Page1of2

DLF Public School

(The Learning Academy)
Managed By Darbari Lal Foundation
Class:XI
Sub:Chemistry
1
st
TerminalExam[201314]
Time :3Hrs. MM:70
Name : RollNo.:.
GeneralInstructions:
Questions1to5carry1markeach.
Questions6to10carry2markseach.
Questions11to22carry3markseach.
Question23carries4marks.
Questions24to26carry5markseach.
Allquestionsarecompulsory.
Uselogtablesifnecessary.
Calculatorsarenotpermitted.
Q1 Whatisthedifferencebetween5gand5.00g?
Q2 Statethephysicalsignificanceof
2
.
Q3 Whatisthedifferenceintheangularmomentumofanelectronpresentin3pandthat
presentin4porbital?
Q4 dz
2
orbitalhaszeroelectrondensityxyplane.Comment
Q5 WritethegroundstateelectronicconfigurationofFe
2+
ion(at.No.ofFe=26).
Q6 Differentiatebetweenprecisionandaccuracy.
Q7 WhyarenoblegasesassignedvanderWaalsradii?
Q8 Considerthefollowingspecies:
N
3
,O
2
,F

,Na
+
,Mg
2+
andAl
3+

a] Whatiscommoninthem?
b] Arrangethemintheorderofincreasingionicradii?
Q9 WhatwouldbetheIUPACnameandsymbolfortheelementwithatomicnumber120?
Q10 Define mole fraction of a component in a solution .What is the sum of the mole
fractionsofallcomponentsinathreecomponentsystem?
Q11 State
a] HundsRule
b] PaulisExclusionprinciple
c] DefineOctetrule.
Q12 a] Copper(I)isdiamagneticwhereascopper(II)isparamagnetic.Givereason.
b) StateGayLussacslawofgaseousvolumes.
Q13 a] Incaseofhydrogenatomwhatwouldbetheincreasingorderofenergy
3d3s1s2p2s3p
b] Listthequantamnumbers(mandl)ofelectronsfor3dorbital.
c] The unpaired electrons in Aland Si are present in 3p orbital. Which electrons will
experiencemoreeffectivenuclearchargefromthenucleus?
Q14 a] Whatislimitingreagent?
b] Whydoesthemolalityofasolutionremainunchangedwithroomtemperature?
c) An element belongs to 3
rd
periodof pblock. It has 4 valence electrons. Predict its
group.Howmanyunpairedelectronsdoesithave?(1+1+1=3)
QPT100811A
Page2of2

Q15 a] Ionic compounds are bad conductor of electricity in its solid state but good
conductorofelectricityinitsmoltenstate.GiveReason?
b] WritetheLewisDotstructureforCaF
2
. (2+1)
Q16 Butyric acid contains only C,H and O. A 4.24 mg sample of butyric acid is completely
burned.Itgives8.45mgofcarbondioxide(CO
2
)and3.46mgofwater.Whatisthemass
percentageofeachelementofbutyricacid?
Q17 Commerciallyavailableconcentratedhydrochloricacidcontain38%HCIbymass.
a] Whatisthemolarityofthissolution?Thedensityis1.19gml
1

b] WhatvolumeofconcentratedHCIisrequiredtomake1.00Lof0.10MHCI?
Q18 Whatisthecauseofdiagonalrelationship.Giveanexample.
Q19 Explaintheterms:
a] screeningeffect
b] penetration
Q20 Whatisthedifferencebetweenthetermselectrongainenthalpyandelectronegativity?
Q21 Theworkfunctionforcaesiumatomis1.9eV.Calculate
a] thethresholdwavelengthand
b] thethresholdfrequencyoftheradiation
OR
Q21 The velocity associated with a proton moving in a potential difference of 1000V is
4.37x10
5
ms
1
.Ifthehockeyballofmass0.1kgis movingwiththisvelocity,calculate
thewavelengthassociatedwiththisvelocity.
Q22 Writeanythreepointdifferencebetweenthewavenatureandtheparticlenatureofa
matter.
Q23 Namanfoundhisvillagewaterpollutedwithchemicalsandpathogenicmicroorganism.
So being a science student, hedecided to take several steps of physical and chemical
treatmenttomakeitsafeforvillagers.
a] Namethetwoelementswhichhavetoxiceffects.
b] Writeanytwocausesofwaterpollution.
c] WhatvaluesarereflectedbyNamansdecision? (1+2+1)
Q24 i] OutofNaClandMgOwhichhashigherlatticeenergyandwhy? (1)
ii] Mentionthebestchoiceinthelist:
a] highestfirstionizationenthalpy Se,S,Te
b] smallestradius C1

,Br

,F

c] leastnegativeelectrongainenthalpy Ba,Sr,Cs
d] lowestsecondionizationenthalpy Ar,K,Ca
e] largestradius S
2
,Cl

,Cl
f] mostnegativeelectrongainenthalpy O,S,Te
g] smallestatom Sn,I,Bi
h] theionwhichcanbemosthydrated Li
+
,K
+
,Rb
+
(8=4)
Q25 Neongashasgenerallyusedinthesignboards.Ifitemitsstronglyat616nm,calculate
a] thefrequencyofemission
b] distancetravelledbythisradiationin30s
c] energyofquantumand
d] numberofquantapresentifitproduces2Jofenergy
Q26 a] MentionthefactorsfavouringtheformationofIonicbond. (3)
b] Writethepropertiesofdblockelements.(Anyfour) (2)

XXX
Page3of2

DLF Public School

(The Learning Academy)
Managed By Darbari Lal Foundation
Class:XI
Sub:Chemistry
1
st
TerminalExam[201314]
Time :3Hrs. MM:70
Name : RollNo.:.
GeneralInstructions:
Questions1to5carry1markeach.
Questions6to10carry2markseach.
Questions11to22carry3markseach.
Question23carries4marks.
Questions24to26carry5markseach.
Allquestionsarecompulsory.
Uselogtablesifnecessary.
Calculatorsarenotpermitted.
Q1 Whatisthedifferenceintheangularmomentumofanelectronpresentin3pandthat
presentin4porbital?
Q2 dz
2
orbitalhaszeroelectrondensityxyplaneComment.
Q3 WritethegroundstateelectronicconfigurationofFe
2+
ion(at.No.ofFe=26).
Q4 Whatisthedifferencebetween5gand5.00g?
Q5 Statethephysicalsignificanceof2.
Q6 WhatwouldbetheIUPACnameandsymbolfortheelementwithatomicnumber120?
Q7 Define mole fraction of a component in a solution .What is the sum of the mole
fractionsofallcomponentsinathreecomponentsystem?
Q8 Differentiatebetweenprecisionandaccuracy.
Q9 WhyarenoblegasesassignedvanderWaalsradii?
Q10 Considerthefollowingspecies:
N
3
,O
2
,F

,Na
+
,Mg
2+
andAl
3+

a] Whatiscommoninthem?
b] Arrangethemintheorderofincreasingionicradii?
Q11 a] Incaseofhydrogenatomwhatwouldbetheincreasingorderofenergy
3d3s1s2p2s3p
b] Listthequantamnumbers(mandl)ofelectronsfor3dorbital.
c] The unpaired electrons in Aland Si are present in 3p orbital. Which electrons will
experiencemoreeffectivenuclearchargefromthenucleus?
Q12 a] Whatislimitingreagent?
b] Whydoesthemolalityofasolutionremainunchangedwithroomtemperature?
c] An element belongs to 3
rd
periodof pblock. It has 4 valence electrons. Predict its
group.Howmanyunpairedelectronsdoesithave? (1+1+1=3)
Q13 Theworkfunctionforcaesiumatomis1.9eV.Calculate
a] thethresholdwavelengthand
b] thethresholdfrequencyoftheradiation
OR
Thevelocityassociatedwithaprotonmovinginapotentialdifferenceof1000Vis4.37x
10
5
ms
1
. If the hockey ball of mass 0.1 kg is moving with this velocity, calculate the
wavelengthassociatedwiththisvelocity.
QPT100811B
Page4of2

Q14 Writeanythreepointdifferencebetweenthewavenatureandtheparticlenatureofa
matter.
Q15 11State
a] HundsRule
b] PaulisExclusionprinciple
c] DefineOctetrule.
Q16 a] Copper(I)isdiamagneticwhereascopper(II)isparamagnetic.Givereason.
b] StateGayLussacslawofgaseousvolumes.
Q17 a] Ionic compounds are bad conductor of electricity in its solid state but good
conductorofelectricityinitsmoltenstate.GiveReason?
b] WritetheLewisDotstructureforCaF
2
. (2+1)
Q18 Butyric acid contains only C,H and O. A 4.24 mg sample of butyric acid is completely
burned.Itgives8.45mgofcarbondioxide(CO
2
)and3.46mgofwater.Whatisthemass
percentageofeachelementofbutyricacid?
Q19 Commerciallyavailableconcentratedhydrochloricacidcontain38%HCIbymass.
a] Whatisthemolarityofthissolution?Thedensityis1.19gmL
1

b] WhatvolumeofconcentratedHCIisrequiredtomake1.00Lof0.10MHCI?
Q20 Whatisthecauseofdiagonalrelationship?Giveanexample.
Q21 Explaintheterms:
a] screeningeffect
b] penetration
Q22 Whatisthedifferencebetweenthetermselectrongainenthalpyandelectronegativity?
Q23 Rajeevfoundhisvillagewaterpollutedwithchemicalsandpathogenicmicroorganism.
So being a science student, hedecided to take several steps of physical and chemical
treatmenttomakeitsafeforvillagers.
a] Namethetwoelementswhichhavetoxiceffects.
b] Writeanytwocausesofwaterpollution.
c] WhatvaluesarereflectedbyRajeevsdecision? (1+2+1)
Q24 a] MentionthefactorsfavouringtheformationofIonicbond. (3)
b] Writethepropertiesofdblockelements.(Anyfour)
Q25 i] OutofNaClandMgOwhichhashigherlatticeenergyandwhy? (1)
ii] Mentionthebestchoiceinthelist:
a] highestfirstionizationenthalpy Se,S,Te
b] smallestradius Cl

,Br,F
c] leastnegativeelectrongainenthalpy Ba,Sr,Cs
d] lowestsecondionizationenthalpy Ar,K,Ca
e] largestradius S
2
,Cl

,Cl
f] mostnegativeelectrongainenthalpy O,S,Te
g] smallestatom Sn,I,Bi
h] theionwhichcanbemosthydrated Li
+
,K
+
,Rb
+
(8=4)
Q26 Neongashasgenerallyusedinthesignboards.Ifitemitsstronglyat616nm,calculate
a] thefrequencyofemission
b] distancetravelledbythisradiationin30s
c] energyofquantumand
d] numberofquantapresentifitproduces2Jofenergy

XXX