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AND J. ERHART
Department of Physics and International Center for Piezoelectric Research,
Technical University of Liberec, H alkova 6, CZ-461 17 Liberec 1,
Czech Republic
Electric eld applicability limits were measured by the resonant methods for D.C. and
pulse electric eld depoled PZT ceramics. It is found that the limiting elds for soft PZT
are in the range of 500700 V/mm for D.C. depoling and in the range of 200500 V/mm
for pulses. Hard PZT ceramics is resistant to the depoling elds up to 1000 V/mm either
for D.C., or pulse depoling elds. Relative changes in the magnitude of the electrome-
chanical properties are 320% for the electric elds up to 1000 V/mm. Some electrome-
chanical tensor components appear more pronounced sensitivity to the external elds
than others.
Keywords PZT ceramics; poling
PACS: 77.84.Dy; 77.22.Ej
1. Introduction
Nowadays, poled PZT ceramics serve as a basis for the production of many components in
electromechanical devices. In recent years many authors were engaged in investigations of
conditions under which changes of electromechanical properties of PZT ceramics would be
possible. PZTceramics is commercially poled by the strong D.C. voltage at elevated temper-
atures, but the poling conditions are not usually provided to the customers. In applications,
alignment of the dipole moments in ferroelectric ceramics is inuenced by the electric eld
in the direction opposite to the poling eld. If it is strong enough, such electric eld could
completely destroy the polarization orientation and therefore also the piezoelectric proper-
ties. While the poling (as well as the following application of electric eld, i.e. so called
depoling) process is basically the dynamic process, different poling (and depoling) results
are supposed from the D.C. or pulse-poling voltage. Poling-dependent material properties
were recently studied in soft and hard lead zirconate titanate (PZT) [1, 2], lead titanate
(PbTiO
3
) [3] and barium titanate (BaTiO
3
) [4] ceramics for the electric elds exceeding the
coercive eld.
Main aim of this contribution is the measurement of the electromechanical properties
for several types of PZTceramics (hard as well as soft) as a function of the depoling voltage.
Electric eld limits for the application of PZT ceramics without the substantial change of
the material properties will be specied.
Received September 6, 2004; In revised form February 28, 2005.
33
d
31
k
31
s
E
11
d
33
k
T
33
d
33
d
31
k
31
s
E
11
d
33
k
p
T
33
APC 840
APC 841
APC 880
2.6
7.9
10.4
10.3
2.6
5.4
13.8
15.5
0.7
17.9
3.6
3.6
8.6
11.6
8.8
16.5
3.6
1.1
10.4
5.1
5.5
10.3
15.9
19.3
8.2
4.7
4.0
4.1
2.8
4.5
7.7
2.7
4.5
7.9
4.8
5.8
3.7
3.4
5.4
6.2
4.3
5.4
a result of the reverted polarization orientation as it was observed. Limits for the electric
elds, not changing the properties substantially, are listed in Table 2. For the hard PZT
ceramics, there were no signicant changes of the material coefcients observed up to the
electric elds of 1000 V/mm. Relative changes of the material coefcients over the entire
depoling electric eld range studied are listed in Table 3. Relative changes are expressed as
a ratio of the maximum change of the property vs. the same property value for not depoled
sample (in absolute value).
Pulse Depoling
Similar behavior as for the D.C. voltage depoling occurs also in this case. Soft PZT ce-
ramics is more sensitive to the depoling eld intensity and the limit elds are even smaller
than for D.C. voltage depoling. This clearly illustrates the dynamic nature of the poling
as well as depoling process. Limiting elds for soft PZT ceramics are listed in Table 2.
Relative changes of the material coefcients for hard PZT (listed in Table 3.) have similar
magnitude (i.e. 320%) like for D.C. depoling (i.e. 118%). There is no big difference
between D.C. and pulse depoling for the hard PZTs studied up to the electric elds of
1000 V/mm.
4. Conclusions
D.C. and pulse electric eld applicability limits were measured for the set of hard as well as
soft PZT ceramics (soft APC 850 and 856, hard APC 840, 841 and 880) up to 1000 V/mm
electric eld strength. Soft PZT ceramics has applicability limits 200700 V/mm for D.C.
eld and 200500 V/mm for pulses. Ceramics is more sensitive to the pulse electric eld
than to D.C. signal. Changes in the material properties are realized by the domain wall
movement, which is more complex phenomenon in pulsed electric elds. Hard PZTs have
their electric eld applicability limits higher than 1000 V/mm and therefore out of the
tested electric eld range. Hard PZT ceramics acquired relative changes in the materials
coefcients measured in the range of 3 to 18%. Piezoelectric coefcients are the most
sensitive material properties studied with respect to the depoling eld.
Our measured values agree well with the published data on soft and hard ceramics,
namely with the limits of 100300 V/mm for soft PZT ([6], Philips, grades PXE5 or 52)
under D.C. depoling and of 300500 V/mm for hard PZT ([6], Philips, grades PXE 41,
56/[282] T. Malysh and J. Erhart
42 or 43). Data similar to our ndings were published also for A.C. depoling for Morgan
Matroc PZT ceramics [7], i.e. 700 V/mm for soft PZT-5A type and >1000 V/mm for hard
PZT-4D and PZT-8 types. Manufacturer of studied PZT types (i.e. APC International Ltd.)
published electric eld applicability limits as high as 720 V/mm for D.C. and 360 V/mm
for A.C. eld for APC840, 600 V/mm for D.C. and 320 V/mm for A.C. eld for APC850
and 800 V/mm for D.C. and 400 V/mm for A.C. eld for APC880 [8].
Some tensor components are more microstructure-dependent than others, e.g. the Pois-
sons ratio
E
shows bigger changes than c
E
33
, which corresponds to the polarization ori-
entation for elementary dipole moments in the direction parallel and perpendicular to the
applied eld. Such effects are related to the textures created by the external elds, grain
geometry etc., which are not topic of this paper.
Acknowledgment
This work has been supported by the Ministry of Education, Youth and Sport under the
project MSM 242200002 and by the Grant Agency of the Czech Republic under the project
No. 202/03/0569.
References
1. T. Ogawa, Ceramics International 26, 383390 (2000).
2. T. Ogawa and K. Nakamura, Jpn. J. Appl. Phys. 38, 54655469 (1999).
3. T. Ogawa, Jpn. J. Appl. Phys. 39, 55385541 (2000).
4. T. Ogawa, Jpn. J. Appl. Phys. 40, 56305633 (2001).
5. IRE Standard, Measurements on piezoelectric ceramics (1961).
6. Data handbook, Piezoelectric ceramics, specialty ferrites, Philips Components 1997, p. 16.
7. Data book for designers, Piezoelectric ceramics, Morgan Matroc Ltd., p. 12.
8. Piezoelectric ceramics, Principles and Applications, APC International Ltd., 2002 (see Table 1.7,
p. 29).