(TM)*Trademark Page 1 of 10 The Dow Chemical Company encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions. 1. Product and Company Identification Product Name Ethylene Dichloride COMPANY IDENTIFICATION The Dow Chemical Company 2030 Willard H. Dow Center Midland, MI 48674 United States Customer Information Number: 800-258-2436 SDSQuestion@dow.com EMERGENCY TELEPHONE NUMBER 24-Hour Emergency Contact: 989-636-4400 Local Emergency Contact: 989-636-4400 2. Hazards Identification Emergency Overview Color: Colorless Physical State: Liquid. Odor: Sweet Hazards of product: WARNING! Flammable liquid and vapor. Causes eye irritation. Harmful if inhaled. Harmful if swallowed. May cause skin irritation. May be harmful if absorbed through skin. May cause central nervous system effects. Aspiration hazard. Can enter lungs and cause damage to body systems. May cause respiratory tract irritation. Keep upwind of spill. Vapor explosion hazard. Vapors may travel a long distance; ignition and/or flash back may occur. Stay out of low areas. Evacuate area. Warn public of downwind explosion hazard. Toxic fumes may be released in fire situations. Suspect cancer hazard. May cause cancer. OSHA Hazard Communication Standard This product is a Hazardous Chemical as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. Material Safety Data Sheet The Dow Chemical Company Product Name: Ethylene Dichloride Issue Date: 02/25/2014 Page 2 of 10 Potential Health Effects Eye Contact: May cause moderate eye irritation. May cause moderate corneal injury. Vapor may cause lacrimation (tears). Skin Contact: Brief contact may cause skin irritation with local redness. Prolonged contact may cause moderate skin irritation with local redness. Prolonged or repeated exposure may cause defatting of the skin leading to drying or flaking of skin. Skin Absorption: Prolonged skin contact is unlikely to result in absorption of harmful amounts. Repeated skin contact may result in absorption of harmful amounts. Inhalation: Prolonged excessive exposure may cause serious adverse effects, even death. In humans, effects have been reported on the following organs: Central nervous system. Lung. Vapor may cause irritation of the upper respiratory tract (nose and throat) and lungs. May cause central nervous system depression. Symptoms may include headache, dizziness and drowsiness, progressing to incoordination and unconsciousness. Ingestion: Moderate toxicity if swallowed. Small amounts swallowed incidentally as a result of normal handling operations are not likely to cause injury; however, swallowing larger amounts may cause serious injury, even death. Aspiration hazard: Based on physical properties, not likely to be an aspiration hazard. Effects of Repeated Exposure: In humans, effects have been reported on the following organs: Liver. Kidney. Adrenal gland. May cause central nervous system effects. In humans, symptoms may include: Nausea and/or vomiting. Headache. Dizziness. Coma. Irregular heartbeats. Cancer Information: Has caused cancer in laboratory animals. Component CAS # Amount 1,2-Dichloroethane 107-06-2 > 99.0 % 4. First-aid measures Description of first aid measures General advice: First Aid responders should pay attention to self-protection and use the recommended protective clothing (chemical resistant gloves, splash protection). If potential for exposure exists refer to Section 8 for specific personal protective equipment. Inhalation: Move person to fresh air. If not breathing, give artificial respiration; if by mouth to mouth use rescuer protection (pocket mask, etc). If breathing is difficult, oxygen should be administered by qualified personnel. Call a physician or transport to a medical facility. Skin Contact: Immediately flush skin with water while removing contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Contaminated leather items such as shoes should be disposed of properly. Eye Contact: Immediately flush eyes with water; remove contact lenses, if present, after the first 5 minutes, then continue flushing eyes for at least 15 minutes. Obtain medical attention without delay, preferably from an ophthalmologist. Suitable emergency eye wash facility should be immediately available. Ingestion: If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by medical personnel. Seek medical attention immediately. Never give anything by mouth to an unconscious person. Most important symptoms and effects, both acute and delayed Aside from the information found under Description of first aid measures (above) and Indication of immediate medical attention and special treatment needed (below), any additional important symptoms and effects are described in Section 11: Toxicology Information. Indication of immediate medical attention and special treatment needed Maintain adequate ventilation and oxygenation of the patient. No specific antidote. Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient. Skin contact may aggravate preexisting dermatitis. Excessive exposure may aggravate preexisting lung, liver, and kidney disease. 3. Composition Information Product Name: Ethylene Dichloride Issue Date: 02/25/2014 Page 3 of 10 5. Fire Fighting Measures Suitable extinguishing media Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers. Foam. General purpose synthetic foams (including AFFF type) or protein foams are preferred if available. Alcohol resistant foams (ATC type) may function. Water fog, applied gently may be used as a blanket for fire extinguishment. Extinguishing Media to Avoid: Do not use direct water stream. Straight or direct water streams may not be effective to extinguish fire. Special hazards arising from the substance or mixture Hazardous Combustion Products: During a fire, smoke may contain the original material in addition to combustion products of varying composition which may be toxic and/or irritating. Combustion products may include and are not limited to: Hydrogen chloride. Carbon monoxide. Carbon dioxide. Unusual Fire and Explosion Hazards: Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Flammable mixtures may exist within the vapor space of containers at room temperature. Flammable concentrations of vapor can accumulate at temperatures above flash point; see Section 9. Advice for firefighters Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Stay upwind. Keep out of low areas where gases (fumes) can accumulate. Water may not be effective in extinguishing fire. Do not use direct water stream. May spread fire. Eliminate ignition sources. Move container from fire area if this is possible without hazard. Burning liquids may be moved by flushing with water to protect personnel and minimize property damage. Water fog, applied gently may be used as a blanket for fire extinguishment. Special Protective Equipment for Firefighters: Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots, and gloves). If protective equipment is not available or not used, fight fire from a protected location or safe distance. 6. Accidental Release Measures Personal precautions, protective equipment and emergency procedures: Use appropriate safety equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection. Evacuate area. Refer to Section 7, Handling, for additional precautionary measures. Keep upwind of spill. Ventilate area of leak or spill. No smoking in area. Only trained and properly protected personnel must be involved in clean-up operations. For large spills, warn public of downwind explosion hazard. Eliminate all sources of ignition in vicinity of spill or released vapor to avoid fire or explosion. Vapor explosion hazard. Keep out of sewers. Check area with combustible gas detector before reentering area. Ground and bond all containers and handling equipment. Environmental precautions: Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information. Methods and materials for containment and cleaning up: Small spills: Contain spilled material if possible. Absorb with materials such as: Vermiculite. Bentonite. Sawdust. Collect in suitable and properly labeled containers. Large spills: Dike area to contain spill. Pump into suitable and properly labeled containers. Pump with explosion-proof equipment. If available, use foam to smother or suppress. See Section 13, Disposal Considerations, for additional information. 7. Handling and Storage Handling General Handling: Keep away from heat, sparks and flame. Do not swallow. Avoid contact with eyes, skin, and clothing. Avoid breathing vapor. Wash thoroughly after handling. Keep container closed. Use with adequate ventilation. No smoking, open flames or sources of ignition in handling Product Name: Ethylene Dichloride Issue Date: 02/25/2014 Page 4 of 10 and storage area. Electrically bond and ground all containers, personnel and equipment before transfer or use of material. Use of non-sparking or explosion-proof equipment may be necessary, depending upon the type of operation. This product is a poor conductor of electricity and can become electrostatically charged, even in bonded or grounded equipment. If sufficient charge is accumulated, ignition of flammable mixtures can occur. Handling operations that can promote accumulation of static charges include but are not limited to mixing, filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and container filling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations. Containers, even those that have been emptied, can contain vapors. Do not cut, drill, grind, weld, or perform similar operations on or near empty containers. Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Other Precautions: Vapors are heavier than air and may travel a long distance and accumulate in low lying areas. Ignition and/or flash back may occur. Never use air pressure for transferring product. Containers, even those that have been emptied, can contain vapors. Do not cut, drill, grind, weld, or perform similar operations on or near empty containers. Storage Hold bulk storage under nitrogen blanket. Minimize sources of ignition, such as static build-up, heat, spark or flame. Keep container closed. Flammable mixtures may exist within the vapor space of containers at room temperature. 8. Exposure Controls / Personal Protection Exposure Limits Component List Type Value | 1,2-Dichloroethane ACGIH TWA 10 ppm OSHA/Z2 TWA 50 ppm OSHA/Z2 Ceiling 100 ppm OSHA/Z2 MAX. CONC 200 ppm 5 minutes in any 3 hours Personal Protection Eye/Face Protection: Use chemical goggles. If exposure causes eye discomfort, use a full-face respirator. Skin Protection: Use protective clothing chemically resistant to this material. Selection of specific items such as face shield, boots, apron, or full body suit will depend on the task. Hand protection: Use gloves chemically resistant to this material. Examples of preferred glove barrier materials include: Chlorinated polyethylene. Polyethylene. Ethyl vinyl alcohol laminate (EVAL). Polyvinyl alcohol (PVA). Styrene/butadiene rubber. Viton. Examples of acceptable glove barrier materials include: Butyl rubber. Natural rubber (latex). Neoprene. Nitrile/butadiene rubber (nitrile or NBR). Polyvinyl chloride (PVC or vinyl). NOTICE: The selection of a specific glove for a particular application and duration of use in a workplace should also take into account all relevant workplace factors such as, but not limited to: Other chemicals which may be handled, physical requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions to glove materials, as well as the instructions/specifications provided by the glove supplier. Respiratory Protection: Respiratory protection should be worn when there is a potential to exceed the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, use an approved respirator. Selection of air-purifying or positive-pressure supplied-air will depend on the specific operation and the potential airborne concentration of the material. For emergency conditions, use an approved positive-pressure self-contained breathing apparatus. In confined or poorly ventilated areas, use an approved self-contained breathing apparatus or positive pressure air line with auxiliary self-contained air supply. The following should be effective types of air- purifying respirators: Organic vapor cartridge. Ingestion: Avoid ingestion of even very small amounts; do not consume or store food or tobacco in the work area; wash hands and face before smoking or eating. Product Name: Ethylene Dichloride Issue Date: 02/25/2014 Page 5 of 10 Engineering Controls Ventilation: Use engineering controls to maintain airborne level below exposure limit requirements or guidelines. If there are no applicable exposure limit requirements or guidelines, use only with adequate ventilation. Local exhaust ventilation may be necessary for some operations. 9. Physical and Chemical Properties Appearance Physical State Liquid. Color Colorless Odor Sweet Odor Threshold No test data available pH Not applicable Melting Point -36 C (-33 F) Literature Freezing Point -36 C (-33 F) Literature Boiling Point (760 mmHg) 83.6 C (182.5 F) Literature . Flash Point - Closed Cup 13 C (55 F) Tag Closed Cup ASTM D56 Evaporation Rate (Butyl Acetate = 1) No test data available Flammability (solid, gas) No Flammable Limits In Air Lower: 4.5 %(V) Literature Upper: 16.9 %(V) Literature Vapor Pressure 33.3 hPa @ 0 C Literature Vapor Density (air = 1) 3.42 Literature Specific Gravity (H2O = 1) 1.2455 Literature Solubility in water (by weight) 7.9 g/l @ 25 C Literature Partition coefficient, n- octanol/water (log Pow) 1.45 Measured Autoignition Temperature 440 C (824 F) Literature Decomposition Temperature No test data available Kinematic Viscosity 0.67 St @ 20 C Calculated Explosive properties Not explosive Oxidizing properties No Liquid Density 1,253 g/l @ 20 C Literature Molecular Weight 98.9 g/mol Literature Percent Volatiles 100 %(m) Literature Henrys Law Constant (H) 1.23E-03 atm*m3/mole; 25 C Estimated. 10. Stability and Reactivity Reactivity No dangerous reaction known under conditions of normal use. Chemical stability Thermally stable at typical use temperatures. Possibility of hazardous reactions Polymerization will not occur. Conditions to Avoid: Exposure to elevated temperatures can cause product to decompose. Avoid open flames, welding arcs, or other high temperature sources which induce thermal decomposition. Incompatible Materials: Avoid contact with oxidizing materials. Avoid contact with: Alkali metal hydroxides. Amines. Ammonia. Avoid contact with metals such as: Aluminum. Aluminum alloys. Hazardous decomposition products Decomposition products depend upon temperature, air supply and the presence of other materials. Decomposition products can include and are not limited to: Hydrogen chloride. Product Name: Ethylene Dichloride Issue Date: 02/25/2014 Page 6 of 10 11. Toxicological Information Acute Toxicity Ingestion LD50, mouse 413 mg/kg LD50, rat 770 mg/kg Dermal LD50, rabbit 4,890 mg/kg Inhalation LC50, 4 h, Vapor, rat 1,886 ppm 7.7 mg/l Eye damage/eye irritation May cause moderate eye irritation. May cause moderate corneal injury. Vapor may cause lacrimation (tears). Skin corrosion/irritation Brief contact may cause skin irritation with local redness. Prolonged contact may cause moderate skin irritation with local redness. Prolonged or repeated exposure may cause defatting of the skin leading to drying or flaking of skin. Sensitization Skin Did not demonstrate the potential for contact allergy in mice. Respiratory No relevant data found. Repeated Dose Toxicity In humans, effects have been reported on the following organs: Liver. Kidney. Adrenal gland. May cause central nervous system effects. In humans, symptoms may include: Nausea and/or vomiting. Headache. Dizziness. Coma. Irregular heartbeats. Chronic Toxicity and Carcinogenicity Has caused cancer in laboratory animals. Carcinogenic effects in the animal study on ethylene dichloride are believed to be related to the route (oral) of exposure and dose administered (greater than a dose the body can easily detoxify) Ethylene dichloride is not believed to present a risk of cancer to humans when handled as recommended. Carcinogenicity Classifications: Component List Classification 1,2-Dichloroethane NTP Anticipated carcinogen. IARC Possibly carcinogenic to humans.; 2B Developmental Toxicity Did not cause birth defects or other effects in the fetus even at doses which caused toxic effects in the mother. Reproductive Toxicity In animal studies, did not interfere with reproduction. Genetic Toxicology In vitro genetic toxicity studies were negative in some cases and positive in other cases. Animal genetic toxicity studies were positive. 12. Ecological Information Toxicity Material is practically non-toxic to aquatic organisms on an acute basis (LC50/EC50/EL50/LL50 >100 mg/L in the most sensitive species tested). Fish Acute & Prolonged Toxicity LC50, Pimephales promelas (fathead minnow), flow-through test, 96 h: 136 mg/l LC50, tidewater silverside (Menidia beryllina): 480 mg/l Aquatic Invertebrate Acute Toxicity EC50, Daphnia magna (Water flea), static test, 48 h, immobilization: 160 mg/l Aquatic Plant Toxicity EbC50, alga Scenedesmus sp., static test, biomass growth inhibition, 72 h: 166 mg/l Product Name: Ethylene Dichloride Issue Date: 02/25/2014 Page 7 of 10 Toxicity to Micro-organisms EC50; activated sludge, 5 d: 1,525 mg/l NOEC; Pseudomonas putida, static test, 16 h: 135 mg/l Fish Chronic Toxicity Value (ChV) Pimephales promelas (fathead minnow), flow-through test, 32 d, weight, NOEC:29 mg/l, LOEC:59 mg/l Aquatic Invertebrates Chronic Toxicity Value Daphnia magna (Water flea), semi-static test, 28 d, number of offspring, NOEC: 11 mg/l, LOEC: 21 mg/l Toxicity to Soil Dwelling Organisms LC50, Eisenia fetida (earthworms), 48 d: 0.06 mg/cm2 Persistence and Degradability Biodegradation under aerobic laboratory conditions is below detectable limits (BOD20 or BOD28/ThOD < 2.5%). Biodegradation may occur under both aerobic and anaerobic conditions (in the presence or absence of oxygen). Biodegradation rate may increase in soil and/or water with acclimation. Indirect Photodegradation with OH Radicals Rate Constant Atmospheric Half-life Method 2.2E-13 cm3/s 73 d Estimated. Biological oxygen demand (BOD): BOD 5 BOD 10 BOD 20 BOD 28 0 - 7 % 7 - 18 % 20 % Chemical Oxygen Demand: 0.99 mg/mg Theoretical Oxygen Demand: 0.81 - 0.97 mg/mg Bioaccumulative potential Bioaccumulation: Bioconcentration potential is low (BCF < 100 or Log Pow < 3). Partition coefficient, n-octanol/water (log Pow): 1.45 Measured Bioconcentration Factor (BCF): 2; Lepomis macrochirus (Bluegill sunfish); Measured Mobility in soil Mobility in soil: Potential for mobility in soil is very high (Koc between 0 and 50). Partition coefficient, soil organic carbon/water (Koc): 33 Measured Henrys Law Constant (H): 1.23E-03 atm*m3/mole; 25 C Estimated. 13. Disposal Considerations DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. All disposal practices must be in compliance with all Federal, State/Provincial and local laws and regulations. Regulations may vary in different locations. Waste characterizations and compliance with applicable laws are the responsibility solely of the waste generator. AS YOUR SUPPLIER, WE HAVE NO CONTROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS INTENDED CONDITION AS DESCRIBED IN MSDS SECTION: Composition Information. FOR UNUSED & UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed, permitted: Reclaimer. Incinerator or other thermal destruction device. 14. Transport Information DOT Non-Bulk Proper Shipping Name: ETHYLENE DICHLORIDE Hazard Class: 3 (6.1) ID Number: UN1184 Packing Group: PG II Product Name: Ethylene Dichloride Issue Date: 02/25/2014 Page 8 of 10 DOT Bulk Proper Shipping Name: ETHYLENE DICHLORIDE Hazard Class: 3 (6.1) ID Number: UN1184 Packing Group: PG II IMDG Proper Shipping Name: ETHYLENE DICHLORIDE Hazard Class: 3 (6.1) ID Number: UN1184 Packing Group: PG II EMS Number: F-E,S-D Marine pollutant: No Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Product Name: ETHYLENE DICHLORIDE Ship Type: 2 Pollution Category: Y ICAO/IATA Proper Shipping Name: ETHYLENE DICHLORIDE Hazard Class: 3 (6.1) ID Number: UN1184 Packing Group: PG II Cargo Packing Instruction: 364 Passenger Packing Instruction: 352 Additional Information Reportable quantity: 100 lb ETHYLENE DICHLORIDE This information is not intended to convey all specific regulatory or operational requirements/information relating to this product. Additional transportation system information can be obtained through an authorized sales or customer service representative. It is the responsibility of the transporting organization to follow all applicable laws, regulations and rules relating to the transportation of the material. 15. Regulatory Information OSHA Hazard Communication Standard This product is a Hazardous Chemical as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community Right-to-Know Act of 1986) Sections 311 and 312 Immediate (Acute) Health Hazard Yes Delayed (Chronic) Health Hazard Yes Fire Hazard Yes Reactive Hazard No Sudden Release of Pressure Hazard No Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and Community Right-to-Know Act of 1986) Section 313 This product contains the following substances which are subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and which are listed in 40 CFR 372. Component CAS # Amount 1,2-Dichloroethane 107-06-2 > 99.0 % Pennsylvania (Worker and Community Right-To-Know Act): Pennsylvania Hazardous Substances List and/or Pennsylvania Environmental Hazardous Substance List: The following product components are cited in the Pennsylvania Hazardous Substance List and/or the Pennsylvania Environmental Substance List, and are present at levels which require reporting. Component CAS # Amount 1,2-Dichloroethane 107-06-2 > 99.0 % Product Name: Ethylene Dichloride Issue Date: 02/25/2014 Page 9 of 10 Pennsylvania (Worker and Community Right-To-Know Act): Pennsylvania Special Hazardous Substances List: The following product components are cited in the Pennsylvania Special Hazardous Substance List, and are present at levels which require reporting. Component CAS # Amount 1,2-Dichloroethane 107-06-2 > 99.0 % US. New Jersey Worker and Community Right-to-Know Act (New Jersey Statute Annotated Section 34:5A-5) The following product components are cited in the New Jersey Environmental Hazardous and Workplace Hazardous Substance Lists: Component CAS # Amount 1,2-Dichloroethane 107-06-2 > 99.0 % US. New Jersey Worker and Community Right-to-Know Act (New Jersey Statute Annotated Section 34:5A-5) The following product components are cited in the New Jersey Special Hazardous Substance List: Component CAS # Amount 1,2-Dichloroethane 107-06-2 > 99.0 % Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA) Section 103 This product contains the following substances which are subject to CERCLA Section 103 reporting requirements and which are listed in 40 CFR 302.4. Component CAS # Amount 1,2-Dichloroethane 107-06-2 > 99.0 % California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986) WARNING: This product contains a chemical(s) known to the State of California to cause cancer. Component CAS # Amount 1,2-Dichloroethane 107-06-2 > 99.0 % US. Toxic Substances Control Act All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory requirements under 40 CFR 720.30 16. Other Information Recommended Uses and Restrictions Identified uses Raw material for the production of PVC. Revision Identification Number: 50038 / 1001 / Issue Date 02/25/2014 / Version: 5.0 Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this document. Legend N/A Not available W/W Weight/Weight OEL Occupational Exposure Limit STEL Short Term Exposure Limit TWA Time Weighted Average Product Name: Ethylene Dichloride Issue Date: 02/25/2014 Page 10 of 10 ACGIH American Conference of Governmental Industrial Hygienists, Inc. DOW IHG Dow Industrial Hygiene Guideline WEEL Workplace Environmental Exposure Level HAZ_DES Hazard Designation Action Level A value set by OSHA that is lower than the PEL which will trigger the need for activities such as exposure monitoring and medical surveillance if exceeded. The Dow Chemical Company urges each customer or recipient of this (M)SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and understand the data contained in this (M)SDS and any hazards associated with the product. The information herein is provided in good faith and believed to be accurate as of the effective date shown above. However, no warranty, express or implied, is given. Regulatory requirements are subject to change and may differ between various locations. It is the buyers/users responsibility to ensure that his activities comply with all federal, state, provincial or local laws. The information presented here pertains only to the product as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is the buyers/users duty to determine the conditions necessary for the safe use of this product. Due to the proliferation of sources for information such as manufacturer-specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the (M)SDS you have is current, please contact us for the most current version.