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Objectives
ih ( x , t ) = H ( x , t )
t
The stationary solutions have the form
where
is determined by
h2 2
[
+ V ( x )]( x ) = E( x )
2m
h2 2 1 2
[
+ Kx ]( x ) = E( x )
2m
2
d2
2
)
+
(
) ( ) = 0
2
d
=x (dimensionalless)
4=42 mK/h2,
dimensionless eigenvalue
=(4E/h) (m/)1/2=4/hc
c= (K/m)1/2 is the angular frequency
of the corresponding classical
harmonic oscillator
( ) = H ( )e
1 2
H ( )'' 2H ' + ( 1) H = 0
(*)
H ( ) = s (a0 + a1 + a2 + ...)
a0 0
s0
(**)
Assumption:
The equation (*) is to be valid for all values of , so that, once we substitude
H into the equation, the coefficient of each power of can be equated to zero
s(s-1)a0=0
(s+1)sa1=0
s=0, s=1
s=0 or a1=0 or both
(s+2)(s+1)a2-(2s+0+1-)a0=0
(s+2)(s+1)a2-(2s+2+1-)a1=0
...........................................
(s++2)(s++1)a+2-(2s+2+1-)a=0
is an integer
= 2n + 1
1 h
En = ( n + )
2 c
n = 0,
1,
2, ...
Wave functions
The quantum number n is the highest value of s+ in the series for H. It
will be denoted that Hn is of degree n in and is even or odd according
as n is even or odd.
n ( ) = N n H n (x )e
1 2 2
x
2
H 0 (x ) = 1
H 1 (x ) = 2
H 2 (x ) = 4(x )2 2
S ( , s ) = e
s 2 + 2 s
n= 0
H n ( ) n
s
n!
n
H n ( ) = ( 1) e
e
n
n 2
H 'n = 2nH n1
H n+1 = 2H n 2nH n1
n ( x ) dx =
2
Nn
2
H
(
)
e
d = 1
n
2
The integral on the right can be expressed as a series coefficient in the expansion
of an integral containing the product of two generating functions
s 2 + 2 s t 2 + 2 t 2
d =
n= 0 m = 0
1 / 2 2 st
1/ 2
( 2 st )n
n= 0 n!
s nt m
H n ( ) H m ( )e d
n! m!
2
)e
H n2 (
d = 1 / 2 2n n!
H n ( ) H m ( )e d = 0
2
nm
orthogonality
From the first equation one can deried that the normalizing constant can be chosen:
Nn = (
( 1 / 2 2n n! )
)1 / 2
2 ( x ) = ( 1 / 2 )1 / 2 [4(x )2 2]e
2
1/ 2
1 ( x ) = ( 1 / 2 ) 2xe
2
0 ( x ) = ( 1 / 2 )1 / 2 e
1 2 2
x
2
1 2 2
x
2
1 2 2
x
2
( p ) 2
+ K ( x ) 2
m
Minimizing this energy by taking the derivative with respect to the position x
energy and setting it equal to zero gives
energy allowed:
This is a very significant physical result because it tells us that the energy of a
system described by a harmonic oscillator potential cannot have zero energy.
Physical systems such as atoms in a solid lattice or in polyatomic molecules in a
gas cannot have zero energy even at absolute zero temperature. The energy of
the ground vibrational state is often referred to as "zero point vibration".
The zero point energy is for instance sufficient to prevent liquid helium-4 from
freezing at atmospheric pressure, no matter how low the temperature.
1
1 (E -is the total energy)
1
1 2n + 1 1
= n* Kx 2n ( x )dx = K
=
(
n
+
)
h
=
En n
c
2
2
2
2
2
2
2