10.

1 Assessed HW Mark Scheme

1.1 Assessed Homework Mark Scheme
1. (a) Relative charge 1 (1)
Relative mass 1/1800 or 5.55 10
4
(1) 2
Accept zero / negligible
(b) (i) Protons = 24 (1)
(ii) Netrons = 28 (1)
(iii) Nee! (relative) abn!ance or "ea# height or intensit$ / amont / nmber / % /
&raction o& each element (1) '
Not: ratio o each isotope!
(c) (i) "eason 1: (o allo) "articles to be accelerate! / !e&lecte! / !etecte! or to
cont
"eason #: *harge! "articles or to generate a crrent in the !etector An$ #
(2)
Not: to allo% m/z to be meas&red!
(ii) +agnetic &iel! or electric &iel! or electromagnet (1)
(iii) ,e&lection !e"en!s on mass or m/- (1) 4
[9]
2. (a) Proton mass = 1 charge = .1 1
/lectron mass 1/1800 0r 5.1 2 10
4
charge = 1
'(o not accept )1 or proton mass or g! &nits* 1
(b) (i) 1' 1
(ii) 3i 1
+ass nmber = 28 and atomic nmber = 14 1
'(o not accept #+.1 or #+.0 or Silicon!*
(c) +ean (average) mass o& an atom / all the isoto"es 1
1/12
th
mass o& atom o&
12
* 1
0r +ass o& 1 mole o& atoms o& an element (1)
1/12
th
mass o& 1 mole o&
12
* (1)
0r 4verage mass o& an atom / all the isoto"es (1)
relative to the mass o& a
12
* atom ta#en as e5actl$ 12 / 12.000 (1)
',enalise %eight! once onl$* '-gnore a.erage! mass o
1#
/*
'(o not allo% mass o a.erage atom!*
(!) 4
r
= (24 2 0.6'5) . (25 2 0.101) . (21 2 0.114) 1
= 24.4 1
'mark M# conse0 on transcription error or incorrect addition
o 1*
(e) +
r
= highest m/- vale 1
'N23 highest/largest/right4hand! peak*
1
10.1 Assessed HW Mark Scheme
[10]
3. (a) (i) 4toms )ith the same nmber o& "rotons / "roton nmber (1)
N23 same atomic n&mber
)ith !i&&erent nmbers o& netrons (1)
NOT dierent mass n&mber / e%er ne&trons
(ii) *hemical "ro"erties !e"en! on the nmber or amont o& (oter) electrons (1)
0R7 isoto"es have the same electron con&igration / same nmber o& e

'
(b) 1s
2
2s
2
2"
1
's
1
(1) 1
accept s&bscripted ig&res
(c) 8ighest energ$ e

/ oter e

s / last e

in (')! sb9shell (1) 1

2" d s&b4shell being illed / is incomplete
2" highest energ$ s&b4shell is '5*d
N23 transition element / e
6
conig&ration ends at 5d
7 o 8
(!) N
15
7
N correct s$mbol (1)
allo%
15
7
N
+ass nmber = 15 4N, atomic nmber = 6 (1) 2
[7]
4. (a) 8igh s"ee! electrons 0R electrons &rom an electron gn (1)
:noc#s ot an (oter9shell) electron (on the chromim atom) (1) 2
Accept /r'g* ) e
6
/r
)
'g* ) #e
6
N23 e
6
g&n alone / beam o e
6
/ bombardment %ith e
6
(b) /lectric &iel! 0R (attraction to) 9ve "late 0R electrostatic attraction (1) 1
0R (re"elle! b$) .ve "late 0R charge! "late
N23 high p.d. / electromagnetic ield / electric plates
(c) +agnet 0R magnetic &iel! 0R electromagnet(1) 1
(!) A
r
= (50 2 0.04') . (52 2 0.8'8) . (5' 2 0.0;5) . (54 2 0.024) (1)
52.01 0R 52.05 (1) 2
Mark conse0&entiall$ on transcription9 or addition o 19 error
[6]
5.
(a) 1s
2
2s
2
2"
'
(1)
1s
2
2s
2
2"
1
(1) 2
(b) Na 1s
2
2s
2
2"
1
's
1
(1)
<e 1s
2
2s
2
2"
1
's
2
'"
1
'!
1
4s
2
(1) 2
acce"t '! an! 4s trans"ose!
(c) '!
10
4s
1
or reverse or!er (1)
'!
;
(1)
2
10.1 Assessed HW Mark Scheme
(allo) &ll con&igration i& correct= i& )rong "enalise once) 2
(!) 1s
2
2s
2
2"
1
(1) 1
(e) (1s
2
2s
2
) 2"
1
's
2
'"
2
(1) 1
[]
6. (a) /nthal"$ change/re>ire! )hen an electron is remove!/#noc#e! 1
ot/!is"lace! (?gnore @minimmA energ$)
<rom a gaseos atom 1
'co&ld get this mark rom e0&ation*
(b) +g
.
(g) +g
2.
(g) . e

/>ation 1
!r +g
.
(g) . e

+g
2.
(g) . 2e

3tate s$mbols (3ied to M1) 1

(c) ?ncrease!/stronger nclear charge or more "rotons 1
3maller atom or electrons enter the same shell or same/similar shiel!ing 1
(!) /lectron remove! &rom a shell o& lo)er energ$ or smaller atom or e

nearer 1
ncles or e

remove! &rom 2" rather than &rom 's

Bess shiel!ing 1
'(o not accept e
6
rom inner shell!*
[]
3