Authors: Mojtaba Kalhor Mohammadi, Curtin University of Technology, Western Australia
Co-authors: A. Professor J orge Sampaio, Curtin University of Technology, Western Australia Dr. Koorosh Tahmasbi, Petroleum University of Technology, Iran Dr. Frank Almassi, Baker Hughes Drilling Fluids, Perth, Australia
Abstracts Drilling operations have always been considered by environmental agencies because of generating large volumes of wastes during operation include drilling fluid, cuttings, rig wash water, etc. Discharge of these wastes in the environment is the main concern and requires waste management plan before starting the project in the drilling site. Many practices and treatment have been introduced in the drilling site to treat and manage of the drilling waste but there are still some issues about environmental friendly, operational and cost effective practices in drilling operation. This paper describes the dewatering process as a drilling waste management practices in a drilling project in Western Australia. The main significant objective of this project is to remain the operator in compliance with current regulations and the cost of waste management practice. Also preplanning laboratory test has optimized chemical consumption and helped to find out the dewatering efficiency in waste treatment. 1 Introduction Environmental legislation in the exploration and production of oil and gas requires plans for managing of wastes during operations by operators, service companies and contractors. As the view of the waste generation, environmental agencies consider the drilling as one of the important operation in exploration and production. During the Drilling Waste Management in Onshore Environmental Sensitive Areas First Iranian Petroleum Engineering Congress
2 drilling operations large volumes of wastes is generated including drilling fluid, cuttings, rig wash water, etc. Discharge of these wastes in environment is the main concern because of their effects on the environment and there are some policies and regulations on discharge of wastes by the environmental organizations and governments. Environmental sensitive areas including islands, lakes, all areas surrounding the river and life of animals and vegetations are considered by the environmental agencies. Traditionally, drilling wastes were discharged in ocean or onsite location without any concern about future environment problems. Nowadays, preserving these environmental area considered as the global awareness has been started from 1990s and the liability of the future environmental problem will be remained by the initial waste producer in the site. There were two significant aspects in managing of the drilling waste in onshore environmental sensitive areas; the first one is to recognize harmful wastes, volume of wastes and limitation of the discharge. The second one is to select an efficient, operational and economical option for waste management. 2 Drilling Waste Management As a definition, Drilling Waste Management is a management system for selecting optimal strategies, determining successful practices and technologies for treating the drilling waste in a given geographical or environmental setting. Geographical locations and environmental requirements play an important role to find proper management systems in drilling sites. Most of operators plan treatments and practices for waste management according to drilling locations and limitations. Usually, limitations dictate by the environmental organizations and governments. But an efficient drilling waste management system follows goals including minimization of the drilling waste, reusing/recycling and efficient disposal plan. To approach these goals, many practices introduce to drilling industry. Traditionally, most of them were increased the well cost but during the last 10 years, many cost effective options have been introduced to onshore and offshore drilling industries.
Drilling Waste Management in Onshore Environmental Sensitive Areas First Iranian Petroleum Engineering Congress
3 3 Case Study The case study herein shows the drilling waste management practices in an onshore environmental sensitive in Western Australia. Zero discharge practice in drilling operation is one of the environmental requirements in WA. All operators must use waste management plan during the drilling operation to manage drilling wastes including; drill cutting, drilling fluids and waste water. As the initial waste management plan, the drilling fluid was designed as water based mud to reduce the environmental impact by providing technical requirements during drilling operation. Collection and treatment of the generated waste water from tanks washing and rig washing are the other waste management plan before final discharge in this project. The main issue in this project was the liquid waste including remained drilling fluids after operation for each section of the drilling. Collection of these wastes in reserve tanks and hauling of them to shore was not the acceptable solution as there is still some issue about spillage or leakage during hauling and shipping. On the other hand, volume of the liquid waste, distance from disposal facility and cost of the shipping associated with environmental concern. All of these reasons caused to plan onsite treatment on the drilling waste before final discharge of wastes. 4 Theory Theory of the dewatering process is based on pH controlling of the drilling fluid wastes and surface charge of fines and ultra fines. In the pH range of the drilling fluids that is typically being between 7 to 11, ultra fine particles in the drilling fluids tend to be charged negatively. These negative charges repel the particles and prevent from clumping of the particles. This causes difficulty in removing the ultra fine particles even with a high-speed centrifuge with 2000 g force. To solve this problem, it is necessary to treat the drilling fluids or waste fluids chemically to agglomerate the solids to make them large enough to be removed by a high-speed centrifuge. The process of agglomeration to create large, dense clusters requires two steps: 1. Destabilize the submicron particles so they no longer repel each other. This is easily achieved by lowering the pH from its original pH to approximately 5.5. Drilling Waste Management in Onshore Environmental Sensitive Areas First Iranian Petroleum Engineering Congress
4 2. Flocculate, bundle, or wrap together to create large dense clusters. These two steps can be accomplished by sequentially adding three chemicals; or sometimes only one or two chemical additives can accomplish all three steps. Today, ranges of polymers produce by companies with different molecular weight of cationic coagulants, non-ionic, anionic and cationic flocculants.
Figure 1- Schematic procedure of dewatering
4.1 Technical Consideration As the technical consideration, dewatering process requires laboratory procedures such as jar test to select the proper coagulants and flocculants. But there is a problem in finding the optimum dosage/concentration of chemicals in jar test. Optimization of chemical concentration is necessary in the dewatering process. Otherwise, it increases the cost of chemical consumption in the field. To approaching this goal, series of the laboratory tests have been done to select the proper chemicals and the proper dosages of them by centrifuge simulation as the additional procedure to common jar test. This has helped to simulate the separation process as the field condition to obtain the optimum chemical dosage in the dewatering process and also find out the dewatering efficiency in reducing the waste volume and monitoring the quality of the produced water in the dewatering process. Bridging Flocculation Polymer chains can "bridge" particles to create larger masses that settle out Charge Neutralization Like charged particles repel removal of charge can enable particles to approach close enough to coagulate Drilling Waste Management in Onshore Environmental Sensitive Areas First Iranian Petroleum Engineering Congress
5 5 Results Initially, pH of the drilling fluid waste reduced to neutralized point with different percentage of wastes with water. Monitoring of pH has shown that 50% dilution of the waste with water has reduced the concentration of acid to 50% in comparison with the 25% water dilution (Figure 2). Mixing the waste with water helps to destroy the balance of the chemicals in the drilling fluids especially the portion of the polymers in it. Also, it is cost effective to reduce the consumed volume of the acid by adding water. In the next step, different volumes of the flocculants have been added to compare the settlement of the solids during the time. This has helped to find the proper flocculants for dewatering. (Figure3). The initial concentration of the flocculant obtains by comparing the solid settlements within the first minutes after adding the flocculant in figure 3. As figure 3 has showed after a certain concentration, solids precipitation has remained constant as concentration graphs overlap on each other but this is not the optimum concentration. Until this step it is possible to introduce the proper flocculant with the initial concentration. 5 5.5 6 6.5 7 7.5 8 8.5 9 9.5 10 10.5 11 11.5 12 0 5000 10000 15000 20000 25000 30000 35000 Concent r at ion of Acid (ppm)
p H
No Dilution, Real Waste 25% Dilution of water 50% Dilution of water
Figure 2-pH control of the drilling fluids waste Dilution of the waste with water is effective on reducing the concentration of pH control chemicals and helps to better mixing of the acid with waste in a lower time as desired in the dewatering process. 50% dilution of water reduces the required acid to 14000 ppm from the initial value (29000 ppm) at the neutralized point. Drilling Waste Management in Onshore Environmental Sensitive Areas First Iranian Petroleum Engineering Congress
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0 2 4 6 8 10 12 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 30 32 Time,Min S o l i d s
P r e c i p i t a t i o n
( % ) 40ppm 80ppm 120ppm 160ppm 200ppm
Figure 3-Solid precipitation with different concentration of the flocculant In the dewatering process, flocculation must be considered within the first minutes after adding flocculant. As the figure shows, solids precipitation increases as the concentration of the polymer increases until 160 ppm. More than 160 ppm overdosing occurs as there is no increase in the solid precipitation in the first minutes. To find the optimum concentration of the acid to reduce pH, solid separation versus different concentration of the acid has been compared. According to the figure 4, after a certain concentration, the solid separation has remained constant as there is not much increase in the solid percentage. This concentration is the optimum value for the pH reduction. To find the optimum concentration of flocculants, the same procedure has been done with adding different concentration of the flocculant and centrifuging for one minute. Comparing results in figure 5 shows that by increasing the concentration of the flocculant the solid precipitation increases but the difference is eligible for the last two samples in each experiment, and it can be understand more concentration of the flocculant cause overdosing. Also, feeling the produced water after centrifuging has showed the amount of polymeric flocculant in the water. Figure 6 shows the complete dewatering process after centrifuging.
Drilling Waste Management in Onshore Environmental Sensitive Areas First Iranian Petroleum Engineering Congress
Figure 4-Solid precipitation versus concentration of the acid Centrifuging of the sample after adding acid has shown that there is not more affect on the solid separation after 17000 ppm. This concentration of acid can be the optimum value in the lab scale
0 5 10 15 20 25 30 35 40 45 0 40 80 120 160 Concent r at ion (ppm) S o l i d s
S e p a r a t i o n ( % ) Only Polymer (wit hout Acid) Acid = 5700 ppm Acid = 11500 ppm Acid = 17200 ppm Acid = 23000 ppm
Figure 5-Solid precipitation with different concentration of the acid and flocculants after centrifuge This graph has provided the solid separation with different concentration of acid and polymer. There is over dosing on the last two column of the graph as there is not much difference on solid precipitation for 160 ppm of polymer.
Drilling Waste Management in Onshore Environmental Sensitive Areas First Iranian Petroleum Engineering Congress
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Figure 6- Dewatering simulation of the drilling fluids waste by the laboratory centrifuge scale
5.1 Economical Consideration Dewatering has become common in many instances, especially as technology has advanced and the units have become less expensive. Using cost effective practices such as dewatering process to get the clear water from drilling wastes reduce operating costs and also reduce the concern about the environment for exploration and production companies. The main benefit of the dewatering process is providing the acceptable format of the waste discharging. As the economical consideration, the cost of hauling of the waste to disposal facilities has reduced significantly. In addition the produced water was used as the recycle water in the system. So the cost of used water in the circulation system is reduced. The only concern about this process is the quality of the produced water that must be considered by controlling the pH and other extra ions in the produced water that must be control in the field.
6 Conclusion In conclusion, drilling waste management is the decision of using proper technologies and practices according to environmental requirements to reduce the environmental Drilling Waste Management in Onshore Environmental Sensitive Areas First Iranian Petroleum Engineering Congress
9 impacts and cost of the waste management plan. The dewatering process describe herein is one of the efficient treatments to treat the waste before discharging that has been an expensive technology for many years. But it has been changed to a cost effective option in drilling site with more flexibility. Finally, optimization of the chemical consumption in the waste treatment is the hidden part in the waste management practices that can change expensive practices to the cost effective solutions. The volume of the drilling fluid waste reduces to at least 50% of the initial volume after dewatering process with production of the water that can be released or reused in the drilling system as required. Acknowledgment The authors wish to acknowledge the support and assistance provided by Baker Hughes Drilling Fluids Company in Perth, especially Marc Quesnel; Distric Manager- Drilling Fluids and Chris Hargreaves; Senior Co-Ordinator, Simon Geraghty; Project Management Consultant, Dusan Andovski; Fluids Laboratory Technician. Also special thanks to Dr. Emmazadeh; Petroleum University of Technology and also Professor R.T. Rajeswaran; Curtin University of Technology.
References [1] Veil, J .A, Drilling Waste Management: Past, Present, and Future, SPE Annual Technical Conference and Exhibition, 2002. [2] Muhammad Ali, Reinhard J . Oswald and Umar Iqbal, SPE Annual Technical Conference, OMV'S DRILLING WASTE MANAGEMENT A PROACTIVE APPROACH,2004 [3] Drilling Fluid Processing Handbook , Chapter 16 ,ASME Shale Shaker Committee, 2004 [4] Guide to Dewatering Drilling Fluids, Ciba Co. , 1999 [5] Dobias, B. ,Coagulation and Flocculation : Theory and application, 1993 [6] Briji M., Engineering Foundation Conference, Flocculation, Sedimentation and Consolidation, 1985