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 Title: Chapter 16(2) Started: October 4, 2009 7:07 PM Submitted: October 4, 2009 7:15 PM Time spent: 00:07:19

Total score: 3/3 = 100%

Maximum possible score: 3

1. Mechanism and Rate Law 8

The proposed mechanism for a reaction is

Cl 2

+ H 2 S => HCl + Cl + + HS - Slow

Cl + + HS - => HCl + S

Fast

Which of the following would be a rate law for the reaction?

 Student Correct Response Value Answer Feedback 1. rate = k[Cl 2 ] 0% 2. rate = k[Cl 2 ][H 2 S] 100% 3. rate = k[H 2 S] 0% 4. rate = 0% k[HCl][S] 5. rate = 0% [Cl + ][HS - ][HCl] Score: 1/1

2. Mechanism and Rate Law 5

The proposed mechanism for a reaction is

1. ClO - (aq) + H 2 O(l) => HClO(aq) + OH - (aq) SLOW

2. I - (aq) + HClO(aq) => HIO(aq) + Cl - (aq) FAST

3. OH - (aq) + HIO(aq) => H 2 O(l) + IO - (aq) FAST

Which of the following would be a rate law for the reaction?

 Student Correct Response Value Answer Feedback 1. rate = k[ClO - ][H 2 O] 100% 2. rate = 0% k[I - ][HClO]
 View Attempt https://scholar.uh.edu/webct/ViewStudentAttempt.dowebct?attempt=1770 3. rate = k[OH - ][HIO] 0% 4. rate = k[ClO - ] 0% [H 2 O][I - ] 5. rate = k[ClO - ] 0% [H 2 O][I - ][OH - ] Score: 1/1 3. Arrhenius E 1 set of conditions

A first order reaction has a rate constant of 0.882 at 28 o C. Given that the Arrhenius constant for the reaction is 7.80 x 10 11 sec -1 , calculate the value of the activation energy in KILOJOULES (enter answer in E format to 3 significant figures. Remember - 2.41 would be

2.41E0)