8/13/2014 Patent CN1847208A - Material gas stage associating process and apparatus for producing methanol ...

- Google Patents
http://www.google.com/patents/CN1847208A?cl=en 1/4
Patents
Publication number CN1847208 A
Publication type Application
Application number CN 200510056689
Publication date Oct 18, 2006
Filing date Apr 14, 2005
Priority date Apr 14, 2005
Also published as CN100596293C
Inventors ,
Applicant
Export Citation BiBTeX, EndNote, RefMan
Referenced by (2), Classifications (3), Legal Events (8)
External Links: SIPO, Espacenet
CLAIMS (5) translated from Chinese
A method of coal, oil, natural gas, coke oven gas and other raw materials of
methanol and ammonia synthesis classification method and apparatus,
characterized in that the system containing H2, CO, CO2, N2, CH4 purified to
remove other components of the raw methanol synthesis gas of harmful
substances, first by the consumption of methanol synthesis gas for methanol
production part of the raw materials, the production of methanol remaining after
the methanol synthesis purge gas compressed to a high pressure for methanol
synthesis, high-pressure purge gas through the methanation of methanol and
other methods removal of CO, CO2 and other harmful gases go after ammonia
synthesis ammonia synthesis.
(2) The classification according to claim 1 to produce methanol and
ammonia synthesis method characterized in that the low-pressure
methanol synthesis pressure of 4 ~ 9MPa.
3 Classification according to claim 1 to produce methanol and ammonia
synthesis method characterized in that the pressure of high-pressure
methanol synthesis 10 ~ 32MPa.
4 Classification according to claim 1, the production of methanol and
ammonia synthesis method characterized in that the methanol produced
by low-pressure methanol synthesis and methanol production pressure
ratio greater than 2.
5 classification according to claim 1 to produce methanol and ammonia
synthesis method characterized in that the raw material gas into the
methanol synthesis CO> 10%.
Material gas stage associating process and
apparatus for producing methanol and
ammonia
CN 1847208 A
ABSTRACT
The present invention is stepped process and apparatus of synthesizing methanol
and ammonia with coal, petroleum, natural gas, coke oven gas and other
material. Partial purified material gas is first low pressure synthesized to produce
methanol, the rest gas is compressed to high pressure for synthesizing methanol
further, and the high pressure methanol is pressure reduced, methanated to
eliminate CO, CO2 and other harmful gas and synthesized to produce ammonia.
The present invention has the advantages one less investment, low power
consumption, high yield, etc.
DESCRIPTION translated from Chinese
Grading raw gas of methanol and ammonia co-production method and apparatus
Technology
The invention belongs to chemical production plants and equipment, especially
the joint production of methanol and ammonia device, particularly suitable for
hydrogen, nitrogen, carbon monoxide, carbon dioxide, methanol and ammonia
synthesis feed gas occasions.
BACKGROUND
Prior to the making of the present invention, the hydrogen, nitrogen, carbon
monoxide, carbon dioxide feed gas joint production of methanol and ammonia unit
are the following: First, China began in 1967 to establish a joint methanol and
ammonia production unit (abbreviated Methanol plant , see Fengyuan Qi editor of
"linking alcohol production," Chemical Industry Press, 1989) from the five sections
of the feed gas compressor outlet (pressure 11MPa or so) the string into the
methanol synthesis unit, and then with liquid copper tower after the alcohol series
of trace gas carbon monoxide dioxide removal, and then washed gas into the
compressor sixth copper imports go through compressed to about 32MPa
ammonia synthesis unit, Methanol plant for this original transformation from
ammonia production unit, which is known as pressure-linked alcohol. Second,
Hunan Anchun company will subsequently linked alcohol after a copper wash
methanation method to replace the switch, namely pressure methanol
methanation, this method is mainly used for ammonia synthesis feed gas
purification. Third, from a floor equal to 1992 Sou Lam isobaric invention combined
type methanol and ammonia production unit (Chinese invention patent
ZL93105920.8) or called high-pressure methanol methanation, the invention has
been Jiangshan, Linyi, Shanxi Fengxi successful operation of such plants.
However, although the above-linked alcohol laws have their technical and
economic advantages, but they are mainly in the production of synthetic ammonia, methanol production as deputy, although
some methanol production plant close to the actual production of ammonia, methanol production is greater than in the case
of ammonia methanol synthesis is carried out under high pressure in the large investment and increases the compression of
electrical energy consumption.
The present invention is in the case of methanol production increased to provide a reasonable process, energy consumption,
Find prior art Discuss this application View PDF Download PDF

Grant Chinese Application English
Sign in
8/13/2014 Patent CN1847208A - Material gas stage associating process and apparatus for producing methanol ... - Google Patents
http://www.google.com/patents/CN1847208A?cl=en 2/4
low cost method of methanol and ammonia production and cogeneration facilities.
The present invention, the invention is a kind of coal, oil, natural gas, coke oven gas and other raw materials for synthesis of
methanol and ammonia classification method and apparatus are obtained mainly containing H2, CO, CO2, N2, CH4 and other
components by purification to remove harmful substances for methanol synthesis feed gas, first by methanol synthesis
consumes part of the feed gas to produce methanol, the methanol production remaining after the methanol synthesis purge
gas compressed to high pressure for methanol synthesis; pressure methanol purge gas is methane technology and other
methods to remove CO, CO2 and other harmful gases go after ammonia synthesis ammonia synthesis.
In the classification method for synthesis of methanol and ammonia, the low pressure methanol synthesis pressure of 4 ~
9MPa.
In the classification method for synthesis of methanol and ammonia, the pressure of high-pressure methanol synthesis 10 ~
32MPa.
In the classification method for synthesis of methanol and ammonia, the low pressure methanol synthesis of methanol
produced by the high-pressure methanol production ratio greater than 2.
In the classification method for synthesis of methanol and ammonia in methanol into the low pressure in the feed gas CO>
10%.
BRIEF DESCRIPTION
Further described below in conjunction with the accompanying drawings of the present invention. In the drawings: Figure 1 is
a coke oven gas or natural gas or oil as a raw material for synthesis of methanol and ammonia classification methods.
Figure 2 is graded coal as raw materials for synthesis of methanol and ammonia method.
Figure 3 is a gas coal as raw material often suppress small ammonia plant into a graded methanol and ammonia synthesis
methods.
Figure 1 is a preferred embodiment of the coke oven gas or natural gas or oil as the raw material flow diagram embodying the
present invention, coke oven gas contains about 28% of CH4 and CmHn, 4 ~ 8% of N2, the rest of H2, CO, CO2, etc., the
pressure is 4 ~ 9MPa, temperature about 900 , the reformer using steam, and oxygen or oxygen-enriched air or catalytic
conversion catalyst, the conversion of CH4 and other H2, CO gas and other raw materials. For the catalytic conversion of
coke oven gas, you must first desulfurization of non-catalytic conversion can be converted after the line in fine desulfurization
catalyst for methanol purification to remove harmful substances. Oil is used as raw material obtained in pure oxygen
gasification gas also needs fine desulfurization catalyst for methanol purification to remove harmful substances. Using natural
gas as raw material, after the first compressed natural gas desulfurization for steam reforming of natural gas can be converted
into a period of transformation and Sec stove or autothermal reforming, the available oxygen can also be enriched, and then
into the low pressure methanol synthesis loop consumption raw material gas for methanol synthesis section, and the
remaining methanol purge gas compressed to 10 ~ 32MPa, successively consumed by high pressure methanol synthesis
CO, CO2 and H2 to methanol, the CO + CO2 <0.6%, then the high pressure methanation obtain CO + CO2 < 20ppm feed
gas, when necessary, supplemented with pure nitrogen gas containing H2 and N2 in a ratio of about 3 to ammonia gas
refining. In this Act according to the needs of ammonia ratio alcohols into pure oxygen or oxygen-enriched transformed when
using oxygen is converted into nitrogen gas increases, for reducing alcohol ammonia ratio, increase ammonia production.
Figure 2 is used as the raw material coal flow diagram of the present invention, raw coal in a coal gasification furnace in the
first syngas, coal slurry gasification Texaco gasifier can be used, or a dry pulverized coal gasifier Shell gasification or
atmospheric fixed bed gasifier gasifier, gasification agent in addition to water vapor, but also according to different gasifier and
methanol and ammonia synthesis yield required oxygen or oxygen-enriched air or air brake gas, synthesis gas obtained
subject to purification, CO conversion and de CO2, fine desulfurization and other harmful substances removed for methanol
synthesis, the need for constant suppression of compressed air, and then by low-pressure methanol synthesis loop consume
some raw gas for methanol synthesis, The remaining methanol purge gas compressed to 10 ~ 32MPa, successively
consumed by high pressure methanol synthesis CO, CO2 and H2 to methanol, the CO + CO2 <0.6%, then the high pressure
methanation obtain CO + CO2 <20ppm H2 and N2 containing ratio of about 3 to ammonia gas refining. In this Act according
to the needs of ammonia ratio alcohols into pure oxygen or oxygen-enriched transformed when using oxygen is converted into
nitrogen and oxygen gas increases, for reducing alcohol ammonia ratio, increase ammonia production.
Figure 3 is a small to medium atmospheric fixed bed coal gasification plant using ammonia old classification of the invention
block synthesis of methanol and ammonia flow diagram. Old device uses steam, air pressure fixed bed gasification system in
crude gas, converted into law the introduction of new equipment for the pressure increasing means coal gasifier, crude gas
confluence with the old gas stove gas through crude gas desulphurization, and then sub- a portion of the gas from the old
multi-stage compressor compression (I), the other part by the new multi-stage low pressure compressor low pressure
cylinder compression (I) to 0.8MPa or so, after merging with the old compressor gas CO shift, off CO2, then separate part of
the gas is compressed by the new low-pressure compressor (II) to 5 ~ 6MPa, and then through the old compressor with
8/13/2014 Patent CN1847208A - Material gas stage associating process and apparatus for producing methanol ... - Google Patents
http://www.google.com/patents/CN1847208A?cl=en 3/4
compressed (II) to 5 ~ 6MPa gas after confluence, and then the methanol synthesis gas to methanol consumption of some
raw materials, and the remaining methanol purge gas is compressed (III) to 10 ~ 32MPa, successively consumed by high
pressure methanol synthesis CO, CO2 and H2 to methanol, the CO + CO2 <0.6%, then the high pressure methanation
obtain CO + CO2 <20ppm H2 containing and N2 ratio of about 3 to ammonia gas refining. In this Act according to the needs
of ammonia ratio alcohols into pure oxygen or oxygen-enriched transformed when using oxygen is converted into nitrogen and
oxygen gas increases, for reducing alcohol ammonia ratio, increase ammonia production.
Most of the present invention, the feed gas at low pressure methanol synthesis, significantly reduce compressed synthesis
gas and electricity consumption, a substantial increase in catalyst production strength, low-pressure methanol synthesis
equipment to reduce investment, high-pressure methanol synthesis produces only a small amount of methanol as co-
methanation for gas purification the methanol plant to produce the same yield investment than the existing medium voltage
methanol methanation save 1/3 much.
Examples of the original 30,000 tons of synthetic ammonia plant using small Figure 3 above process of the invention to
increase the gas stove and low-pressure compressor, the use of atmospheric water vapor in the air to give a crude gas Gas
(1), the crude gas purification, the crude desulfurization , respectively, by the new and old compressor compression (I) to
0.8MPa, after CO shift and CO2 removal was raw gas (2) compressed (II) to 5.5MPa to methanol synthesis, using JW low
temperature type methanol synthesis reactor, Synthetic Tower 2 meters in diameter low-pressure methanol catalyst loading
25m3NC307 methanol synthesis was 90,000 tons / year, low methanol purge gas (3) recompression (III) go to 30MPa high-
pressure methanol synthesis was 10,000 tons / year of methanol, and then by methanation was refined gas (4) to ammonia
synthesis was 30,000 tons / year of ammonia. Calculated data, see Schedule:
Image not available. View PDF
Reading the following detailed description of the invention, and without departing from the spirit and scope of the invention in
the case of ordinary skill in the art can easily carry out the present invention, various changes and modifications. The present
invention includes within the scope of the appended claims various changes and modifications, in addition to the above may
also be after methanol synthesis purge gas using CO methanation decarburization low to achieve CO + CO2 <20ppm after
the ammonia synthesis method .
REFERENCED BY
Citing Patent Filing date Publication date Applicant Title
CN100551888C Jun 6, 2008 Oct 21, 2009

Process for combined production for methanol, natural gas for automobile and
synthetic ammonia form industrial end gas rich in carbon and hydrogen
CN101214922B Dec 26, 2007 Jun 2, 2010
Combined purifying technique for ammonia preparation from natural gas, ammonia
preparation from coal and methanol preparation from coal
CLASSIFICATIONS
International Classification C01C1/04, C07C29/151, C07C31/04
LEGAL EVENTS
Date Code Event Description
Jul 14, 2010 C41
Transfer of the
right of patent
application or
the patent
right
Jul 14, 2010 COR
Bibliographic
change or
correction in
the description
Free format text: CORRECT: ADDRESS; FROM: 310030 NO.212, ZHENHUA ROAD, SANDUN TOWN
SCIENCE ECONOMY PARK, XIHU DISTRICT, HANGZHOU CITY, ZHEJIANG PROVINCE TO: 310012 (HIGH-
TECH ZONE), ROOM 2008, TOWER A, XIHU INTERNATIONAL TECHNOLOGY BUILDING, NO.391, WENER
ROAD, HANGZHOU CITY, ZHEJIANG PROVINCE
Jul 14, 2010 ASS
Succession or
assignment of
patent right
Effective date: 20100608
Free format text: FORMER OWNER: HANGZHOU LINDA INDUSTRY TECHNOLOGY DESIGN INSTITUTE
Owner name: HANGZHOU LINDA CHEMICAL INDUSTRY TECHNOLOGY ENGINE
Mar 31, 2010 C14 Granted
Mar 31, 2009 ASS
Succession or
assignment of
patent right
Owner name: HANGZHOU LINDA INSTITUTE OF INDUSTRIAL TECHNOLOGY
Free format text: FORMER OWNER: HANGZHOU LINDA CHEMICAL TECHNOLOGY AND ENGINEERING
CO., LTD.
Effective date: 20090206
Transfer of the
8/13/2014 Patent CN1847208A - Material gas stage associating process and apparatus for producing methanol ... - Google Patents
http://www.google.com/patents/CN1847208A?cl=en 4/4
Mar 4, 2009 C41
right of patent
application or
the patent
right
Apr 2, 2008 C10
Request of
examination
as to
substance
Oct 18, 2006 C06 Publication
Google Home - Sitemap - USPTO Bulk Downloads - Privacy Policy - Terms of Service - About Google Patents - Send Feedback
2012 Google