COATINGS WEG Rodovia BR 280, Km 50 - Phone: +55 (47) 3276-4000 - Fax: +55 (47) 3276-5500 - CEP 89270-000 - Guaramiri m SC EMERGENCY: +55 (11) 5012-5311 - E-mail: tintas@weg.net - www.weg.net 1. PRODUCT AND COMPANY IDENTIFICATION Product Name: LACKPOXI N 1277 GRAY Internal Code: 10002943 3,12 L Company Name: WEG Indstrias S.A. Qumica Address: Rodovia BR 280, Km 50 CEP 89270-000 - Guaramirim SC Tel: (+55) 47 3276-4000 Fax: (+55) 47 3276-5500 Emergency Number : (+55) 11 5012-5311 (Intoxication Control Center ) E-mail and site: tintas@weg.net - www.weg.net
2. HAZARDOUS INGREDIENT INFORMATION Product Type: Prepared Chemical characteristic : Epoxy Paint based in solvent . Hazardous ingredients:
Name CAS N Concentration Synonyms Risk Classification Xylene 1330-20-7 10 30% DiMethyl benzene; Methyl toluene T, F + , Xn, Xi Epoxy Resin of Bisphenol A 25068-38-6 10 40% - - Zinc 7440-66-6 60 90% Blue powder; Merrilite F +
Classification System: The compounds have been classified according to Directive 67/548/EEC
3. HAZARD IDENTIFICAT ION Main Hazards: Teratogenic Product. The product may also cause fetal abnormalities when had chronic exhibition. Pregnant that are on show with a tolerat e concentration above to the limit could present threat of miscarriage.
Health Effects: Ingestion: Ingestion of this product may cause mouth and throat irritation, gastrointestinal discomfort, headache, weakness and nausea.
Eyes: Direct contact of the liquid with the eyes, can cause burn or irritation and chemical conjunctivitis
Inhalation: It can cause irritation in the throat and nose, breathing ways, nauseas, headaches, lung hemorrhage, lose of unconsciousness.
Contact with S kin: Contact with the product can cause dry skin, irritation and contact dermatitis.
Specific Risks: Inflammable liquid: when it was warm abo ve your point of loom, this mate rial wi ll release toxic vapor and flame, and could be burn in the open area if on show in one source of ignition.
4. FIRST AID MEASURES First-Aid Measures Call to the CCI Intoxication Contr ol Center if any doubt or necessity of more information. Phone: (55) (0xx11) 5012-5311 (Available 24 hours a day).
MATERIAL SAFETY DATA SHEET MSDS
Product Name: LACKPOXI N 1277 GRAY Last revision date: 15/12/08 Pgina: 2 / 7
COATINGS WEG Rodovia BR 280, Km 50 - Phone: +55 (47) 3276-4000 - Fax: +55 (47) 3276-5500 - CEP 89270-000 - Guaramiri m SC EMERGENCY: +55 (11) 5012-5311 - E-mail: tintas@weg.net - www.weg.net Inhalation: If vapors, mists or sprays of the product are inhaled, remove victim to fresh air. Keep person warm and quiet. If t he breathing is irregular or has stopped, give artificial respiration. Never give anything by mouth to an unconscious person. Rescuers should be taken for medical attention. Take copy of label and MSDS to health professional with victim.
Skin Exposure : Remove exposed or contaminated material. Remove product with vegetal oil (coking oil). Wash contaminated skin with plenty water. Do not wash contaminated skin with thinner or solvent. Seek medical attention if any skin irritation or adverse reaction or oth er symptoms occurs.
Eye Exposure: Immediately flush thoroughly with running water for at least 15 minutes. Open victims eyelids while under gentle running water. Remove contact lens, if any. Victim must seek immediate medical attention. Take copy of l abel and MSDS to health professional with victim, if possible. Call physician.
Ingestion: If swallowed, do not induce vomiting. Call physician and take copy of label and MSDS with victim if possible.
Measures to be avoided : Induce vomiting. Brief description of the main symptoms and effects : Headaches, dizziness, fatigue, muscle weakness, somnolence, and in extreme cases, unconsciousness. Special notes to Physician: Do a symptomatic treatment. No induce vomit due to risk of aspiration of the gastric content to the lung. The gastric-cleaning is indicate when the pacient intromit a big quantity, more t han 5 ml of the substance in the pu re form. The toxic potential of quantity intromited must be valued according to the risk of aspiration of the gastric- cleaning. The activated coal in solution m ust be useful. However, in same cases the coal induce vomiting.
5. FIRE-FIGHTING MEASURES Fire extinguishing material: Foam, dry chemical, CO 2, water spray. Not recommended fire extinguishing mat erial: Water jet. Specific Risks: The fine particles dispense will take form to the explosive mixtures in the air . In case of fire or dense black fumes, the harmful decomposition products inhalation can provoke health problems. Especial Methods: Refresh closed receptacles aro und the fire. Evacuate immediate area and fight the fire from safe distance. Retain the water used in firefighting in dikes and dispose it in accordance with local hazardous waste disposal regulation. Use water spray or fog to catc h cold containers exposed to fire. Large fires in the storage area should be fought from a safe distance with an unmanned hose holder or monitor nozzle. Firefighter protection: Firefighters must wear self -contained breathing apparatus and full protect ive equipment .
6. SPILL / LEAK CONTROL PROCEDURES Personal protective equipment : Proper personal protective equipment should be used. Evacuate immediate area. Avoid inhalation of fogs/vapor and direct contact with product. Do not smoke.
Eliminate all sources of ignition : Eliminate and/or isolate all sources of ignition. Signal and ventilate area of spill. Use non-sparking tools.
Dust control : Not applicable, since it is a liquid product.
Prevention of inhalation, skin absorption, contact with eyes Proper personal protective equipment should be used, such as: rubber gloves, face mask with OV filter (Organic Vapors) and goggles
MATERIAL SAFETY DATA SHEET MSDS
Product Name: LACKPOXI N 1277 GRAY Last revision date: 15/12/08 Pgina: 3 / 7
COATINGS WEG Rodovia BR 280, Km 50 - Phone: +55 (47) 3276-4000 - Fax: +55 (47) 3276-5500 - CEP 89270-000 - Guaramiri m SC EMERGENCY: +55 (11) 5012-5311 - E-mail: tintas@weg.net - www.weg.net and mucous membranes: Environment protection : Prevent material or firefighting waste water from entering into se wer and river beds. In case of significant spill, retain spilled liquid with inert material, such as sand or e arth. If suitable, absorb spilled liquid with absorbent materials, such as sawdust, cotton waste or other suitable materials.
Cleaning Procedures:
Recovery: Remove contaminated diking mater ial with a vacuum-truck and transfer it to an emergency tank. Earth all used equipment. Maintain product in closed emergency containers proper ly labeled for later recovery or di sposal.
Elimination: Incinerate all contaminated material in authorized plant. Do not pour the product into sewers. The final disposal of this material should be followed -up by disposal experts and made in accordance with the environmental regulations.
7. HANDLING AND STORAG E HANDLING
Technical Measures:
Exposure Control Personal Protection: The use of face mask with OV filter (Org anic Vapors) is recommended. Use appropriate eye protection in case of eventual chemical splash eye contact exists. Wear rubber glov es to avoid direct contact of the product with the skin.
Fire and Exp losion Prevention: Adequate local exhausting ventilation should be provided to keep vapor concentration below explosive limits. All conductive parts of the system in contact with the product shall be grounded electrically. Do not smoke in the working area.
Safe Handling Precaution: Handle product in accordance with safety regulations and industrial hygiene. Emergency showers and eye wash basin shall be provided in the working and storage areas.
Safe Handling Informatio n:
Avoid skin, eye and mucous membrane exposure and vapor inhalation. Do not reuse empty containers. Do not smoke, consume or store food or drinks in areas where the product is handled or stored. Wash hands after handling. Handle the material in cool and well -ventilated areas, far away from flames, sparks or heat sources
STORAGE
Technical Recommendations : The electrical installation must meet the requirements of the standards NEC (National Electrical Code) or IEC (International Electrical Commission) and/or ABNT (Brazilian Association of Technical Standards). The floor of the storage area must be waterproof, not combustible and shall be provided with outfall ditches for draining the product to damming tanks. Storage tanks m ust be surrounded by damming tanks and fitted with draining devices to enable fast drainage in case of leakage
Storage Conditions:
Suitable:
Store the product in a dry, well -ventilated covered area with good marking. Keep this product away from heat and sparking sources, away from foods and strong oxidizer. Keep containers always closed and well identified.
Avoid: Avoid to exposing the product to high temperatures, rain or direct sunlight exposure.
MATERIAL SAFETY DATA SHEET MSDS
Product Name: LACKPOXI N 1277 GRAY Last revision date: 15/12/08 Pgina: 4 / 7
Non-compatible Products and Materials : Do not store the product near explosi ve materials, flammable and/or toxic gases, oxidizers and corrosive agents or near materials that may generate spontaneous combustion.
Safe Materials for Packing : Recommended: Metallic and/or amber type glass containers Unsuitable: Some plastic mate rials
8. EXPOSURE CONTROL PERSONAL PROTECTION Engineering Controls Provide suitable ventilation. Maintain product concentration level below recommended tolerances (T.L.). Otherwise, use suitable breathing mask.
Specific Control Parameters: Occupational Exposure Limit: Name TLV/TWA (ppm) TLV/STEL (ppm) TLV/TETO (ppm) Zinc - - - Xylene 100 150 - N-Butanol 50 - - Source: ACGIH - American Conference of Gov ernmental Industrial Hygienists
Recommended monitoring procedures In areas where chemical products are handled, you must monitor the people exposure according to (PPRA), (Environmental Risk Prevention Program) from NR-9.
Suitable individual personal protection equip ment: Respiratory E quipment: Use respiratory equipment with VO -filter, when concentrat ion level is lower than the tolerance limit and there is no oxygen deficiency. Otherwise, when concentration level is higher than the tolerance limit and there is oxygen deficiency, use respiratory equipment with VO filter and air s upply
Hand Protection: When exposure is prolonged and repeated, wear nitrile rubber gloves. Protection creams may be used for protecting exposed skin areas (never use these creams after exposure).
Eye Protection: Use hermetic goggles for protecti ng eyes against splashes.
Skin and Body Protection: Wear antistatic clothes made of natural fibers and/or made of synthetic fibers resistant to high temperatures. If the product contacts the skin, begin immediately decontamination area with running wa ter.
Special precautions : Only well trained people should handle chemical products. The EPIs should be Approval Certified. When chemical product is handled, follow strictly all recommended operational and safety instructions inform ed by the manufact urer of the chemical product. Never r euse empty containers of chem ical products for storing foods. Monitor the people exposure in area where chemical products are handled. Adopted monitoring procedure shall be in accordance with PPRA (Environmental Risk P revention Program) from NR -9.
Hygiene Measures: Clean clothes and shoes thoroughly after use. General control methods applie d in Industrial Hygiene should minimize product exposure. Do not smoke, consume food or drinks when che mical products are handled.
9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid Color: Gray
MATERIAL SAFETY DATA SHEET MSDS
Product Name: LACKPOXI N 1277 GRAY Last revision date: 15/12/08 Pgina: 5 / 7
COATINGS WEG Rodovia BR 280, Km 50 - Phone: +55 (47) 3276-4000 - Fax: +55 (47) 3276-5500 - CEP 89270-000 - Guaramiri m SC EMERGENCY: +55 (11) 5012-5311 - E-mail: tintas@weg.net - www.weg.net Smell: Characteristic pH: not applicable, non-aqueous solvent . Specific temperatures or temperature ranges where occurs changes in the physical state : Boiling Point (C): 167,5 Decomposition Temperature (C): N.A. Flash Point (open cup C): 40,0 Self-ignition Temperature (C): 527 Explosiveness Limits : Lower: 1,0%
The information indicated abo ve was derived from components present in higher concentration levels.
10. STABILITY AND RECTIVITY Specific Conditions:
Instability: Product is stable in the recommended storage and handle conditions.
Dangerous reactions: No dangerous reaction occurs when product is stored, handled and processed correctly.
Conditions to be avoid : Avoid exposing p roduct to extremely high temperatur es and to open flames. Material with which product is incompatible: Plastic material soluble in the Xylene. Requirement for addition of additives and inhibitors : Not required. Dangerous decomposition products : Product generates harmful gases, such as carbon monoxide (CO), carbon dioxide (CO 2), nitrogen oxide (NOX).
11. TOXICOLOGICAL INFORMATION Information in accordance with the different exposure conditions :
Acute Toxicity The Xylene is very soluble i n the blood and in the tissue, especially in the greasy tissue. Is absorbed too through the skin in the liquid form and in the vapor form. Exposure to component solvent vapors in concentration levels above occupation exposure limits my have adverse effect on the health, such as irritation of the mucous membrane and respiratory system, harmful effect t o kidney, liver and central nervous system The symptoms include headaches, dizziness, fatigue, muscle weakness, somnolence, and in extreme cases, unconsciousne ss. Repeated or prolonged contact with the skin can cause the loss of the natural skin oil, resulting in non -allergic contact dermatitis and dry skin due to absorption. Can cause skin sensibility and, sometimes the risk are irreversible. Direct contact wit h the eyes, can cause irritation.
MATERIAL SAFETY DATA SHEET MSDS
Product Name: LACKPOXI N 1277 GRAY Last revision date: 15/12/08 Pgina: 6 / 7
Xylene Zinc rat, oral: 4300 mg/kg - DL50 rabbit, skin: > 1700 mg/kg - CL50 rat, inhalation: 5000 ppm for 4 hours Man inhalation: 124mg/m 3
Carcinogenicity A4 Non classified as carcinogenic for human A4 Non classified as carcinogenic for human Mutagenicity Non classified as mutagenic product Non classified as mutagenic product Teratogenicity* Teratogenic Product Teratogenic Product
Chronic Toxicity : Prolonged contact of the product with the skin removes the oil from the skin and may cause skin fissures, dryness, dermatitis and eczema. The mo st common disturbs relating t o the formulation components are fatigue, headaches, irr itability, dizziness, fatigue, weakness, unconsciousness, somnolence, humming, humor and equilibrium disturbs, nauseas and appetite loss. Also the respiratory system may be affected by chronic bronchi tis and reduction of the breat hing volume. The product may al so cause infertility, fetal abnormalities, and renal pathologies in kids whose mothers have been exposed to the product. Exposure of pregnant women to concentrations above the tolerance limits ma y cause miscarriage. The product may also cause anemia and affect the central nervous system and the peripheral nervous system, causing vascular and nervous injuries, headaches, irritability, visual disturbs, unconsciousness, wild, convulsion, lost the mot ors and sensorial functions. Toxic to kidney and digestive disturbs.
12. ECOLOGICAL INFORMATION Product behavior and impact on the environment : As the product is not totally biodegradable, do not contaminate sewer and river beds, soils and waterc ourses.
Mobility: The product infiltrates easily into the soil. Bioacummulation: Product is not potentially bioaccumulative. Ecotoxicity: The product is harmful to fauna and flora. It contaminates ground waters .
13. DIOSPOSAL AND TREATMENT CONSIDERATIONS Treatment Methods for Disposal Product : Do not discard the product into sewers, rivers, lakes and watercourses. Dispose it in landfills or incinerate it in accordance with the local regulations.
Product re sidues: Do not discard the pr oduct residues in watercourses. Dispose it in landfills or incinerate it in accordance with the local regulations.
Used containers: Discard them in authorized installation. Do not reuse empty containers.
14. TRANSPORTATION INFORMATION National and Interna tional Regulations:
Truck/rail ONU 1263 Hazard Category 3 Hazard Class Number 30 Packing Group III Proper Shipping Name Related material to Coating Ocean IMDG / GGVsea / ONU 1263 Hazard Category 3 Hazard Class Number 30 Packing Group III EmS F-E,S-E MFAG 310,330
MATERIAL SAFETY DATA SHEET MSDS
Product Name: LACKPOXI N 1277 GRAY Last revision date: 15/12/08 Pgina: 7 / 7
COATINGS WEG Rodovia BR 280, Km 50 - Phone: +55 (47) 3276-4000 - Fax: +55 (47) 3276-5500 - CEP 89270-000 - Guaramiri m SC EMERGENCY: +55 (11) 5012-5311 - E-mail: tintas@weg.net - www.weg.net Proper Shipping Name Related material to Coat ing Air ONU 1263 Hazard Category 3 Hazard Class Number 30 Packing Group III Proper Shipping Name Related material to Coat ing
15. REGULATORY INFORMATION Information about hazard and safet y as indicated on label: Product is labeled in accordance with decree law 120/92 dated 06.30.92 and administrative ruling 1164/92 dated 12.18.92.
Hazard Class: I Inflammable
16. ADDITIONAL INFORMATION Used Abbreviations Glossary:
F + Highly inflammable T Toxic Xn harmful Xi Irritant N Harmful to the environment CAS Chemical Abstract Service VO Organic vapors NEC National Electrical Code IEC International Electrical Commission ABNT Brazilian Association of Technical Standards ACGIH American Conference of Governmental Industrial Hygienists TLV Threshold Limit Va lue TLV/TWA Threshold Limit Value/Time Weighted Average TLV/STEL Short Term Exposure Limit TLV/C Threshold Limit Value / upper limit EPI Personal protect ive equipment CA Approval Certification PPRA Prevention Program for Environment Hazard NR Regulatory Standard NFPA National Fire Protection Agency mmHg Millimeters of mercury pressure unit DL50 Lethal average dose CL50 Average lethal concentra tion ppm parts per million N. A. Not available
The information contained here is based on our current knowledge on the product and is in accordance with standard NBR 14725. However the working conditions adopted by the user are out of our k nowledge and control. The product should not be used for other purposes, without previous written authorization by manufacturer than its application through the current available and proven suitable methods. User is responsible for meeting all regulatory requireme nts.