Documenti di Didattica
Documenti di Professioni
Documenti di Cultura
SCF
2
/1.20
In &hich<
dp = a {(Q + Q ) /
2}
b
/1."0
*
S
> s-ecific flu4 at o-erating conditions>
In &hich a and 1 are coefficients> s-ecific
for element and feed s-acer configuration.
,he 3alues for these coefficients are o1tained
e4-erimentally.
!"'"% Solute 2rans3ort
Solute trans-ort through an RO mem1rane
is e4-ressed as a solute flu4. ,his solute flu4
is -ro-ortional to the concentration difference
across the mem1rane. ,he a3erage feed
concentration /feed and concentrate0 is used
in the feed side to calculate solute trans-ort.
*nd the rate of solute trans-ort is defined 1y
re;ection or salt -assage as follo&s<
*
n
> s-ecific flu4 at nominal conditions
S$
S
> salt -assage at o-erating conditions>
S$
n
> salt -assage at nominal conditions
/F
7
0
n
> -ermeate flu4 at o-erating
conditions> /F
7
0
n
> -ermeate flu4 at nominal
conditions
,C'> correlation factor of tem-erature /1=
on s-ecific flu4> = on salt -assage0
SC'> correlation factor of feed
concentration /1= on s-ecific flu4> = on salt
-assage0
''> fouling factor
J
S
= B (C
fave
C
p
)
R = 1 (C
p
/ C
fave
)
SP = 1 R = C
p
/ C
fave
In &hich<
/1.#0
/1.%0
/1.)0
In com-uter -rogramming> estimated
-erformance 1ased on the nominal 3alue is
automatically calculated 1y using a1o3e
e+uations.
!"( RO System Design
Guidelines
F
S
> solute flu4> B> solute -ermea1ility> R>
re;ection> S$> salt -assage
Re;ection and salt -assage are usually
e4-ressed as -ercent.
!"'"' 1orrelation of O3erating
1onditions
RO mem1rane system -erformance /flu4
and re;ection or salt -assage0 is influenced 1y
o-erating conditions such as o-erating
-ressure> tem-erature> feed concentration etc.
So the -arameters of RO -erformance
/s-ecific flu4 and salt -assage0 are re3ised 1y
!"("! -ouling 2enden#y ,ith
O3erating 1onditions
,he factor &hich has the greatest influence
on the RO system design guideline is the
fouling tendency of the feed &ater. Mem1rane
fouling is caused 1y -articles and colloidal
materials &hich are -resent in the feed &ater
and 1ecome concentrated at the mem1rane
surface. ,he Silt Density Inde4 /SDI0 of
-retreated feed &ater is an inde4 of the fouling
-otential of -article or colloidal materials in the
RO system. ,he concentration of the fouling
materials at the mem1rane surface increases
&ith increasing -ermeate flu4> increasing
f c
element reco3ery and decreasing concentrate
flo& rate. ,herefore the a3erage -ermeate flu4
of the RO system /total -roduct flo& rate
di3ided 1y total mem1rane area0 should 1e
lo& if a strong fouling en3ironment is
antici-ated.
!"("% Re#ommended Range of
Element O3erating
1onditions 4Design
Guideline5
,he RO mem1rane system should 1e
designed such that each element of the
system o-erates &ithin the recommended
o-erating conditions to minimize the fouling
-ossi1ility> and to e4clude mechanical
damage. ,he limiting conditions are the
ma4imum reco3ery /system and element0> the
ma4imum a3erage -ermeate flu4> the
minimum concentrate flo& rate> the ma4imum
feed flo& rate> the ma4imum lead element
-ermeate flu4> and so on. ,he higher the
fouling tendency of the feed &ater> the limits
of the -arameters 1ecome stricter.
,a1le 1. sho&s the range of these
-arameters according to the ty-e of the feed
&ater and the ty-e of -retreatment. ,he
mem1rane -retreatment im-ro3es the feed
&ater +uality in 3ie& of the fouling. In the ta1le
the -arameter of mem1rane -erformance
changes &ith time is added /flu4 decline rate
and salt -assage increase0.
,he range of -arameters sho&n in the
ta1le is recommended 3alue to minimize the
fouling -ossi1ility> 1ut it does not mean that
the system design out of the -arameter range
is im-ossi1le. It means that the -ossi1ility of
the fouling 1ecomes higher.
Lead
Element
*ermeate
-lu
Average
*ermeate
-lu
1on#en&
trate -lo,
Rate
*ressure
Dro3 3er
6essel
Element
Re#overy
Rate
-lu
De#line
Rate
Salt
*assage
In#rease
-eed .ater
2y3e
-eed -lo,
Rate
Munici-al
Su--ly
/12!#0
D 3 I 3.% D 13 D .6 D 1# I 16 I 16
BracBish (ells
2
/#!330
D "3 I 3.6 D 1% D 3.6 D 6 I ) I 16
Surface (ater
Media 'iltration
1
/18!"0
D 31 I 3.% D 13 D .6 D 1# I 16 I 16
Surface (ater
M'?C'
'iltration
)
/3!20
D 32 I 3.6 D 1# D 3.6 D 1) I ) I 16
Secondary
(aste
Media 'iltration
11
/2!130
D 12 I 3.% D 1 D .6 D 1 I 1# I 1#
Secondary
(aste
M'?C'
'iltration
1)
/13!60
D # I 3.% D 13 D .6 D 13 I 1# I 16
Sea&ater
IntaBe
Media 'iltration
1"
/1!1%0
D 8 I 3.% D 1" D .6 D 16 I 16 I 16
Sea&ater
IntaBe
M'?C'
'iltration
1)
/1#!120
D 3 I 3.% D 1" D 3.6 D 1 I 16 I 16
Sea&ater
Beach (ells
1)
/1#!120
D 3# I 3.% D 1# D 3.6 D 1 I ) I 16
RO $ermeate
3#
/36!320
D "8 I ." D 1) D 3.6 D 36 I 3 I #
,a1le 1.< RO system design guideline
8
9
!") Ste3s to design RO
gi3en. ,he 9*5@ESS recommended design
:
membrane system
flu4 3alues for 9e&a1rane RO mem1rane
!")"! System Design Information
and -eed .ater
,he RO mem1rane system highly de-ends
on the a3aila1le feed &ater. ,herefore> the
system design information /customer?OEM>
re+uired -roduct flo& rate> e4-ected reco3ery
rate> annual &ater tem-erature> &ater source>
a--lication> -retreatment> re+uired -roduct
&ater +uality> o-erating -ressure limit> etc.0
and the feed &ater analysis should 1e
thoroughly studied and considered in selection
elements are listed in ,a1le 1.. In some
cases> the design flu4 3alue is determined 1y
-ilot e4-eriment data or customerJs
e4-erience.
!")"' 1al#ulation of Number of
2otal RO Elements
,he relationshi- 1et&een the num1er of
total elements> the -roduct flo& rate and the
a3erage -ermeate flu4 is e4-ressed as follo&
e+uation<
of the RO system design. If the re+uired
-ermeate &ater +uality is so high that the
+uality cannot 1e achie3ed 1y 1-ass RO
system> and then a -ass RO system should
1e considered. *s an alternati3e to the -ass
RO> an ion e4change resin system may also
1e a 3ia1le design o-tion.
!")"% Sele#tion of Element 2y3e
N
E
=Q
p
/ J
V ,ave
(M
A
)
E
In &hich<
5
E
K total element num1ers
H
-
K -roduct flo& rate
F
7> a3e
K a3erage -ermeate flu4
/3.160
and Average *ermeate -lu
*ccording to the feed &ater source>
-retreatment and feed &ater salinity> the ty-e
of RO mem1rane element is selected. ,he
relationshi- 1et&een the feed salinity and
general selection of RO element is sho&n in
,a1le 1.3. In the case that the RO feed &ater
is a &aste&ater> the lo& fouling RO element
may 1e also 1e considered.
/M
*
0
E
K mem1rane area of element /as
sho&n in data sheet0
,he calculated num1er of RO elements
may 1e a slightly changed 1ased on the
decision of element arrangement> that is> the
num1er of -ressure 3essels and RO elements
-er -ressure 3essel.
!")"( De#ision of Re#overy Rate
9o& conc. BracBish &ater
/u- to #66mg?l0
BracBish &ater /u- to
< B(RO /9o& energy0
In an RO mem1rane system> a reco3ery
rate as high as -ossi1le is desira1le> 1ut a
high reco3ery rate can also cause some
#>666 mg?l0
< B(RO /Standard0
BracBish &ater /more
-ro1lems as follo&s<
than #>666 mg?l0>
Sea&ater
< S(RO
$ossi1ility of scale formation increase
1ecause of the increase of
concentration factor
,a1le 1.3< Selection of RO element according to the
feed salinity
Once the &ater source> -retreatment and
RO element ty-e are fi4ed 1y the designer>
the recommended 3alue of the a3erage
-ermeate flu4 /also called Ldesign flu4M0 is
Osmotic -ressure increase 1ecause of
the increase of concentration factor
Concentrate flo& rate decrease
$ermeate &ater +uality deterioration
1ecause of a3erage feed
concentration increase
Re#overy Rate 1on#entration -a#tor
10
#6A
)#A "
86A #
26A 16
,a1le 1."< Relationshi- 1et&een Reco3ery Rate and
Concentration 'actor
,he relationshi- 1et&een reco3ery rate
and concentration factor is sho&n in ,a1le
1.".
Csually in 1racBish &ater desalination> the
reco3ery rate is decided 1y scale formation>
and in sea&ater desalination> 1y feed
-ressure limit. Some customers often re+uire
the highest -ossi1le reco3ery rate> 1ut in that
case> the 3alue of the reco3ery rate should 1e
decided 1y considering the -otential for the
a1o3e -ro1lems.
!")") De#ision of Number of
Stages
,he num1er of RO stages defines ho&
many -ressure 3essels are in series in the RO
mem1rane system. E3ery stage consists of a
certain num1er of -ressure 3essels in -arallel.
,he num1er of stages is a function of the
system reco3ery rate> the num1er of elements
-er 3essel> and the feed &ater +uality sho&n
in ,a1le 1.#.
!")"+ De#ision of Number of RO
Elements 3er *ressure
6essel
RO mem1rane elements can 1e cou-led
together in series in the -ressure 3essel>
ty-ically 1!8 elements -er one -ressure
3essel. In deciding the num1er of RO
elements -er -ressure 3essel> -lant size is
usually considered first. In a large!scale -lant
/I "6 m3?h0> %!8 elements -er -ressure 3essel
are usually ado-ted> and in a smaller -lant> 3!
# elements -er -ressure 3essel. In all cases>
the s-ace re+uired to install or remo3e the RO
elements should 1e considered in the -lant
design.
By increasing the num1er of RO elements
-er -ressure 3essel> almost all RO design
-arameters &ill change. RO design
-arameters are a3erage -ermeate flu4> lead
element -ermeate flu4> concentrate flo& rate>
feed flo& rate> indi3idual element reco3ery
rate> and -ressure dro- -er 3essel> etc.. Some
factors im-ro3e /1ecome desira1le0 and some
factors 1ecome &orse /undesira1le0. ,a1le
1.% sho&s RO system design -arameters and
the correlation 1et&een an increase in num1er
of RO element -er -ressure 3essel> and
change in RO system design -arameters. It is
recommended that these -arameters are in
accordance &ith the design guideline /,a1le
1.%0.
1 stage system< D #6A
Csual reco3ery S(RO /D #6A0
stage system< D )#!86A
Csual reco3ery B(RO /D 86A0
Eigh reco3ery S(RO /D %6A0
Eigh reco3ery nd -ass /D 26A0
3 stage system< D 8#!26A
Eigh reco3ery B(RO /D 26A0
Eigh reco3ery nd -ass /D 2#A0
/s-ecial case0
S(RO< sea&ater desalination> B(RO<
BracBish &ater desalination
,a1le 1.#< Relationshi- 1et&een reco3ery rate
and num1er of RO stage
RO System
Design *arameters
Effe#t of in#reasing number of
Elements76essel
8udgement of
the effe#t
*3erage $ermeate 'lu4 Same 5o change
9ead Element 'lu4 9arger Cndesira1le
Concentrate 'lo& Rate -er
7essel
9arger Desira1le
'eed 'lo& Rate -er 7essel 9arger Cndesira1le
$ressure Dro- -er 7essel 9arger Cndesira1le
$ressure Dro- -er Element 9arger Cndesira1le
Reco3ery Rate of Element Smaller Desira1le
Reco3ery Rate of System Same 5o change
5um1er of 7essel Smaller Desira1le
,a1le 1.%< Effects of changing the RO design
!")"/ De#ision of Element
Arrangement
,he RO element arrangement /array0
means element num1ers -er 3essel> 3essel
num1ers -er stage and stage num1ers -er
-ass. 'or the decision of element
arrangement> the system design -arameters
should 1e consistent &ith the design flu4
guideline. Eo&e3er> not all the -arameters are
suita1le to the guideline. In the case that not
e3ery -arameter is in accordance &ith the
design guideline> it is necessary to maBe a
-riority in the -arameters. Csually a3erage
-ermeate flu4> concentrate flo& rate and
-ressure dro- -er 3essel should 1e of higher
-riority.
,o decide the array> se3eral calculations
for case study should 1e done 1y com-uter
-rogram and these results should 1e
com-ared. Some case studies should 1e done
&ith the consideration of different o-erating
conditions /feed concentration> tem-erature>
etc.0 or -erformance changes &ith time. 'or
each ty-ical case> a com-arison should 1e
done in consideration of 3alue of design
-arameter> the num1ers of RO elements or
-ressure 3essel> and satisfying the customers
demand /-roduct &ater +uality> limit of feed
-ressure etc.0.
!")"9 Relations bet,een Nominal
*erforman#es and -ield
Results
,he relationshi- 1et&een nominal
-erformances /data sheet 3alues0 and actual
field results are as follo&s<
a0 (ith same mem1rane area and at the
same nominal test conditions> a higher
nominal flo& rate element &ill re+uire lo&er
feed -ressure.
10 *t different test conditions and ?or
different mem1rane area> feed -ressure &ill
1e defined 1y &ater -ermea1ility /s-ecific
flu40.
c0 (ith the same mem1rane area> the
same nominal test conditions> and the same
-ermeate flo& rate> a higher salt re;ection
element &ill -roduce a -ermeate of lo&er
salinity.
d0 *t different mem1rane area and? or
nominal test conditions> a lo&er relati3e salt
-assage element /multi-lier of nominal
-ermeate flu4 1y nominal salt -assage0 &ill
-roduce a -ermeate of lo&er salinity.
e0 ,he nominal -ermeate flu4 /catalogue
3alue0 is usually +uite large /large enough that
it &ill not cause mem1rane fouling0>
,herefore> the a3erage -ermeate flu4 in
actual field 1ecomes smaller than the nominal
-ermeate flu4.
!")": 1om3aring A#tual
*erforman#e of Le,abrane;
Elements to *ro<e#tion
*rogram
,he 9e&a$lus
,M
-ro;ection -rogram is a
tool used to estimate sta1ilized -erformance
for a s-ecific RO mem1rane system under
design or actual conditions. ,he -ro;ected RO
mem1rane system -erformance is 1ased on a
nominal -erformance s-ecification for the
9e&a1rane: elements used in the gi3en
system. * fouling factor of 1 in the -ro;ection
-rogram is used to calculate the -erformance
of ne& elements 1ased on the nominal flo&
rate /data sheet 3alue0. * fouling factor of D 1
should 1e used &hen maBing a design for
long!term o-eration.
In the actual RO mem1rane system> the
RO elements may ha3e a flo& rate 3ariation of
N?!1#A of the nominal 3alue> or &hate3er
3ariation is s-ecified for a gi3en element ty-e.
*lso> the salt re;ection of an indi3idual element
may 1e higher or lo&er than the nominal salt
re;ection /1ut more than the minimum 3alue0.
,herefore> the measured sta1ilized
-erformance is unliBely to 1e e4actly the same
as the com-uter -ro;ected -erformance> 1ut
as a rule of thum1> the com-uter -ro;ection for
RO systems &ith more than 3% ne& elements
should come close to the com-uter design
-ro;ection.
,he actual fouling factor of a sta1ilized ne&
RO system &ith at least 3% elements should
range 1et&een 6.2# and 1.6#. ,he actual
measured ,DS 3alue of -ermeate should 1e
no higher than a1out 1.# times the calculated
,DS 3alue. 'or RO mem1rane systems &ith
only one> or a fe& elements> the de3iation of
the measured actual -erformance from the
-ro;ected -erformance may 1ecome as large
as the s-ecified -erformance 3ariation.
DIS1LAIMER
Eealth and Safety Information< *--ro-riate
literature has 1een assem1led &hich -ro3ides
information concerning the health and safety
-recautions that must 1e o1ser3ed &hen
handling the 9*5@ESS -roducts mentioned in
this -u1lication. 'or materials mentioned
&hich are not 9*5@ESS -roducts> a--ro-riate
industrial hygiene and other safety
-recautions recommended 1y their
manufacturers should 1e follo&ed. Before
&orBing &ith any of these -roducts> you must
read and 1ecome familiar &ith the a3aila1le
information on their hazards> -ro-er use and
handling. ,his cannot 1e o3erem-hasized.
Information is a3aila1le in se3eral forms> e.g.>
material safety data sheets> -roduct
information and -roduct la1els. Consult your
9*5@ESS re-resentati3e in .ermany or
contact the Regulatory *ffairs and $roduct
Safety De-artment of 9*5@ESS Deutschland
.m1E or ! for 1usiness in the CS* ! the
9*5@ESS $roduct Safety and Regulatory
*ffairs De-artment in $itts1urgh> $*> CS*.
Regulatory Com-liance Information< Some
of the end uses of the -roducts descri1ed in
this -u1lication must com-ly &ith a--lica1le
regulations> such as the 'D*> BfR> 5S'>
CSD*> and C$SC. If you ha3e any +uestions
on the regulatory status of these -roducts>
contact ! for 1usiness in the CS* ! your
9*5@ESS Cor-oration re-resentati3e> the
9*5@ESS Regulatory *ffairs Manager in
$itts1urgh> $*> CS* or for 1usiness outside
CS the Regulatory *ffairs and $roduct Safety
De-artment of 9*5@ESS Deutschland .m1E
in .ermany.
,he manner in &hich you use and the
-ur-ose to &hich you -ut and utilize our
-roducts> technical assistance and information
/&hether 3er1al> &ritten or 1y &ay of
-roduction e3aluations0> including any
suggested formulations and recommendations
are 1eyond our control.
,herefore> it is im-erati3e that you test our
-roducts> technical assistance and information
to determine to your o&n satisfaction &hether
they are suita1le for your intended uses and
a--lications. ,his a--lication!s-ecific analysis
must at least include testing to determine
suita1ility from a technical as &ell as health>
safety> and en3ironmental stand-oint. Such
testing has not necessarily 1een done 1y us.
Cnless &e other&ise agree in &riting> all
-roducts are sold strictly -ursuant to the terms
of our standard conditions of sale. *ll
information and technical assistance is gi3en
&ithout &arranty or guarantee and is su1;ect
to change &ithout notice. It is e4-ressly
understood and agreed that you assume and
here1y e4-ressly release us from all lia1ility>
in tort> contract or other&ise> incurred in
connection &ith the use of our -roducts>
technical assistance> and information.
*ny statement or recommendation not
contained herein is unauthorized and shall not
1ind us. 5othing herein shall 1e construed as
a recommendation to use any -roduct in
conflict &ith -atents co3ering any material or
its use. 5o license is im-lied or in fact granted
under the claims of any -atent.
O 61 G *ll Rights Reser3ed
9*5@ESS Deutschland .m1E
1ON2A12
9*5@ESS Deutschland .m1E
Business Cnit Ion E4change Resins
Chem-arB 9e3erBusen
#13%2 9e3erBusen> .ermany
Email< l e & a1ra n e P l an 4 e s s .c o m
Edition= Octo1er 61