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----> H:
: H
H
NH
3
= N (5 dots) + H. + H. + H. ----> H:
H
CCl
4
= C (4 dots) + 4 Cl (7 dots) ---->??
In order to do harder examples you must know certain simple mathematics, there are 4 Chlorines and one
Carbon, the Carbon has 4 dots, and each chlorine has 1 dot, hence you must think how can carbon bond 4?
It gets surrounded by 4 chlorines and hence CCl
4
is created.
Molecules with multiple covalent bonds:
O
2
= O (6 dots) + O (6 dots) ----> in this case a double bond has to be incorporated because just sharing one
electron wont achieve the noble gas configuration. However when they share 2 each, they both are
allowed to have their shared electrons for themselves, thus each oxygen atom has 8 electrons
N
2
= N( 5 dots) + N (5 dots) ---> even after a double bond, sometimes triple bonds may occur, this is when a
double bond just doesnt work. When nitrogen atoms share electrons they must reach the electronic
configuration of 8, they each have 5 so mathematically they must already share 1 because each atom must
contribute at least 1 into the bond. In this manner, Nitrogen has to share 3 electrons with each other
combining to make 5 + 3 = 8. Bingo
The rest are basic mathematical knowledge!
Describe Molecules as particles which can move independently of each other.
A molecule is a group of two or more atoms held together by chemical bonds, these are covalent bonds
where each atom involved in the bond contributes an electron to the shared pair. When bonded the shared
pair of electrons occupy a volume of space that surrounds both the nuclei, and even though the strong
covalent bonds bind the atoms together within each molecule, their discrete energy levels allow them to
move about independently in their volume of shared electrons.
Distinguish between molecules containing one atom (the noble gases) and molecules with more than one
atom.
Elements can be diatomic (I
2
, Br
2
, Cl
2
) or polyatomic (P
4
, S
8
); the noble gases are all monatomic gases,
meaning their molecules exist as single atoms. You must know the strict definition of a molecule:
A molecule is the smallest particle of a substance that can have a separate existence, and can move around
independently of other particles. That is, inert gases have molecules of just one atom. Hydrogen has
diatomic molecules and Lattice structures (ionic or covalent network) are not molecules.
Describe the formation of covalent molecules in terms of sharing of electrons.
All covalent substances are held together by covalent bonds that is, atoms sharing pairs of electrons. In a
covalent bond, both atoms contribute one electron to the shared pair. In dative or co-coordinative covalent
bonds both the electrons in the shared pair is supplied by the one atom. E.g. CO, NH
4
.
In molecular covalent, the intramolecular bonding is covalent, but the intermolecular bondings are weak
intermolecular forces. When a molecular substance is melted, the intermolecular forces are broken only.
Since these forces are weak, the energy required to break them is not great, so the melting and boiling
points are relatively low. The molecules do not have an overall charge.
In network covalent substances such as silicon carbide (SiC), silicon dioxide (SiO
2
), diamond (C) and silicon
(Si) strong covalent bonds extend throughout the 3 dimensional lattice. Much energy is needed to break
these bonds, so their melting points and boiling points are very high. The lattice is made of atoms.
Construct formulae for compounds formed from:
- Ions
- Atoms sharing electrons
Ionisation:
H
2
SO
4
+ 2H
2
O -----> 2h
3
O
+
+ SO
4
2-
(lots of ions form, this means this is a conductor and is a strong electrolyte)
HCl + H
2
O -- H
3
O
+
+ Cl
-
(another example)
Metals:
Na
(s)
------> Na
+
(aq) or (s)
+
(showing the ionization of sodium)
Mg
(s)
------> Mg
2+
(s)
+ 2
Al
(s)
--------> Al
3+
(s)
+ 3 the compound overall is neutral
Non-Metals: Shows the ratio of binding
S
(s)
+ 2 -------> S
2-
(s)
ions in the crystal lattice
Cl
2 (g)
+ 2 ------> 2Cl
-
(g)
Reaction forming Ionic Substance:
Mg
(S)
+ S
(S)
--------> MgS
(S)
Mg
(S)
+ Cl
2 (g)
--------> MgCl
2 (S)
PART 4.
Identify the differences between physical and chemical change in forms of rearrangement of particles.
Physical changes are changes in physical properties. Physical properties include odour, colour, taste,
hardness, density, malleability, electrical conductivity, thermal conductivity, melting point, boiling point
and solubility. The physical changes are usually very easy to reverse, such as melting ice and re-freezing it.
There is no change in the composition of a substance. Generally relatively small amounts of energy are
absorbed or released.
E.g. Iron is a grey solid, with metallic lustre, fairly soft when pure, malleable, ductile, good electrical and
thermal conductor and has high melting point all of these are physical properties.
Chemical change occurs when new substances with new compositions formed. This involves large
quantities of energy being absorbed or released, generally in the form of heat, light or electricity. These
changes are quite hard to reverse, such as re combining H
2
and O
2
with a high temperature spark.
E.g. Combustion of fuels or decomposition
NaOH
(S)
-----> Na
(S)
+ O
2(g)
+ H
2(g)
Chemical properties are those that related to the ability of a substance to form a new substance. That is
reactions with oxygen, water, acids and bases or specific reactions with other substances.
Irons chemical properties include:
Reacts slowly with moist air to form rust
If finely divided will burn in oxygen when heated
Reacts with steam and dilute acids to form hydrogen
Summarise the differences between the boiling and electrolysis of water as an example of the difference
between physical and chemical change.
When we boil water, the H
2
O liquid becomes H
2
O gas, and it is still in its elemental form, only there is a
change of state. Thus the intermolecular forces here are broken and this requires less energy than to break
the intramolecular bonds. requires energy input (heat)
When we put water through electrolysis, it decomposes into its constituent elements, the strong covalent
bonds within the molecule must be overcome thus the intramolecular forces are broken; and new covalent
bonds between H and O must be formed. This requires more energy than boiling supplied by electrolysis.
Boiling water does not alter the actual particles (molecules): it just separates them from one another: the
water vapour contains the same water molecules as the liquid did. Electrolysis actually breaks the particles
up (water molecules broken up and hydrogen and oxygen (H
2
and O
2
) molecules formed)
Identify light, heat and electricity as the common forms of energy that may be released or absorbed
during the decomposition or synthesis of substances and identify examples of these changes occurring in
everyday life.
Light:
Causes decomposition of some silver salts the light energy is absorbed and decomposes the salts. Also,
light energy can be absorbed in photosynthesis to produce glucose:
6Co
2
+ 6H
2
O ----light chlorophyll--> C
6
H
12
O
6
+ 6O
2
Light energy can also cause the decomposition of some compounds for example silver salts such as silver
chloride decompose when exposed to light to produce silver metal. The use of silver bromide in black and
white photographic film is dependent upon this decomposition reaction.
Heat:
Thermal heat can decompose many compounds - this is a chemical change.
CuCO
3
-----> CuO + CO
2
CaCO
3
-----> CaO + CO
2
(limestone turned into lime and carbon dioxide.)
Electrolysis:
The process of electrolysis greatly increased our ability to extract metals from their ores. Metals such as
aluminium and sodium can only be extracted from their ores in this way. For example water can be
decomposed into the elements of hydrogen and oxygen if an electric current is passed through it.
Common everyday uses:
Decomposition reactions, such as air bags in motor cars, sodium azide are decomposed to sodium and
nitrogen gas (by igniting it with a detonating cap)
Calcium carbonate is decomposed by heating it to make lime, cements and glass.
Direct combination reactions are also common, when the rusting of iron and steel (to form iron (III) oxide
from the direct combination of iron with oxygen.)
The burning of coke (carbon) releases much heat energy that we utilize in many different ways.
Lightning which creates such a localised high temperature that nitrogen the oxygen gases combine to form
gaseous nitric oxide, NO. This same combination reaction also occurs in the combustion chamber of cars
and this nitric oxide along with nitrogen dioxide. NO
2
, to which it is partly converted, is one of the major
pollutants produced by cars.
Explain that the amount of energy needed to separate atoms in a compound is an indication of the
strength of the attraction, or bond, between them.
In covalent bonds the shared bonding electrons are simultaneously attracted to the nuclei of both bonded
atoms. It is this simultaneous electrostatic attraction of both nuclei for the shared electrons that
constitutes the covalent bond. To separate atoms joined by a covalent bond requires considerable
quantities of energy. This is sometimes referred to as the bond energy.
When compounds are decomposed into their constituent elements, large quantities of energy are usually
required. This is because the decomposition reaction involved breaking strong covalent or ionic bonds
within these substances. On the other hand, changes or state such as liquid water to steam require much
smaller quantities of energy. This process only involves breaking weak intermolecular forces between
molecules.
The stronger the chemical bonding in compound results in more energy required to break the compound
into its elements. Alternatively, the stronger the chemical bonding in a compound more energy is released
when the compound is formed from its elements.
Identify differences between physical and chemical properties of elements, compounds and mixtures.
Physical properties are those that can be determined without changing the chemical composition of the
substance. Chemical properties are those that relate to the ability of a substance to form new substances.
Elements and compounds are all pure substances. Each element and each compound has its own unique
properties which are characteristic and do NOT vary. For example, pure water has a fixed melting point,
boiling point, density, acidity, conductivity, etc. It is these unique properties which allow us to recognise
and identify water, and every other substance.
Minerals are not pure/ the properties of mixtures are usually a blend of the properties of its parts, and
vary according to its exact composition. For example salt water, has properties of both salt and water and
its density, boiling point and taste vary according to the proportions of each mixture
Substance: Chemical Properties: Physical Properties:
Paper:
(mixture)
*Burns in oxygen to produce soot. *Variable Colour
*Odourless
Petrol:
(mixture)
*Burns in oxygen to produce CH
2
and H
2
O.
*Less dense in water
*Volatile vapours easily
Water:
(compound)
*Decomposable into H
2
+ O
2
*Liquid at room temperature
*Non-Conductor
Natural gas:
(compound)
*Reacts with oxygen to produce
CO
2
+ H
2
O.
*Gas at room temperature and
pressure.
PART 5.
Six bottles contain sodium chloride, oxygen, copper (II) sulphate, water, iron and sulphur. What physical
properties would be used to identify each one?
Sodium Chloride generally known as salt, see by salty taste and white colour.
Oxygen is a gas at room temperature -
Copper (II) Sulphate is a blue solution in room temperature colour
Water generally no taste and obviously recognisable
Iron is a metal, lustrous shiny and has electrical conductivity
Sulphur is a grainy yellow texture, very fine power. Colour, texture, density.
Describe the physical properties used to classify compounds as ionic or covalent molecular or covalent
network.
All substances are made of atoms, ions or molecules. The way these particles are arranged in the substance
is the structure. This depends on:
The nature of the particles.
The forces holding the particles together.
The substance is a solid:
Melting Point-
Low:
The substance is covalent molecular substance. The conductivity of solid and molten state is non-
conducting.
High:
Not a covalent molecular substance-
Conductivity of the High melting point substance
Conducting substance with high melting point:
The substance is metallic, with high melting point and conducts electricity in the solid state.
Non-conducting with high melting point:
The substance is not covalent molecular or metallic.
Conductivity of molten state-
Conducting in the molten state, with high melting point and does not conduct in solid state:
This substance is Ionic
Non-conducting in the molten state, with high melting point that does not conduct in the solid state:
This substance is of covalent network or covalent lattice.
Distinguish between metallic, ionic and covalent bonds.
Metallic bonding is the bonding between metals, usually a lot of positive metal ions surrounding by a sea of
delocalised electrons.
Ionic bonding is the taking and giving of electrons between a non-metal and metal in order to achieve the
noble gas electronic configuration. This is gained through electrostatic attraction of positive and negative.
Covalent bonding is the sharing of electrons from two non-metals which simultaneously gives both
substances a noble gas configuration. This is gained through electron attraction to opposite substances
nuclei.
Describe metals as three-dimensional lattices of ions in a sea of electrons.
Covalent lattice solids or more simple covalent lattices are solids in which the covalent bonding extends
indefinitely throughout the whole crystals. This is also generally known as covalent network Metals
consist of an orderly three-dimensional array of positive ions held together by a mobile sea of delocalised
electrons. The valence electrons break away from their atoms, leaving behind positive ions. These free
electrons, called delocalised because they no longer belong to particular atoms, move randomly through
the lattice and, by being shared by numerous positive ions, provide the chemical bonding which holds the
crystal together.
Metals can be bent, rolled into sheets and drawn into rods and wires. These processes are possible because
when the orderly array of positive ions is sheared, the mobile electrons are able to adjust to the new
arrangement of positive ions and again stabilise the whole assembly of positive ions.
Describe ionic compounds in terms of repeating three-dimensional lattices of ions.
With ionic compounds, you dont just get one atom reacting with another. In real situations there are
billions of atoms. After all the ions have formed, each positive ion is attracted to every nearby negative one
and vice versa. The result is that you dont just get pairs of opposite ions, but huge repeating, 3 dimensional
lattices of positive and negative ions all electro-statically attracted to one another. In the solid state an
ionic compound forms a crystal, which is a huge array of billions of ions in a lattice.
Explain why the formula for an ionic compound is an empirical formula.
The chemical formula for an ionic compound is always in the empirical form because for any ionic
compound formula, it only shows the ratio in which the ions are a part of, not the actual numbers that are
present. Such formulae that give ratio by atoms of elements in a compound rather than the actual numbers
of atoms in a molecule are called empirical formula. Formulae for ionic compounds are therefore always
empirical because there are no molecules.
Identify common elements that exist as molecules or as covalent lattices.
Covalent Molecules:
H
2
O Water H
2,
F
2
, Cl
2
, O
2
and N
2
are diatomic gases.
NH
3
Ammonia Br
2
is a diatomic liquid.
HCl
Hydrogen Chloride I
2
is a diatomic solid.
Phosphorus and Sulphur exist as covalent P
4
and S
8
covalent molecules respectively.
Covalent Lattices:
Carbon exists as diamond which is a three-dimensional lattice and as graphite which is a two dimensional
lattice. The semi-metals B, Si, Ge, As, Sb and Te closely approximate covalent lattice though their bonding
electrons are not as firmly localised as in diamond.
Many substances in the lithosphere are covalent lattices:
Sand and quartz as silicon dioxide
Some gemstones are silicon dioxide with traces of impurities which provide the colour, while others
are silicates which are covalent lattices with some ionic bits incorporated. (Emerald, aquamarine,
topaz and garnet.)
Mica, talc and asbestos are also silicate lattices
Clays and zeolites are alumina-silicate lattices, again with some ionic portions.
Explain the relationship between the properties of conductivity and hardness and the structure of ionic,
covalent molecular and covalent network substances.
Types of solids and
their properties:
Molecular Solids: Metallic: Ionic: Covalent Network:
Melting and
Boiling points:
Low Variable High High
Conducts
electricity?
No Yes
As solid: NO
As liquid/molten:
YES
No
Hardness and/or
workability?
Soft
Variable hardness;
malleable and
ductile
Hard and Brittle Hard and Brittle
Forces holding
particles in the
solid
Intermolecular
Delocalised sea of
electrons
(metallic bonding)
Electrostatic
attraction
Covalent bonding
throughout the
crystal
Network Covalent:
Property: Reason:
Non-Conductors when solid or molten
Electrons bonded (Graphite is an exception to this
rule)
Very high melting and boiling points
Strong covalent bonding throughout the lattice
Hard
Strong covalent bonding extending in three
dimensions throughout the lattice giving a rigid
structure.
Brittle Distortion breaks covalent bonds
Chemically inert Stable Structure
Insoluble in water and most other solvents
Bonding is very strong
Covalent Molecular:
Property: Reason:
Low melting and boiling points
Weak intermolecular bonding
Non-conductors of electricity in solid or molten
state
Few react with solvent that they dissolve in to form
solutions that are electrolytes.
E.g. HCl, H
2
SO
4
Most dissolve in water to remain as neutral
molecules.
They form solids that are quite soft and have a waxy
appearance.
Weak intermolecular forces.