Page 1/5

Material Safety Data Sheet

According to 91/155 EC
Printing date 17.09.2001 Reviewed on 17.09.2001
DR
1 I dentification of substance:
Product details:
Trade name: CF-I 750 B2; CF-F 750(600/400) B2
Manufacturer/Supplier:
Hilti (Gt. Britain) Ltd. / 1 Trafford Wharf Road
Trafford Park / GB- Manchester M17 1By
I nforming department: see section 16
Emergency information:
Tel.: 0800 886 100
Fax.: 0800 886 200
2 Composition/Data on components:
Chemical characterization
Description: Urethane prepolymer with propellant liquified under pressure, containing no CFC
Dangerous components:
101-68-8 diphenylmethane-4,4'-di-isocyanante
!"#
Xn; 20-36/37/38-42/43 2.5-10%
106-97-8 butane, pure
!"$
F+; 12 2.5-10%
115-10-6 dimethyl ether
!"$
F+; 12 2.5-10%
3 Hazards identification
Hazard designation:
!"#!"$
Xn Harmful
F+ Extremely flammable
I nformation pertaining to particular dangers for man and environment
R 12 Extremely flammable.
R 36/37/38 Irritating to eyes, respiratory system and skin.
R 42/43 May cause sensitization by inhalation and skin contact.
Contains isocyanates. See information supplied by the manufacturer.
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50C, i.e. electric
lights. Do not pierce or burn, even after use.
Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No
smoking.
Classification system
The classification is in line with current EC lists. It is expanded, however, by information from technical
literature and by information furnished by supplier companies.
4 First aid measures
After inhalationSupply fresh air; consult doctor in case of symptoms.
After skin contact
Treat affected skin portions with cotton wool or cellulose. Then wash and rinse thoroughly with water and a
mild cleaning agent.
After eye contact Rinse opened eye for several minutes under running water. Then consult doctor.
After swallowingDo not induce vomiting; instantly call for medical help.
I nformation for doctor
The following symptoms may occur: Allergic reactions
5 Fire fighting measures
Suitable extinguishing agents
CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam.
For safety reasons unsuitable extinguishing agentsWater with a full water jet.
(Contd. on page 2)
GB
Page 2/5
Material Safety Data Sheet
According to 91/155 EC
Printing date 17.09.2001 Reviewed on 17.09.2001
Trade name: CF-I 750 B2; CF-F 750(600/400) B2
(Contd. of page 1)
DR
Special hazards caused by the material, its products of combustion or resulting gases:
Can be released in case of fire
Carbon monoxide (CO)
Hydrogen chloride (HCl)
Hydrogen fluoride (HF)
Hydrogen cyanide (HCN)
Protective equipment: Wear self-contained breathing apparatus.
Additional informationCool endangered containers with water spray jet.
6 Accidental release measures
Person-related safety precautions:
Ensure adequate ventilation
Wear protective clothing.
Measures for environmental protection: Do not allow product to reach sewage system or water bodies.
Measures for cleaning/collecting:
Allow to solidify. Collect mechanically.
Dispose of contaminated material as waste according to item 13.
7 Handling and storage
Handling
I nformation for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Ensure good interior ventilation, especially at floor level. (Fumes are heavier than air).
Keep away from heat and direct sunlight.
Danger of bursting!
I nformation about protection against explosions and fires:
Beware: Container is pressurized. Keep away from direct sun exposure and temperatures over 50C. Do not
open by force or throw into fire even after use.
Do not spray on flames or red-hot objects.
Keep ignition sources away - Do not smoke.
Storage
Requirements to be met by storerooms and containers:
Keep containers securely closed and dry, store at 5 - 25C.
Observe official regulations on storing packagings with pressurized containers.
I nformation about storage in one common storage facility:
Store away from foodstuffs.
Store away from flammable substances.
Further information about storage conditions: Protect from heat and direct sunlight.
Storage classAs per VCI (1991) storage classification concept.
Class according to regulation on inflammable liquids: Void
8 Exposure controls and personal protection
Additional information about design of technical systems: No further data; see item 7.
Components with limit values that require monitoring at the workplace:
101-68-8diphenylmethane-4,4'-di-isocyanante
MEL Short-term value: 0.07 mg/m
Long-term value: 0.02 mg/m
Sen; as -NCO
115-10-6dimethyl ether
OES Short-term value: 958 mg/m, 500 ppm
Long-term value: 766 mg/m, 400 ppm
(Contd. on page 3)
GB
Page 3/5
Material Safety Data Sheet
According to 91/155 EC
Printing date 17.09.2001 Reviewed on 17.09.2001
Trade name: CF-I 750 B2; CF-F 750(600/400) B2
(Contd. of page 2)
DR
106-97-8butane, pure
OES Short-term value: 1810 mg/m, 750 ppm
Long-term value: 1450 mg/m, 600 ppm
Additional information: The lists that were valid during the compilation were used as basis.
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures should be adhered to general rules for handling chemicals.
Wash hands during breaks and at the end of the work.
Avoid contact with the eyes and skin.
Do not eat, drink or smoke while working.
Breathing equipment:
Use breathing protection in case of insufficient ventilation.
Filter B.
Protection of hands: PVC gloves
Eye protection: Safety glasses
Body protection: Protective work clothing.
9 Physical and chemical properties:
Form: Container under gas pressure
Colour: Light yellow
Odour: Characteristic
Change in condition
Melting point/Melting range: Not determined
Flash point: Not applicable, as aerosol
I gnition temperature: 230C
Decomposition temperature: 100C
Self-inflammability: Product is not selfigniting.
Danger of explosion: In use, may form flammable/explosive vapour-air mixture.
Critical values for explosion:
Lower: 1.5 Vol %
Upper: 18.6 Vol %
Vapour pressure at 20C: 5.5-6 bar
Density at 20C 0.9-1.1 g/cm3
Solubility in / Miscibility with
Water: Unsoluble
10Stability and reactivity
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
Dangerous reactions
Reacts with alcohols, amines, aqueous acids and alkalis
With water (moisture): CO2 is produced; pressure may build up inside closed containers (danger of bursting)
Dangerous products of decomposition: none, if stored and handled correctly.
11Toxicological information
Acute toxicity:
Primary irritant effect:
on the skin: Irritant to skin and mucous membranes.
on the eye: Irritant effect.
(Contd. on page 4)
GB
Page 4/5
Material Safety Data Sheet
According to 91/155 EC
Printing date 17.09.2001 Reviewed on 17.09.2001
Trade name: CF-I 750 B2; CF-F 750(600/400) B2
(Contd. of page 3)
DR
Sensitization:
Sensitization possible by inhalation.
Sensitization possible by skin contact.
Hypersensitve persons may react at very low concentrations of isocyanate.
Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EC
Classification Guidelines for Preparations as issued in the latest version:
Harmful
12Ecological information:
General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage
system.
Not water polluting as a prepolymer in a cured state.
The product reacts with water releasing CO2, to form a solid, insoluble polycarbamide with a high melting
point which, according to present knowledge, is inert and not degradeable.
13Disposal considerations
Product:
RecommendationFor disposal, local regulations issued by the authorities must be observed.
European waste catalogue
08 04 04 hardened adhesives and sealants
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.
14Transport information
Land transport ADR/RI D (cross-border)
ADR/RI D-GGVS/E Class: 2 Gases.
Number/Letter: 5f
UN-Number: 1950
Designation of goods: Pressurised container
1950 Aerosols
Maritime transport I MDG:
I MDG Class: 2
Page: 2102
UN Number: 1950
Packaging group: II
EMS Number: 2-13
MFAG: 620
Marine pollutant: No
Correct technical name: Aerosols
Air transport I CAO-TI and I ATA-DGR:
I CAO/I ATA Class: 2.1
UN/I D Number: 1950
Correct technical name: Aerosols, flammable
Transport/Additional information: Container is pressurised.
GB
(Contd. on page 5)
Page 5/5
Material Safety Data Sheet
According to 91/155 EC
Printing date 17.09.2001 Reviewed on 17.09.2001
Trade name: CF-I 750 B2; CF-F 750(600/400) B2
(Contd. of page 4)
DR
15Regulatory information
Designation according to EC guidelines:
The product has been classified and labelled in accordance with EC Directives / Ordinance on Hazardous
Materials (GefStoffV)
Code letter and hazard designation of product:
Xn Harmful
F+ Extremely flammable
Risk phrases:
12 Extremely flammable.
36/37/38 Irritating to eyes, respiratory system and skin.
42/43 May cause sensitization by inhalation and skin contact.
Safety phrases:
2 Keep out of the reach of children.
23 Do not breathe aerosol.
25 Avoid contact with eyes.
36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where
possible).
51 Use only in well-ventilated areas.
Special designation of certain preparations:
Contains isocyanates. See information supplied by the manufacturer.
Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50C, i.e. electric
lights. Do not pierce or burn, even after use.
Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No
smoking.
National regulations
Classification according to VbF: Void
Technical instructions (air):
Class Share in %
III 10-25
Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.
16Other information:
These data are based on our present knowledge. However, they shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Changes made since last issue dated - at the following points: *
Department issuing data specification sheet:
Hilti Corp.
BU Chemicals (HEG II)
Quality/Safety/Environment
Hiltistrasse 26
D-86916 Kaufering
Tel: +49 8191 90 6494
Fax: +49 8191 90 6360
Contact: Michael Kaindl
GB