p.

1
0
3
0
He a lt h
Fire
Re a c t iv it y
Pe rs o na l
Pro t e c t io n
3
0
0
Material Safety Data Sheet
Sodium Hypochlorite, 12% MSDS
Section 1: Chemical Product and Company Identification
Product Name: Sodium Hypochlorite, 12%
Catalog Codes: SLS3076
CAS#: Mixture.
RTECS: Not applicable.
TSCA: TSCA 8(b) inventory: Sodium hypochlorite; Water
CI#: Not applicable.
Synonym: Chlorine Bleach, Soda Bleach; Sodium
Hypochlorite, Solution, 12% Available Chlorine.
Chemical Name: Not applicable.
Chemical Formula: Not applicable.
Contact Information:
Sciencelab.com, Inc.
14025 Smith Rd.
Houston, Texas 77396
US Sales: 1-800-901-7247
International Sales: 1-281-441-4400
Order Online: ScienceLab.com
CHEMTREC (24HR Emergency Telephone), call:
1-800-424-9300
International CHEMTREC, call: 1-703-527-3887
For non-emergency assistance, call: 1-281-441-4400
Section 2: Composition and Information on Ingredients
Composition:
Name CAS # % by Weight
Sodium hypochlorite 7681-52-9 12-14
Sodium hydroxide 1310-73-2 1
Water 7732-18-5 85-87
Toxicological Data on Ingredients: Sodium hypochlorite: ORAL (LD50): Acute: 5800 mg/kg [Mouse]. 8910 mg/kg [Rat].
Sodium hydroxide LD50: Not available. LC50: Not available.
Section 3: Hazards Identification
Potential Acute Health Effects:
Very hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, . Hazardous in case of skin contact
(corrosive), of eye contact (corrosive). Slightly hazardous in case of inhalation (lung sensitizer). Non-corrosive for lungs. Liquid
or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract. Skin
contact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by
coughing, choking, or shortness of breath. Prolonged exposure may result in skin burns and ulcerations. Over-exposure by
inhalation may cause respiratory irritation. Inflammation of the eye is characterized by redness, watering, and itching. Skin
inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.
Potential Chronic Health Effects:
p. 2
Slightly hazardous in case of skin contact (sensitizer). CARCINOGENIC EFFECTS: Classified 3 (Not classifiable for human.)
by IARC [Sodium hypochlorite]. MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast. [Sodium hypochlorite].
Mutagenic for mammalian somatic cells. [Sodium hydroxide]. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL
TOXICITY: Not available. The substance may be toxic to lungs, mucous membranes, skin, eyes. Repeated or prolonged
exposure to the substance can produce target organs damage. Repeated or prolonged contact with spray mist may produce
chronic eye irritation and severe skin irritation. Repeated or prolonged exposure to spray mist may produce respiratory tract
irritation leading to frequent attacks of bronchial infection.
Section 4: First Aid Measures
Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Cold water may be used. Get medical attention immediately.
Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing
and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly clean
shoes before reuse. Get medical attention immediately.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention immediately.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If
breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek medical
attention.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.
Serious Ingestion: Not available.
Section 5: Fire and Explosion Data
Flammability of the Product: Non-flammable.
Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Not available.
Fire Hazards in Presence of Various Substances: combustible materials, organic materials, metals
Explosion Hazards in Presence of Various Substances:
Slightly explosive in presence of heat. Non-explosive in presence of open flames and sparks, of shocks.
Fire Fighting Media and Instructions: Not applicable.
Special Remarks on Fire Hazards:
Releases chlorine when heated above 35 deg. C. The substance itself is non-combustible and does not burn. However, when
heated to decomposition it emits corrosive and/or toxic fumes. May ignite combustibles. The heat of reaction with combustibles
or organic materials may cause igniton. It may be a fire risk in contact with organic materials. Contact with metals may evolve
flammable hydrogen gas.
Special Remarks on Explosion Hazards:
p. 3
Anydrous Sodium Hypochlorite is very explosive. Primary amines and calcium hypochlorite or sodium hypochlorite react
to form normal chloroamines, which are explosive. Interaction of ethyleneimine with sodium (or other) hypochlorite gives
the explosive N-chloro cmpd. Removal of formic acid from industrial waste streams with sodium hypochlorite soln becomes
explosive at 55 deg C. Several explosions involving methanol and sodium hypochlorite were attributed to formation of methyl
hypochlorite, especially in presence of acid or other esterification catalyst. Use of sodium hypochlorite soln to destroy acidified
benzyl cyanide residues caused a violent explosion, thought to have been due to formation of nitrogen trichloride. (Sodium
hypochlorite)
Section 6: Accidental Release Measures
Small Spill:
Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. If
necessary: Neutralize the residue with a dilute solution of acetic acid.
Large Spill:
Corrosive liquid. Oxidizing material. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material.
Do not get water inside container. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance
damp using water spray. Do not touch spilled material. Use water spray curtain to divert vapor drift. Prevent entry into sewers,
basements or confined areas; dike if needed. Call for assistance on disposal. Neutralize the residue with a dilute solution of
acetic acid.
Section 7: Handling and Storage
Precautions:
Keep locked up.. Keep container dry. Keep away from heat. Keep away from sources of ignition. Keep away from combustible
material.. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Never add water to this product. In case of insufficient
ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or
the label. Avoid contact with skin and eyes. Keep away from incompatibles such as reducing agents, combustible materials,
organic materials, metals, acids.
Storage:
Keep container tightly closed. Keep container in a cool, well-ventilated area. Separate from acids, alkalies, reducing agents
and combustibles. See NFPA 43A, Code for the Storage of Liquid and Solid Oxidizers. Do not store above 20C (68F). Air
Sensitive Sensitive to light. Store in light-resistant containers.
Section 8: Exposure Controls/Personal Protection
Engineering Controls:
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective
threshold limit value.
Personal Protection:
Face shield. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Boots.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits:
Sodium hypochlorite TWA: 1 CEIL: 1 (ppm as Cl2) STEL: 1 (ppm as Cl2) from ACGIH (TLV) [United States] Sodium hydroxide
STEL: 2 (mg/m3) from ACGIH (TLV) [United States] TWA: 2 CEIL: 2 (mg/m3) from OSHA (PEL) [United States] CEIL: 2 (mg/
m3) from NIOSH Consult local authorities for acceptable exposure limits.
Section 9: Physical and Chemical Properties
p. 4
Physical state and appearance: Liquid. (Clear Liquid.)
Odor: Characteristic. Chlorine-like (Strong.)
Taste: Not available.
Molecular Weight: Not applicable.
Color: Green to Yellowish. (Light.)
pH (1% soln/water): pH of 10% solution (100 g/l): 12 [Basic.]
Boiling Point: The lowest known value is 100C (212F) (Water).
Melting Point: Freezing pt: -3C (26.6F)
Critical Temperature: Not available.
Specific Gravity: 1.19 - 1.215 (Water = 1)
Vapor Pressure: 1.6 kPa (@ 20C)
Vapor Density: The highest known value is 0.62 (Air = 1) (Water).
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water.
Solubility: Easily soluble in cold water, hot water.
Section 10: Stability and Reactivity Data
Stability: The product is stable.
Instability Temperature: Not available.
Conditions of Instability: Incompatible materials, light, air, heat
Incompatibility with various substances: Slightly reactive to reactive with reducing agents, combustible materials, organic
materials, metals, acids.
Corrosivity:
Extremely corrosive in presence of aluminum. Moderately corrosive in presence of stainless steel(304), of stainless steel(316).
Non-corrosive in presence of glass.
Special Remarks on Reactivity:
Decomposed by carbon dioxide from air. Slowly decomposes on contact with air. Unstable in air unless mixed with sodium
hydroxide. Incompatible with ammonium acetate, ammonium carbonate, ammonium nitrate, ammonium oxalate, and
ammonium phosphate. Decompostion of sodium hypochlorite takes place within a few seconds with these salts. Also
incompatible with primary amines, phenyl acetonitrile, ethyleneimine, methanol, acidified benzyl cyanide, formic acid,
urea, nitro compounds, methylscellulose, celloluse, aziridine, ether, ammonia. Mixing this product with chemicals (e.g.
ammonia, acids, detergents, etc.) or organic matter (e.g. urine, feces, etc.) will release chlorine gas. Chloramine gas may be
evolved when ammonia and bleach are mixed. Decomposed by hot water. Sensitive to light. Exposure to light accelerates
decompositon.
Special Remarks on Corrosivity:
Sodium Hypochlorite is extremely corrosive to brass, and moderately corrosive to bronze. There is no corrosivity information
for copper.
Polymerization: Will not occur.
p. 5
Section 11: Toxicological Information
Routes of Entry: Absorbed through skin. Eye contact. Inhalation. Ingestion.
Toxicity to Animals: Acute oral toxicity (LD50): 5800 mg/kg [Mouse]. (Sodium hypochlorite).
Chronic Effects on Humans:
CARCINOGENIC EFFECTS: Classified 3 (Not classifiable for human.) by IARC [Sodium hypochlorite]. MUTAGENIC
EFFECTS: Mutagenic for bacteria and/or yeast. [Sodium hypochlorite]. Contains material which may cause damage to the
following organs: lungs, mucous membranes, skin, eyes.
Other Toxic Effects on Humans:
Very hazardous in case of skin contact (irritant), of ingestion, . Hazardous in case of skin contact (corrosive), of eye contact
(corrosive), of inhalation (lung corrosive).
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans: May affect genetic material (mutagenic) (Sodium hypochlorite)
Special Remarks on other Toxic Effects on Humans:
Potential Health Effects: May cause severe irritation and burns to skin and eyes. Contact with skin may also cause vesicular
eruptions and eczematoid dermatitis which becomes evident upon re-exposure. Prolonged or repeated eye contact may cause
conjunctivitis. Ingestion causes burns to the digestive tract. Symptoms may include: 1. pain and inflammation of the mouth,
pharynx, esophagus, and stomach, 2. erosion of the mucous membranes (chiefly of the stomach), nausea, vomiting, choking,
coughing, hemorrhage, 3. circulatory collapse with cold and clammy skin (due to methemoglobinemia), cyanosis, and shallow
respirations, 4. confusion, delirium, coma, 5. edema of the pharynx, glottis, larynx with stridor and obstruction, 6. perforation of
the esophagus, or stomach, with mediastinitis or peritonitis. Inhalation causes severe respiratory tract irritation and pulmonary
edema. Prolonged or repeated inhalation may cause allergic respiratory reaction (asthma). (Sodium hypochlorite)
Section 12: Ecological Information
Ecotoxicity: It is toxic to fish and aquatic organisms.
BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.
Special Remarks on the Products of Biodegradation: Not available.
Section 13: Disposal Considerations
Waste Disposal:
Do not discharge effluent containing this product into laks, streams, ponds, estuaries, oceans, or public waters unless this
product is specifically identified and addressed in an NPDES permit. Do not discharge effluent containing this product without
previously notifying the sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office of
the EPA. Reduce with agents such as bisulfites or ferrous salt solutions. Some heat will be produced. Keep on alkaline side
and dilute with copious amounts of water. The main end-product is salt water. Waste must be disposed of in accordance with
federal, state and local environmental control regulations.
Section 14: Transport Information
DOT Classification: Class 8: Corrosive material
Identification: : Hypochlorite solution UNNA: 1791 PG: III
Special Provisions for Transport: Not available.
p. 6
Section 15: Other Regulatory Information
Federal and State Regulations:
Pennsylvania RTK: Sodium hypochlorite Florida: Sodium hypochlorite Minnesota: Sodium hypochlorite Massachusetts
RTK: Sodium hypochlorite New Jersey: Sodium hypochlorite TSCA 8(b) inventory: Sodium hypochlorite; Water CERCLA:
Hazardous substances.: Sodium hypochlorite: 100 lbs. (45.36 kg);
Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
Other Classifications:
WHMIS (Canada):
CLASS C: Oxidizing material. CLASS E: Corrosive liquid.
DSCL (EEC):
R8- Contact with combustible material may cause fire. R31- Contact with acids liberates toxic gas. R34- Causes burns. S26- In
case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28- After contact with skin, wash
immediately with plenty of water. S36/37/39- Wear suitable protective clothing, gloves and eye/face protection. S45- In case of
accident or if you feel unwell, seek medical advice immediately (show the label where possible).
HMIS (U.S.A.):
Health Hazard: 3
Fire Hazard: 0
Reactivity: 0
Personal Protection:
National Fire Protection Association (U.S.A.):
Health: 3
Flammability: 0
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator
when ventilation is inadequate. Face shield.
Section 16: Other Information
References: Not available.
Other Special Considerations: Not available.
Created: 10/09/2005 06:32 PM
Last Updated: 05/21/2013 12:00 PM
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for
lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com
has been advised of the possibility of such damages.