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Miranda 20C
9- Heat of Formation of NaCl September 16, 2013
ABSTRACT
The universe is divided into two parts called the system and the surroundings in
which the exchange of energy occurs during a chemical reaction. Whenever a chemical
reaction takes place, heat changes occur with it and these heat changes are measured in
the branch of chemistry called thermochemistry.
The objective of the experiment is to measure the enthalpy of neutralization for
the reaction of the strong base, NaOH, and the strong acid, HCl, and also the heat of
formation of NaCl
(s)
.
For the first part of the experiment in which the enthalpy of the neutralization of
NaOH and HCl is unknown, the acid and base were mixed in a coffee cup calorimeter
which was used to trap the heat from leaking out from the system and into the
surroundings before taking note of the temperature changes and the mass of the solution.
In the second part of the experiment, temperature changes and the mass of the solution
were also recorded when solid NaCl was dissolved in water.
Using the formula to determine H, the value for the heat of reaction in Part A of
the experiment is -52.45 kJ/mol. For the second part, the calculated heat of reaction is
4.09 kJ/mol. With the use of Hesss law the heat of formation of NaCl
(s)
was also derived.
The calculated H
o
f
of
NaCl
(s)
in this experiment is -412.41 kJ/mol.
Therefore, with the use of the experiment, the formula for calculating H, and
Hesss law, the heats of reactions of NaOH
(aq)+
HCl
(aq)
NaCl
(aq)
+H
2
O
(l)
and
NaCl
(aq)
NaCl
(s),
and the heat of formation of NaCl
(s)
were derived.
INTRODUCTION
Thermochemistry measures the heat changes that accompany chemical reactions. The
universe is divided into two: the system, the part to be studied, and the rest, the surroundings.
A system can release (exothermic) or absorb (endothermic) heat to its surroundings. In an
isolated reaction, energy exchange is prevented. To calculate the heat generated per mole of
reactant or product, the formula: -m
solution
cT is used.
In this experiment, the heats of reactions of NaOH
(aq)+
HCl
(aq)
NaCl
(aq)
+H
2
O
(l),
NaCl
(aq)
NaCl
(s),
and the given equations are used to determine the H
o
f
of NaCl
(s)
using
Hesss Law. The sum of all equations should be:
Na
(s)
+
Cl
2(g)
NaCl
(s)
H
o
f
= ?
METHODS
First, 75 mL of 1 M HCl and 75 mL of 1 M NaOH were mixed in a coffee cup calorimeter.
Next, 4.38 g of NaCl
(s)
was dissolved in 150 mL water. Initial and final masses and
temperatures of individual and combined solutions were recorded using a balance and
thermometer.
RESULTS
Table 1. Heats of Reactions in Part A
Part A H
Trial 1 -47.7 kJ/mol
Trial 2 -57.2 kJ/mol
Average Enthalpy -52.45 kJ/mol
Table 2. Heats of Reactions in Part B
Part A H
Trial 1 4.10 kJ/mol
Trial 2 4.07 kJ/mol
Average Enthalpy 4.09 kJ/mol
Table 3. Given Set of Equations and the Heat of Formation of NaCl
(s)
(1) Na
(s)
+ O
2(g)
+ H
2(g)
NaOH
(s)
H= -426.73 kJ/mol
(2) NaOH
(s)
NaOH
(aq)
H= -44.505 kJ/mol
(3) H
2(g)
+ Cl
2(g)
HCl
(g)
H= -92.30 kJ/mol
(4) HCl
(g)
HCl
(aq)
H= -74.843 kJ/mol
(5) NaOH
(aq) +
HCl
(aq)
NaCl
(aq)
+ H
2
O
(l)
H= -52.45 kJ/mol
(6) NaCl
(aq)
NaCl
(s)
H= -4.09 kJ/mol
(7) H
2
O
(l)
H
2
O
(g)
H= +40.668 kJ/mol
(8) H
2
O
(g)
O
2(g)
+ H
2(g)
H= +241.84 kJ/mol
(9) Na
(s)
+ Cl
2
NaCl
(s)
H= -412.41 kJ/mol
*The value of H for equation (6), NaCl
(aq)
NaCl
(s),
became negative because the
reverse reaction from Part B is used so that it will be possible for the substances to be
cancelled.
DISCUSSION
In Part A of the experiment, HCl and NaOH were mixed and the initial and final masses
and temperatures were recorded. Using the formula H=
)
. C . C
(5) Maximum Temperature of Combined
Solution
. C . C
(6) Mass of Combined Solutions 268.93 g 270.07 g
(7) Mass of Solution Only ( (6) (1) ) 150.08 g 150.87 g
Trial 1
H=
x
m= 150.08 g
c= . g C
T= . C - 28.8 C= . C -. C because reaction is exothermic
Mol= MV = (1M) (0.075 L) = 0.075 mol
H=
( )( )( )
x
= -47.7 kJ/mol
Trial 2
H=
x
m= 150.87 g
c= . g C
T= . C - 28.2 C= 6. C -6. C because reaction is exothermic
Mol= MV = (1M) (0.075 L) = 0.075 mol
H=
( )( )( )
x
= -57.2 kJ/mol
Average Enthalpy=
= -52.45 kJ/mol
Part B
Raw Data Table
Trial 1 Trial 2
(1)Empty calorimeter mass 119.29 g 119.37 g
(2) Mass of water (150 mL) 266.28 g 265.27 g
(3) Mass of water only ( (2)-(1) ) 146.99 g 145.90 g
(4) Water temperature . C . C
(5) Lowest Temperature after
Dissolution
. C . C
Trial 1
H=
x
m= 146.99 g
c= . g C
T= . C - . C= -. C . C because reaction is endothermic
Mol= 4.38 g NaCl x
= 0.075 mol
H=
( )( )( )
x
= 4.10 kJ/mol
Trial 2
H=
x
m= 145.90 g
c= . g C
T= . C - . C = -. C . C because reaction is endothermic
Mol= 4.38 g NaCl x
= 0.075 mol
H=
( )( )( )
x
= 4.07 kJ/mol
Average Enthalpy=
= 4.09 kJ/mol
Solving for the Heat of Formation of NaCl
(s)
Using Hesss Law
(1) Na
(s)
+ O
2(g)
+ H
2(g)
NaOH
(s)
H= -426.73 kJ/mol
(2) NaOH
(s)
NaOH
(aq)
H= -44.505 kJ/mol
(3) H
2(g)
+ Cl
2(g)
HCl
(g)
H= -92.30 kJ/mol
(4) HCl
(g)
HCl
(aq)
H= -74.843 kJ/mol
(5) NaOH
(aq) +
HCl
(aq)
NaCl
(aq)
+ H
2
O
(l)
H= -52.45 kJ/mol
(6) NaCl
(aq)
NaCl
(s)
H= -4.09 kJ/mol
(7) H
2
O
(l)
H
2
O
(g)
H= +40.668 kJ/mol
(8) H
2
O
(g)
O
2(g)
+ H
2(g)
H= +241.84 kJ/mol
(9) Na
(s)
+ Cl
2
NaCl
(s)
H= -412.41 kJ/mol
Na
(s)
+ O
2(g)
+ H
2(g)
+ NaOH
(s)
+ H
2(g)
+ Cl
2(g)
+ HCl
(g)
+ NaOH
(aq) +
HCl
(aq)
+
NaCl
(aq)
+ H
2
O
(l)
+ H
2
O
(g)
NaOH
(s)
+ NaOH
(aq)
+ HCl
(g)
+ HCl
(aq)
+ NaCl
(aq)
+ H
2
O
(l)
+
NaCl
(s)
+ H
2
O
(g)
+ O
2(g)
+ H
2(g) =
Na(s) + Cl2 NaCl(s) H
o
f
= -412.41 kJ/mol
*The value of H for equation (6), NaCl
(aq)
NaCl
(s)
,
became negative because the
reverse reaction from Part B is used so that it will be possible for the substances to be
cancelled.
CONLUSION
The heats of reactions of the equations NaOH
(aq)+
HCl
(aq)
NaCl
(aq)
+H
2
O
(l)
and
NaCl
(aq)
NaCl
(s)
were determined using the formula H=