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Title: Chapter 16(1)
Started: September 27, 2009 5:56 PM
Submitted: September 27, 2009 6:31 PM
Time spent: 00:34:59
Total score: 12/12 = 100% Total score adjusted by 0.0 Maximum possible score: 12

1. Average Rate 4
The compound AX2 decomposes according to the equation, 2 AX2(g) => 2 AX(g) + X2(g). In
one experiment, [AX2] was measured at various times, and these data recorded:
Time (s) [AX2] mol/L
0 0.0500
2.0 0.0448
6.0 0.0300
8.0 0.0249
10.0 0.0209
20.0 0.0088

What is the average rate from 2.0 to 6.0 seconds in mol / L s? Use 3 significant figures. [don't
include units in your answer; if you want to use scientific notation, use the E format. e.g.,
0.0011 is 1.1E-3

Student Response Value Correct Answer


Equals 0.0037 (0%)
Equals 3.7E-3 (100%)
1. 3.7E-3 100%
Contains .0037 (100%)
Equals 3.70E-3 (100%)

Score: 1/1

2. Relative Rates of Substances 17


Consider the reaction, 2 D(g) + 3 E(g) + F(g) => 2 G(g) + H(g) When [H] is increasing at 0.47
mol/Ls, how quickly is [D] decreasing?

Student Response Value Correct Answer


Answer .94 100% 0.940

Score: 1/1

3. Rate Law General 6


What is the overall reaction order for Cl2 in a reaction with the following rate law?

Rate = k[Cl2][H+]2[CO]2

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Student
Value Correct Answer Feedback
Response
1. First 100%
2. Second 0%
3. Third 0%
4. Fourth 0%
5. Fifth 0%

Score: 1/1

4. Known Rate Law Change Conc 54


For the reaction, A(g) + B(g) => AB(g), the rate is 0.750 mol/L.s when the initial
concentrations of both A and B are 2.00 mol/L. If the reaction is first order in A and first order
in B, what is the rate when the initial concentration of A = 3.72 mol/L and that of B = 2.69
mol/L (give answers in E notation to 3 significant figures)

Student Response Value Correct Answer


Answer 1.88 100% 1.9

Score: 1/1

5. Known Rate Law, Change Conc 26

Consider the reaction with the rate law, Rate = k[BrO3-][Br-][H+]2


By what factor does the rate change if the concentration of BrO3- is doubled and that of Br- is
tripled? Just put in the number as a whole number or fraction.

Student Response Value Correct Answer


Equals 6 (100%)
1. 6 100%
Equals 6/1 (100%)

Score: 1/1

6. Determine Rate Law 33


Given the data below for the reaction, 2 A + 2 B + 4 C => D + E + 3 F, the reaction is 1.-----
order in A, 2.----- order in B, 3.----- order in C and 4.----- order overall. USE WORDS TO FILL
IN THE BLANKS NOT NUMBERS (i.e., zero, first, second etc) !!!!! :
Experiment Initial conc of A, Initial conc of B, Initial conc of C, Initial rate,
mol/L mol/L mol/L mol/L.s
1 0.1 0.2 0.4 2 x 10-3
2 0.2 0.2 0.4 8 x 10-3

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3 0.3 0.4 0.4 3.6 x 10-2


4 0.4 0.6 0.2 9.6 x 10-2

Student Response Value Correct Answer


1. second 25% Equals second (25%)
2. first 25% Equals first (25%)
3. zero 25% Equals zero (25%)
4. third 25% Equals third (25%)

Score: 1/1

7. Determine Rate Law 7


Consider the reaction of A(g) + B(g) + C(g) => D(g) for which the following data were
obtained:
Experiment Initial [A], mol/L Initial [B], mol/L Initial [C], mol/L Initial rate,
mol/L.s
1 0.0500 0.0500 0.0100 6.25 x 10-3
2 0.100 0.0500 0.0100 2.50 x 10-2
3 0.100 0.100 0.0100 1.00 x 10-1
4 0.0500 0.0500 0.0200 1.25 x 10-2

What is the rate law for the reaction?

Student Correct
Value Feedback
Response Answer
1. rate = 0%
k[A][B][C]
2. rate = 100%
2 2
k[A] [B] [C]
3. rate = 0%
2
k[A] [B][C]
4. rate = 0%
k[A]2[B]2
5. rate = 0%
k[A][B]

Score: 1/1

8. Calculate k from Rate Law 36


Given the data below for the reaction, 2 A + 2 B + 4 C => D + E + 3 F,
Experiment Initial conc of A, Initial conc of B, Initial conc of C, Initial rate,
mol/L mol/L mol/L mol/L.s

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1 0.1 0.2 0.4 2 x 10-3


2 0.2 0.2 0.4 4 x 10-3
3 0.3 0.4 0.4 2.4 x 10-2
4 0.4 0.6 0.2 3.6 x 10-2

Calculate the value of k to 3 significant figures and do not use scientific notation!

Student Response Value Correct Answer


1. 1.25 100% Equals 1.25 (100%)

Score: 1/1

9. Units of k 1
Which of the following would be a reasonable unit for the rate constant of a first order
reaction?

Student Correct
Value Feedback
Response Answer
1. mol/L.sec 0%
2 2
2. mol /sec.L 0%
3. 1/sec 100%
4. L/mol.sec 0%
5. L2/mol2.sec 0%

Score: 1/1

10. IRL 1 t 1

In a first order decomposition in which the rate constant is 0.0780 sec-1, how long will it take
(in seconds) until 0.207 mol/L of the compound is left, if there was 0.821 mol/L at the start?
(give answer to 3 sig figs using E notation)?

Student Response Value Correct Answer


Answer 1.77E1 100% 17.664

Score: 1/1

11. IRL 1 kt % 2

In a first order decomposition, the constant is 0.00354 sec-1. What percentage of the
compound has decomposed after 43.3 seconds?

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Student Response Value Correct Answer


Answer 14.2 100% 14

Score: 1/1

12. IRL 1 k 1
When 0.990 mol/L of a compound X decomposes via a first order reaction, there are 0.360
mol/L left after 66.3 seconds. Calculate the rate constant, k, in sec-1.

Student Response Value Correct Answer


Answer .0153 100% 0.0153

Score: 1/1

Done

5 of 5 27-Sep-09 6:31 PM