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Physical Properties
F2
Cl2
Br2
I2
Atomic radii
Ionic radii
Vdws
m.p & b.p
Electronegativity
I.E.
Electron affinity
Bond length
Bond strength
Bond enthalpies
Solubility
Reactivity
State (RTP)
Colour
Electronic configuration:
Displacement reactions
Cl :
Cl2 ( )
Br2 ( )
Br :
53
I :
I2 ( g )
I2 ( aq)
Definition
Electronegativity:...........................................................
......................................................................................
1stI.E:..............................................................................
.......................................................................................
1st Electron affinity:.......................................................
.......................................................................................
Bond enthalpy:.............................................................
.....................................................................................
* = Hydrogen bond
Cl2 + H2O
0
Cl2 + NaOH
0
Reactivity
Thermal
stability
Acidic
strength
FCl-
b.p.*
BrI-
Ppt
Formula
dil.
NH3(aq)
conc.
NH3(aq)
Cl
Br
12
Oxidising ability of
halogens
Explanation:
..............................................
..............................................
..............................................
..............................................
..............................................
..............................................
..............................................
..............................................
KI
Disproportionation reactions
KBr
Iodine
Halogen + Hydrogen
X2(g) + H2(g) 2HX(g)
Polar bonds
H F*
H
Cl
H
Br
H
I
I2
Chlorine
Bromine
KCl
Manufacture of Bromine
Uses of chlorine
Br2
Cl2
Redox
OIL:............................................
RIG:............................................
OXIDANT:...................................
REDUCTANT:................................
35
I2 ( s )
F2
Cl2(g) + KBr(aq)
17
F2 ( )
Chemical Properties
10
The order of use is indicated by the NUMBERED CIRCLES (make it easier for students to follow). This can be changed to suit your style of teaching.
Use arrows to indicate increase or decrease in trends (all trends are down the group as indicated by the huge black arrow next to the elements or ions).
e.g.
Atomic radius
Reactivity
Everything in RED relates to chemical properties.
Show the states and discuss the colours of chlorine, bromine and iodine.
Opportunity to discuss uses
Demonstrate sublimation and recrystallisation of iodine.
Demonstrate displacement reaction.
Demonstrate test for halide ions.
Discuss thermal stability of hydrogen halides using suitable data (the ones below might be useful).
BOILING POINT / C
100
H2O
The higher than expected boiling
points of NH3, H2O and HF are due to
intermolecular HYDROGEN BONDING
HF
0
50
100
140
Mr
NH3
GROUP IV
GROUP V
GROUP VI
GROUP VII
Source: www.Chemguide.co.uk
-160
Just an observation: Students appreciate Large A3 size coloured printout of this mind map!