4.6. [Adiabatic process]
One-half mole of helium is expanded adiabatically and quasi-statically from an initial pressure
of 5 atm and temperature of 500K to a final pressure of 1 atm. Find:
a) The final temperature. [Ans: 262.65 K ]
b) The final volume. [Ans: 0.0109 m3 ]
c) The work done by the gas. [Ans: 1480 J ]
d) The change in the internal energy of the gas. [Ans: 1480 J ]
e) The change in enthalpy of the gas. [Ans: 2466.67 J]
Question 4.7. [Adiabatic-Isothermal process]
One mole of gas in a container is initially at a temperature 127 C. It is expanded adiabatically
to twice its initial volume. Then, it is isothermally compressed to its original volume. The final
temperature is found to be 3 C. What is for the gas ? [Ans: = 1.567]
Question 4.8. [Polytropic process]
1 kg of a perfect gas is compressed from 1.1 bar, 27 C according to a lawP V 1.3 = constant,
until the pressure is 6.6 bar. Calculate the heat flow to or from the cylinder walls if the gas is
ethane (molar mass 30 kg/ kmol), which has cp = 2.1 kJ/ kg K. [Ans: 138.16 kJ, gained by
the system]
Thermodynamic Cycles, Second Law of Thermodynamics: Entropy, Heat Engines and Refrigerators
Question 5.1. The compression ratio in an air-standard Otto cycle is 8. At the beginning
of the compression stroke, the pressure is 0.1 MP a and the temperature is 15 C. The heat
transfer to the air per cycle is 1800 kJ/ kg. Determine:
a) The pressure and temperature at the end of each process of the cycle. [Ans: P2 =
1.838 MP a, T2 = 661.65K, P3 = 8.817 MP a, T3 = 3174K, P4 = 0.4797 MP a, T4 =
1381K]
b) The thermal efficiency. [Ans: = 56.5%]
(Take: = 1.4, cv = 0.7165 kJ/ kg K)
P
3
Adiabatic expansion
Q in
Q out
Adiabatic contraction
1
V
M1
500 KJ
350 KJ
M2
150 KJ
400 KJ
100 KJ
500 K
300 KJ
M3
200 KJ
Tl = 150 K
Heat Transfer
500 K
M4
300 KJ
200 KJ
500 K
M5
500 KJ
100 KJ
ts
[ C]
184.1
188.0
191.6
195.0
198.3
vf
vg
uf
ug
hf
hf g
hg
3
3
[ m /kg] [ m /kg] [ kJ/ kg] [ kJ/ kg] [ kJ/ kg] [ kJ/ kg] [ kJ/ kg]
0.001133 0.1774
780
2586
781
2000
2781
0.001139 0.1632
797
2588
798
1986
2784
0.001144 0.1512
813
2590
815
1972
2787
0.001149 0.1408
828
2593
830
1960
2790
0.001154 0.1317
843
2595
845
1947
2792
Turbine
Exit
Pressure
Temperature
Dryness Fraction
Speed
Elevation above reference plane
Inlet
Conditions
2.0 MP a
350 C
Exit
Conditions
0.1 MP a
50 m/s
6m
100%
200 m/s
3m
Theory
Proof of the relation between the internal energy and the specific heat at constant volume.
Proof of the relation between the specific heat at constant volume and the specific heat
at constant pressure.
Drawing of all processes in the P V and T S diagrams.
The relations between P , V and T for all processes.
Proofs for the relations between P V , P T and V T for the adiabatic process.
The relations between P V , P T and V T for the polytropic process.
Equations for W , Q and U for all processes.
Proof of the equation for work in the isothermal process.
Proof of the equation for work in the adiabatic process.
Carnot cycle on the P V and T S diagrams.
12
TL
|QL |
=
.
QH
TH
13