5.

2 TEST MS
1. (a) (i) Equation Na
2
O + H
2
O 2NaOH (1)
pH 1114 (1)

(ii) Equation SO
2
+ H
2
O H
2
SO
3
(1)
pH 25 (1)

(b) Covalent oxides acidic solutions (1)
ionic oxides alkaline solutions (1)
[6]
2.
(i) Maco!olecula"#iant covalent"#iant !olecula
(ii) Silicon"Si
(iii) e$#$ CaO + SiO
2
CaSiO
3
%ase
%alanced
[4]
3. (a) (i) SO
2
+4
(ii) 4& + 5O
2
2&
2
O
5
o &
4
+ 5O
2
&
4
O
1'
(b) (i) %
(
)*e+ *ave lo, !eltin# -oints
o t*ee ae ,eak van de .aals /oces bet,een !olecules
(ii) 0dd ,ate o *eat in a /la!e
)est -H c*eck /la!e colou
13"14 +ello,
[9]
4. (a) (i) can form a solution with pH less than 31 &
4
O
1'
o SO
3
(1)
(ii) can form a solution with with a pH greater than 121 Na
2
O (1)
penalise any wrong answer to zero
(b) (i) M#O + 2HNO
3
M#(NO
3
)
2
+ H
2
O o an ionic e2uation (1)
i$e$ M#O + 2H
+
M#
2+
+ H
2
O
not O
2
+ 2H
+
H
2
O
(ii) 2NaOH + SiO
2
Na
2
SiO
3
+ H
2
O o ionic e2uation (1)
i$e$ SiO
2
+ 2OH

2Na
+
+ H
2
O
(iii) 3Na
2
O + 2H
3
&O
4
2Na
3
&O
4
+ 3H
2
O etc o ionic e2uation (1)
i.e. Na
2
O + 2H
+
2Na
+
+ H
2
O
5. (a) (i) NaOH !a+ be s*o,n as ions$ %alanced usin# H
2
o 3 H
2
2Na + 2H
2
O 2NaOH + H
2
(ii) silicon /o!s a #iant covalent " ato!ic lattice " *as a
!aco!olecula stuctue " *as dia!ond stuctue (1)
contains !an+ covalent bonds " /o!s 4 bonds -e
ato! " lattice is ston# " t*e bondin# is ston# " bonds ae
ston# " silicon is non4-ola (1)
condone 5bond is ston#6

(b) (i) SiO
2
" &
2
O
5
" &
4
O
1'
" &
2
O
3
" &
4
O
7
" SO
2
" SO
3
" Cl
2
O " ClO
2
"
Cl
2
O
7
" Cl
2
O
8
(ii) Na
2
O " Na
2
O
2
" M#O
(iii) 0l
2
O
3
!ust #ive /o!ulae
[6]
6. (a) (i) 9eductions1
:onic (1)
:ons not /ee to !ove in t*e solid state (1)
:ons /ee to !ove ,*en !olten o in a2ueous solution (1)
:dentit+ o/ P1 Na
2
O o sodiu! oxide (1)
N.B. If a formula given this must be correct
(2uation1 Na
2
O + H
2
O 2 NaOH (1)
(ii) 9eductions1
Covalent
:nte!olecula /oces ae ,eak o van de .aals /oces;
o di-ole4di-ole
N.B. Any answer including a reference to hydrogen
bonding is incorrect
:dentit+ o/ Q1 SO
2
o sul-*u dioxide (1)
(2uation1 SO
2
+ H
2
O H
2
SO
3
(1)
NB Allow ma one for !"
#
4
(b) (i) 0!-*oteic (1)
(ii) (2uation ,it* NaOH
0l(OH)
3
+ NaOH Na0l(OH)
4
"$ Al%"&'
#
%&
(
"'
#
) "&
*
[Al%"&'
4
%&
(
"'
(
]
*
) &
(
"
"$ Al%"&'
#
) "&
*
[Al%"&'
4
]
*
R identi/ied as 0l(OH)
3
o 0l(OH)
3
(H
2
O)
3
(1)
0 balanced e2uation (1)
N.B. Allow e+uation with si co,ordinate Aluminium and u- to
si "&
*
ligands
N.B. Allow e+uation mar. if /%"&'
#
given in a balanced
e+uation
(2uation ,it* H
2
SO
4
20l(OH)
3
+ 3H
2
SO
4
0l
2
(SO
4
)
3
+ 7H
2
O
O< 0l(OH)
3
(H
2
O)
3
+ H
+
=0l(OH)
2
(H
2
O)
4
+
+ H
2
O
NB Allow e+uations with si co,ordinate Aluminium and u- to
si &
(
" ligands
NB Allow e+uation mar. if &%"&'
#
given in a balanced e+uation
Coect 0l s-ecies as -oduct (1)
0 balanced e2uation (1)
(iii) >a#e lattice ene#+
o ston# covalent bonds
o H
soln
is ve+ -ositive
o ? is ve+ -ositive
o su! o/ *+dation ene#ies less t*an covalent bond ene#ies (1)
[01]
(c) &
4
O
1'
is a !olecula (stuctue) o si!-le covalent (1)
.eak inte!olecula /oces o van de .aals /oces (bet,een !olecules)
(1)
SiO
2
is a !aco!olecule " #iant covalent " #iant !olecule (1)
Not giant lattice
(Ston#) covalent bonds (bet,een ato!s) !ust be boken (1)
[9]