Historical photographic processes

Thanks to developments in photographic technology in recent years, the creation of

technically perfect photographs is becoming a simple matter, even for those with no
specialist knowledge. Digital photography can now be used very easily for purposes of
information and documentation, and traditional photography can hardly compete with it in
this area.

Of course, if we examine the potential of digital photography for individual artistic creation,
it soon becomes clear that formulaic photo-editing programs, and the essential sameness of
digital prints, even when the photographs are of completely different types, lead to a certain
predictability in the results. The photographs are perfect, but all very much alike.

The easier it becomes to take digital photographs and prepare them for printing, the more
likely it is that people will want to return to the techniques of traditional photography for
their creative efforts, or to combine the techniques of digital and traditional photography,
especially when producing the final version of a photograph in the creation of a unique,
artistic original, or in other words, in the actual process of transferring the picture to paper.

One of the basic characteristics of traditional photography, based on the sensitivity of silver
salts to light, is the fact that the photographer can carry out many of the processes himself,
adding his own creative touch. The final photograph can take many different forms. Each
picture is a unique original. This variety in working methods, the utterly individual
character of the result, and the fact that we are always producing an original work, will
undoubtedly enable traditional photography to hold its own, though now in the role of an
artistic technique.

If we look abroad, we find that alternative photographic techniques are steadily gaining in
popularity. These are in fact revived historical techniques dating from the beginnings of
photography. In the USA, there was an increased interest in the 1980s, but this has
increased further in the last few years. Processing kits for practically all the processes ever
used are available on the market there. Although some are rather expensive, people buy
them. A particular favourite is platinotype, despite the fact that the set of processing
chemicals costs about $130. There have been dozens of US publications on the subject,
regular creative workshops are organised and there are many articles on the internet, where
there is also a discussion group.

Old photographs have a charm of their own. They are unreproducible, each is a unique
creation, and even when several are printed from a single negative, no two are exactly the
same. A high proportion of personal creativity goes into each photograph. Every picture is
different produced by a different process, on different paper, with different tonality.
Photographs printed in the modern minilab, though they are cleanly produced, free of grain
and in perfect colour, are worlds apart from carbon or platinum prints.

We know from the history of photography that high-grade printing methods survived for
a long time. For example, many of our photographers continued producing oil prints and
bromoil prints until the 1930s, although gelatine silver-bromide paper of a type which is
still used today, without any substantial changes had long been widely available. Why did
people continue so long with those laborious, time-consuming processes? Perhaps because
their greater malleability brought greater pleasure and satisfaction in the results.

Those who are interested in individually oriented creation find even greater possibilities in
historical photographic processes than in classical photography: not only is there a range of
processes (salt process, cyanotype, platinotype, oil print etc.), but there is a choice of
methods for achieving the final result (sensitising solution, type of paper, method of
processing etc.).

In todays conditions the historical processes most widely used are those which involve
copying a negative. Sensitising the paper for copying is much more practicable than, for
example, preparing light-sensitive glass plates for the collodion process. This means that the
first part of the negative-positive process, i.e. the negative, has to be achieved by other
means.

The old photographic techniques all involve contact printing, so we need a negative of the
same size as the final photograph. In classical photography, this means either photographing
directly in large format, or making a duplicate negative of the required size. Only a
photographer with a fair amount of experience and a well-equipped darkroom can handle
this task.

Digital technology now makes it possible to create negatives without a darkroom. Many
believe it is precisely this fact that has contributed to such an upsurge of interest in
historical methods in the last few years.

In any case, historical photographic techniques do not require a conventional darkroom. The
sensitive paper is prepared and processed with an ordinary low-wattage tungsten bulb. For
the exposure, an enlarger is not necessary; a wooden contact-printing frame with glass is all
that is needed. The exposure can be made outdoors, for example on a balcony.

With its freedom from conventional photographic technology, this entire creative field is
opening up to people with no photographic background all you need to do is print the
negative on transparent film, coat suitable paper with the chosen sensitive solution, make a
contact copy, and then process the picture in low-intensity artificial light.

There are many different processes to choose from within the range of what is affordable,
of course. If you make a pinhole camera and use the salt process, youll get pictures at less
cost than with classical photography. But if you choose the higher-grade platinum process,
you may spend ten times as much.

One thing is certain: the pictures will be interesting and nice to look at, whichever of these
processes is used even the cheapest, cyanotype. The high proportion of handwork clearly
plays a role here, lending a touch of artistry.

In the Czech Republic, historical photographic processes are of course still waiting to be
discovered. The sets of chemicals needed for processing are not yet available on the Czech
market, and buying them from the USA is probably rather expensive for the average Czech.
There is no literature in this field in Czech. Foreign books are difficult to track down and
are expensive. There is some information on the internet, but for the moment, of course,
only a few people can read English. And of those people, not many will start trying things
out for themselves they would have the difficult task of tracking down the chemicals and
trying everything from scratch, with only the literature to guide them. Far better to start on
the more complex processes when someone has shown us, first hand, the methods they use
and the potential difficulties. We will be more inclined to try things out for ourselves if we
see some fine pictures at an exhibition or in a friends collection. For the moment, thats
still something to look forward to.

Types of historical contact processes

1. Processes based on the light sensitivity of silver salts

The sensitive material is silver chloride and the resulting image is formed by particles of
silver. Silver chloride can be dispersed in various types of binding agent.

The salt process (salted paper prints)

Suitable paper is coated with a solution of sodium chloride (table salt) and then, after
drying, with a solution of silver nitrate. This produces silver chloride, which is sensitive to
light. The picture is produced directly upon exposure (contact process). After exposure, the
surplus silver nitrate and silver chloride are washed off in water, and a thiosulphate fixer is
used. The image is formed by fine particles of silver anchored directly in the mass of the
paper, without a binding agent. Because of the large number of silver particles and the fact
that they are finely dispersed, the picture is reddish-brown in colour (as with all other
contact processes). The salt process was first used by Fox Talbot in 1834. Salt papers were
most widely used in the years 1840-1850 (alongside daguerrotypes). Most of the
photographs on paper dating from those years were produced directly by the salt process.
Some of them are toned with salts of gold or platinum and their colouring varies often
brownish-black, blue-black or a neutral grey-black. A gold or platinum image is not
susceptible to changes due to the surrounding atmosphere, and is notably long lasting.

For its simplicity and convenience, and especially because it is so easy to understand, the
salt process is very suitable for use in todays conditions. It is not as problem-free as, for
example, the Van Dyke brownprint (see below), but the knowledge that we are working just
as photographers did in the 1850s is something quite magical.

In the National Technical Museum, we have devoted a great deal of attention to
reconstructions of the salt process because this was the process used in 1835 by the inventor
of photography on paper, Fox Talbot, for preparing his first pictures. A further advantage is
the fact that the mechanism and chemical reactions of the salt process are so simple and
straightforward that even a reasonably attentive schoolboy can easily understand them.

The albumen process

Thin paper is laid on the surface of some salted egg white. After drying, it is coated with a
solution of silver nitrate. As in the salt process, the image is formed by fine particles of
silver, but these are not embedded directly in the paper, but in the layer of the binding agent
of egg white which the surface of the paper is coated with. This makes it possible to achieve
a more saturated black and greater brilliance and contrast.

The albumen process was most widely used in the years 1855-1895 most of the
photographs dating from those years are on albumen paper. The image, as in the case of the
salt process, is reddish-brown. It is often toned with gold or platinum. This increases its
resistance to environmental factors. But albumen photographs are almost always yellowed
in the lighter parts, because of the ageing of the binding agent itself egg white.

Collodion papers

Silver chloride is held in a binding medium consisting of a mixture of collodion and
camphor. Collodion is cellulose tetranitrate dissolved in ether and alcohol. On a paper base,
the binding agent containing silver chloride (the emulsion layer) is covered with a layer of
barium sulphate with gelatine. The image is formed by fine particles of silver in the layer of
binding agent, and as with other contact processes, it is reddish-brown. The surface may be
either glossy or matt.

Collodion papers were very popular and were used from 1865 until the 1920s. Most studio
portraits from that time were taken on collodion paper. They were often toned with salts of
gold or platinum.

Gelatine papers

In appearance, these are almost indistinguishable from collodion papers, but instead of
collodion, gelatine is used as the binding agent. They were used from 1884 until the 1920s,
concurrently with collodion papers, but they were too expensive to compete with collodion.
Once again, the image was reddish-brown, and was often toned with gold or platinum.

All the processes mentioned so far are contact processes, in which the picture is produced
during the exposure, and subsequent processing merely gives it definition and stabilises it.
This distinguishes them from the other group of processes, known as developing
processes, in which only a faint (or even invisible) image is created during exposure, and is
developed by subsequent processing. We shall discuss some developing processes below.

2. Processes based on the light sensitivity of iron salts

These processes use ferric salts of organic acids which, under the action of light (its
ultraviolet component), are reduced to ferrous salts. For example, ferric oxalate is reduced
to ferrous oxalate. This ferrous oxalate is retained as a reducing agent which reduces the
ions of noble metals such as silver, platinum or palladium into a solid metallic state,
creating the picture. The sensitive solution is applied directly to the paper, so that the
picture is anchored directly in the paper without a binding agent.

Instead of the salt of a noble metal, the cyanotype process uses potassium
hexacyanoferrate(III), which, with a ferrous salt (produced from a ferric salt under the
action of light), creates a blue pigment.

The cyanotype process

The sensitising solution contains iron ammonium citrate and potassium
hexacyanoferrate(III). Developing is done in water. Depending on the method used, the
image is created in Turnbull or Prussian (Berlin) blue. The image is produced directly
during exposure; this is therefore a contact process. It was in use from 1842 onwards.

Cyanotype is, relatively speaking, a very simple, quick and inexpensive process. For this
reason, it is one of the first processes tried by many of the people who are now turning to
historical photographic techniques. If the picture is toned, there are many options. It can be
toned with tea, coffee or tannin after previous bleaching with alkali. Salts of lead or copper
are also used. Depending on the toning used, it is possible to obtain various shades of grey,
black, brown, red or yellow.

The callitype process

The sensitising solution contains ferric oxalate and silver nitrate. The image is formed by
metallic silver. During exposure, only a very faint image is produced; this is intensified by
subsequent development in a solution of borax or sodium potassium tartrate. This is
therefore a developing process. It came into use in 1844.

The platinotype process

The sensitising solution contains ferric oxalate and potassium chloroplatinate. A faint image
is produced, and is developed in a solution of potassium oxalate or some other organic acid
salt. The image is formed by particles of metallic platinum embedded directly in the paper
(process in use from 1873 onwards).

Platinotype is a very popular process in the USA, despite the fact that it is, relatively
speaking, quite expensive. Apparently the US tradition plays a part here a number of
famous photographers in the last century used this technique to create many impressive
photographs, which people come across in exhibitions, and quite naturally this stimulates
their desire to make their own platinum prints. Another reason may be the fact that this
technique produces completely unique and valuable pieces of work, which may survive not
only us, but perhaps several generations to come, without any deterioration.

Van Dyke brownprint

The sensitising solution contains iron ammonium citrate and silver nitrate. The image is
created during exposure a contact process. This is followed by washing in water and
fixing in thiosulphate. The image is formed by metallic silver of a reddish-brown colour,
without a binding agent, directly in the paper. The process was in use from 1889 onwards.

The Van Dyke brownprint is another relatively simple, rapid process which may present
fewer problems than other processes. With suitable paper, a satisfying result can be
achieved on the very first attempt. The processing of the exposed image is simple, too no
chemicals other than fixer are required.

The process as a whole is quite inexpensive. The sensitising solution contains just three
ordinary substances. One of them is silver nitrate, which is quite expensive, but because
only a little sensitising solution is needed to coat the paper, the process does not cost too
much. And the resulting picture looks every bit as good as, say, a platinotype, which is
considerably more complex and many times more expensive to produce. But if we still wish
to achieve the qualities of a platinotype by this process, we can tone the finished picture
with salts of platinum or palladium, or both together. This gives a platinum/palladium-based
picture, i.e. a copy identical in quality at about one quarter of the price of a platinotype. Of
course we choose only the really successful pictures for toning, which is likely to mean a
further saving.

The main advantage of platinotype is its durability. But if we want to use the old processes
mainly for pleasure, the advantage of unlimited durability is probably not so essential.
Although silver-based photographs produced by contact processes are less stable than those
on modern baryta papers, our pictures will probably survive us just the same. Although the
surviving photographs on salted papers from the 1850s have faded considerably, the images
are still clearly visible and have their own charm.

The relative affordability and advantages of the Van Dyke brownprint have led us, at the
National Technical Museum in Prague, to start with this process as the first to be presented
in our creative workshops, Reconstruction of Historical Photographic Processes. These
workshops are intended for interested members of the public, and the aim is that
participants should become sufficiently familiar with the old processes to be able to use
them at home. We will provide them with the necessary chemicals for this purpose.

3. Processes based on the light sensitivity of bichromated gelatine or gum arabic (high-
quality prints)

These are based on the fact that bichromated gelatine and gum arabic (known as glue
stock) harden in light, so that that they no longer swell in water and are not soluble in it.
The parts of the picture which have not been exposed to light remain water soluble and are
washed away during development in water. In the case of a pigment print, the image is
formed by pigment which is finely dispersed in the binding medium when the sensitive
layer is prepared. In the case of oil and bromoil prints, the image is formed with colour
applied subsequently to the relief which was produced in the gelatine when the light-
exposed surface was washed in water. In this way it is possible to obtain sharp, high-quality
halftone images.

Before exposure, the paper is sensitised with a solution of potassium or ammonium
dichromate.

The paper is exposed to light with a significant proportion of UV radiation, and developed
in water; no fixer is used.

Pigment prints

The sensitive paper is prepared as follows: suitable paper is coated with a layer of gelatine
containing finely dispersed pigment. This may be a pigment powder or carbon powder in
which case, it is called a carbon print.

Before exposure, the paper is sensitised by soaking in a solution of potassium bichromate.
After drying, the paper is exposed to produce a contact negative. The exposed paper is
soaked and then pressed onto transfer paper (paper coated with a layer of pure gelatine).
The image from the original paper adheres in its entirety to the transfer paper, so that its
bottom layer is now on the top. All parts of the original gelatine with pigment which were
not exposed to light (and are therefore not hardened) can now be washed off with water.
This produces an image which has the thickest covering in the places which were exposed
to the most light, as a result of the hardening of the pigmented gelatine. In this way, a
positive is obtained from the negative. The original paper, on which the exposure was made
and from which the entire image was detached, is then discarded.

Pigment prints, particularly carbon prints, were once very popular among our
photographers, and we often see them in exhibitions. If you learn to prepare pigment paper
yourself, you will find it is a relatively simple and rapid process. Since inorganic pigments
are very stable, the picture is almost as durable as a platinotype.

Gum prints

The paper is coated with a solution of gum arabic with potassium dichromate, to which
watercolour or tempera paint or powder pigment has been added. After drying, the negative
is copied in sunlight, in a contact printing frame. After exposure, the picture is only slightly
modulated. It has to be developed in cold water, which dissolves the unexposed areas,
leaving the exposed areas (the shadows in the picture). Because of the thinness of the layer,
the exposed parts reach the surface of the paper and adhere firmly to it, so that the picture,
unlike pigment prints, does not need to be transferred. During development in cold water,
the unexposed parts are washed away, with the colour, as far as the surface of the paper.
The picture does not require any fixing, because the chrome salt is washed away as well.

Gum printing is thus a very simple method, but in order to get good results, we need to gain
some experience. We also have to accept the fact that the single-stage gum print described
above cannot reproduce all the halftones of the negative. With the single-stage process,
there is always a certain amount of detail missing, either in the highlights or in the shadows
depending on how the sensitive layer is prepared, and the choice of exposure and
development times.

A picture with saturated shadows and more detailed highlights can be obtained only by
several stages of re-copying. After the first development and drying, which provides only
middle tones, the picture has to be coated again with a sensitive solution containing less
gum arabic and colour; it is copied again and developed until the highlights appear. After
drying, it is coated again, with a solution containing the largest amount of gum arabic and
colour, and copied for a shorter time, then developed until only the deepest shadows remain.

For a good rendition of tones, it is often necessary to make a second and third print. Usually
it is also necessary, between individual prints, to size the paper again, because the original
sizing agent is washed off the paper during processing in water. If the paper is not re-sized,
the sensitive solution penetrates deep between the fibres of the paper and cannot be washed
out during processing, so that there is a haze of colour even in the clearest highlights.

A multilayered gum print with well reproduced halftones is thus quite labour intensive and
cannot be prepared in one day. But even with single-stage gum printing, it is possible to
obtain perfectly good pictures, provided we accept the limitations of the process and choose
suitable motifs, and perhaps copy only the middle tones. Fortunately, gum printing is not,
for us, the only possible technique, and negatives in which we need a more perfect rendition
of halftones can be processed more simply for example, by pigment printing.

Oil printing

Based on the principle that a gelatine layer sensitised with dichromate hardens in the places
where it is affected by light, so that these parts do not swell during subsequent soaking.

After a contact print has been made, the picture is soaked, and the places unaffected by light
become swollen, while the exposed parts do not. Thus, during soaking, a relief is created, in
which the raised areas correspond to the highlights and the hollows to the shadows. When
thick, oily colour is applied to this moist, swollen gelatine relief, it is left adhering only to
the light-exposed parts (not swollen, and therefore forming hollows), and the more these
places were exposed to light (and therefore hardened), the greater the amount of adhering
colour. This produces a picture with all the halftones. A positive is produced from the
negative.

Colour is applied with special brushes, and more or less colour can be applied, more or less
thickly, in different places. The density and tonality of various parts of the picture can
therefore be influenced to a significant extent. This process differs from pigment and gum
printing in that these contain colour before the contract print is made, while in oil printing it
is applied afterwards, in a chosen quantity. The advantage is that coloured parts with which
we are not satisfied can be cleaned with petrol.

Bromoil prints

These differ from oil prints in that an ordinary photograph, i.e. a silver bromide positive, is
used for preparing a swollen-gelatine relief. The photographic paper we use should not have
an excessively hardened gelatine layer, because this would not swell much in water. Many
types of paper on a resin coated (RC) base, and some traditional baryta papers provided
they are not intended for glazing, and therefore harder are suitable.

The photograph with well defined highlights and shadows is bleached in a solution of
copper sulphate and potassium dichromate. It is then washed, fixed, washed again, and
finally dried. The dried picture is soaked and left to swell, and is then coated with oil
pigments, as in the case of oil prints. Nowadays, instead of the traditional method of
dabbing the colour onto the picture with a fitch brush, the colour is sometimes applied with
a foam roller.

The coloured picture can be printed onto another piece of ordinary paper. The picture can
then be coloured again, and it is also possible to create a series of prints.

The end result is just as good, whether its a bromoil print or an oil print. But bromoil
printing has many advantages. In particular, the fact that it does not require a large negative,
because you work directly with an enlargement the same size as the final picture. There is
also no need to make contact prints in sunlight using a contact printing frame. This removes
the need for difficult decisions about the necessary exposure time. Another advantage is that
you can easily influence the degree of contrast in the final picture through the choice of the
grade of photographic paper used for preparing the initial positive. But it should be
emphasised that the relative ease of preparing the basic gelatine relief in no way relieves us
of the need to become thoroughly proficient in the next stage, the application of colour,
which requires a high degree of skill and plenty of experience. You cant expect successful
pictures at the first attempt.

Because of their advantages, bromoil prints were very popular with our photographers until
about the 1920s, and they are often seen in exhibitions.

Choosing the process

If you want to try a historical process yourself, its a good idea, initially, to choose one of
the simpler ones that doesnt require too much outlay. Fortunately, even with the simpler
and less expensive processes, you can obtain pictures which are just as good as with the
more demanding and costly ones. Every process has its own character and possibilities. Its
just a matter of knowing it well and choosing the motifs to which it is best suited.

Even with the cheapest process, e.g. cyanotype, we can create very impressive photographs.
But their intense blue colour is only suited to certain subjects snowy or misty landscapes,
for example. On the other hand, these subjects are not suited, for example, to the salt
process. This gives a brown tonality in which snow or mist appears unnaturally brown. On
the other hand, the salt process is suited to autumn pictures with fallen leaves.

So its best to choose processes which can be carried out with simple resources and minimal
experience, and to select the subject matter accordingly. Such processes are, for example,
cyanotype, the salt process and Van Dyke brownprint.

With these processes, you obtain a picture embedded directly in the fibres of the paper
without a binding agent. The fact that the picture is on paper without a layer of binding
agent, means that it has much in common with a lithographic print. Unlike ordinary
photographs, these pictures do not curl up in heat. If you choose suitable colours and
structures for preparing the paper, you can obtain really special, unreproducible originals.

Text and photografy Ing. MgA. Tom tanzel.Translated by Nicholas Miller PhotoArt.
The author works as a curator of the Department of the History of Photographic
and Film Technology at the National Technical Museum in Prague and in the scope of his
work
he is also involved in the program "Reconstruction of Historical Photograph Techniques".

Contact:
National Technical Museum
Kostelni 42
170 78 Prague 7
Czech Republic
tel.: +420 220 399 179
http://www.ntm.cz/projekty/fototechniky/en/