UNIVERSITI TEKNOLOGI MARA

FAKULTI KEJURUTERAAN KIMIA

PROCESS ENGINEERING LABORATORY II (CPE 554)

NAME
GROUP
EXPERIMENT
DATE
PROG/CODE
SUBMIT TO
No
1
2
3
4
5
6
7
8
9
10
11
12
13

:
:
:
:
:
:

NURSYAZA NAURAH BINTI MOHD HIDZIR (2012472346)

EH 2225A
L12-PLUG FLOW REACTOR
26 SEPTEMBER 2014
EH 242
MR. MOHAMAD SUFIAN BIN SOAIB
Title

Abstract
Introduction
Objectives
Theory
Procedures/Methodology
Apparatus
Results
Calculation
Discussion
Conclusion
Recommendations
References
Appendices
TOTAL

Allocated
Marks(%)
5
5
5
5
10
5
10
10
20
10
5
5
5
100

Marks

Remarks:
Checked by:
Date:

Rechecked by:
Date:

TABLE OF CONTENT

Content
Abstract and Summary
Introduction
Aims/Objectives
Theory
Apparatus
Procedure
Result
Discussions
Conclusions
Recommendations
References
Appendices

Page
3
3
3
4
5
7
8
11
12
12
12
12

ABSTRACT & SUMMARY

INTRODUCTION
AIMS & OBJECTIVES
THEORY
APPARATUS
PROCEDURE
RESULTS
EXPERIMENT 3
Flow
300
rate(ml/min)
Volume
of 23.00
titration
NaOH(ml)
Volume
of 9.20
quenching HCl
unreacted with
NaOH
in
sample(ml)

250

200

150

100

22.30

22.00

21.30

200

8.92

8.80

8.52

8.00

Volume of HCl
reacted
with
NaOH
in
sample (ml)
Mole of HCl
reacted
with
NaOH
in
sample
Mole of NaOH
unreacted
in
sample
Concentration
of
NaOH
unreacted with
Ethyl Acetate
(M)
Steady
state
fraction
conversion of
NaOH,Xa
Concentration
of
NaOH

0.80

1.08

1.20

1.48

2.00

2.00x10-4

2.75x10-4

3.00x10-4

3.70x10-4

5.00x10-4

2.00x10-4

2.75x10-4

3.00x10-4

3.70x10-4

5.00x10-4

0.004

0.0055

0.006

0.0074

0.01

0.92

0.89

0.88

0.85

0.80

0.046

0.0445

0.044

0.0426

0.040

reacted
with
Ethyl Acetate
(M)
Mole of NaOH
reacted
with
Ethyl Acetate
in sample (ml)
Concentration
of
Ethyl
Acetate
reacted
with
NaOH (M)
Concentration
of
Ethyl
Acetate
unreacted (M)
1/Ca
Residence
time(s)
Conductivity
(Q1)
Conductivity
(Q2)
Rate constant,
k(ml/mol.s)
-rA (mol/ml2.s)

0.0023

0.00223

0.0022

0.00213

0.002

0.046

0.0446

0.044

0.0426

0.04

0.054

0.0554

0.056

0.0574

0.06

250
40

181.8
47.96

166.67
60.06

135.14
80.00

100
119.76

6.8

7.3

7.0

6.9

7.2

5.3

5.4

5.3

4.9

5.0

2.875

1.687

1.221

0.708

0.334

1.814x10-4

2.04x10-4

1.76x10-4

1.59x10-4

1.34x10-4

Residence time against x

0.94
0.92
0.9

0.88
0.86
0.84
0.82
y = -0.0014x + 0.9661
R = 0.976

0.8
0.78
0

20

40

60

80

Residence time

100

120

140

SAMPLE OF CALCULATION
For flow rate 300
(A) Volume of titrating NaOH (mL) = 23.0 mL = 0.023L
(B) Volume of quenching HCl Unreacted with NaOH in Sample (mL)
=
=

x (A)
x 23.0 mL

=9.2 mL
(C) Volume of HCl Reacted with NaOH in sample (mL)
= VHCl (B)
= 10 mL 9.2 mL
= 0.8 mL = 0.0008L
(D) Mole of HCl Reacted with NaOH in sample (mol)
= CHCl, stdx (C)
= 0.25 mol/L x 0.0008 L
= 2.00 x 10 -4mol
(E) Mole of NaOH unreacted in Sample
= (D)(mol)
=2.00 x 10 -4mol

(F) Concentration of NaOH unreacted with Ethyl Acetate (mol/L)

=
=
= 0.004mol/L
(G) Steady State Fraction Conversion of NaOH (XA) CAO
=1
=1= 0.92

(H) Concentration of NaOH reactedwith Ethyl Acetate (mol/L)

= CNaOH,O (F)
= 0.05 mol/L - 0.004mol/L
= 0.046mol/L
(I) Mole of NaOH reacted with Ethyl Acetate in Sample(mol)
= (H) x VS
= 0.046mol/L x 0.05 L
= 0.0023mol
(J) Concentration of Ethyl Acetate reacted with NaOH (mol/L)
=
=
= 0.046mol/L
(k) Concentration of Ethyl Acetate unreacted (mol/L)
= CEA,O (J)
= 0.1 mol/L 0.046 mol/L
= 0.054 mol/L
(l) Residence time

=
= 33.33 s
(m) Rate constant

=
= 2.875 ml/mol.s
(n) ra, reaction rate
- ra = kCa02(1-x)2
= (2.875)(0.1)2(1-0.92)2
= 1.84 x 10-4 mol/ml2.s

DISCUSSIONS
CONCLUSIONS
RECOMMENDATIONS
REFFERENCES
APPENDICES