Chemical Equilibrium (SCQ)

49. The equilibrium concentrations of A and B for the reaction

( ) ( ) ( )
2
g g g
A B C +

are 3M and 4M
respectivel. !hen the volume of the vessel is doubled and the equilibrium is allo"ed to reestablish the
concentration of B is found to be 3M. The equilibrium constant #$ for the reaction is
A) %2 B) 4 $) &.2' () &.&)33
* Key : not provided
'2. !hen
'
PCl
(*as)
( . 2&).2) M W
is heated and if dissociates into ( )
3
PCl g
and ( )
2
Cl g
. The densities
of the *as mi+ture at
&
2&& C and
&
2'& C are ,&.2 and
'- . g cc
respectivel at equilibrium. Then the
de*ree of dissociation of
'
PCl
at
&
2'& C
(A) &.-29 (B) &.)2, ($) &.%&4 (() &.2'4
2,. The follo"in* equilibria are *iven /
2 2 3
0 31 201 +

2#%
2 2
0 3 203 +

2#2
2 2 2
%
1 3 1 3
2
+

2#3
The equilibrium constant of the reaction
3 2 2
'
201 3 203 31 3
2
+ +

in terms of #%4 #2 and #3 is
(A)
% 2
3
# #
#
(B)
2
% 3
2
# #
#
($)
3
2 3
%
# #
#
(()
% 2 3
# # #
2-. !hat is the value of #eq of the follo"in* reaction (#b of 01431 5 %&
6'
)
01431 7 1
7


014
7
7 123
(A) %&
89
(B) %&
9
($) %&
8'
(() %&
'

3&. #
p
for an endothermic chemical reaction is %& atm. Then bac9"ard reaction is favoured at
(A) 1i*h pressure4 hi*h temperature (B) 1i*h pressure4 lo" temperature
($) :o" pressure4 hi*h temperature (() :o" pressure4 lo" temperature
23. 2 moles of 0234 is heated to form 03 and 32. As soon as 03 and 32 are formed the react to form
023'. T"o equilibria
0234

203 7 32 2 (i)
203 7
2
3
3
2

023' 2 (ii)
are simultaneousl established. At equilibrium4 the de*ree of dissociation of 0234 "as found to be
'&;. !hich of the follo"in* is correct at equilibrium.
(A) <03= 7 <32= 5 <0234= 7 <023'= (B) <32= 7
%
2
<023'= 5
%
2
<03=
($)
%
2
<03= 5
3
2
<32= (() 2<0234= 5 <03= 7
3
2
<32= 7 <023'=
%
2'. The rate constant #% of a reaction is found to be double that of rate constant #2 of another reaction.
!hat is the relationship bet"een correspondin* activation ener*ies of the t"o reactions. The
Arrhenius constant is same for the reaction
(A) >2 5 >% 6
RT
2 ln
(B) >2 5 >%
RT
2 ln
($) >2 7 >% 5
RT
2 ln
(() >2 5 >% 7 ?T ln 2
2,. @olume of the flas9 in "hich species are transferred is double of the earlier flas9. An "hich of the
follo"in* cases4 equilibrium is affectedB
(A) 02 (*) 7 312 (*) 2013 (*)
(B) 02 (*) 7 32 (*) 203 (*)
($) 12 (*) 7 A2 (*) 21A (*)
(() 203Br (*) 02 (*) 7 32 (*)
EC. Ke questions
87. The electric charge for electrodeposition of 1 eq. of a substance is
!" one a#pere per second $" %&'(( coulo#bs per second
C" one a#pere for one hour )" charge on one #ole of electrons
88. 1 coulo#b of electricity produces m *g of a substance +. Electroche#ical equivalent of + is
!" m $"
3
%& m
C"
3
%& m

)" all ,rong
8%. Electroche#ical equivalent of a substance is .(((&7-'. its eq. ,t. is
!" &' $" &7.-'
C" 1-( )" cannot be calculated
%(. /hen electricity is passed through a solution of
3
Al$l
0 1-.' g of !l is deposited. The nu#ber of
faradays #ust be
!" 1.( $" 1.'
C" (.' )" 1.(
4). 2.3 *rams of a mi+ture of 032 and 0234 have a pressure of &.)2 atm at temp T #4 and volume v
liters4 Af
%
3&&
V
T
_

,
in ma*nitude4 The value of
2
NO
P
"ill be. (Assume that all the 032 "as formed
from 0234).
(A) &.'2 atm (B) &.3) atm
($) &.%9 atm (() &.4% atm
Key . )
2ol: usin* C@ 5
W
RT
M

2.3 &.&)2%
,9
D &.)2. 3&& D
M



0234

2032
f 5 & % &
f 5 eq. %8+ 2+
2
,9 5
2 4, (% )92
%
x x
x
+
+
+ 5 %.3
2
%
2
2
3
&.)2 &.)2
% 4. 3
NO
x
P
x

+
5 &.4% atm
Key 3 2olutions

52 B
26. C
27. B
30 B
23 B
25 D
26 A
'2.
D d
x
d

%&4.% '-
&.)2,
'-
x


2, ($)
#% 5
2
3
3
2 2
<01 =
<0 =<1 =

#2 5
2
2 2
<03=
<0 =<3 =

#3 5
2
%. 2
2 2
<1 3=
<1 =<3 =
#2.#3
3
5
3 2
2
3 3. 2
2 2
2 2
<1 3= <03=
<0 =<3 =
<1 = <3 =

2013 7
2 2
'
3 203 31 3
2
+


3
2 3
%
# .#
#
5
3 3 2
2 2 2
3 3. 2 2
2 2
2 2 3
<1 3= <0 =<1 = <03=
<0 =<3 =
<1 = <3 = <01 =

5
2 3
2
'. 2 2
2 3
<03= <1 3=
<3 = <01 =
5 #
3
2-. (B)
[ ]
4
4
01
#eq
01 31 1
+
+
1
]

1
]
5
[ ]
4
9 b
"
4
01 31
#
%&
#
01 31 31 1
+
+
1 1
] ]

1 1
] ]
3&. (B)
Eor bac9"ard reaction 1 5 6ve and n* 5 6%
23. (B)
0234

203 7 32
26+6 (2+ 7 262F) ( + 7
3
F
2
)
203 7
2
3
3
2


023'
2+ 7262F +7
3
F
2
F
<32= 7
%
2
<023'= 5
%
2
<03=
b is correct
2'. (()
%
%
>a
ln # ln A
?T

or
[ ]
% 2 %
2 %
2
# >a >a %
ln >a >a
# ?T ?T ?T

>a2 6 >a% 5
%
2
#
?Tln
#
(as *iven #%5 2#2)
>a2 5 >a% 7 ?T ln 2
2,. (A)
n &.
2ingle Choice
4-. At 2-3 # G % atm %& lt of
2 4
N O
decomposes to
2
NO
accordin* to equation
2 4( ) 2( )
2
g g
N O NO

"hen the ori*inal volume is 2' ; less than that of e+istin* volume4 then the de*ree of dissociation is
(a) &.2' (b) &.33 (c) &.,, (d) &.'
#e / B
HolI
4

2 4 2
2
&
2
N O NO
a
a a a

3ri*inal volume 5
-'
%&&
volume at equilibrium
a 5
&.-' (% ) a +
&.33
4). The equilibrium constant
c
K
for the follo"in* reaction at )42 C is
3
-.9 %&

. !hat is
p
K
at the
same temperature
2( ) ( )
%
2
g g
F F
(a)
'
).,4 %& (b)
4
).2, %&

(c)
2
-.9 %&

(d)
3
-.', %&

#e / (
Hol/
( )

p c
K K RT

49.
2
COCl
dissociates4
2( ) ( ) 2( ) g g g
COCl CO Cl +
"hen heated to -&& #4 the densit of *as mi+ at %.%,
atm and equilibrium is %.%, *.lit. The de*ree of dissociation of
2
COCl
at -&& 9 is
(a) &.2) (b) &.'& (c) &.-2 (d) &.42
#e / $
Hol /
&
'-.4
dRT
M
p

99 '-.4-
&.-2
'-.4-

4-. The increasing order of = <
+
Ag in
(i) Haturated solution of
AgCl
) %& % . (
%&
AgCl o! K"p
(ii) Haturated solution of ) %& 9 (
%,
Ag# o! K"p Ag#
(AAA)
+
= ) ( < %
2 3
NO Ag M in
)
2 3 3
%& = ) ( < ( % . &
+
N$ Ag o! Kd MN$
(iv)

)= ( < %
2
CN Ag M in
2%
2
%& = ) ( < ( % . &

CN Ag o! Kd MKCN
(A) A J ii J iii J iv (B) iv J iii J ii J i
($) iv J ii J iii J A (() iv J ii J A J iii
Key : C
4. An reaction ( ) ( )
2 4 2
0 3 * 203 * 4
The observed molecular "ei*ht )&* mol
6%
at 3'& #. The
percenta*e dissociation of 0234 (*) at 3'& # is
(A) %&; (B) %';
($) 2&; (() %);
Key. $
2ol: (e*ree of dissociation
( )
M m
+
m n %

n 2 Q I M 92 I m )&
+ &.%'
'
; dissociation 5 %'
2. Credict the nature of reaction to"ards for"ard direction
2AB(*) A2(*) 7 B2(*) #eq. 5 2 %&
62
at 3'K$.
#eq. 5 2 %&
64
at %3'K$
(A) >+othermic (B) >ndothermic
($) 1 & (() LK 5 &
Key : !
3. At a certain temperature the equilibrium constant ( ) Kc
for the equilibrium
( )
2 2 3
SO NO (g) SO (g) NO g + +

is %,.
Af one mole each of the four *ases are ta9en in a one litre vessel then the concentration of
2
NO
at
equilibrium "ould be
(A)
1
1.6 mol L

(B)
1
0.4 molL

($)
1
2 mol eL

(()
1
2.4 molL

#e / B
HolI
2 2
SO NO +

3
SO NO +
%8+ %8+ %7+ %7+
( ) ( )
( ) ( )
1 x 1 x
Kc 16
1 x 1 x
+ +


x 0.6
[ ]
2
NO 1 x 0.4
%. Eor the reaction 2 4 2
N O (g) 2NO (g)

the de*ree of dissociation of
2 4
N O
at equilibrium is &.2 at
one atmosphere. The equilibrium constant #p "ill be
(A)
1
2
(B)
1
4
($)
1
6
(()
1
8
Key : C
Hol/ 2 4 2
N O (g) 2NO (g)


14 (.15(.8 1 6 (.1 5 (.7
Total no. of #oles 5 (.8 8 (.7 5 1. 1
2 4 2
N O NO
0.8 0.4
P , P
1.2 1.2

( )
2
2 4
2
NO
N O
0.4 0.4
P
0.4 0.4 1
1.2 1.2
K
0.8
P 1.2 0.8 6
1.2

2. The equilibrium constant #p at

0
2! C for a homo*eneous *aseous reaction is
8
10

. The standard free

ener* chan*e
0
" for the reaction is ( )
1 1
R 2c#lK mole

(A)
11.0$Kc#l
(B) 1.8Kc#l
($)
4.14$4Kc#l
(()
4.14$4Kc#l +
Key : !
,
HolI 1.
0
" 2.303RTlogK
3 8
2.303 2 10 300 log10 11.0$Kc#l


3. The values of #p are
6
10

3
#%m and
4 3
10 #%m

at 29) # and 323 # respectivel for the reaction

4 2 4 2
C&SO .3' O(() C&SO (() 3' O(g) +


0
'
for the reaction is
(A) -.- #M (B) 14!K)
($)
14!.4K)
(()
14.!K)
Key : C
H3:/
0
2 2 1
1 1 2
* ' T T
log
* 2.303R TT
1

1
]
4 0
6
10 ' 2$
log
10 2.303 8.314 2+8 323

1

]
0
' 2$
2
2.303 8.314 2+8 323

0
' 14!.4K)
4. !hich of the follo"in* "ill shifts the equilibrium in the for"ard direction for the follo"in*
equilibrium

2 2
N (g) O (g) +


203 (*)
0
' 181K) +
(A) Ancrease of pressure (B) Ancrease in the concentration of 03
($) (ecrease in pressure (() Ancrease in temperature
Key : )
HolI The reaction is endother#ic in the for,ard direction. 9ncrease in te#perature shifts the
equilibriu# in the for,ard direction.
'. Af LK for the reaction *iven belo" is %.- 9MI the equilibrium constant of the reaction4
21A(*)


12(*) 7 A2(*) at 2'K$ is
(A) 24.& (B) 3.9
($) 2.& (() &.'
Key: )"
2:;: 3. LK 5 62.3&3 ?T lo* #p
%.- 5 62.3&3 ).3%4 %&
63
29) lo* #p
#p 5 &.'
,. At temperature T a compound AB2(*) dissociates accordin* to the reaction
2AB2

2AB(*)7B2(*) "ith a de*ree of dissociation + "hich is small compared "ith unit. The
e+pression for #C in terms of + and total pressure C is
(A)
3
C+
2
(B)
2
C+
3
($)
3
C+
3
(()
3
C+
2
Key : !
2ol: <iven che#ical reaction is
1!$1

1!$ 8 $1
-
initial concentration % + +.2
concentration at equilibriu# % + + +.2
( )
n
2
total
$ $ 2
C + .+ C
# # .
total moles % +
2 % +

_ _


+
, ,
% NN + Q
3
C
C+
#
2

-. At certain temperature compound AB2(*) dissociates accordin* to the reaction

2 2
2AB (*) 2AB(*) B (*) +


!ith de*ree of dissociation

4 "hich is small compared "ith unit. The e+pression of #p4 in terms of

and initial pressure C is/

(A)
3
C
2

(B)
2
C
3

($)
3
C
3

(()
2
C
2

Key : !
2ol.
2 2
2AB (*) 2AB(*) B (*) +


C & &
C(% ) C
C
2

2
2
C
(C )
2
#p 4% %
(C(% ))
_


,
<<


3
C
#p
2

). An aqueous solution of volume '&& ml contains the reaction

2A*
7
(aq.) 7 $u(s)

$u
27
(aq.) 7 2A*(s) in equilibrium "ith <$u
27
(aq.)= 5 +M. 0o" '&& ml of
"ater is further added. 3n reset of above equilibrium <$u
27
(aq.)= "ill be
(A) +M (B) 2+M
($) Bet"een +M and +.2 M (() less than +.2 M
Key : )
Hol/
2A*
7
(aq.) 7 $u(s) $u
27
(aq.) 7 2A*(s)
$oncentration at equilibrium (sa) +
#c 5
2
+

)
3n dilution <A*
7
(aq.)= and <$u
27
(aq.)= both "ill be halved
ne" concentration 2A*
7
(aq.) 7 $u(s) $u
27
(aq.) 7 2A*(s)
.2 +.2
Oc 5
2 2
+ . 2 +
2
(. 2)

Oc > #c and reaction "ill proceed bac9"ard.

9. #c for the snthesis of 1A (*) from 12(*) and A2(*) is '&. The de*ree of dissociation of 1A is
(A) &.%& (B) &.%4
($) &.%) (() &.22
Key : )
2ol: (()
2 2
21A(*) 1 (*) A (*) +


( )
2
2
%
'&
2 2

5 &.22
4'. Af at a certain temperature4 the follo"in* equilibrium is established4
$3(*) 7 032(*)

$32(*) 7 03(*)
3ne mole of each of the four *ases is mi+ed in one litre container and the reaction is allo"ed to reach
equilibrium state. !hen e+cess of barta "ater is added to the equilibrium mi+ture4 the "ei*ht of
"hite precipitate obtained is 23,.4 *. The equilibrium constant4 #c of the reaction is
A) %.2 B) 2.2' $) 2.% () 3.,
Key : $
Hol/ ,n% ,#ll-
A% e.&,l,/0,&m

( ) ( ) ( ) ( )
2 2
1 1
1 1
0.8 1.2
0.8 1.2
CO g NO g CO g NO g + +


( )
2 3 2
2
1.2 mole( 1.2
1.2
B# O' CO B#CO ' O + +
c
1.2 1.2
K 2.2$
0.8 0.8

'%. 3ne mole of 02(*) is mi+ed "ith 2 moles of 12(*) in a 4 litre vessel. Af '&; of 02(*) is converted
to ( )
3
01 *
b the follo"in* reaction/
( ) ( ) ( )
2 2 3
0 * 31 * 201 * +
!hat "ill be the value of #c for the follo"in* equilibriumB
( ) ( ) ( )
3 2 2
% 3
01 * 0 * 1 *
2 2
+
a) 2', b) %, c)
%
%,
d) 0one of these
Key : C
2:;.
( )
( ) ( )
2 3 2
3 2
g g
g
N $ N$ +


(%) (2) (&)
9
At eq. % 6 + 2 6 3+ 2+
!here + 5 &.'
#c 5
2
3
%
4
2',
&.' &.'
4 4
_

,

_ _

, ,
eq. constant for
( ) ( ) ( )
3 2 2
% 3
2 2
g g g
N$ N $ +


%
% %
%,
c
c
K
K

'2. $onsider the reaction/
( ) ( ) ( ) 2 * * *
AB AB B +
. Af the initial pressure of AB2 is '&& torr and
equilibrium pressure is ,&& torr4 then equilibrium constant #p in terms of torr is
a) 2& b) '& c) 2' d) %&&
Key : C
2ol:
( )
( ) ( )
2
g
AB AB g B g +


'&&torr 3 3
'&& 6 + + +
Liven '&& 6 + 7 + 7 + 5 ,&&
+ 5 %&&
'&&
p
x x
K
x

5 2' torr
29. The correct relationship bet"een free ener* chan*e in a reaction and the correspondin* equilibrium
constant #c is/
a)
&
ln
c
% RT & b)
&
ln
c
% RT & c)
ln
c
% RT &
d)
ln
c
% RT &
Key : $
2:;.
&
ln % RT ' I "here O is reaction quotientI at equilibrium
&
c
% ad ' K
&
ln
c
% RT K
3%. The *aseous reaction
( ) ( ) ( )
2
g g g
A B C +
is found to be first order "ith respect to A. Af the reaction is
started "ith CA 5 9& mm 1*4 the pressure after %& min is found to be %)&mm 1*. The rate constant of
the reaction is
a) %.%' + %&
83
s
8%
b) 2.3& + %&
83
s
8%
c) &.&,9& s
8%
d) 4.,& + %&
83
s
8%
Key : !
2o;:
%&
( ) ( )
&
& &
&
&
2
& 9&
2 2 %)&
2 %)& 9&
4'
2.3&3
lo*
2.3&3 9&
lo*
%& ,& 9& 4'
A B C
at t p
at t t p x x x p x
x
x
p
K
t p x
K
+

+

4'. Af at a certain temperature4 the follo"in* equilibrium is established4
$3(*) 7 032(*)

$32(*) 7 03(*)
3ne mole of each of the four *ases is mi+ed in one litre container and the reaction is allo"ed to reach
equilibrium state. !hen e+cess of barta "ater is added to the equilibrium mi+ture4 the "ei*ht of
"hite precipitate obtained is 23,.4 *. The equilibrium constant4 #c of the reaction is
A) %.2 B) 2.2' $) 2.% () 3.,
Key . $
2ol. 4'. ,n% ,#ll-
A% e.&,l,/0,&m

( ) ( ) ( ) ( )
2 2
1 1
1 1
0.8 1.2
0.8 1.2
CO g NO g CO g NO g + +


( )
2 3 2
2
1.2 mole( 1.2
1.2
B# O' CO B#CO ' O + +
c
1.2 1.2
K 2.2$
0.8 0.8

4,. A reaction ta9es place in 3 steps havin* rate constants 9%4 924 93 respectivel. The overall rate constant
1 3
2
* *
*
*

. Af ener*ies of activation for the three steps are 4&4 3&4 2& 9M .mole respectivel4 the overall
ener* of activation is
A) %& 9M.mole B) %' 9M.mole $) 3& 9M.mole () ,& 9M.mole
Key : C
2ol: 4,.
1 3
2
* *
*
*

differentiatin* "ith respect to T

1 3
2
* * 1* 1
1T 1T *
1

1
]
3 1 2
# # # #
2 2 2 2 20 40 30 30 *)3 mole + + +
4-. A and B are *aseous substances "hich react reversibl and *ive t"o *aseous substances $ and (4
accompanied b the liberation of heat. !hen the reaction reaches equilibrium4 it is observed that
p c
K K
. The equilibrium canPt be disturbed b
(A) addition of A (B) addition B
($) raisin* the temp (() increasin* the pressure.
Key . )
2:;:
p c
K K
it su**ests
&
g

so pressure has no effect on the equilibrium.
%%
4). ( ) ( ) ( )
2
2 2 NOBr g NO g Br g +
. Af nitrosl bromide is 34; dissociated at 2'
&
$ and a total pressure
of &.2' atm4
p
K
for the dissociation at this temperature is.(The reaction is started "ith one mole of
03Br)
(A)
3
%.3- %&

(B)
3
9.-) %&

($)
2
2.%, %&

(()
3
'.,- %&

Key . $
49. At certain temperature the value of equilibrium constant correspondin* to the equation
2 2 2
2 2 N O NO +
is %&& "hich of the follo"in* is the equilibrium constant for
2 2 2
%
2
NO N O + B
(A) %& (B) &.&%& ($) &.%& (() %&&
Key . C
2o;. 49.
2 2 2
2 2 N O NO +
I
eq
K
5 %&&
2 2 2
2 2 NO N O +
I
eq
K
5
%
%&&
2 2 2
%
2
NO N O + I
eq
K
5
%
&.%&
%&&

'&. 3 2 A B C D + + for this hpothetical reaction4 initial moles of A is t"ice that of B. Af at
equilibrium4 moles of B and $ are equal4 the percent of B reacted is
(A) %&; (B) 2&; ($) 4&; (() ,&;
Key . )
2ol:
3 2 A B C D + +
Anitial 2a a & &
at equilibrium 2a 6 x a 6 3x 2x x
Most of B and $ are equal / *iven a 6 3x 5 2x
2&;
'
a
x
B reacted

3x 5 2& + 3 5 ,&;
'2. The bond in molecular iodine is quite "ea94 and hot iodine vapour contains a proportion of atoms.
!hen %.&&* of A2 is heated to %&&&9 in a sealed container4 of volume % dm
3
4 the resultin* equilibrium
mi+ture contains &.)3&* of A2. $alculate Q9P for the dissociation equilibrium ( ) ( )
2
2 B # g # g


(A)
4 3
3 %& . mol dm

(B)
' 3
%.2 %& . mol dm

($)
- 3
2.' %& . mol dm

(()
3 3
&.'4 %& . mol dm


* Key . =ot provided
49.
2
( ) COCl g dissociates accordin* to the equation/ ( ) ( )
2 2
( ) COCl g CO g Cl g +

. !hen
2
( ) COCl g
is heated to -24# at %&%.32' #paI densit of the *as mi+ture at equilibrium is %.%,2 *.l. The de*ree
of dissociation and #p for the reaction at -24# respectivel are
(A) &.34'4 &.29 (B) &.43'4 &.23 ($) &.22-4 &.%9 (() &.24'4 &.%,
* Key . =ot provided
%2
%. A(*) 7 B(*)

$(*) 7 ((*)
above homo*eneous reaction is carried out in a 2 litre container at a particular temperature b ta9in*
% mole each of A4 B4 $ and ( respectivel. Af #$ for the reaction is %.4 then equilibrium
concentration of $ is
(A)
%
3
M (B)
2
3
M ($)
4
3
M (()
%
2
M
Key : $
3. Af #C of an equilibrium $a$33(s)

$a3(s) 7 $32(*) is %.' atm at 29K$ then the moles of $a3
formed if e+cess $a$33(s) is bein* placed in a %lt of closed container containin* $32 *as at &.' atm
pressure at same temperature is/
(A)
%
',
(B)
%
24
($)
%
%2
(()
%
%3
Key : $
2:;. 3. Rse C@ 5 n?T as e+tra $32 produced to find QnP "hich "ill equal to net of moles of $a3.
%. The follo"in* equilibrium constant "ere determined at %%2& # /
2$3 (*)

$ (s) 7 $32 (*) I
%4 %
p
%
# %& atm

$3 (*) 7 $l2 (*) $3$l2 (*) I

3 %
p
2
# , %& atm


!hat is the equilibrium constant #c for the follo"in* reaction at %%2& # /
$(s) 7 $32 (*) 7 2$l2 (*)

2$3$l2 (*)
(A) 3.3% S %&
%%
M
6%
(B) '.' S %&
%&
M
6%
($) '.'% S %&
,
M
6%
(() 0one of these
Key : !
2ol: %. !"
$(s) 7 $32 (*)

2$3 (*) I 2(i)

%4
p
2
# %& atm
2$3(*) 7 2$l2 (*)

2$3$l2 (*) I 2(ii)

3 2 2
p
2
# (, %& ) atm


Add (i) and (ii)
$(s) 7 $32 (*) 7 2$l2(*)

2$3$l2 (*) I
#p 5
%4 ,
%& 3, %&

5 3, S %&
)

Eor *iven reaction n* 5 6 %

c p
# # (?T)

5 3, S %&
)
S &.&)2% S %%2&

%% %
c
# 3.3% %& M

2.
The *as A2 in the left flas9 is allo"ed to react "ith *as B2 presence in ri*ht flas9 as
%3
A2 (*) 7 B2 (*)

2AB (*) I #c 5 4 at 2-K$. !hat is the concentration of AB "hen equilibrium is
established B
(A) %.33 M (B) 2.,, M ($) &.,, M (() &.33 M
Key : C
2ol. 2. ($)
A2 (*) 7 B2 (*)

2AB (*)
Moles at eqm 2 6 + 4 6 + 2+
2
c
4+
#
(2 +) (4 +)

+ 5
32
%.33 mole
24

<AB(*)= 5
2 %.33
&.,,M
4

3. 203Br(*)

203(*) 7 Br2 (*). Af nitrosl bromide (03Br) is 4&; dissociated at a certain
temperature and a total pressure of &.3& atm. #p for the rection
203(*) 7 Br2(*)

203Br(*) is 8
(A) 4' (B) 2' ($) &.&22 (() &.2'
Key : !
Hol/ !"
203Br(*)

203(*) 7 Br2 (*)
Anitial pressure C & &
At eqm C 6 2+ 2+ +
!here 2+ 5 &.4&
+ 5 &.2& C I
%.2& C 5 &.3&
C 5 &.2' atm

2
03 Br
2
p 2
0A3Br
C C
#
C

=
2
2
(&.4C) (&.2C)
&.&222
(&.,C)

#p 5 for the reaction
203 7 Br2 203Br is
%
4'
&.&222

4. A reaction sstem in equilibrium accordin* to reaction 2H32(*) 7 32(*)

2H33(*) in one litre
vessel at a *iven temperature "as found to be &.%2 mole each of H32 and H33 and ' mole of 32. An
another vessel of one litre contains 32 * of H32 at the same temperature. !hat mass of 32 must be
added to this vessel to order that at equilibrium 2&; of H32 is o+idiFed to H33 B
(A) &.4%2' * (B) %%., * ($) %., * (() 0one of these
Key : $
%4
2ol: 4. (B)
2H32(*) 7 32(*)

2H33(*)

2
c 2
(&.%2)
# &.2
(&.%2) '

Another vessel
2H32(*) 7 32(*)

2H33(*)
Moles at eqm &.' 6 2+ 6 + 2+
As per *iven 2+ 5
2&
&.' &.%
%&&

2
c 2
(&.%)
# &.2&
(&.4) ( &.&')

5 &.3,2' mole

mass of 32 added 5 %%., *

%. Eor the reaction A 2B 2$ +


at equilibrium <$= 5 %.4 M. <A=o 5 % M4 <B=o 5 2M4 <$=o 5 3 M.
Then value of #c is (*iven vol. 5 % litre4 <=o is initial concentration)
(a) &.&)4 (b) ).4 (c) 4) (d) none of these
Key . !
2. #p for a reaction at 2'
o
$ in %& atm. Then #c for the reaction at 4&
o
$ "ill be
(Liven/ 1 5 ) 9M and antilo* (&.&,-) 5 &.%%,-)
(a) 4.33 %&
8%
M (b) 3.33 %&
82
M (c) 3.)9 %&
8%
M (d) none of these
Key . )
2:;. 2. (d)
#p 5 #c(?T)
n
4 here n 5 %

c
)'.,)
#
&.&)2% 3%3

#c 5 3.33
3. #c for the snthesis of 1A (*) from 12(*) and A2(*) is '&. The de*ree of dissociation of 1A is
(a) &.%& (b) &.%4 (c) &.%) (d) &.22
Key . )
2:;. -. d"
2 2
21A 1 A +


( )
2
2
%
'&
2 2

5 &.22
49. The equilibrium concentrations of A and B for the reaction
( ) ( ) ( )
2
g g g
A B C +

are 3M and 4M
respectivel. !hen the volume of the vessel is doubled and the equilibrium is allo"ed to reestablish the
concentration of B is found to be 3M. The equilibrium constant #$ for the reaction is
A) %2 B) 4 $) &.2' () &.&)33
Key : )
2ol: 49. :et the concentration of $ be QaPM
%'
Then4
2
3 4 4)
C
a a
K
(

3n doublin* the volume the reaction "ill proceed in bac9"ard direction

( ) ( ) ( )
2
3 4
2
2 2 2
g g g
A B C
a
x x x
+
+ +


4 %
2 3
2 2
x x +
2
%
4
2 2 3 4)
C
a a
K a M
( (

3. Eor the equilibrium / ( ) ( ) ( )
2
3 3 3
.3 . 2 4 9 )iCl N$ * )iCl N$ * N$ g Kp atm +

at
&
2- C
. A
4.92 litre vessel contains &.% mole of
3
. )iCl N$
. 1o" man moles of
3
N$
should be added to the
flas9 at this temperature to drive the bac9 "ard reaction for completion B
(A) &.4 moles (B) &.% moles ($) &.3 moles (() &.) moles
Key : )
2ol. 3.
2
4 3
p
K p p atm
PV RT
3 4.92 &.&)2 3&&
n5&.,
( ) ( )
( )
3 3 3
. 2 .3
&.% &
& &.2 &.%
)iCl N$ * N$ g )iCl N$
#itial mole* a
mole* at equilibrium a
+

Moles of ( )
3
&.2 N$ a
5 &.,
&.) a
'(. 3ne mole of H33 "as placed in a t"o litre vessel at a certain temperature. The follo"in* equilibrium
"as established in the vessel
3(*) 2(*) 2(*)
2H3 2H3 3 +


The equilibrium mi+ture required &.2 moles of #Mn34 in acidic medium hence #c of reaction is
(A) &.'& (B) &.2'
($) &.%2' (() none of these
Key : C
2:;. '(. ($)
3(*) 2(*) 2(*)
2H3 2H3 3
% & &
% + + + . 2
+

>q. of #Mn3
4
5 eq. of H3
2

&.2

' 5 +

+ 5 &.'
Ho
3 2 2
H3 H3 3
n &.'4 n &.'4 n &.2'
%,
[ ] [ ]
[ ]
2
2
2 2
c 2 2
3
&.2' &.'
3 H3
2 2
# &.%2'
&.' H3
2
_ _

, ,

_

,
'2. !hen
'
PCl
(*as)
( . 2&).2) M W
is heated and if dissociates into ( )
3
PCl g
and ( )
2
Cl g
. The densities
of the *as mi+ture at
&
2&& C and
&
2'& C are ,&.2 and
'- . g cc
respectivel at equilibrium. Then the
de*ree of dissociation of
'
PCl
at
&
2'& C
(A) &.-29 (B) &.)2, ($) &.%&4 (() &.2'4
Key : $
2ol: '2.
D d
x
d

%&4.% '-
&.)2,
'-
x


4. Eor the reaction
A 2B 2$ +


at equilibrium <$= 5 %.4 M. <A=o 5 % M4 <B=o 5 2M4 <$=o 5 3 M.
Then value of #c is (*iven vol. 5 % litre4 <=o is initial concentration)
(A) &.&)4 (B) ).4 ($) 4) (() none of these
Key . !
'. #p for a reaction at 2'
o
$ is %& atm. Then #c for the reaction at 4&
o
$ "ill be
(Liven/ 1 5 ) 9M and antilo* (&.&,-) 5 &.%%,-)
(A) 4.33 %&
8%
M (B) 3.33 %&
82
M ($) 3.)9 %&
8%
M (() none of these
Key . )
2o;. '. (d)
#p 5 #c(?T)
n
4 here n 5 %

c
)'.,)
#
&.&)2% 3%3

#c 5 3.33
,. 12 7 A2


21A
#c for the snthesis of 1A (*) from 12(*) and A2(*) is '&. The de*ree of dissociation of 1A is
(A) &.%& (B) &.%4 ($) &.%) (() &.22
Key . )
2ol.
,. (d)
2 2
21A 1 A +


( )
2
2
%
'&
2 2

5 &.22
3. The equilibrium constant for the decomposition of "ater4
( ) ( ) ( )
2 2 2
%
1 3 * 1 * 3 *
2
1
+
1
]

is *iven b
%-
(A)
( ) ( )
3 %. 2
%. 2
p
#
% 2

(B)
( ) ( )
3. 2 %. 2
%. 2
p
#
% 2

+
($)
3 %. 2
p
#
2

(()
( ) ( )
3 3. 2
%. 2
p
#
% 2

+
Key . $
4. Acetic acid under*oes dimerisation4 "hen dissolved in benFene
2 $ 1 6 $ 3 3 1
3
$ 1 6
3
$
3
3 1
3
3 1
$ $ 1
3
!hich amon* the follo"in* relation is correct B
(A)
( d
2
d
_


,
(B)
( d
2
(
_


,
($)
d (
2
d
_


,
(()
2d
( d

"here4 d 5 3bserved vapour densit

( 5 Theoretical vapour densit
Key . C
'%. ,& m: of
2
$ and 42 m: of
2
l are heated in a closed vessel. At equilibrium the vessel contains 2) m:
1l4 calculate the de*ree of dissociation of 1l/
(a) -2; (b) 3,; (c) )&; (d) 2&;
Key. !
2:;. '%. $hemical reaction is
2 2
2 4 &4 $ l $l $ +


temperature is constant4 so volume is ta9en as mole.
2 2
2 $ l $l +


Anitial4 ,& 4& &
At eq.4 ,&8+ 4&8+ 2+
2 2)4 %4 x x
c
K
for reaction is 5
2
4
(,& )(42 )
x
x x
Eind
c
K
b puttin* value of +.
2 2
2$l $ l +


% & &
% . 2 . 2
2
%
2
% ( . 2)
(% )
c
c
K
K

%)
B this "e calculate de*ree of dissociation (d) of 1l.
-1" An &.&&%M 4 concentration of ion is
%) 2) 3) 4)
Key. 1
Hol/
-1" The hdronium ion concentration of a solution is at . The hdro+ide ion
concentration in the same solution is
%) 2) 3) 4)
Key: -
2:;. -1"
--" The dissociation constants of t"o acids and are and respectivel. Af both
are havin* equal concentrations the relative stren*th of acids is
%) ' / 2 2) 2 / ' 3) ' / % 4) % / '
#eT I 3
2ol.
-7" of and buffer is 4.). An "hich of the follo"in* conc. $onditions4 the
buffer capacit "ill be ma+imum
%) &.%M &2M 2) &.2M &.%M 3) &.34M &3M 4) &.34M &3M
Key : -
%9
2ol: -7"
Buffer capacit is ma+imum
!hen p15p9a
-'" The of a buffer solution is '. of the acid present in its is '. of the acid present in it is 4.
!hat is the ratio of acid and salt present in the solution
%) %/% 2) %/%& 3) %&/% 4) %/2
Key : 1
2:;. -'"
-&" The follo"in* is a reversible reaction
%) heated in a sealed tube2) heated in a closed vessel
3) heated in a closed vessel 4) heated "ith e+cess of in a closed vessel
Key : -
2o;. -&" An closed sstem can combine to form
-7" !hich of the follo"in* is not affected b chan*e in pressureB
%) 2)
3) 4)
Key : 1
2&
2o;. -7"
-8" The dissociation of ta9es place as per the equation . is 2&;
dissociated at equilibrium "ith an initial pressure of '&&mm "hile the equilibrium pressure of
mi+ture is ,&&mm of . $alculate assumin* the volume to be constant
%) '& 2) %&& 3) %,,.) 4) ,&&
Key : 1>
2ol. -8"
-%" Active mass of ', * of contained in 2 ltr. Elas9 is
%) %, Mole. 2) 32 Mole. 3) %.&& Mole. 4) &.% Mole.
Key : -
2o;. -%"
7(" >quilibrium constant #
c
for the reaction
%) 2) 3) 4)
Key : -
2:;. 7(" Active mass of solid substances are considered as unit
71" The active mass of '., litres of at HTC is
%) '.,.22.4 2) ).'., 3) 32.'., 4) &.2'.'.,
2%
Key : 7
2:;. 71" Active mass
71" At $ and % atmosphere pressure is 2&; dissociated into find
%) &.2 2) &.%,, 3) &.%' 4) &.%&
Key : 1
2:;. 71" :et the initial moles be % if 2&; of % is &.2
77" Eor the follo"in* reactions4 equilibrium constants are indicated on the arro"
Then equilibrium constant for the reaction "ill be
%) 2) 3) 4)
Key : -
2:;: 77" !hen t"o of more equations are added their equilibrium constant value is ta9en as square
root
7'" Eor the reaction the relation connectin* the de*ree of dissociation of
"ith the equilibrium constant is
%) 2) 3) 4)
Key : -
2o;. 7'"
22
?earran*in*4 "e *et
7&" An a chemical equilibrium "hen one mole of each of the t"o reactants are mi+ed &.,
mole each of the products are formed. The equilibrium constant calculated is
%) % 2) &.3& 3) 2.2' 4) 4.9
Key : -
2:;. 7&"
77" % mole of "ith 2 moles of "ere placed in 3 lit vessel and heated to 4&& #. !hen
equilibrium "as established onl &.- moles of remained. !hat is the value of equilibrium
constant for the reaction
%) &.2' lit . mole 2) %.3% mole . lit
3) &.-, lit . mole 4) 2., mole . lit
Key : -
2o;. 77"
23
78" Eor reaction 4 "e start "ith 2 mole of A and B each. At equilibrium &.) moles of
AB is formed. Then ho" much of A chan*es to AB/
%) 2&; 2) 4&; 3) ,&; 4) 4;
Key : 1
2:;. 78"
Thus ; of A chan*ed into
7%" Eor the reaction at . A 3 litre vessel contains %42 G 4 mole of A4B and $
respectivel. Credict the direction of reaction if for the reaction is %&
%) Bac9"ard 2) Eor"ard 3) >quilibrium 4) An direction
Key : 1
2:;. 7%"
'(" An the equilibrium 4 the partial pressures of 4 and are &.,,2
atms.. &.%&% atms. And &.,,2 atms. ?espectivel find the value of
%) 2) 3) 4)
Key : 1
2o;. '("
'1" $onsider the reactions i)
ii) the addition of an inert *as at constant volume
24
%) !ill increase the dissociation of as "ell as
2) !ill reduce the dissociation of as "ell as
3) !ill reduce the dissociation of and set up the formation of
4) !ill not disturb the equilibrium of the reactions
Key : 7
2:;. '1" $onceptual tpe
'1"
Temperature TI # at "hich
%) %&&& # 2) 2&&& # 3) 4)
Key : 7
2:;. '1"
4). Eor the follo"in* reactions4 equilibrium constants are indicated are indicated on the arro"
1
K
3 4 2 4
' PO ' ' PO
+

+

2
K
2
2 4 4
' PO ' 'PO
+

+

3
K
2 3
4 4
'PO ' PO
+

+

Then equilibrium constant for the reaction
3
3 4 4
' PO 3' PO
+

+

"ill be
(A)
1 2 3
K K K + +
(B)
1 2 3
K K K
($)
1 2 3
K K K
(()
1 2 3
1
K K K
Key : C
2o;: 4).!hen t"o of more equations are added their equilibrium constant value is ta9en as square root
2'
''. 3 mole of
$
PCl
9ept in a % : closed vessel "as allo"ed to attain equilibrium at 3)& # . $alculate the
composition of the mi+ture at equilibrium Kc 1.8
(A) [ ]
$
PCl 1.414
[ ] [ ]
3 2
PCl Cl 2.$+4
(B)
[ ]
$
PCl 1.414
[ ] [ ]
3 2
PCl Cl 1.$+4
($)
[ ]
$
PCl 1.414
[ ] [ ]
3 2
PCl Cl $.$+4
(()
[ ]
$
PCl 1.414
[ ] [ ]
3 2
PCl Cl +.$+4
Key : $
2ol:
[ ] [ ]
[ ]
3 2
$
PCl Cl
Kc
PCl

3. At certain temperature compound AB2(*) dissociates accordin* to the reaction

2 2
2AB (*) 2AB(*) B (*) +


!ith de*ree of dissociation

4 "hich is small compared "ith unit. The e+pression of #p4 in

terms of

and initial pressure C is/

(A)
3
C
2

(B)
2
C
3

($)
3
C
3

(()
2
C
2

Key : !
2ol. 3.
2 2
2AB (*) 2AB(*) B (*) +


C 3 3
C(% )
C
C
2

2
2
C
(C )
2
#p 4% %
(C(% ))
_


,
<<

3
C
#p
2

1. The reaction "hose #eq

%
vs
T
*raph is *iven
2,
ln #eq
T
T
The reaction must be
(A) >+othermic (B) >ndothermic
($) Al"as spontaneous (() 0ever spontaneous
Key . $
2:;. 1.
C
2
dln# d1
dT ?T

#eI
#e I
2-
#e /
#e/
P
#e /
#e/
2)
#e /
#e/
-. Liven that hpohalous acids form b the follo"in* reaction /
U2 (aq) 7 123(l)

13U (aq) 7 1
7
(aq) 7 U

(aq)
!hich of the follo"in* chan*es "ill increase the ield of 13UB
(A)Add U (B)Add "ater ($) increase the p1 (() decrease the p1
Key : C
%. At a certain temperature 2 moles of $3 and 3 moles of $l2 "ere mi+ed and allo"ed to reach
equilibrium in a '.& : vessel accordin* to the reaction
$3(*) 7 $l2(*)

$3$l2 (*)
At equilibrium4 if % mol of $3 is present4 then equilibrium constant (#
c
) for the reaction is
(A) 2 (B) 2.'
($) 3.' (() 4.
Key: $
2ol: %. (B)
2 2
$3 $l $3$l
2 3
2 + 3 + +
+



2 6 + 5 %
+ 5 %
%
'
'
#
% 2
2
' '

5 2.'
29
1" 3bserve the follo"in* data at %&&&
&
$ and % atm.

3
( ) CaCO * ( ) CaO *
2
( ) CO g
&
!
$ D
8%2&,.99M 8,3'.%9M 8393.'9M
&
"
92.9M.# 3).2M.# 2%3.-M.#
The partial pressure of
2
CO in the *iven reaction appro+imatel is
3 2
( ) ( ) ( ) CaCO * CaO * CO g +


A) %& atm B) -.)9 atm $) 4.99 atm () 2 atm
Key : !
Hol/
% $ T "
2.3&3 lo* % RT Kp
2

CO
Kp P
7"
$onsider the partial decomposition of QAP as
( ) ( ) ( )
2 2 +


g g g
A B C
. At equilibrium -&&m: *aseous
mi+ture contains %&& m: *as $ at %& atm and 3&&#. !hat is the value of #p for the reaction
( ) ( ) ( )
%
2
+


g g g
B C A .
A) '.- B) -.' $) 2.) () %.,-
#e / (
Hol/
( )
( ) ( ) ( ) * * *
% 2A 2B $
At equil / 4&&m: 2&&m: %&&m:
+


equil
C %& atm
p
2
2
2&& %&&
%& %&
-&& -&&
#
4&&
%&
-&&
_ _


, ,

,
&.3'-%
( )
( ) ( ) ( )
( )
p
* * *
%
2 B $ A
2
# for 2nd equilibrium
+


( )
st
p
%
# for % equilibrium

3&
%.,-3
8"
T"o equilibria are simultaneousl e+istin* in a vessel at
&
2' C
( ) ( ) ( )
2 2 3 %
4 NO g NO g N O g Kp +


( ) ( )
2 2 4 2
2 4 ) NO g N O g Kp atm


Af initiall onl NOand
2
NO
are present in a 3 / ' mole ratio4 the total pressure at
equilibrium is '.' atm "ith the equilibrium pressure of
2
NO
as &.' atm. The
( )
%
%
Kp atm

is
A) 2.& B) '.' $) 2.' () &.4&
Key : )
2ol:

Anitiall. 3p 'p & atm
At equilibrium p
2
4
(%)
( 2 atm of requires 4 atm of )
Total pressure at equilibrium
Holvin* (%) 4(2) and (3)
'1" A vessel contains 12 and 12H *ases at a partial pressures of % and 2 atm respectivel
at certain temperature then the reaction4
2 2 )
)1 H (*) )1 (*) H (s) + occurs. At is
found that
2 2
2 2
1 1 H
1 1 H
at time4 t & at equilibrium
n n
n n

1 1
1 1
1 1
] ]
(n represents no of moles)
Then identif the correct value of the *iven propert
A) #C 5 %.2',
B) #C 5 2',
$) At equilibrium the volume of the *aseous mi+ture is doubled "hen provided
"ith frictionless piston
() #C 5 #$ 5 32&
Key: $
3%
Hol/ Anitiall
2
2
1
1 H
n
%
n
2

2 2 )
)1 H )1 H +
Anitial moles / 2 % 8
moles at equil / 26+ %7+ 8
At equilibrium /
2
2
1
1 H
n
% +
2
n
2 +
+

1ence + 5 %
) )
C
# 2 % 2',
3. The dissociation constant for
C h 6 $ 1 6 $ 3 3 1
$ l
and 1$0 at 2'K are %.' S %&
6'
and
4.' S %&
63
respectivelI the equilibrium constant for
$ 0 7 C h 6 $ 1 6 $ 3 3 1
$ l
1 $ 0 7 C h 6 $ 1 6 $ 3 3
$ l
6
" o u l d b e
6

(A) 3 S %&
2
(B) 3 S %&
62
($) 3.33 S %&
63
(() ,.-' S %&
6-
Key: C
2:l:
3. ($)
C h 6 $ 1 6 $ 3 3 1
$ l
C h 6 $ 1 6 $ 3 3
$ l
6
7 1 I % . ' S % & . . . ( i )
6 '
6
I 4 . ' S % & . . . ( i i )
6 3
1 $ 0
1 7 $ 0
7
$ 0 7 1
6
7
1 $ 0 I 4 . ' S % & . . . ( i i i )
6 3
%
C h 6 $ 1 6 $ 3 3 1
$ l
C h 6 $ 1 6 $ 3 3
$ l
6
7 $ 0
6
7 1 $ 0 I 9 5 9 S 9
% 2
A d d i n * ( i ) a n d ( i i i )
7
' 3
3
%
%.' %& 3.3 %&
4.' %&

32